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离子注入铜薄一的氧化行为 总被引:1,自引:0,他引:1
为克服铜易氧化造成薄膜电阻增加、机械性能下降的缺点,采用离子注入技术对铜薄膜表面进行改性研究。离子注入后进行了氧化试验,并结合X射线衍射和卢瑟福背散射进行了分析。结果表明,离子注入对原有薄膜的电阻影响是很小的;随注入剂量的增大,抗氧化能力提离;离子注入不但改善了铜薄膜的抗氧化能力,而且氧化行为及氧化层的结构也发生了变化,未经注入的铜薄膜形成的氧化铜以Cu2O为主,注入后氧化铜则为Cu2O和CuO复 相似文献
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溅射NiCrAlY涂层对Ti3Al金属间化合物氧化性能的影响 总被引:4,自引:0,他引:4
采用称重法研究了溅射NiCrAlY涂层对Ti_3Al金属间化合物在850~950℃空气中的氧化性能的影响。结果表明,Ti_3Al的抗氧化性能较差。氧化时,其表面不能形成单一的Al_2O_3保护膜,氧化膜易剥落;溅射NiCrAlY涂层能通过在涂层表面形成粘附性良好的富Al_2O_3氧化膜而显著改善Ti_3Al的抗氧化性能。但在950℃时有少量合金基体中的Ti扩散到涂层表面形成TiO_2。同时涂层中的Ni的强烈向内扩散及基体中的Ti强烈地向外扩散导致沿涂层与合金基体间形成扩散带。 相似文献
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对航空轴承用钢GCr15进行了硼离子、氮离子及其复合注入试验。利用扫描电镜和X射线衍射仪对注入层的组织结构进行了分析,并测试了注入层的硬度、耐磨性、耐蚀性。结果表明:GCr15离子注入层形成了多种弥散相和非晶相,表层的残余奥氏体含量也有所减少。表层的硬度、耐磨性以及耐蚀性经离子注入后明显增加。 相似文献
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C/C复合材料防氧化复合涂层的制备及其性能 总被引:13,自引:1,他引:12
提出并制备一种C/C复合材料防氧化复合涂层,其基本结构为TiC粘结层/SiC氧阻挡层/ZrO2-MoSi2外涂层,研究了其制备工艺、组织结构、对各单一涂层的防氧化作用及效果进行了分析,并对其抗氧化性能进行了测试。通过比较四种成分组成的抗氧化陶瓷外层的抗氧化性能,结果表明:随着外涂层中MoSi2含量的增多,复合涂层的抗氧化性能增强,其中带有TiC/SiC/MoSi2涂层的C/C复合材料试样在1300 相似文献
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内氧化制备A1_2O_3/Cu复合材料载流条件下表面磨损形貌和摩擦学性能研究(英文) 总被引:2,自引:0,他引:2
Liu Ruihua Song Kexing Jia Shuguo Xu Xiaofeng Gao Jianxin Guo Xiuhua 《中国航空学报》2008,21(3):281-288
Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and copper against brass are investigated and compared. The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope (SEM) and energy dispersive X-ray spectrum (EDS). The results show that the wear resistance of the Al2O3/Cu composites is superior to that of copper under the same conditions, Under a given electrical current, the wear rate of Al2O3/Cu composites decreases as the Al2O3-content increases, However, the wear rates of the Al2O3/Cu composites and copper increase as the sliding speed and pressure increase under dry sliding condition. The main wear mechanisms for Al2O3/Cu composites are of abrasion and adhesion; for copper, it is adhesion, although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise. 相似文献
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向远博%刁训刚%郝雷%顾宝霞 《宇航材料工艺》2008,38(5)
采用多弧离子镀制备了具有不同色彩的Cr/Cr2O3薄膜,利用紫外-可见光分光光度计研究了薄膜在可见和红外波段的光谱特性,利用SEM进行薄膜表面结构和形貌的分析,利用四探针测阻仪测试了样品的方块电阻,利用红外发射率测量仪测试了样品的红外发射率。结果表明:Cr/Cr2O3薄膜具有丰富的色彩,在可见光区有明显的反射峰,可见光区光谱特性主要受膜厚的影响,方块电阻随膜厚增加而有变大,样品的红外发射率主要取决于金属层,平均红外发射率最小降至0.371。 相似文献
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针对目前电沉积法制备的CuInS2(CIS)薄膜存在S元素含量不足以及微观形貌差的问题,通过在普通镀液中加入SiO2溶胶,采用一步电沉积技术在ITO导电玻璃上制备Cu In S预制薄膜,镀液的主要组成为金属盐、硫代硫酸钠和不同浓度SiO2溶胶。在空气气氛中对Cu In S预制薄膜进行退火处理以获得多晶的CIS薄膜,并通过X射线衍射(XRD)、扫描电镜(SEM)、能量色散谱仪(EDS)及开路电位对CIS薄膜的结构、形貌、成分组成及光响应性能进行研究。结果表明:SiO2溶胶浓度为4 mL/L时,得到的CIS薄膜的结晶度提高,同时,SiO2溶胶作用下得到的CIS薄膜的表面形貌、成分组成和光响应性能都得到改善。因此,镀液中加入SiO2溶胶有利于提高CIS薄膜的性能,尤其是浓度为4 mL/L时,性能提高得最为明显。 相似文献
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IBAD法沉积TiN薄膜的机械和耐腐性 总被引:4,自引:0,他引:4
用离子束辅助沉积(IBAD)方法在医用不锈钢317L基底上沉积TiN陶瓷薄膜。通过X射线衍射(XRD)和俄歇电子能谱(AES)分析研究了薄膜的微结构;测试了薄膜的耐磨性及薄膜与基底的附着力:运用电化学腐蚀的方法检测了薄膜在Hank’s模拟体液中的耐腐蚀性能。研究结果表明:用高、低能氮离子束兼用的IBAD方法沉积TiN多晶薄膜后,材料表面结构和性能发生明显改变。表面硬度和耐磨性有明显提高,在Hank’s模拟体液中显示出更强的抗腐蚀能力。 相似文献
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GAO Jian-xina XU Xiao-fenga SONG Ke-xinga * LI Pei-quanb GUO Xiu-huaa LIU Rui-huaa aSchool of Materials Science Engineering Henan University of Science Technology Luoyang China bJiang Yin Xing Cheng Special Steel Works CO. LTD Jiangyin China 《中国航空学报》2006,19(Z1)
Alumina dispersion strengthened copper composite (nano-Al2O3/Cu composite) was recently emerged as a kind of potentially vi-able and attractive engineering material for applications requiring high strength, high thermal and electrical conductivities and resistance to softening at elevated temperatures. The nano-Al2O3/Cu composite was produced by internal oxidation. The microstructures of the composite were analyzed by the TEM and its hot deformation behavior was investigated by means of continuous compression tests per-formed on a Gleeble 1500 thermo-simulator. Making use of the modified algorithm–Levenberg-Marquardt (L-M) algorithm BP neural network, a model for predicting the flow stresses during hot deformation was set up on the base of the experimental data. Results show that the microstructures of the composite are characterized by uniform distribution of nano-Al2O3 particles in Cu-matrix. The sliding of dislocations is the main deformation mechanism. The dynamic recovery is the main softening mode with the flow stress decreasing gen-tly from 500 ℃ to 850 ℃. The recrystallization of Cu-matrix can be retarded late into as high as 850 ℃, when it happens only partially. The well-trained BP neural network model can accurately describe the influence of the temperature, strain rate, and true strain on the flow stresses, therefore, it can precisely predict the flow stresses of the composite under given deforming conditions and provide a new way to optimize hot deforming process parameters. 相似文献
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Two AhO3/Cu composites containing 0.24 wt.% A1203 and 0.60 wt.% A1203 separately are prepared by internal oxidation.Effectsof sliding speed and pressure on the fi-ictional characteristics of the composites and copper against brass are investigated and compared.The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope (SEM) and energy dispersive X-ray spectrum (EDS).The results show that the wear resistance of the AI203/Cu composites is superior to that of copperunder the same conditions.Under a given electrical current,the wear rate of AI203/Cu composites decreases as the AleO3-content increases.However,the wear rates of the Al203/Cu composites and copper increase as the sliding speed and pressure increase under drysliding condition.The main wear mechanisms for AleO3/Cu composites are of abrasion and adhesion;for copper,it is adhesion,although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise. 相似文献
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在18%(质量分数,下同)H_2SO_4+5%C_2H_2O_4水溶液中,采用脉冲(PC)电流对2198和5A90两种铝锂合金进行阳极氧化处理。用扫描电子显微镜(SEM)观察铝锂合金阳极氧化膜表面和截面形貌;用能谱仪(EDS)对其成分进行面扫描和线扫描;用动电位极曲线检测氧化膜在3.5%NaCl水溶液中的耐蚀性。结果表明:2198和5A90铝锂合金阳极氧化膜主要由Al的氧化物组成;2198合金氧化膜表面存在细小颗粒,厚度约为150μm;5A90合金氧化膜表面存在微孔,为后续封孔处理提供结构条件,厚度约为180μm;用脉冲方法在两种铝锂合金表面生成的较厚阳极氧化膜具有较高的耐蚀性。 相似文献
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CHENG Xing-hua QIAO Liang BI Xiao-fang* School of Materials Science Engineering Beijing University of Aeronautics Astronautics Beijing China 《中国航空学报》2006,19(Z1)
In an attempt of being used as buffer layers and electrodes for the textured BaTiO3 (BTO) ferroelectric thin films, highly (100)-oriented LaNiO3 (LNO) thin films of different thicknesses were deposited directly on Si (100) substrate with radio-frequency (RF) magnetron sputtering method. It is observed that the substrate temperatures and the film thicknesses bring main influences on the micro-structures and orientation of the thin film. The effects of the thicknesses and substrate temperatures on the orientation of the films were studied on the LNO films of different thicknesses. The highly (100)-oriented LNO thin films were obtained at the substrate temperature of 600 ℃. The existence of epitaxially grown BTO films indicates that the oriented LNO thin films obtained in this work could be used as a buffer layer for epitaxial growth. 相似文献