Aerospace lithium solid polymer batteries

Lockheed Martin Missiles and Space and Ultralife Batteries, Inc. are developing batteries for spacecraft and launchers based on Li-ion solid-polymer-electrolyte cell technology. These cells utilize a carbon anode, a manganese dioxide cathode and a solid polymer electrolyte. Electrode and electrolyte layers are thin and flexible. The electrode assembly is easily fabricated into thin, flat prismatic shapes using ordinary lamination techniques and is hermetically sealed in thin foil packaging. Cells ranging in capacity from 4 Ah to 50 Ah have been designed and are in development testing. The packaged cells have specific energies in excess of 100 Wh/kg. Prototype 30 volt batteries have also been designed and are being assembled and tested along with the critical battery cell charge management controllers needed to recharge all cells to full capacity while preventing overvoltage damage. The major results of this development effort are reviewed and the key issues for advancing this technology to flight qualification demonstrations are discussed     

Prismatic lithium-ion batteries

Lithium-ion (Li-ion) batteries have demonstrated the ability to fulfill the energy storage needs of many new technologies. The most significant drawbacks of currently available technologies, such as LiCoO ₂ based Li-ion cells, is their high cost and significant environmental hazards. Li-ion cells which use a lithium manganese oxide (LiMn₂O₄) spinel based cathode material should be much less costly and safer than LiCoO₂ based cells. Performance data from prismatic design cells which use a LiMn₂O₄ based cathode material is presented and shown to meet many military performance criteria. The most significant drawback of this technology is the short cycle life     

Remaining useful life prediction of aircraft lithium-ion batteries based on F-distribution particle filter and kernel smoothing algorithm

As an emergency and auxiliary power source for aircraft, lithium (Li)-ion batteries are important components of aerospace power systems. The Remaining Useful Life (RUL) prediction of Li-ion batteries is a key technology to ensure the reliable operation of aviation power systems. Particle Filter (PF) is an effective method to predict the RUL of Li-ion batteries because of its uncertainty representation and management ability. However, there are problems that particle weights cannot be updated in the prediction stage and particles degradation. To settle these issues, an innovative technique of F-distribution PF and Kernel Smoothing (FPFKS) algorithm is proposed. In the prediction stage, the weights of the particles are dynamically updated by the F kernel instead of being fixed all the time. Meanwhile, a first-order independent Markov capacity degradation model is established. Moreover, the kernel smoothing algorithm is integrated into PF, so that the variance of the parameters of capacity degradation model keeps invariant. Experiments based on NASA battery data sets show that FPFKS can be excellently applied to RUL prediction of Li-ion batteries.     

富锂锰基正极材料研究进展

随着社会发展,电动汽车、消费类(3C)电子产品、储能装置等对锂离子电池的能量密度提出了更高要求。富锂锰基正极材料具有高比容量(≈250 mAh/g)、高工作电压(≈3.6 V)及低成本等优势,有望成为下一代商用高比能电池正极材料。首次库仑效率低、倍率性能差、电压/容量衰减快等问题限制了富锂锰基正极材料的工程化应用。本文综述了富锂锰基正极材料的最新研究进展,重点从材料结构、电化学反应机理、失效机制和改性方法等几方面进行了阐述。研究表明,采用离子掺杂、表面包覆、晶体结构调控等技术,可显著改善富锂锰基正极材料的电化学性能。最后,对富锂锰基正极材料的发展方向进行了展望。     

Advanced materials for next generation NiMH portable, HEV and EVbatteries

While Ovonic NiMH batteries are already in high volume commercial production for portable applications, advances in materials technology have enabled performance improvements in specific energy (100 Wh/kg), specific power (600-1000 W/kg), high temperature operation, charge retention, and voltage stability. Concurrent with technology advances, Ovonic NiMH batteries have established performance and commercial milestones in electric vehicles, hybrid electric vehicles, as well as scooter, motorcycle and bicycle applications. As important as these advances, significant manufacturing cost reductions have also occurred which allow continued growth of NiMH technology. In this paper, advances in performance, applications and cost reduction are discussed with particular emphasis on the improved proprietary metal hydride and nickel hydroxide materials that make such advances possible     

纤维金属层板的开发和应用现状

随着我国航空航天领域器械的飞速发展,对该领域中结构件所用材料的综合性能及轻量化提出了新的要求。在过去几十年里,大型客机的市场需求不断扩大,刺激了新型材料的兴起,使材料向着高性能,轻质量发展。纤维金属层板是由铝合金与纤维预浸料交替铺层固化而成的层间混杂复合材料。纤维金属层板结合了金属与复合材料的优良特性,具有密度小、损伤容限优良、抗冲击和疲劳性能,越来越受到航天航空和轨道交通领域的关注。目前用于商业生产的金属纤维层压板(FMLs)多以基于芳纶纤维(ARALL)与基于高强玻璃纤维(GLARE)的层板为主。概括了纤维金属层板的制备前表面处理工艺,对其弯曲测试、拉伸测试、冲击测试和疲劳测试等力学性能的测试方法进行综述,同时对未来新型纤维金属层板的开发进行探究,为纤维金属层板的开发提供参考信息。     

High reliability lithium rechargeable batteries for specialties

Since their development in the late 1980s, lithium rechargeable batteries have enjoyed rapid growth and wide use as a commodity battery known for its higher energy density storage and lightweight convenience. These same attributes are emerging as a strong platform in power source development for the medical and aerospace sectors with highly customized applications and narrowly defined criteria. Accordingly, this new generation of lithium rechargeables must be hermetically sealed, have long-term storage capability, and zero-fault tolerances for common causes of field failures such as electrolyte leakage or short circuits from mechanical deformation. Quallion has been developing and manufacturing highly reliable lithium rechargeable cells for medical, aerospace, and specialty applications. Summarized in this paper are some key technologies developed at Quallion for designing and manufacturing of this new class of lithium rechargeable batteries. They include: 1) leakage reliability; 2) self-extinguishing electrolyte system; 3) mechanical impact resistance; 4) deep discharge storage; and 5) high reliability manufacturing.     

Lithium-ion battery software safety protection

Production Li-ion batteries include hardware and software safety protection. The hardware protection includes PTC (positive temperature coefficient) thermistor switch, electrical circuit disconnect and rupture vent. The software protection involves a charging algorithm (charging to ultimate voltage), which is used with internal electrical circuitry (cell voltage control and equalization circuit). This paper discusses a specific charging algorithm and additional software protection features associated with hard, soft and chemical shunt recognition     

A new high rate lead acid battery

A new approach to the design of lead acid batteries has been developed based on the use of very thin lead foil current collectors. The basic cell construction and the performance characteristics for the new cell are described. Spiral wrap cells based on this electrode concept exhibit extremely high power output with excellent capacity maintenance. Additionally, these cells exhibit very flat voltage at all currents, and are capable of very rapid recharge. Applications for this high power technology cover a broad spectrum such as portable power tools, UPS systems, electrically heated catalytic converters, military pulse power applications and electric and hybrid vehicles     

Flywheel technology: past, present, and 21st century projections

This paper describes the present status of flywheel energy storage technology, or mechanical batteries, and discusses realistic future projections that are possible based on stronger composite materials and advancing technology. The origins and use of flywheel technology for mechanical energy storage began several hundred years ago and was developed throughout the Industrial Revolution. One of the first “modern” dissertations on the theoretical stress limitations of rotational disks (isotropic only) is the seminal work by A. Stodola whose first translation to English was made in 1917. The next big milestones were during the 1960s and 1970s when NASA sponsored programs proposed energy storage flywheels as possible primary sources for space missions. However, it was not until the 1980's when microelectronics, magnetic bearing systems and high power density motor-generators became enabling technologies. The next decade proved that a mechanical battery could surpass chemical batteries for many applications     

Performance characteristics of lithium-ion cells for NASA's Mars2001 Lander application

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to the attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including Mars rovers and landers. The Mars 2001 Lander (Mars Surveyor Program MSP 01) will be one of the first missions which will utilize lithium-ion technology. This application will require two lithium-ion batteries, each being 28 V (eight cells), 25 Ah and 8 kg. In addition to the requirement of being able to supply at least 200 cycles and 90 days of operation on the surface of Mars, the battery must be capable of operation (both charge and discharge) at temperatures as low as -20°C. To assess the viability of lithium-ion cells for these applications, a number of performance characterization tests have been performed, including: assessing the room temperature cycle life, low temperature cycle life (-20°C), rate capability as a function of temperature, pulse capability, self-discharge and storage characteristics, as well as mission profile capability. This paper describes the Mars 2001 Lander mission battery requirements and contains results of the cell testing conducted to-date in support of the mission,     

一代材料技术，一代大型飞机

 介绍了用于大型飞机的新材料的发展现状和趋势。当前,欧美大型飞机机体的材料结构正从以铝合金为主过渡至以复合材料为主,50%复合材料用量是未来飞机的起点。新一代大型飞机的材料技术特色首先是复合材料和钛合金用量创历史新高,以大幅度减轻飞机结构重量和降低燃油消耗;其次反映于一些具有新意的材料技术的成功推出,其中包括复合材料整体机身段、全钛发动机挂架、纤维金属层板、第3代铝锂合金、新型高强铝合金7085、新型高强高韧钛合金Ti-55531等。最后,对中国刚立项研制的大型飞机的选材原则提出了建议。     

刚性隔热材料的力学性能

采用纤维烧结法制备了刚性隔热材料,研究了材料密度、纤维取向、测试温度、与气凝胶复合等因素对材料力学强度的影响规律.结果表明:隔热材料力学强度随着密度的提高而增加;隔热材料平面方向拉伸和压缩强度均达到厚度方向的4倍以上;800和1 000℃下,材料的压缩强度保持率分别达到90%和50%;与气凝胶复合后隔热材料在拉伸强度维持不变的情况下,压缩强度增加35%以上.     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

The Business Case for System-Wide Information Management

In today's National Airspace System (NAS), when an application requires information from another application, a custom application-to-application interface is built. This results in an increasingly complex system, where applications are tightly coupled and expensive to develop and maintain. System-Wide Information Management (SWIM) addresses these shortfalls by implementing a shared infrastructure for managing NAS information. SWIM is based on a service-oriented architecture, a fast growing trend in information technology. It will help the Federal Aviation Administration (FAA) meet the information-sharing needs of the Next Generation Air Traffic System (NGATS) and the federal government's E-government Initiative. SWIM will reduce the cost, complexity, and cycle time for building new applications and help the FAA implement SWIM-enabled applications that increase FAA and user productivity.     

Historical pathways for fuel cells

With the turn of the century, we are entering a new era of individual and personal electricity. It will be created at our personal command to power our cars, homes, work, and communications. Electricity is the positive response to the drivers of: environmental factors, toxic emissions and greenhouse gases, improved energy efficiency, dispersion and decentralization. Internet, telecommunications, and satellites will increasingly tie people together globally. Fuel cells and batteries are the essential systems to develop for this age of personal electricity. History of the pathways of fuel cells will help guide the development of present and future electrical systems     

混杂复合材料层合板抗冲击性能研究

为了探究复合材料层合板在实际应用中因承受冲击载荷而造成的结构安全问题,本研究采用实验和仿真相结合的方法,首先探究冲头形状对复合材料层合板损伤机理的影响,然后结合不同冲击能进一步揭示层合板的承载力和能量吸收变化规律。结果表明,相同冲击能下,层合板的损伤范围和承载力随着圆锥头、半球头、平头依次增加;相应的层合板的临界穿透能量随着圆锥头、半球头、平头依次增大;冲头形状和冲击能对层合板的吸能能力有较大的影响。     

基于无迹卡尔曼滤波法的串联型电池系统 荷电状态估计研究

以锂离子电池为载体的电源系统为航天器稳定可靠运行提供了一种有效的方式.多个电池单体经串联可扩大电池系统容量,即串联型电池系统.为准确估计串联型锂离子电池系统的荷电状态(State of Charge,SOC),针对扩展卡尔曼滤波(Extended Kalman Filter,EKF)计算复杂、精度不高等问题,结合串联型电池系统空间状态方程,提出基于无迹卡尔曼滤波法(Unscented Kalman Filter,UKF)的串联型电池系统荷电状态估计算法.在恒流和脉冲两种工况下,通过对比分析UKF与EKF算法的仿真结果与实验数据的匹配情况,证明了提出算法的准确性和高鲁棒性.     

Operational testing of valve regulated lead acid batteries incommercial aircraft

Valve regulated lead acid (VRLA) batteries provide electrical performance that is virtually identical to sintered plate nickel-cadmium battery systems. In addition, the VRLA batteries offer the user a no-maintenance battery and other enhanced features that make this a very desirable battery for aircraft applications. In field trials, where VRLA batteries were substituted for nickel-cadmium batteries, the VRLA provided the user with a high reliability turbine engine starting battery under a wide variety of climatic conditions