富锂锰基正极材料研究进展

随着社会发展,电动汽车、消费类(3C)电子产品、储能装置等对锂离子电池的能量密度提出了更高要求。富锂锰基正极材料具有高比容量(≈250 mAh/g)、高工作电压(≈3.6 V)及低成本等优势,有望成为下一代商用高比能电池正极材料。首次库仑效率低、倍率性能差、电压/容量衰减快等问题限制了富锂锰基正极材料的工程化应用。本文综述了富锂锰基正极材料的最新研究进展,重点从材料结构、电化学反应机理、失效机制和改性方法等几方面进行了阐述。研究表明,采用离子掺杂、表面包覆、晶体结构调控等技术,可显著改善富锂锰基正极材料的电化学性能。最后,对富锂锰基正极材料的发展方向进行了展望。     

Perspective on ultracapacitors for electric vehicles

Recent advances in performance of chemical double layer capacitors (DLC) with aqueous and non-aqueous electrolytes have made it possible to seriously consider them for commercialization. Non-aqueous (organic) carbon based laboratory monopolar devices have recently met key U.S. Department of Energy (DoE) mid-term specifications (> 5 WNkg, >500 W/kg and >100,000 life cycles) for load-leveling electric vehicles batteries. All DLC technologies currently under development by DoE are discussed. Each technology has distinct advantages and none are clear winners at this time. A study has been completed by the General Electric Company on the interface electronics needed to best utilize the energy of capacitors for load-leveling batteries. System costs are presented based on this study, several battery technologies, and capacitor projections     

Electric-vehicle batteries

Electric vehicles that can't reach trolley wires need batteries. In the early 1900's electric cars disappeared when owners found that replacing the car's worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today's electric cars are still propelled by lead-acid batteries. General Motors in their prototype Impact, for example, used starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon's new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda traveled 260 km on a single charge of its zinc-bromine battery. A German 3.5-ton postal truck traveled 300 km with a single charge in its 650-kg (146 Wh/kg) zinc-air battery. Its top speed was 110 km per hour     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

Segmented battery charger for high energy 28 V lithium ion battery

Since they were first introduced in the early 1990s, lithium ion batteries have enjoyed unprecedented growth and success in the consumer marketplace. Combining excellent performance with affordability, they have become the product of choice for portable computers and cellular phones. Building on the same energy and life cycle attributes, which marked their consumer market success, but adding new high power storage capability, lithium ion technology is now poised to play a similar role in the transportation, military, and space sectors. With major program in various aspects of electric and hybrid electric vehicles, Saft has developed a family of battery products that address the power and energy storage where lightweight, long life, and excellent energy or power storage capabilities are needed. Significant progress in the packaging and control of high power, yet compact, batteries has been accomplished for a variety of vehicle applications. This paper discusses the charger and balancing strategies of one of this family of products     

Battery management considerations for multichemistry systems

The performance advantage of Li-ion batteries versus NiCd and NiMH technology has created a worldwide demand for Li-ion cells that is much greater than current manufacturing capacity. This is keeping prices high and supplies scarce-a situation expected to continue for at least several more years. Multichemistry chargers, while challenging to design, keep price-performance points flexible and guard against interruptions in supply. This paper surveys the design issues in implementing chargers that handle NiCd, NiMH, or Li-ion cells interchangeably     

A new high rate lead acid battery

A new approach to the design of lead acid batteries has been developed based on the use of very thin lead foil current collectors. The basic cell construction and the performance characteristics for the new cell are described. Spiral wrap cells based on this electrode concept exhibit extremely high power output with excellent capacity maintenance. Additionally, these cells exhibit very flat voltage at all currents, and are capable of very rapid recharge. Applications for this high power technology cover a broad spectrum such as portable power tools, UPS systems, electrically heated catalytic converters, military pulse power applications and electric and hybrid vehicles     

Artificial hearts, batteries, and electric vehicles

New battery applications ranged from an implanted battery that powers an artificial heart, to powering a seismic sensor behind an oil-well drilling bit as it grinds through rock looking for oil-bearing structure. These applications require high reliability that justifies the cost of thorough qualification testing, production control, acceptance testing of every cell, and tracking every cell by its serial number through its lifetime. Electric vehicle developments ranged from electric scooters for commuting to work in Europe to electric cars connected to the electric grid when not being driven. Availability of their battery energy for carrying load peaks is so valuable that the electric utility being supported could offer to replace the vehicles batteries whenever they wear out, with no cost to the car owner.     

Recent developments of electric vehicles and their propulsionsystems

Major recent electric vehicle (EV) programs in North America, Europe, and Japan are reviewed. The developments discussed include electric vehicles for fleet operation and electric passenger cars for urban transit. All major auto makers have had their own concept electric vehicle programs, targeted at commercial production in the late 1990s. It Is noted that, with different objectives for various electric vehicles, considerations such as cost, reliability, efficiency, maintenance, durability, weight, size, and noise level should be compromised for the propulsion system design. Consequently, DC motor drives, induction motor drives, and permanent magnet brushless DC motor drives will continually be used for EV propulsion systems in the future, with DC drives being gradually replaced by AC drives. The rapid advances in power semiconductor devices and microprocessors have made it possible to build reliable and cost-effective AC drive systems     

Applications of aluminum-air batteries

Advances in aluminum-air batteries are described. These include alloys that show higher efficiencies and therefore lower hydrogen evolution, low-cost air cathodes that can be fabricated in production quantities, and methods for handling the aluminum hydroxide reaction product. Emphasis is placed on the advances in air cathodes. The application of this technology to new products and the implications for electric vehicles are discussed     

Performance characteristics of lithium-ion cells for NASA's Mars2001 Lander application

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to the attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including Mars rovers and landers. The Mars 2001 Lander (Mars Surveyor Program MSP 01) will be one of the first missions which will utilize lithium-ion technology. This application will require two lithium-ion batteries, each being 28 V (eight cells), 25 Ah and 8 kg. In addition to the requirement of being able to supply at least 200 cycles and 90 days of operation on the surface of Mars, the battery must be capable of operation (both charge and discharge) at temperatures as low as -20°C. To assess the viability of lithium-ion cells for these applications, a number of performance characterization tests have been performed, including: assessing the room temperature cycle life, low temperature cycle life (-20°C), rate capability as a function of temperature, pulse capability, self-discharge and storage characteristics, as well as mission profile capability. This paper describes the Mars 2001 Lander mission battery requirements and contains results of the cell testing conducted to-date in support of the mission,     

Making batteries last longer [for electric vehicles]

The early 1900's era of electric cars ended because the batteries didn't last long enough, and a new gasoline-engine-powered car cost less than a replacement battery. Long-life batteries are the key to achieving a low life-cycle cost for the electric vehicles that will help solve the air-pollution problem in our cities. New ways of making batteries last longer are discussed     

Space power-whats old is new again

The nation is presently seeking smaller and faster space missions that cost less. Furthermore, there is pressure to spin off technologies into the commercial sector as well as spin in technologies to the space program. In this environment, ideas that were dismissed in the past have come to the forefront again. This paper discusses high performance photovoltaic devices, solar dynamic systems, new batteries and power management and distribution schemes. Spin offs of power technologies are impacting aeronautical, terrestrial and naval applications as well. It is believed that interactions with terrestrial commercial industries will lead to deeper understanding of how to reduce space costs as well as increasing quality and reliability     

Comparison of AC drives for electric vehicles-a report on experts'opinion survey

It is recognized that wide applications of electric vehicles (EVs) will bring tremendous social, economical and ecological benefits. With the growing interests in electric vehicles, much effort is demanded for the development of efficient, reliable and economical AC drives' for EV propulsion purpose. Both induction motor (IM) drives and permanent magnet brushless DC motor (IM) drives have been applied to EVs. Switched reluctance motor (SRM) drives have been proposed as an alternative for EV propulsion. In order to assess the suitability of IM, BDCM and SRM drives for EV applications and to provide a technical support for the development and selection of future EV propulsion systems, the existing EV AC propulsion drives were compared, and a survey of experts' opinions was conducted. Comparison of the three AC drives was made on a relative and a quantitative basis using the survey questionnaires. According to the majority of the experts, induction motor drives are best suited for EV propulsion purpose, due to their low cost, high reliability, high speed, established converter and manufacturing technology, low torque ripple/noise and absence of position sensors. BDCM drives feature compactness, low weight and high efficiency and therefore provide an alternative for EV propulsion. The experts regard insulated gate bipolar transistors (IGBTs) as the most suited power semiconductor devices for AC drive converters at the present stage     

Fibre reinforced composites in aircraft construction

Fibrous composites have found applications in aircraft from the first flight of the Wright Brothers’ Flyer 1, in North Carolina on December 17, 1903, to the plethora of uses now enjoyed by them on both military and civil aircrafts, in addition to more exotic applications on unmanned aerial vehicles (UAVs), space launchers and satellites. Their growing use has risen from their high specific strength and stiffness, when compared to the more conventional materials, and the ability to shape and tailor their structure to produce more aerodynamically efficient structural configurations. In this paper, a review of recent advances using composites in modern aircraft construction is presented and it is argued that fibre reinforced polymers, especially carbon fibre reinforced plastics (CFRP) can and will in the future contribute more than 50% of the structural mass of an aircraft. However, affordability is the key to survival in aerospace manufacturing, whether civil or military, and therefore effort should be devoted to analysis and computational simulation of the manufacturing and assembly process as well as the simulation of the performance of the structure, since they are intimately connected.     

A microcontroller-based intelligent battery system

State-of-charge indication for a secondary battery is becoming increasingly important for battery-operated electronics. Consumers are demanding fast charging times, increased battery lifetime, and fuel gauge capabilities. All of these demands require that the state of charge within a battery be known. One of the simplest methods employed to determine state of charge is to monitor the voltage of the battery. However, this method alone is not a good indicator of battery energy, since both NiMH and NiCd batteries have voltage-versus-energy curves that are essentially flat. This paper presents a more effective method of determining the state of charge in secondary cell batteries. A NiMH battery is used as our test vehicle, since it is one of the more difficult batteries to determine state of charge. This method monitors the battery's temperature, voltage, and discharge/charge rate. A microcontroller then manipulates the information, using look-up tables to determine the state of charge. Also, by modifying the look-up tables, this technique can be employed in many other battery technologies and is not limited to NiMH     

Safety testing of lithium ion batteries for navy devices

Lithium ion battery technology is being introduced into power supplies used by our armed forces for a variety of applications. In many cases, the same cells and design parameters that support commercial battery packs are being used in military battery packs. This approach is expected to result in a major decrease in the total life cycle cost of the equipment these batteries support. On June 13, 1991, NAVSEA issued INST9310.1B1, which states that all lithium battery powered equipment must undergo safety evaluation and approval prior to fleet use. This safety program governs a process whereby approvals are issued for lithium batteries to be used in specific equipment on ground facilities, surface combatants, air combatants, and/or submarines. The Naval Ordnance Safety and Security Activity (NOSSA) manages the program. The chief technical advisors are Code 644 at NSWC Carderock Division and Code 609A at NSWC Crane Division. This paper describes three battery designs that incorporate lithium ion technology, and the results of battery safety tests conducted in accordance with navy requirements.     

Global avionics in the future

The following topics are discussed: new batteries for old airplanes; new charge controls for lengthening battery life; fast methods for batteries charging; AC conductance measurement based battery testing; pulse power; bipolar lead-acid batteries vs supercapacitors; Ni electrode cells for spacecraft; worn-out battery disposal; recycling technology; vehicle batteries cost; high energy content batteries; and energy storage for electric utilities     

Advances in the development of ovonic nickel metal hydridebatteries for industrial and electric vehicles

The environmental advantages of ovonic NiH₂ batteries, due to the nontoxicity of ovonic alloys, are briefly discussed, and their general performance is described. Commercial progress in their development is summarized. Their use in electric vehicles is examined