Advanced lithium ion battery charger

A lithium ion battery charger has been developed for four and eight cell batteries or multiples thereof. This charger has the advantage over those using commercial lithium ion charging chips in that the individual cells are allowed to be taper charged at their upper charging voltage rather than be cutoff when all cells of the string have reached the upper charging voltage limit. Since 30-60% of the capacity of lithium ion cells may be restored during the taper charge, this charger has a distinct benefit of fully charging lithium ion batteries by restoring all of the available capacity to all of its cells     

Global avionics in the future

The following topics are discussed: new batteries for old airplanes; new charge controls for lengthening battery life; fast methods for batteries charging; AC conductance measurement based battery testing; pulse power; bipolar lead-acid batteries vs supercapacitors; Ni electrode cells for spacecraft; worn-out battery disposal; recycling technology; vehicle batteries cost; high energy content batteries; and energy storage for electric utilities     

The Hy-StorTM battery

The Hy-Stor^TM Battery is a rechargeable battery being developed for electric vehicles and other large battery applications. The battery combines the high energy storage capability of metal hydride alloys with the high cycle life and discharge rate capabilities of nickel-hydrogen cells. It is a hybrid battery concept that offers potential performance, economic and safety advantages over other large battery technologies. Very recent developments indicate that much smaller batteries can also be produced to meet the needs of the portable computer and other portable electronic device markets. Initial tests demonstrated the ability of a metal hydride storage system to achieve high cycle life when absorbing hydrogen that was saturated with battery electrolyte solution and then passed through a purifier. Based on positive test results, a patent for the Hy-Stor battery was applied for and granted     

High reliability lithium rechargeable batteries for specialties

Since their development in the late 1980s, lithium rechargeable batteries have enjoyed rapid growth and wide use as a commodity battery known for its higher energy density storage and lightweight convenience. These same attributes are emerging as a strong platform in power source development for the medical and aerospace sectors with highly customized applications and narrowly defined criteria. Accordingly, this new generation of lithium rechargeables must be hermetically sealed, have long-term storage capability, and zero-fault tolerances for common causes of field failures such as electrolyte leakage or short circuits from mechanical deformation. Quallion has been developing and manufacturing highly reliable lithium rechargeable cells for medical, aerospace, and specialty applications. Summarized in this paper are some key technologies developed at Quallion for designing and manufacturing of this new class of lithium rechargeable batteries. They include: 1) leakage reliability; 2) self-extinguishing electrolyte system; 3) mechanical impact resistance; 4) deep discharge storage; and 5) high reliability manufacturing.     

A new high rate lead acid battery

A new approach to the design of lead acid batteries has been developed based on the use of very thin lead foil current collectors. The basic cell construction and the performance characteristics for the new cell are described. Spiral wrap cells based on this electrode concept exhibit extremely high power output with excellent capacity maintenance. Additionally, these cells exhibit very flat voltage at all currents, and are capable of very rapid recharge. Applications for this high power technology cover a broad spectrum such as portable power tools, UPS systems, electrically heated catalytic converters, military pulse power applications and electric and hybrid vehicles     

Galileo probe battery system

NASA's pair of Galileo spacecraft arrived at Jupiter on 7 December 1995. The Probe descended into the upper Jovian atmosphere, performing its planned sequence of scientific measurements of the properties of that medium for about an hour. This Probe has been the most ambitious planetary entry vehicle to date. It evolved over several years of planning and construction, its launch was postponed many times, for a variety of reasons; and it required more than 6 years of travel after launch to reach the planet. Its electrical power was provided by a primary Li-SO₂ battery, supplemented with two thermal batteries (CaCrO₄-Ca) used for firing pyrotechnic initiators during the atmospheric entry. These power sources were designed to be robust, to assure they would perform their intended function after surviving several years in space. This paper discusses the final production, qualification, and the systems testing of these batteries prior to and following launch. Their excellent performance at Jupiter confirmed their life enhancement design features     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

富锂锰基正极材料研究进展

随着社会发展,电动汽车、消费类(3C)电子产品、储能装置等对锂离子电池的能量密度提出了更高要求。富锂锰基正极材料具有高比容量(≈250 mAh/g)、高工作电压(≈3.6 V)及低成本等优势,有望成为下一代商用高比能电池正极材料。首次库仑效率低、倍率性能差、电压/容量衰减快等问题限制了富锂锰基正极材料的工程化应用。本文综述了富锂锰基正极材料的最新研究进展,重点从材料结构、电化学反应机理、失效机制和改性方法等几方面进行了阐述。研究表明,采用离子掺杂、表面包覆、晶体结构调控等技术,可显著改善富锂锰基正极材料的电化学性能。最后,对富锂锰基正极材料的发展方向进行了展望。     

Development of a long cycle life sealed nickel-zinc battery forhigh energy-density applications

Nickel-zinc battery technology is being developed for commercial applications requiring high energy density and high power capability. Development cells have demonstrated the ability to deliver over 60 Watt-hours per kilogram at the one hour rate. Cycle life has been improved to more than 600 cycles at 80% depth of discharge by using a patented, reduced solubility zinc electrode and an improved sealed cell design. More than 8000 charge/discharge cycles at 10% depth-of-discharge have been completed. Large quantities of sealed prismatic cells have been manufactured, including a 140 cell, 220 V battery for a hybrid electric vehicle (HEV)     

燃料电池无人机混合电源动态平衡能量管理策略

飞机电推进的动力系统趋于混合能源形式的发展方向，不同类型的源具有不同的特性，混合能源协调工作的方式可以提高动力系统的性能。本文所研究的飞机电推进系统的能源形式为燃料电池和锂电池所做成的混合能源。针对无人机动力系统工况的特殊性，本文在基于规则的能量管理策略研究基础上，提出了一种基于燃料电池氢气消耗的动态平衡能量管理策略，使燃料电池和辅助电源的能量消耗处于相对平衡的状态，避免了其中一种电源能量先耗尽的情况，可以满足多种工况的变化，提高了混合电源的能量利用率和稳定性，保证了无人机动力系统的可靠性。通过仿真分析结果证明了可行性，最后设计了能量管理系统的硬件并进行了实验验证，通过对实验结果计算分析验证了该能量管理策略的可行性。     

Advanced lithium ion solid polymer electrolyte battery development

Lockheed Martin Missiles & Space (LMMS), Ultralife Batteries, Inc. (UBI), Eagle Picher Technologies, LLC (EPT), Sandia National Laboratories (SNL) and Rentech, Inc. (RTI) are developing lithium ion solid polymer electrolyte (Li-ion SPE) batteries. Under a new Advanced Technology Program (ATP), this team will develop new high-energy density cells and batteries for space and portable electronics applications. These new batteries will utilize new high-energy density anode and cathode active materials developed by SNL and RTI. UBI will incorporate these new materials into an optimized Li-ion SPE electrode laminate. EPT will develop batteries for aerospace applications based on this electrode laminate technology while LMMS will design the battery charge management controller and provide system expertise     

Safety testing of lithium ion batteries for navy devices

Lithium ion battery technology is being introduced into power supplies used by our armed forces for a variety of applications. In many cases, the same cells and design parameters that support commercial battery packs are being used in military battery packs. This approach is expected to result in a major decrease in the total life cycle cost of the equipment these batteries support. On June 13, 1991, NAVSEA issued INST9310.1B1, which states that all lithium battery powered equipment must undergo safety evaluation and approval prior to fleet use. This safety program governs a process whereby approvals are issued for lithium batteries to be used in specific equipment on ground facilities, surface combatants, air combatants, and/or submarines. The Naval Ordnance Safety and Security Activity (NOSSA) manages the program. The chief technical advisors are Code 644 at NSWC Carderock Division and Code 609A at NSWC Crane Division. This paper describes three battery designs that incorporate lithium ion technology, and the results of battery safety tests conducted in accordance with navy requirements.     

航空蓄电池能量均衡技术研究

航空电池组中单体电池之间会逐渐出现不一致性,会降低电池组性能和使用寿命,甚至引发安全事故。本文提出了一种基于主动均衡的航空蓄电池组能量均衡系统结构,提出了一种能量集中式双向传递的Cúk型均衡电路,设计了顶部均衡和底部均衡的均衡控制策略。开发了航空镍镉蓄电池能量均衡系统,进行了镍镉电池组能量均衡实验分析,实验结果表明新型能量均衡器具有均衡速度快、均衡电池单体可任意选择、能量双向传递的优点,通过电池组能量均衡控制能明显改善电池组内单体之间的不一致性,提高电池组容量利用率和使用寿命。     

Prismatic lithium-ion batteries

Lithium-ion (Li-ion) batteries have demonstrated the ability to fulfill the energy storage needs of many new technologies. The most significant drawbacks of currently available technologies, such as LiCoO ₂ based Li-ion cells, is their high cost and significant environmental hazards. Li-ion cells which use a lithium manganese oxide (LiMn₂O₄) spinel based cathode material should be much less costly and safer than LiCoO₂ based cells. Performance data from prismatic design cells which use a LiMn₂O₄ based cathode material is presented and shown to meet many military performance criteria. The most significant drawback of this technology is the short cycle life     

Battery configurations for multi-megawatt pulse power

The capability of lead-acid batteries for supplying very high power for a short time is explored. The application of such a battery for accelerating a hypersonic plane is used to illustrate the requirements. A technique for analyzing batteries and controlling voltage for pulse loads is described. Evaluation of lead-acid batteries in production and voltage regulation by switching batteries in and out are covered. Alternatives to batteries, including superconducting magnetic energy storage, are discussed     

Advanced materials for next generation NiMH portable, HEV and EVbatteries

While Ovonic NiMH batteries are already in high volume commercial production for portable applications, advances in materials technology have enabled performance improvements in specific energy (100 Wh/kg), specific power (600-1000 W/kg), high temperature operation, charge retention, and voltage stability. Concurrent with technology advances, Ovonic NiMH batteries have established performance and commercial milestones in electric vehicles, hybrid electric vehicles, as well as scooter, motorcycle and bicycle applications. As important as these advances, significant manufacturing cost reductions have also occurred which allow continued growth of NiMH technology. In this paper, advances in performance, applications and cost reduction are discussed with particular emphasis on the improved proprietary metal hydride and nickel hydroxide materials that make such advances possible     

Bipolar nickel-metal hydride battery for hybrid vehicles

Hybrid electric vehicles are receiving increased interest as an approach to decrease vehicle pollution, dependence, and consumption of liquid petroleum and meet forthcoming Government vehicle emission standards. A number of schemes are under consideration (heat engine battery, fuel cell battery, peaking battery, inner-city battery, etc.). The success of any of the approaches will be dependent on battery capabilities, i.e., power, density, life, and cost. The nickel-metal hydride system appears to be the most promising of the candidate battery chemistries. Preliminary designs and analysis have been prepared and are presented for various configurations. Initial performance characterization tests are presented. It is concluded that a bipolar package arrangement for the Ni-MH chemistry appears most suited for the hybrid vehicle application considered     

基于等效时间的混合储能系统高功率密度优化配置

越来越多的电力电子装置应用到多电飞机（MEA）电力系统中,导致MEA用电负荷功率呈现脉动特性,采用混合储能系统（HESS）平抑负荷功率脉动。为减少HESS重量,提出了一种高功率密度的优化配置方法。为建立负荷功率与储能介质之间的关系,提出了等效时间（ET）的概念,比较两者的ET常数作为储能系统类型选取的依据。进一步提出空间矢量法,采用能量型储能介质矢量和功率型储能介质矢量合成负荷功率,确定最优单体和截止频率,实现了HESS高功率密度配置。同时,从能量约束和功率约束两个方面进行HESS的容量的计算。最后,通过算例配置和仿真分析验证了本文所提方法的可行性和正确性。