Exobiology and future Mars missions: The search for Mars'' earliest biosphere

The primordial Mars may have possessed a thick carbon dioxide atmosphere, with liquid water common on the surface, similar in many ways to the primordial Earth. During this epoch, billions of years ago, the surface of Mars could have been conducive to the origin of life. It is possible that life evolved on Mars to be later eliminated as the atmospheric pressure dropped. Analysis of the surface of Mars for the traces of this early martian biota could provide many insights into the phenomenon of life and its coupling to planetary evolution.     

The CO2 greenhouse effect and the thermal history of the atmosphere.

The influence of the expected rise of CO2 content in our atmosphere upon terrestrial temperature is uncertain. A significant increase in temperature could be threatening to certain aspects of terrestrial biology. On the other hand, it is a general consensus among paleobiologists that the Earth possessed a CO2 atmosphere in the past billion years, without dramatic temperature variations endangering the continuity of life. In order to clarify this problem, and to contribute to the understanding of the CO2 greenhouse effect on Venus we have computed the absorption spectrum of CO2 for a wide range of atmospheric concentrations. More than 2500 spectral lines of the 15 micron band were taken into account in our line-by-line calculation. We have used an empirical exponential line-shape function at the line edges. Our results agree with the experimental data of F. W. Taylor. The estimated increase in surface temperature does not reach the boiling point of water even for CO2 concentrations thousands of times larger than the present concentrations. Higher energy (>666 cm-1) CO2 bands and/or an increase in atmospheric H2O may, however, amplify the greenhouse effect.     

Life on Mars? II. Physical restrictions.

The primary physical factors important to life's evolution on a planet include its temperature, pressure and radiation regimes. Temperature and pressure regulate the presence and duration of liquid water on the surface of Mars. The prolonged presence of liquid water is essential for the evolution and sustained presence of life on a planet. It has been postulated that Mars has always been a cold dry planet; it has also been postulated that early mars possessed a dense atmosphere of CO2 (> or = 1 bar) and sufficient water to cut large channels across its surface. The degree to which either of these postulates is true correlates with the suitability of Mars for life's evolution. Although radiation can destroy living systems, the high fluxes of UV radiation on the martian surface do not necessarily stop the origin and early evolution of life. The probability for life to have arisen and evolved to a significant degree on Mars, based on the postulated ranges of early martian physical factors, is almost solely related to the probability of liquid water existing on the planet for at least hundreds of millions to billions of years.     

Life in the solar system.

Life, defined as a chemical system capable of transferring its molecular information via self-replication and also capable of evolving, must develop within a liquid to take advantage of the diffusion of complex molecules. On Earth, life probably originated from the evolution of reduced organic molecules in liquid water. Organic matter might have been formed in the primitive Earth's atmosphere or near hydrothermal vents. A large fraction of prebiotic organic molecules might have been brought by extraterrestrial-meteoritic and cometary dust grains decelerated by the atmosphere. Any celestial body harboring permanent liquid water may therefore accumulate the ingredients that generated life on the primitive Earth. The possibility that life might have evolved on early Mars when water existed on the surface marks it as a prime candidate in a search for bacterial life beyond the Earth. Europa has an icy carapace. However, cryovolcanic flows at the surface point to a possible water subsurface region which might harbor a basic life form. The atmosphere and surface components of Titan are also of interest to exobiology for insight into a hydrocarbon-rich chemically evolving world. One-handed complex molecules and preferential isotopic fractionation of carbon, common to all terrestrial life forms, can be used as basic indicators when searching for life beyond the Earth.     

我国火箭探测资料与CIRA 1986稿的比较

本文用我国气象火箭探测获得的中层大气风、温度、密度和气压等数据,与国际参考大气模式CIRA 1986稿作了比较.结果看到,我国火箭探测温度数据值在模式给出的平均值剖面上下波动,符合的程度在国际比对偏差范围之内;用探测数据分析得到的风的季节性和声重波强度等与模式给出的描述都很符合.从而说明,用CIRA 1986稿来表征我国上空的中层大气结构是合适的.      

密闭空间内氢气和二氧化碳甲醇化系统的非均相模型及反应特性

在载人密闭空间内通过电解水方式为乘员供氧会产生副产物氢气（H₂）。此外,乘员还呼出二氧化碳（CO₂）。将H₂和CO₂催化合成甲醇（CH₃OH）是消除载人密闭空间内富余H₂和CO₂的最优方式之一。对其开展反应过程建模及反应特性研究有助于进行反应过程的控制,更好地维持载人密闭空间内的大气平衡。本文采用微元法建立了H₂和CO₂催化合成甲醇的物料计算模型和温度一维非均相模型,研究了不同反应压力、冷却介质温度以及入口反应气体中CO₂与CO比值等反应条件下的反应特性变化规律。结果显示,反应压力的增加、冷却介质的温升以及入口气体中CO₂与CO比值的减小均能促进各反应速率增加,进而使得H₂和CO₂消除量增加、甲醇合成率上升以及催化剂和反应气体最高温度上升。在保证反应速率增加且催化剂最高温度不超过合理反应温度区间的最大值573.15 K时需维持反应压力不大于8 MPa,冷却介质温度不高于538.15 K以及CO₂与CO比值不小于1。      

The temporal variation of mean gravity of atmosphere

One of the precise widely used global Zenith Hydrostatic Delay (ZHD) model is based on the gravity value at the centroid of the atmospheric column at the station of observation and gravity value at the centroid is constant in this model for a specific location throughout the year. However, as the content and extent of atmosphere varies temporally, its centroid and consequently gravity value at the centroid also varies. Apart from this, the actual atmospheric condition of different region is not alike. Therefore, there is a need to develop a regional mean gravity model and development of such model has been discussed in this paper. To obtain the mean gravity model, first a regional model of centroid height of atmospheric column was developed as a function of the surface pressure and temperature. It was developed by multiple regressions between estimated centroid of the atmosphere and surface pressure, surface temperature using radiosonde data of five radiosonde stations spread over the Indian subcontinent. Three years radiosonde data from 2006 to 2008 was used for each station. The root mean square error in estimating centroid of the atmospheric column is about ±326 m, which is negligible considering the variability of the atmosphere and its content. The centroid height model has been used to formulate the mean gravity model, considering uniform lapse rate in gravity with height. It is found that proposed mean gravity model provides temporal variation of mean gravity values at the centroid and thus matches with the reality. The interesting advantage of the developed model is that the model shows diurnal variation of mean gravity. The accuracy of ZHD has shown of the order of about 0.3 mm using the developed regional mean gravity model. However, already developed ZHD model has shown a slight inferior result compared to the developed model. These models have shown accuracy of about 0.8 mm and 0.6 mm.     

Neutral upper atmospheres of Venus and Mars

Numerous measurements of the neutral upper atmosphere above 100 km have been made from spacecraft over Venus and over Mars. The Venus exospheric temperatures are unexpectedly low (less than 300°K near noon and less than 130°K near midnight). These very low temperatures may be partially caused by collisional excitation of CO₂ vibrational states by atomic oxygen and partially by eddy cooling. The Venus atmosphere is unexpectedly insensitive to solar EUV variability. On the other hand, the Martian dayside exospheric temperature varies from 150°K to 400°K over the 11-year solar cycle, where CO₂ 15-μm cooling may be less effective because of lower atomic oxygen mixing ratios. On Venus, temperature increases with altitude on the dayside (thermosphere), but decreases with altitude from 100 to 150 km on the nightside (cryosphere). However, dayside Martian temperatures near solar minimum for maximum planet-sun distance and low solar activity are essentially isothermal from 40 km to 200 km. During high solar activity, the thermospheric temperatures of Mars sharply increase. The Venus neutral upper atmosphere contains CO₂, O, CO, C, N₂, N, He, H, D and hot nonthermal H, O, C, and N, while the dayside Mars neutral upper atmosphere contains CO₂, O, O₂, CO, C, N₂, He, H, and Ar. There is evidence on Venus for inhibited day-to-night transport as well as superrotation of the upper atmosphere. Both atmospheres have substantial wave activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.     

Surface-atmosphere interactions on Titan compared with those on the pre-biotic Earth.

The surface and atmosphere of Titan constitute a system which is potentially as complex as that of the Earth, with the possibility of precipitation, surface erosion due to liquids, chemistry in large surface or subsurface hydrocarbon reservoirs, surface expressions of internal activity, and occasional major impacts leading to crustal melting. While none of the above have been observed as yet, the composition, density and thermal properties of Titan's atmosphere make it uniquely suited in the outer solar system as a place where such processes may occur. The one attribute of the Earth not expected on Titan is biological activity, which has had a profound effect on the evolution of the Earth's surface-atmosphere system. The earliest environment of Titan could have been warm enough for liquid ammonia-water solutions to exist on or near surface; pre-biotic organic processes may have taken place in such an environment. After a few hundred million years surface ammonia-water would have disappeared. Therefore, study of Titan through the Cassini-Huygens mission, planned for launch in 1997, primarily affords the opportunity to understand planet-wide surface-atmosphere interactions in the presence of fluids but in the absence of life. More speculative is the possibility that endogenic and exogenic heating continue to provide short-lived environments on Titan wherein pre-biotic organic processes in the presence of water happen.     

太赫兹火星大气临边探测仿真研究

对火星大气进行连续高分辨率观测是研究火星大气物理和化学过程的重要手段.太赫兹临边探测技术通过测量火星大气中的风和光化学循环中的重要气体（CO,O₃,H₂O,H₂O₂等）提高对火星的认知.针对火星大气遥感的探测需求,分析了300～1000GHz频段的频谱特征.针对探测卫星对于载荷质量、功耗等参数的要求,提出一个560GHz频段的火星大气太赫兹临边探测仪设计方案,并利用辐射传输模型ARTS中的行星工具箱进行仿真.仿真结果显示:火星大气温度的反演精度优于4K,其中45km高度以下优于2K;H₂O丰度的反演精度在90km以下优于50%,30km以下优于2%;H₂O₂的反演精度在40km以下优于50%;O₃的反演精度在50km以下优于60%;大气风速度的反演精度在65km以上优于5m·s-1,最高可以达到2m·s-1.研究结果表明,利用太赫兹波段的吸收谱线可以很好地探测火星大气中各成分的丰度、变化趋势以及中高层大气的风,可为后续火星表面及大气探测提供参考.      

Bio-markers and the search for extinct life on Mars.

Geologic and climatologic studies suggest that conditions on early Mars were similar to early Earth. Because life on Earth is believed to have originated during this early period (3.5 billion years ago), the Martian environment could have also been conducive to the origin of life. To investigate this possibility we must first define the attributes of an early Martian biota. Then, specific geographic locations on Mars must be chosen where life may have occurred (i.e. areas which had long standing water), and within these distinct locations search for key signatures or bio-markers of a possible extinct Martian biota. Some of the key signatures or bio-markers indicative of past biological activity on Earth may be applicable to Mars including: reduced carbon and nitrogen compounds, CO3(2-), SO4(2-), NO3-, NO2- [correction of NO2(2)], Mg, Mn, Fe, and certain other metals, and the isotopic ratios of C, N and S. However, we must also be able to distinguish abiotic from biologic origins for these bio-markers. For example, abiotically fixed N2 would form deposits of NO3- and NO2-, whereas biological processes would have reduced these to ammonium containing compounds, N2O, or N2, which would then be released to the atmosphere. A fully equipped Mars Rover might be able to perform analyses to measure most of these biomarkers while on the Martian surface.     

Statistical global and regional atmospheric models of temperature and gas components over the northern hemisphere

Statistical mid-latitude models of altitude distribution of temperature, water vapor, ozone, carbon dioxide and trace gases (CO, CH₄, N₂O, NO, NO₂) are considered. The mean characteristics of altitude profiles of these parameters, as well as their time and space variability, have been taken into account. The statistical regional models were constructed using a temperature-humidy complex. The considered statistical mid-latitude models have been constructed as applied to solutions of the problems on remote sounding of the atmosphere and underlying surface from outer space.     

基于钠激光雷达观测数据的中间层顶大气温度分布特性研究

作为中间层和热层的边界层,中间层顶存在多种能量交换方式,是大气能量耦合的重要区域。本文利用部署于中国科学院廊坊临近空间大气探测站的钠荧光多普勒激光雷达2013年的观测数据,研究了廊坊上空中间层顶区域大气温度的年度和季节分布特性,并分析了影响温度分布的多种因素。年平均温度廓线图显示,中间层顶位于约97.5 km高度处,温度约191.2 K。受放热化学反应的影响,年平均温度廓线91 km高度处出现了一个198 K的相对温度高点。中间层顶区域大气温度的季节分布受太阳辐射和大气动力学因素综合影响,夏季在大气动力学影响下,中间层顶高度较低,位于88 km高度处,温度也较低,约177 K;冬季太阳辐射起主导作用,中间层顶位于99 km高度处,温度为181 K。通过拟合月平均温度分析了中间层顶区域大气温度年变化和半年变化的振幅和相位特征。结果显示,中间层顶区域上部温度分布主要受太阳辐射的影响;在中间层顶区域下部,大气波动主导了温度分布。      

卫星精密测定轨中的对流层延迟估算系统

基于V isual Basic编程,设计了卫星精密测定轨中的实时气象采集与对流层延迟估算系统。利用实时采集ZQZ-A型自动气象站的温度、相对湿度、大气压等气象要素,采用Saastamoinen模型进行估算天顶方向对流层静力延迟和湿延迟,同时采用地基双波段微波辐射计测量大气水汽总量和云液态水总量,进而估算更高精度的湿延迟,在其有效时与模型计算的静力延迟相加,得到天顶方向总延迟;无效时采用模型计算的总延迟。最后将其投影到卫星方向得到总延迟。实际应用表明,设计的对流层延迟估算系统人机界面友好,具有易用性,能实时、稳定地为卫星精密测定轨提供服务。     

Limits of photosynthesis in extrasolar planetary systems for earth-like planets.

We present a general modeling scheme for investigating the possibility of photosynthesis-based life on extrasolar planets. The scheme focuses on the identification of the habitable zone in main-sequence-star planetary systems with planets of Earth mass and size. Our definition of habitability is based on the long-term possibility of photosynthetic biomass production as a function of mean planetary surface temperature and atmospheric CO2-content. All the astrophysical, climatological, biogeochemical, and geodynamic key processes involved in the generation of photosynthesis-driven life conditions are taken into account. Implicitly, a co-genetic origin of the central star and the orbiting planet is assumed. The numerical solution of an advanced geodynamic model yields realistic look-up diagrams for determining the limits of photosynthesis in extrasolar planetary systems, assuming minimum CO2 levels set by the demand of C4 photosynthesis.     

Europa, tidally heated oceans, and habitable zones around giant planets.

Tidal dissipation in the satellites of a giant planet may provide sufficient heating to maintain an environment favorable to life on the satellite surface or just below a thin ice layer. In our own solar system, Europa, one of the Galilean satellites of Jupiter, could have a liquid ocean which may occasionally receive sunlight through cracks in the overlying ice shell. In such case, sufficient solar energy could reach liquid water that organisms similar to those found under Antarctic ice could grow. In other solar systems, larger satellites with more significant heat flow could represent environments that are stable over an order of Aeons and in which life could perhaps evolve. We define a zone around a giant planet in which such satellites could exist as a tidally-heated habitable zone. This zone can be compared to the habitable zone which results from heating due to the radiation of a central star. In our solar system, this radiatively-heated habitable zone contains the Earth.     

Transport of extraterrestrial biomolecules to the Earth: problem of thermal stability.

The idea of extraterrestrial delivery of organic matter to the early Earth is especially attractive at present and is strongly supported by the detection of a large variety of organic compounds, including amino acids and nucleobases, in carbonaceous chondrites. Whether these compounds can be delivered by other space bodies is unclear and depends primarily on capability of the biomolecules to survive high temperatures during atmospheric deceleration and impacts to the terrestrial surface. In the present study we estimated survivability of simple amino acids (alpha-aminoisobutyric acid, L-alanine, L-valine and L-leucine), purines (adenine and guanine) and pyrimidines (uracil and cytosine) under rapid heating to temperatures of 400 to 1000 degrees C under N2 or CO2 atmosphere. We have found that most of the compounds studied cannot survive the temperatures substantially higher than 700 degrees C; however at 500-600 degrees C, the recovery can be at a per cent level (or even 10%-level for adenine, uracil, alanine, and valine). Implications of the data for extraterrestrial delivery of the biomolecules are discussed.     

Validation on MERSI/FY-3A precipitable water vapor product

The precipitable water vapor is one of the most active gases in the atmosphere which strongly affects the climate. China's second-generation polar orbit meteorological satellite FY-3A equipped with a Medium Resolution Spectral Imager (MERSI) is able to detect atmospheric water vapor. In this paper, water vapor data from AERONET, radiosonde and MODIS were used to validate the accuracy of the MERSI water vapor product in the different seasons and climatic regions of East Asia. The results show that the values of MERSI water vapor product are relatively lower than that of the other instruments and its accuracy is generally lower. The mean bias (MB) was ?0.8 to ?12.7?mm, the root mean square error (RMSE) was 2.2–17.0?mm, and the mean absolute percentage error (MAPE) varied from 31.8% to 44.1%. On the spatial variation, the accuracy of MERSI water vapor product in a descending order was from North China, West China, Japan -Korea, East China, to South China, while the seasonal variation of accuracy was the best for winter, followed by spring, then in autumn and the lowest in summer. It was found that the errors of MERSI water vapor product was mainly due to the low accuracy of radiation calibration of the MERSI absorption channel, along with the inaccurate look-up table of apparent reflectance and water vapor within the water vapor retrieved algorithm. In addition, the surface reflectance, the mixed pixels of image cloud, the humidity and temperature of atmospheric vertical profile and the haze were also found to have affected the accuracy of MERSI water vapor product.     

Atmospheric response to a Hot SST Event in November 2006 as observed by the AIRS instrument

Using Atmospheric Infrared Sounder (AIRS) products of atmospheric temperature and geopotential height, we investigate the atmospheric response to HE0611, which was found and investigated by [Qin, H., Kawamura, H., Sakaida, F., Ando, K. A case study of the tropical Hot Event in November 2006 (HE0611) using a geostationary meteorological satellite and the TAO/TRITON mooring array. J. Geophys. Res. 113, C08045, doi: 10.1029/2007JC004640, 2008]. HE0611 was formed by connecting two very high SST areas, HE0611-East and HE0611-West. The period-mean atmosphere temperatures at levels of 925 and 850 hPa in HE0611-West are higher, by about 0.5 K, than those in WE0611-East while the atmospheric temperatures at middle to high levels (700–300 hPa) are higher in HE0611-East. The period-mean geopotential heights HE0611-East are much lower than those in HE0611-West for the levels from the surface to 400 hPa. The mean geopotential heights from 400 hPa to 200 hPa are higher in HE0611-East. In the middle and high layers over HE0611-West, the atmosphere temperatures gradually decrease from 7th to 17th, and then increase significantly. The increase in HE0611-East starts from 15th November, which is earlier than that of HE0611-West. The geopotential heights in the high layer of both the areas also show corresponding behaviors. The lagged atmospheric response in the western part is confirmed by the correlation analysis. It emerges that the atmospheric response to HE0611 is well organized and associated with deep convention in HE0611-East and subsidence in HE0611-West. These are also consistent with the HE0611 features and evolution revealed by earlier HE studies.     

Determination of land surface temperature using precipitable water based Split-Window and Artificial Neural Network in Turkey

Land surface temperature (LST) calculation utilizing satellite thermal images is very difficult due to the great temporal variance of atmospheric water vapor in the atmosphere which strongly affects the thermal radiance incoming to satellite sensors. In this study, Split-Window (SW) and Radial Basis Function (RBF) methods were utilized for prediction of LST using precipitable water for Turkey. Coll 94 Split-Window algorithm was modified using regional precipitable water values estimated from upper-air Radiosond observations for the years 1990–2007 and Local Split-Window (LSW) algorithms were generated for the study area. Using local algorithms and Advanced Very High Resolution Radiometer (AVHRR) data, monthly mean daily sum LST values were calculated. In RBF method latitude, longitude, altitude, surface emissivity, sun shine duration and precipitable water values were used as input variables of the structure. Correlation coefficients between estimated and measured LST values were obtained as 99.23% (for RBF) and 94.48% (for LSW) at 00:00 UTC and 92.77% (for RBF) and 89.98% (for LSW) at 12:00 UTC. These meaningful statistical results suggest that RBF and LSW methods could be used for LST calculation.