太赫兹大气临边探测仪遥感中高层大气风仿真

太赫兹大气临边探测仪（TALIS）是中国正在预研的第一台THz频段的临边探测仪，主要用于高精度、高分辨率的大气遥感测量.TALIS的观测目标主要包括大气温度、大气压强、大气成分（例如H₂O，O₃，HCl，ClO，N₂O，HNO₃等）的垂直分布以及长期变化趋势.由于TALIS的频段覆盖了许多重要的吸收谱线，其观测数据中包含大气风的多普勒信息，因此可以用于反演中高层风的廓线.本文针对TALIS视线多普勒风的观测进行仿真，利用辐射传输模型（ARTS）评估了TALIS测风的潜力和相应的反演精度.结果表明，TALIS的118GHz谱仪具有较好的测量精度，在70km处的精度为12m·s-1.183GHz，633GHz和658GHz谱仪也有一定的测量信息，反演精度分别为19m·s-1（60km），19m·s-1（50km），16m·s-1（50km）.TALIS有一个候选的测风谱仪位于655GHz频段，其在55km处的反演精度为11m·s-1.此外，虽然降低谱分辨率能有效提高系统灵敏度，但并不能提高反演精度，需要通过降低系统噪声来提高测风的精度.      

贫燃型汽车尾气NOx的催化净化

用溶胶-凝胶混合法制备了Al₂O₃,Ag/Al₂O₃,Sn/Al₂O₃,Ga/Al₂O₃,Co/Al₂O₃和Pt/Al₂O₃等催化剂.在相同实验条件下,比较了C₃H₆在这些催化剂上还原NO的活性,并考察了反应条件对C₃H₆和CH₃OH在Ag/Al₂O₃上还原NO性能的影响.结果表明,Ag/Al₂O₃的还原NO活性优于其它催化剂.H₂O对Ag/Al₂O₃催化剂的NO还原具有可逆抑制作用,SO₂降低C₃H₆在Ag/Al₂O₃上还原NO的活性,但会显著提高CH₃OH还原NO的活性.     

艇载声波测量临近空间风场可行性分析

提出一种临近空间艇载原位测量大气风场的新方法,该方法利用声波传播时延差测量临近空间大气风场.介绍了该方法的原理,分析了测风误差来源和测风精度.通过分析声波在临近空间高度的衰减,对信号载波频率和传播距离进行了选择,并对不同信噪比条件下声波时延估计精度进行了仿真分析.结果表明:在临近空间20~50km高度,传播距离为2~5m,距离测量精度为1mm,平台测速精度为0.1m·s-1,信噪比优于-2dB条件下,时延估计精度优于1μs,利用该方法测风精度能达到0.2m·s-1的较高水平.      

二维H2/O2混合和流动的直接数值模拟

用高阶精度的紧致差分方法,对低速的随时间发展的二维可压缩H-2/O-2混合层流动编制了直接数值模拟的计算机程序,对雷诺数Re为400、来流马赫数Ma分别为0.4(上部的H₂)和1.57(下部的O₂)的H₂/O₂亚跨超声速混合层流动进行了计算,得到了相应的计算结果,并对结果进行了分析和研究.     

基于斜向探测最高可用频率反演电离层参数

提出了一种利用斜向探测F₂层最高可用频率及其对应时延反演传播路径中点临界频率f₀F₂和3000km传输因子M（3000）F₂的新方法.该方法从工程实用角度出发,利用射线传播理论直接反演得到临界频率和3000km传输因子.通过对长春-径阳和新乡-赤峰两条斜向探测链路中点电离层参数的反演分析,验证了方法的稳定性;利用反演结果与北京垂直探测数据对比,验证了方法的准确性;通过与Smith方法的对比,验证了方法的实用性.统计分析显示,此方法具有与Smith方法可比的精度,明显优于参考电离层模型给出的结果,其均方误差为0.48MHz,相对误差为10.50%;具有较好的稳定性,对不同距离的探测链路有较好的适应性,反演精度差异为0.03MHz;具有可操作性强,易于实现的特点.本研究成果可用于短波通信频率实时预报、动态频率管理及其相关领域.      

铝合金阳极化膜上铈转化膜沉积的电化学研究

阳极氧化膜在含1g/L CeCl₃和2.7 g/L H₂O₂的水溶液中阴极电解可以在其表面沉积富铈转化膜.用循环伏安、φ-t和j-t曲线等电化学测试方法对转化膜成膜反应进行了研究,以期获得对成膜机理的深入了解和证实根据其它工作提出的成膜机理.研究结果表明铈转化膜的生成包括阳极氧化膜的化学溶解和4价铈化合物的电化学还原两个过程;在阴极电位达到析氢电位之前,这两个过程主要是由H₂O₂在阴极的电还原改变了阴极表面附近溶液的局部pH值引起的,而O₂的还原通常不能引起这两个过程的发生.      

氧气A(0,0)波段气辉体发射率和临边辐射强度模拟与分析

临近空间大气参数如温度、密度、风场等对预报模型精度及航天器运行安全等有较大的影响，而气辉的辐射模拟是大气参数反演的重要过程.本文基于光化学模型计算了氧气A（0，0）波段气辉的体发射率和临边辐射强度.基于氧气A（0，0）波段气辉的光化学反应机制、大气动力学和光化学反应理论，建立产生O₂（b1Σ_g+）的光化学模型.计算气辉体发射率，基于临边探测几何路径进行气辉辐射强度模拟.体发射率计算结果与AURIC模型结果的辐射值及辐射高度均一致.基于计算和模拟结果，对氧气A波段气辉体发射率和辐射强度的影响因素进行了分析.      

基于树模型机器学习方法的GNSS-R海面风速反演

GNSS-R是基于GNSS卫星反射信号的一种新技术.GNSS-R技术可以运用到海面风场反演中，传统的GNSS-R技术反演海面风场主要有波形匹配和经验函数两种方法，风速反演精度约为2m·s-1.波形匹配方法耗时多，计算量大；经验函数方法通常只使用少量物理观测量，会造成信息浪费，损失一定的反演精度.为了提高海面风速的反演精度，引入机器学习领域常用的树模型算法决策树、随机森林、GBDT等对海面风速进行预测.利用GNSS-R与ECMWF数据构成训练集和验证集，训练集用于模型学习，验证集用于检验模型的反演效果.实验结果显示，决策树和随机森林预测误差约为0.6m·s-1，GBDT等算法的预测误差约为2m·s-1，满足风速反演要求.与GNSS-R传统反演方法相比，机器学习树模型算法效果更好，在验证集上表现稳定且误差较小.因此，可以将机器学习树模型算法运用到海面风速反演中.      

发动机燃气喷流红外辐射场的数值模拟

在高温流动中热辐射与流场是耦合的,但在发动机燃气喷流流场的温度范围内可以在流场计算中忽略热辐射的影响,于是流场与辐射场的模型方程可解耦.为此提出了模拟飞行器绕流流场红外辐射的解耦模型以及相应的算法.该算法首先采用总变差减小TVD(Total Variation Diminishing)格式对流场进行模拟,再引入有限体积概念,应用所取得的流场参数,在同一组网格上计算流场中的红外辐射特征.以轴对称喷管内N₂,O₂,CO₂,H₂O,CO,HCl,H₂等7组分高度欠膨胀冻结流与均匀绕流干扰流场为算例进行了验证性的模拟计算,并与已有试验和计算数据进行了对比,表明该算法是可靠的,可在较大幅度地降低计算量的情况下给出满足工程需要的结果.     

液体火箭喷焰红外特性的数值仿真

用传输方程积分法计算液体火箭喷焰在光谱2~5?μm的红外特性,并考虑了经过海平面一定长度的水平路程后大气对液体火箭喷焰辐射的衰减作用.计算喷焰的形状为圆柱形,温度和组分的摩尔分数沿轴向和径向变化.计算中考虑气体组分H₂O,CO₂,CO的吸收与发射,喷焰内燃气的光谱透过率用SLG模型计算,大气的光谱透过率用LOWTRAN7.0计算.给出一台推力为1.125×10⁶N的液体火箭发动机喷焰表面以及经过海平面0.88?km水平路程大气衰减后的光谱辐射强度,经比较与参考文献给出的结果基本一致.     

Neutral upper atmospheres of Venus and Mars

Numerous measurements of the neutral upper atmosphere above 100 km have been made from spacecraft over Venus and over Mars. The Venus exospheric temperatures are unexpectedly low (less than 300°K near noon and less than 130°K near midnight). These very low temperatures may be partially caused by collisional excitation of CO₂ vibrational states by atomic oxygen and partially by eddy cooling. The Venus atmosphere is unexpectedly insensitive to solar EUV variability. On the other hand, the Martian dayside exospheric temperature varies from 150°K to 400°K over the 11-year solar cycle, where CO₂ 15-μm cooling may be less effective because of lower atomic oxygen mixing ratios. On Venus, temperature increases with altitude on the dayside (thermosphere), but decreases with altitude from 100 to 150 km on the nightside (cryosphere). However, dayside Martian temperatures near solar minimum for maximum planet-sun distance and low solar activity are essentially isothermal from 40 km to 200 km. During high solar activity, the thermospheric temperatures of Mars sharply increase. The Venus neutral upper atmosphere contains CO₂, O, CO, C, N₂, N, He, H, D and hot nonthermal H, O, C, and N, while the dayside Mars neutral upper atmosphere contains CO₂, O, O₂, CO, C, N₂, He, H, and Ar. There is evidence on Venus for inhibited day-to-night transport as well as superrotation of the upper atmosphere. Both atmospheres have substantial wave activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.     

Atmospheric photochemistry above possible martian hot spots

Considering the possibility of outgassing from some localized sources on Mars, we have developed a one-dimensional photochemical model that includes methane (CH₄), sulfur dioxide (SO₂) and hydrogen sulfide (H₂S). Halogens were considered but were found to have no significant impact on the martian atmospheric chemistry. We find that the introduction of methane into the martian atmosphere results in the formation of mainly formaldehyde (CH₂O), methyl alcohol (CH₃OH) and ethane (C₂H₆), whereas the introduction of the sulfur species produces mainly sulfur monoxide (SO) and sulfuric acid (H₂SO₄). Depending upon the flux of the outgassed molecules from possible hot spots, some of these species and the resulting new molecules may be detectable locally, either by remote sensing (e.g., with the Planetary Fourier Spectrometer on Mars Express) or in situ measurements.     

Radiation stability of organic matter in liquid and frozen H2O, NH3 and water-ammonia mixtures

The redox properties of irradiated liquid and frozen H₂O, NH₃ and H₂O/NH₃ mixtures at 298 K and 77 K, resp., towards some simple organic molecules have been checked by injecting carrierfree ¹¹C atoms and analyzing their chemical state by means of radiochromatography. The reactions and the stability of organic products versus radiation dose (in this study by MeV protons) depend on temperature, phase state, mobility of radicals, their concentration and reactivity. Especially dangerous are the reactive OH and O₂H radicals which oxidize organic material to inorganic CO₂. Highest stability has been found at low temperatures (solid state, reduced mobility of radicals) and for systems containing H-donors (H₂O/NH₃ mixtures), which reduce the concentration of oxidizing radicals. The fact that many bodies in space consist of H₂O-ice with NH₃ and CH₄ additives at temperatures between 10 and 150 K is promising in view of the survival of organic matter under high doses of radiation.     

H2O对空间站5A分子筛CO2去除性能影响

为进一步研究分子筛CO2去除系统应用于空间站的工作可靠性和鲁棒性,针对空间站4床分子筛(4-BMS)系统中可能出现的湿度失效保护问题展开了实验研究.测试了两种载人航天分子筛材料TC-5A与PSA-5A,研究了不同相对湿度对CO2吸附性能的影响;比较了相同湿度条件下,进口气体CO2浓度、粒径及吸附温度的变化对分子筛吸附CO2性能的影响,采用不同实验方法探究了H2O和CO2在两种分子筛材料中的竞争吸附关系.结果表明:PSA-5A吸附CO2性能优于TC-5A,但对H2O的吸附率略低于TC-5A.H2O的存在对分子筛吸附CO2影响非常大,空气中相对湿度达到60%时,分子筛基本失去了吸附CO2的能力.此外,温度升高会造成CO2的吸附量显著下降,但对H2O的吸附量影响相对较小,尤其是当相对湿度较高时.这对中国未来长期运行的空间站分子筛CO2去除系统工作有效性与工作鲁棒性的评价具有指导意义.     

The search for nitrogen compounds on the surface of Mars

Nitrogen is an essential element for life. Specifically, “fixed nitrogen” (i.e., NH₃, NH₄⁺, NO_x, or N that is chemically bound to either inorganic or organic molecules and is releasable by hydrolysis to NH₃ or NH₄⁺) is the form of nitrogen useful to living organisms. To date no direct analysis of Martian soil nitrogen content, or content of fixed nitrogen compounds has been done. Consequently, the planet's total inventory of nitrogen is unknown. What is known is that the N₂ content of the present-day Martian atmosphere is 0.2 mbar. It has been hypothesized that early in Mars' history (3 to 4 billion years ago) the Martian atmosphere contained much more N₂ than it does today. The values of N₂ proposed for this early Martian atmosphere, however, are not well constrained and range from 3 to 300 mbar of N₂. If the early atmosphere of Mars did contain much more N₂ than it does today the question to be answered is, Where did it go? The two main processes that could have removed it rapidly from the atmosphere include: 1) nonthermal escape of N-atoms to space; and 2) burial within the regolith as nitrates and nitrites. Nitrate will be stable in the highly oxidized surface soil of Mars, and will tend to accumulate in the soil. Such accumulations are observed in certain desert environments on Earth. Some NH₄⁺---N may also be fixed and stabilized in the soil by inclusion as a structural cation in the crystal lattices of certain phyllosilicates replacing K. Analysis of the Martian soil for traces of NO₃⁻ and NH₄⁺ during future missions will supply important information regarding the nitrogen abundance on Mars, its past climate as well as its potential for the evolution of life.     

Preliminary calibration results of VEGA 1 and 2 SIGMA-3 gas chromatograph

SIGMA - 3 gas chromatograph on board VEGA 1 and 2 landing probes has been operated successfully in the 60 - 50 km altitude range, providing several in - situ chemical analysis of the gas and the aerosols of Venus cloud layers. Post flight calibration required to derive atmospheric abundancies from gas chromatograms were carried out using the SIGMA - 3 spare model. A Venus atmospheric aerosol simulation chamber was used in which sulfuric acid droplets were generated. Preliminary results of these calibration experiments indicate that the concentration of sulfuric acid in the upper part of the clouds ( 60 to 55 km) is about 1 mg/m³ and suggest that an additional constituant must be present in noticeable amount in the aerosols. From these experiments the mixing ratio upper limits of SO₂ is 100 ppmV and of H₂S and COS is few 10 ppmV.     

受控生态生保系统内红萍供氧特性研究

研究红萍载人供O₂特征, 为红萍生物部件进行系统总体地面模拟试验及空间应用奠定基础,构建了受控生态生保系统密闭试验舱和红萍栽培装置, 在“红萍-鱼-人”共存情况下, 测定密闭舱内O₂, CO₂浓度的变化. 试验结果显示, 单位重量的鱼耗O₂量. 0805～0.0831 L·kg-1·h-1, 排放CO₂量为0.0705～0.0736 L·kg-1·h-1; 试验志愿者耗O₂量19.71 L·h-1, 呼吸释放CO₂量18.90 L·h-1. 人工光照保持7000～8000 lx条件下, 红萍的光合作用与人和鱼的呼吸作用相辅相成, 舱内O₂, CO₂浓度趋于平衡. 密闭舱内CO₂浓度升高对促进红萍群体净光合效率有明显效果, 红萍光合放O₂能力很强, 能有效促使密闭舱内O₂, CO₂浓度朝着有利于人生存的环境方向平衡, 进而验证了红萍的空间应用前景.