Fabrication of Diamond-like Carbon Films by Ion Assisted Middle Frequency Unbalanced Magnetron Sputtering

Diamond-like carbon (DLC) films are deposited by the Hall ion source assisted by the mid-frequency unbalanced magnetron sput-tering technique. The effects of the substrate voltage bias, the substrate temperature, the Hall discharging current and the argon/nitrogen ratio on the DLC film’s performance were studied. The experimental results show that the film’s surface roughness, the hardness and the Young’s modulus increase firstly and then decrease with the bias voltage incrementally increases. Also when the substrate temperature rises, the surface roughness of the film varies slightly, but its hardness and Young’s modulus firstly increase followed by a sharp decrease when the temperature surpassing 120 ℃. With the Hall discharging current incrementally rising, the hardness and Young’s modulus of the film decrease and the surface roughness of the film on 316L stainless steel firstly decreased and then remains constant.     

化学镀镍层对30CrMo及LY12疲劳性能的影响

研究了两种不同磷含量化学镀镍层的组织结构、硬度及弹性模量,并着重研究了３０ＣｒＭｏ及ＬＹ１２经化学镀镍后的旋转弯曲疲劳性能。结果表明,低磷微晶镀层较高磷非晶镀层具有更高的硬度、弹性模量和疲劳抗力;化学镀镍层导致了３０ＣｒＭｏ疲劳强度的显著下降,但能提高ＬＹ１２的疲劳强度,表明化学镀镍层对基体疲劳性能的影响作用主要取决于基体本身疲劳抗力的高低。     

有机硅改性聚氨酯的制备及其对有机-无机层合玻璃性能的影响

以聚丙二醇和异佛尔酮二异氰酸酯为合成单体,γ-氨丙基三乙氧基硅烷(KH-550)为有机硅源,采用预聚体法合成有机硅改性聚氨酯,并以其为中间粘接层,制备有机-无机层合玻璃。研究不同有机硅含量对改性聚氨酯光学性能、机械性能以及有机-无机层合玻璃界面粘接性能的影响。结果表明:在相同聚合条件下,随着KH-550含量增加,聚氨酯聚合程度降低,导致透明度降低、雾度增大,表面硬度降低;改性聚氨酯初始储能模量先增大后减小,硬段的玻璃化转变温度先增大后减小,均在KH-550添加量为1%时达到最大值。以聚氨酯胶层作为层合玻璃中间层,未改性的层合玻璃界面剪切强度为6.7 MPa,含有0.5%KH-550的层合玻璃界面剪切强度达到7.7 MPa。     

热障涂层杨氏模量和泊松比的测试

为了降低航空发动机热端部件的温度,空气等离子喷涂已被广泛地应用。为确定热障涂层的残余应力、结合力、断裂韧性、疲劳裂纹扩展速率等性能和特性,需要知道其杨氏模量和泊松比。因为涂层厚度非常薄且使用时是结合在基体上的,所以需要一个能够在原处测量涂层的杨氏模量和泊松比的方法。采用等离子喷涂工艺在GH150高温合金上喷涂了MCrAIY和陶瓷层,利用一种改进的悬臂梁方法测量了热障涂层的杨氏模量和泊松比。这种无损测试方法为测定其他薄膜材料的杨氏模量和泊松比提供了借鉴。     

溅射工艺对TiAlN薄膜摩擦学性能的影响

研究利用反应磁控溅射法在高速钢基体上制备TiAlN薄膜材料,采用XRD测试薄膜晶体结构,用UMT显微力学测试仪测试薄膜摩擦系数.在此基础上讨论铝含量、直流偏压及后期处理对薄膜摩擦系数的影响.结果表明,不同铝含量的TiAlN薄膜中都存在面心立方相和六方相,随着铝含量的增高,面心立方相比例逐渐减小,六方相增多.铝的引入使膜层的硬度明显提高.随着Al含量增加,GCr15与TiAlN膜层之间的摩擦系数下降.另外,直流偏压和后期处理亦可显著改善薄膜的抗摩擦性能.     

Kinetic Monte Carlo Simulation of EB-PVD Film:Effects of Substrate Temperature

The 2D kinetic Monte Carlo (KMC) simulation was used to study the effects of different substrate temperatures on the microstruc-ture of Ni-Cr films in the process of deposition by the electron beam physical vapor deposition (EB-PVD). In the KMC model, substrate was assumed to be a “surface” of tight-packed rows, and the simulation includes two phenomena: adatom-surface collision and adatom diffusion. While the interaction between atoms was described by the embedded atom method, the jumping energy was calculated by the molecular static (MS) calculation. The initial location of the adatom was defined by the Momentum Scheme. The results reveal that there exists a critical substrate temperature which means that the lowest packing density and the highest surface roughness structure will be achieved when the temperature is lower than the smaller critical value, while the roughness of both surfaces and the void contents keep decreasing with the substrate temperature increasing until it reaches the higher critical value. The results also indicate that the critical substrate temperature rises as the deposition rate increases.     

Preparation and Mechanical Properties of Glass Coats with High Temperature Radar Absorber

BaO-La2O3-B2O3 (BLB) glass, suitable to be used as a sealing between metals, was chosen to be the binder in preparing glass coats on the Ti-alloy substrate. The SiCN nano-powder was introduced as the filler for the absorbing coat because it is considered to be a good high temperature absorber. The effect of the coating temperature and coating time on the tensile strength of the glass coat was investigated and the proper coating parameters to get good mechanical properties were determined. In addition, the effects of the SiCN content on the tensile strength of the absorbing coat were also discussed. Results show that it is possible to prepare the glass coat using the BLB glass as a binder. That the coat formed at 730 ℃ for 30 min has the best tensile strength witnesses 730 ℃, 30 min to be the proper parameter to prepare the glass coat. The BLB glass coat without SiCN powder possesses good tensile strength and the introduc-tion of the SiCN absorber into the glass coat will lower the tensile strength. As the SiCN content increases, the tensile strength of the absorbing coat decreases, which could be attributed to the aggregation of SiCN in the coats.     

Preparation and Microstructure of Highly-Oriented LaNiO_3 Thin Films by RF Sputtering Method

In an attempt of being used as buffer layers and electrodes for the textured BaTiO3 (BTO) ferroelectric thin films, highly (100)-oriented LaNiO3 (LNO) thin films of different thicknesses were deposited directly on Si (100) substrate with radio-frequency (RF) magnetron sputtering method. It is observed that the substrate temperatures and the film thicknesses bring main influences on the micro-structures and orientation of the thin film. The effects of the thicknesses and substrate temperatures on the orientation of the films were studied on the LNO films of different thicknesses. The highly (100)-oriented LNO thin films were obtained at the substrate temperature of 600 ℃. The existence of epitaxially grown BTO films indicates that the oriented LNO thin films obtained in this work could be used as a buffer layer for epitaxial growth.     

纳米压痕技术表征T800碳纤维的弹性模量和硬度

利用纳米压痕技术对T800SC碳纤维不同取向(纤维轴向与纳米压痕测试面成θ夹角)的弹性模量和硬度进行了测试,结合Weibull分布函数对T800SC碳纤维不同取向的弹性模量和硬度进行统计分析。结果表明:随着测试面与纤维轴向夹角的增大,T800SC碳纤维的弹性模量和硬度逐渐增大。T800SC碳纤维的弹性模量从平行纤维轴向时的(15.84±2.00)GPa增加到垂直纤维轴向时的(50.96±5.73)GPa;T800SC碳纤维的硬度从平行纤维轴向时的(2.71±0.51)GPa增加到垂直纤维轴向时的(5.24±0.91)GPa。对于纤维不同取向的弹性模量,其Weibull模数在9.0~10.5;对于纤维不同取向的硬度,其Weibull模数在6.0~8.0。     

Preparation,Growth Mechanisms and Characterizations of ZnSe Films via the Solvothermal Method

With diethylamine as a solvent, ZnSe films were formed on the Si substrate directly from zinc and selenium through the modified solvothermal method. The effects of holding temperature, deposition time and substrate surface treatment on the quality and morpholo-gies of the ZnSe films were investigated. The growth mechanism of ZnSe films was proved to be a layer-nucleation growth process, which was tied in with the Stranski-Krastanov (SK) model. ZnSe films were identified by the X-ray diffraction pattern (XRD), the scan-ning electron microscope (SEM), the X-ray photoelectron spectroscope (XPS) and the photoluminescence (PL) techniques. The results indicate that the modified solvothermal method with diethylamine as a solvent is suitable to prepare high quality ZnSe films.     

可见光迷彩低红外发射率薄膜制备及其特性

采用多弧离子镀技术,在Al基底上制备了TiO2/TiN多层膜。通过控制基底材料的粗糙度使制备出的薄膜在可见波段具有非镜面反射效果。采用扫描电镜、红外辐射率测量仪、紫外-可见-近红外光光度计等测试手段对薄膜样品进行了表征。结果表明,采用多弧离子镀法在Al基底上制备了结合力良好、具有迷彩效果的低红外发射率薄膜。研究发现,随氧化层厚度增加,薄膜发射率趋向稳定(0.2左右)。薄膜电阻随氧化层厚度的变化无明显变化。     

用离子束辅助沉积(IBAD)工艺制备TiCxNy膜的研究

用离子束辅助沉积（ＩＢＡＤ）工艺在９Ｃｒ１８、ＧＣｒ１５钢基体上形成了ＴｉＣｘＮｙ膜。ＴＥＭ观察发现膜均呈多晶结构,都具有（１１１）、（２００）和（２２０）择优取向。ＡＥＳ和ＸＰＳ分析进一步证实,ＴｉＣｘＮｙ膜呈含氧配置。干摩擦表明膜的抗氧化性能优良,其存在能有效抑制基体在摩擦过程中氧化膜的形成。又由于膜的硬度高,润滑性良好,每种基体的磨损特性都得到了显著地改善。但随着基体不同,膜的力学机械性能随     

C/G层内混杂复合材料力学性能的实验研究

研究了C／G(碳／玻)层内混杂单向复合材料的力学性能，对其拉伸、弯曲、层间剪切、振动阻尼等性能进行了实验研究，并与同样铺层的纯C、G复合材料进行了对比分析。研究表明：C／G层内混杂复合材料可充分利用C、G纤维的各自优点，改善单一材料的模量、强度、断裂韧性、振动阻尼特性等力学性能，模量预测值与实验值较为接近，强度因影响因素较多，二者存在一定的差异，力学性能随C、G体积分数的变化符合混合律，说明了实验方法的合理性。通过C、G相对体积分数的合理设计可满足结构的实际要求。     

γ-TiAl金属间化合物合金激光表面合金化组织与摩擦学性能

分别利用预涂活性碳粉和 Ti C粉 2种方法对γ-Ti Al基合金 Ti-4 8Al-2 Cr-2 Nb进行激光表面合金化,制得了无裂纹、表面光滑、内部组织致密、厚度可达 1.6mm以上的、以硬质 Ti C树枝晶为增强相的快速凝固“原位”金属基耐磨复合材料表面改性层,分别采用 OM,SEM,EDS,XRD等方法分析了激光合金化耐磨表面改性层的显微组织,分别在销 -环滑动磨损、Si C纤维刷式高速滑动磨损及微动磨损条件下评价了激光表面改性层的摩擦学性能。结果表明 :采用上述 2种方法所获激光表面合金层组织均匀、与基体间结合为完全冶金结合,合金层硬度及在 3种磨损条件下的耐磨性均大幅度提高。激光表面合金化是提高γ-Ti Al合金摩擦性能的一种很有前途的表面改性方法     

基于频响函数的复合材料空间分布模量场识别

针对纤维编织复合材料宏观力学性能的非均匀特性,提出了基于频响函数(FRF)的复合材料梁空间分布弹性模量场的识别方法。采用基于灵敏度分析的方法构造优化问题,以实测和计算加速度频响残差范数最小为目标函数,进而通过迭代求解识别出复合材料梁弹性模量的空间分布。首先,以悬臂梁模型为研究对象进行数值仿真分析,验证识别方法的正确性。进一步开展复合材料梁模态试验研究,将复合材料三点弯曲试验获取的近似均质化弹性模量作为优化问题的初值;利用非接触测量方法获取模态试验中梁上各测点处的动位移响应,并计算得到各测点的加速度频响函数作为优化问题的输入值。结果表明:采用所提出的识别方法获取的模量场计算得到的梁上各处频响函数与试验获取值吻合,且所提方法在实测动响应存在噪声污染工况下是可行的。该方法能够为复合材料等效建模提供更加准确的弹性模量场。     

High-temperature tribological behaviors of a Cr-Si co-alloyed layer on TA15 alloy

A Cr-Si co-alloyed layer was successfully deposited on TA15 alloy by the double glow plasma surface technology to improve its poor wear resistance at elevated temperature.The microstructure,composition,and phase structure of the layer were investigated by SEM,EDS,and XRD.The tribological behaviors of the Cr-Si co-alloyed layer at 20 ℃ and 500 ℃ were analyzed in details.The results indicated that the friction coefficient and wear rate of the Cr-Si coalloyed layer at 20 ℃ and 500 ℃ were much lower than those of the substrate,which was due to higher hardness and superior elastic modulus.This layer may become an approach to effectively improving the wear resistance of TA15 alloy at elevated temperature.     

Near-Field Seismic Propagation and Coupling Through Mars’ Regolith: Implications for the InSight Mission

NASA’s InSight Mission will deploy two three-component seismometers on Mars in 2018. These short period and very broadband seismometers will be mounted on a three-legged levelling system, which will sit directly on the sandy regolith some 2–3 meters from the lander. Although the deployment will be covered by a wind and thermal shield, atmospheric noise is still expected to couple to the seismometers through the regolith. Seismic activity on Mars is expected to be significantly lower than on Earth, so a characterisation of the extent of coupling to noise and seismic signals is an important step towards maximising scientific return.In this study, we conduct field testing on a simplified model of the seismometer assembly. We constrain the transfer function between the wind and thermal shield and tripod-mounted seismometers over a range of frequencies (1–40 Hz) relevant to the deployment on Mars. At 1–20 Hz the displacement amplitude ratio is approximately constant, with a value that depends on the site (0.03–0.06). The value of the ratio in this range is 25–50% of the value expected from the deformation of a homogeneous isotropic elastic halfspace. At 20–40 Hz, the ratio increases as a result of resonance between the tripod mass and regolith. We predict that mounting the InSight instruments on a tripod will not adversely affect the recorded amplitudes of vertical seismic energy, although particle motions will be more complex than observed in recordings generated by more conventional buried deployments. Higher frequency signals will be amplified by tripod-regolith resonance, probably reaching peak-amplification at \(\sim 50\) Hz. The tripod deployment will lose sensitivity at frequencies \(>50\) Hz as a result of the tripod mass and compliant regolith.We also investigate the attenuation of seismic energy within the shallow regolith covering the range of seismometer deployment distances. The amplitude of surface displacement decays as \(r^{-n}\), where \(1.5 < n < 2\). This exceeds the value expected for a homogeneous isotropic elastic halfspace (\(n \sim 1\)), and reflects an increase in Young’s modulus with depth. We present an updated model of lander noise which takes this enhanced attenuation into account.     

化学镀Ni-P合金涂层及其耐磨性

 对化学镀 Ni- P的硬度和耐磨性的关系进行了研究。低温长时加热可以获得高硬度 ,继续保温后其值不变。高温加热硬度达最大硬度以后保温硬度降低。不同温度处理其最大值相同 ,但耐磨性不同 ,高温处理优于低温处理。光电子能谱分析表明镀层表面富磷     

树脂基体的韧性对复合材料力学性能的影响

以双酚A型环氧树脂——无规羧基丁腈橡胶——2-乙基-4-甲基咪唑体系为代表,考察了树脂基体的韧性对单向玻璃纤维复合材料力学性能的影响。试验结果表明:随着树脂基体韧性的提高,所得复合材料的伉断裂性能相应地增加,但提高的幅度较树脂基体本身韧性的提高值小;复合材料的短梁剪切强度、除拉伸模量以外的横向力学性能也随树脂基体韧性的增加而提高,而弯曲性能及纵向力学性能受树脂基体韧性的影响不明显。     

用离子束辅助沉积(IBAD)工艺制备TiCxNy膜的研究

TiC_xN_y films were formed on 9Cr18 and GCr15 substrates using ion beam assisted deposition and studied with TEM, AES and XPS. TEM results showed that the films have polycrystalline structure with preferential growth orientations in (111),(200) and (220) directions. The AES and XPS results confirmed that the TiC_xN_y films contain oxygen coordination. The dry friction test indicated that oxidation resistance of the films is excellent, formation of the oxide film in the friction process can be effectively inhibited because of its presence on the steel substrates. At the same time,the wear properties of substrates were obviously improved because of high hardness and excellent lubriction of the films. However, the mechanical properties of TiC_xN_y films deposited by different N fluence appear different variance rule with the diffrent substrates. Microhardness and friction properties of TiC_xN_y films are relative to its N content and a excessively high N content has a harmful influence on the hardness and friction properties.