Volatile Trapping in Martian Clathrates

Thermodynamic conditions suggest that clathrates might exist on Mars. Despite observations which show that the dominant condensed phases on the surface of Mars are solid carbon dioxide and water ice, clathrates have been repeatedly proposed to play an important role in the distribution and total inventory of the planet’s volatiles. Here we review the potential consequences of the presence of clathrates on Mars. We investigate how clathrates could be a potential source for the claimed existence of atmospheric methane. In this context, plausible clathrate formation processes, either in the close subsurface or at the base of the cryosphere, are reviewed. Mechanisms that would allow for methane release into the atmosphere from an existing clathrate layer are addressed as well. We also discuss the proposed relationship between clathrate formation/dissociation cycles and how potential seasonal variations influence the atmospheric abundances of argon, krypton and xenon. Moreover, we examine several Martian geomorphologic features that could have been generated by the dissociation of extended subsurface clathrate layers. Finally we investigate the future in situ measurements, as well as the theoretical and experimental improvements that will be needed to better understand the influence of clathrates on the evolution of Mars and its atmosphere.     

The PROCESS experiment: an astrochemistry laboratory for solid and gaseous organic samples in low-earth orbit

The PROCESS (PRebiotic Organic ChEmistry on the Space Station) experiment was part of the EXPOSE-E payload outside the European Columbus module of the International Space Station from February 2008 to August 2009. During this interval, organic samples were exposed to space conditions to simulate their evolution in various astrophysical environments. The samples used represent organic species related to the evolution of organic matter on the small bodies of the Solar System (carbonaceous asteroids and comets), the photolysis of methane in the atmosphere of Titan, and the search for organic matter at the surface of Mars. This paper describes the hardware developed for this experiment as well as the results for the glycine solid-phase samples and the gas-phase samples that were used with regard to the atmosphere of Titan. Lessons learned from this experiment are also presented for future low-Earth orbit astrochemistry investigations.     

Solar Irradiance Variability Since 1978

Since November 1978 a set of total solar irradiance (TSI) measurements from space is available, yielding a time series of more than 25 years. Presently, there are three TSI composites available, called PMOD, ACRIM and IRMB, which are all constructed from the same original data, but use different procedures to correct for sensitivity changes. The PMOD composite is the only one which also corrects the early HF data for degradation. The results from the detailed analysis of the VIRGO radiometry allow a good understanding of the effects influencing the long-term behaviour of classical radiometers in space. Thus, a re-analysis of the behaviour of HF/NIMBUS-7 and ACRIM-I/SMM was indicated. For the former the situation is complicated by the fact that there are no in-flight means to determine changes due to exposure to solar radiation by comparison with a less exposed radiometer on the same spacecraft. The geometry and optical property of the cavity of HF is, however, very similar to the PMO6-type radiometers, so the behaviour of the PMO6V radiometers on VIRGO can be used as a model. ACRIM-I had to be revised mainly due to a henceforth undetected early increase and a more detailed analysis of its degradation. The results are not only important for solar radiometry from space, but they also provide a more reliable TSI during cycle 21. The differences between the revised PMOD composite and the ACRIM and IRMB are discussed by comparison with a TSI reconstruction from Kitt-Peak magnetograms. As the PMOD composite is the only one which has reliable data for cycle 21, the behaviour of the three solar cycles can now be compared and the similarities and differences discussed.     

Solar radiometry: Total irradiance measurements

The operating principles of modern absolute radiometers are discussed and the methods of their characterization, that is the accurate determination of the uncertainties, are described. In view of this analysis, the results of the solar constant determinations of the last 6 years are reviewed and an estimate of their uncertainties given. Procedures for the strategy of future experiments are recommended.     

Potential fossil endoliths in vesicular pillow basalt, Coral Patch Seamount, eastern North Atlantic Ocean

The chilled rinds of pillow basalt from the Ampère-Coral Patch Seamounts in the eastern North Atlantic were studied as a potential habitat of microbial life. A variety of putative biogenic structures, which include filamentous and spherical microfossil-like structures, were detected in K-phillipsite-filled amygdules within the chilled rinds. The filamentous structures (～2.5 μm in diameter) occur as K-phillipsite tubules surrounded by an Fe-oxyhydroxide (lepidocrocite) rich membranous structure, whereas the spherical structures (from 4 to 2 μm in diameter) are associated with Ti oxide (anatase) and carbonaceous matter. Several lines of evidence indicate that the microfossil-like structures in the pillow basalt are the fossilized remains of microorganisms. Possible biosignatures include the carbonaceous nature of the spherical structures, their size distributions and morphology, the presence and distribution of native fluorescence, mineralogical and chemical composition, and environmental context. When taken together, the suite of possible biosignatures supports the hypothesis that the fossil-like structures are of biological origin. The vesicular microhabitat of the rock matrix is likely to have hosted a cryptoendolithic microbial community. This study documents a variety of evidence for past microbial life in a hitherto poorly investigated and underestimated microenvironment, as represented by the amygdules in the chilled pillow basalt rinds. This kind of endolithic volcanic habitat would have been common on the early rocky planets in our Solar System, such as Earth and Mars. This study provides a framework for evaluating traces of past life in vesicular pillow basalts, regardless of whether they occur on early Earth or Mars.     

Investigation of the Influence of Magnetic Anomalies on Ion Distributions at Mars

Using data from the Mars Express Ion Mass Analyzer (IMA) we investigate the distribution of ion beams of planetary origin and search for an influence from Mars crustal magnetic anomalies. We have concentrated on ion beams observed inside the induced magnetosphere boundary (magnetic pile-up boundary). Some north-south asymmetry is seen in the data, but no longitudinal structure resembling that of the crustal anomalies. Comparing the occurrence rate of ion beams with magnetic field strength at 400 km altitude below the spacecraft (using statistical Mars Global Surveyor results) shows a decrease of the occurrence rate for modest (< 40 nT) magnetic fields. Higher magnetic field regions (above 40 nT at 400 km) are sampled so seldom that the statistics are poor but the data is consistent with some ion outflow events being closely associated with the stronger anomalies. This ion flow does not significantly affect the overall distribution of ion beams around Mars.     

Determination of aerosol optical depth from ground measurements

The methods used to determine the aerosol optical depth as a function of wavelength are briefly described and discussed. Some results from the operational network of the World Meteorological Organization and other, more research oriented studies, are reviewed and critically analysed to assess the reliability and accuracy of such determinations and their value as ground truth measurements for space applications.     

The elemental composition in energetic particle events at high heliospheric latitudes

The relative abundances of low energy ions (0.6–2.0 MeV/n) in solar energetic particle (SEP) and corotating interaction region (CIR) events have been measured by the EPAC experiment aboard Ulysses since launch in October 1990 until the present time. We give an overview of the abundances of heavy ions (He, C, Ne, Fe) relative to oxygen during energetic particle events lasting longer than 5 days during the in- and out-of-ecliptic phase of the mission. While the period Oct. 1990 to Aug. 1992 was dominated by high solar activity the Ulysses out of ecliptic passage at solar latitudes up to 45° went parallel to the declining phase of solar activity. Thus a very clear structure of corotating interaction regions was observed. While the in-ecliptic composition is in general agreement with measurements made near the Earth, the development of the CIR-composition shows two phases: From Aug. 1992 to May 1993 the C/O-ratio is 0.55–0.70, afterwards it increases to 0.8–0.9. This increase is correlated to the disappearance of the current sheet at 30° solar latitude reported by Smithet al. (1993).     

Using Precise Solar Limb Shape Measurements to Study the Solar Cycle

Despite 20 years of total solar irradiance measurements from space, the lack of high precision spatially resolved observations limits definitive answers to even simple questions like ``Are the solar irradiance changes caused solely by magnetic fields perturbing the radiative flux at the photosphere?" More subtle questions like how the aspheric structure of the sun changes with the magnetic cycle are only now beginning to be addressed with new tools like p-mode helioseismology. Solar 5-min oscillation studies have yielded precise information on the mean radial interior solar structure and some knowledge about the rotational and thermal solar asphericity. Unfortunately this progress has not been enough to generate a self-consistent theory for why the solar irradiance and luminosity vary with the magnetic cycle. We need sharper tools to describe and understand the sun's global aspheric response to its internal dynamo, and we need to be able to measure the solar cycle manifestation of the magnetic cycle on entropy transport from the interior to the photosphere in much the same way that we study the fundamentally more complex problem of magnetic flux transport from the solar interior. A space experiment called the Solar Physics Explorer for Radius, Irradiance and Shape (SPHERIS) and in particular its Astrometric and Photometric Telescope (APT) component will accomplish these goals.

     

The Theory of Gamma-Ray Bursts

This chapter gives a brief review on the theory of gamma-ray bursts (GRBs), including the models of multi-messengers (e.g., prompt multiwavelength electromagnetic emissions, high-energy neutrinos, ultra-high-energy cosmic rays, and gravitational waves) and central engines (in particular, mergers of binary neutron stars for short GRBs). For detailed reviews, please see (Piran in Phys. Rep. 314:575, 1999; Rev. Mod. Phys. 76:1143, 2004; Mészáros in Annu. Rev. Astron. Astrophys. 40:137, 2002; Rep. Prog. Phys. 69:2259, 2006; Zhang and Mészáros in Int. J. Mod. Phys. A 19:2385, 2004; Zhang in Chin. J. Astron. Astrophys. 7:1, 2007; Nakar in Phys. Rep. 442:166, 2007; Kumar and Zhang in Phys. Rep. 561:1, 2015).