激光快速熔凝Al2O3/YAG共晶陶瓷的制备与组织

采用激光快速熔凝技术制备Al₂O₃/YAG共晶自生复合陶瓷, 研究Al₂O₃/YAG共晶陶瓷在高能激光束作用下,不同扫描速率(0.01~2.0mm/s)、超高温度梯度下的凝固组织特征及其生长机制,探索激光熔凝过程控制参数与凝固组织的关系.研究结果表明:激光熔凝Al₂O₃/YAG共晶陶瓷由无规则连续分布的Al₂O₃相和YAG相两相组成,没有晶界和其他相,Al₂O₃相的体积分数为(45.0±2.0)%,两相耦合生长,交错分布,是典型的快速凝固层片状非规则共晶组织;共晶层间距细密, 并随激光扫描速度的增大而减小,扫描速度为0.02mm/s 时,共晶间距约为1~2μm,扫描速度为2.0mm/s时,共晶间距仅为0.5μm左右;综合热分析表明,Al₂O₃/YAG共晶熔点为2096K,与相图吻合.     

Vertical distribution of NH3 in the upper Jovian atmosphere from IUE observations

The first unambiguous identification of ammonia in the upper atmosphere of Jupiter has been obtained from the observation of individual NH₃ bands in an IUE high resolution spectrum in the 2100–2400 Å spectral range. The variation with wavelength of the strengths of these NH₃ bands implies that the NH₃ abundance has to be strongly reduced by photolysis in the upper jovian atmosphere. Preliminary analysis by means of scattering models shows that the ammonia mixing ratio cannot be constant with altitude. The mixing ratio NH₃/H₂ ranges from 5 10^?8 to 5 10^?7 at the 250 mb pressure level, and decreases as P or P² toward higher altitudes.     

顺电相PbTiO3晶体的电子结构和光学性质

应用全电势线形平面波缀加方法对铁电晶体钛酸铅的顺电立方相的电子能带结构、态密度、电子密度分布进行了计算.能带结构的计算结果表明立方顺电相晶体PbTiO₃为直接带隙的半导体,带隙大小为1.7eV.通过态密度和电子密度的计算结果分析,得到价带和导带的电子组成情况,并且指出Ti原子和O原子存在较强的共价键合.在电子结构的计算基础上,计算得到了与实验符合较好的PbTiO₃晶体的介电函数的实部和虚部,分析了虚部所对应的能带跃迁,并得到了其它的光学性质的参数(光学吸收系数、折射率、消光系数、能量损失曲线、反射率).     

The neutral particle impact de-excitation cross-section of the fine structure level3P1 of atomic oxygen in the thermosphere

A new upper limit value (9.9 × 10^?21cm²) of the mean equivalent de-excitation cross-section of O(³P₁) by collision with neutral particles in the thermosphere is obtained by comparing the³P₁ state de-excitation rate due to neutral practice impact with that due to electron impact. The existing data of the cross-section obtained from the aeronomic study are compared with the theoretical data, and it indicated that the former is much less than the latter.     

Estimation of the elastic Earth parameters (h2, l2) using SLR data

We present results for the global elastic parameters h₂ and l₂ derived from the analysis of Satellite Laser Ranging (SLR) data. SLR data for the two satellites LAGEOS 1 and LAGEOS 2 observed during 2.5 years from January 3, 2005 until July 1, 2007 with 18 globally distributed ground stations were analysed using different approaches. The analysis was done separately for the two satellites and approaches to estimate the two elastic parameters independently and together were performed. We do a sequential analysis and study the stability of the estimates as a function of length of the data set used. The adjusted final values for h₂ equal to 0.6151 ± 0.0008 and 0.6152 ± 0.0008, and those for l₂ equal to 0.0886 ± 0.0003 and 0.0881 ± 0.0003 for LAGEOS 1 and LAGEOS 2 tracking data are compared to other independently derived estimates. These parameters and their errors achieve stability at about the 24 and 27 month time interval for h₂ and l₂, respectively.     

Plasma chemical reactions in C2H2/N2, C2H4/N2, and C2H6/N2 gas mixtures of a laboratory dielectric barrier discharge

Plasma chemical reactions in C₂H₂/N₂, C₂H₄/N₂, and C₂H₆/N₂ gas mixtures have been studied by means of mass spectrometry at a medium pressure of 300 mbar in a laboratory dielectric barrier discharge. A major reaction scheme is production of larger hydrocarbons like C_nH_m with n up to 12 including formation of functional CN groups.     

Measurement of minor species (H2, Cl,O3, NO) in the earth's atmosphere by the occultation technique

The stellar occultation technique is a clean and powerful means of detecting and quantifying minor gases in the earth's atmosphere. The results obtained are totally insensitive to knowledge of the absolute flux of the star, and are not influenced by instrument calibration problems. Pioneering observations of nocturnal mesospheric ozone and thermospheric molecular oxygen by the stellar occultation technique were made in 1970 and 1971 with the Wisconsin stellar photometers on board the Orbiting Astronomical Observatory-2. A limb crossing geometry was used. The high resolution Princeton ultraviolet spectrometer aboard Copernicus was used in the summers of 1975, 1976 and 1977 to measure altitude profiles of molecular hydrogen, atomic chlorine and nitric oxide in addition to ozone and molecular oxygen. A limb grazing geometry was employed. The ozone densities show wide variation from orbit to orbit and particularly betewen the OAO-2 and Copernicus observations. A H₂ density of 1×10⁸ cm^?3 at 95 km, and a NO density less than 10⁶ cm^?3 for altitudes greater than 85 km were measured.     

Pressure,O2, and CO2, in aquatic Closed Ecological Systems

Pressure increased during net photosynthetic O₂ production in the light and decreased during respiratory O₂ uptake during the dark in aquatic Closed Ecological Systems (CESs) with small head gas volumes. Because most CO₂ will be in the liquid phase as bicarbonate and carbonate anions, and CO₂ is more soluble than O₂, volumes of gaseous CO₂ and gaseous O₂ will not change in a compensatory manner, leading to the development of pressure. Pressure increases were greatest with nutrient rich medium with NaHCO₃ as the carbon source. With more dilute media, pressure was greatest with NaHCO₃, and less with cellulose or no-added carbon. Without adequate turbulence, pressure measurements lagged dissolved O₂ concentrations by several hours and dark respiration would have been especially underestimated in our systems (250–1000 ml). With adequate turbulence (rotary shaker), pressure measurements and dissolved O₂ concentrations generally agreed during lights on/off cycles, but O₂ measurements provided more detail. At 20 °C, 29.9 times as much O₂ will distribute into the gas phase as in the liquid, per unit volume, as a result of the limited solubility of O₂ in water and according to Henry’s Law. Thus even a small head gas volume can contain more O₂ than a larger volume of water. When both dissolved and gaseous O₂ and CO₂ are summed, the changes in Total O₂ and CO₂ are in relatively close agreement when NaHCO₃ is the carbon source. These findings disprove an assumption made in some of Taub’s earlier research that aquatic CESs would remain at approximately atmospheric pressure because approximately equal molar quantities of O₂ and CO₂ would exchange during photosynthesis and respiration; this assumption neglected the distribution of O₂ between water and gas phases. High pressures can occur when NaHCO₃ is the carbon source in nutrient rich media and if head-gas volumes are small relative to the liquid volume; e.g., one “worse case” condition developed 800 mm Hg above atmospheric pressure and broke the glass container. Plastic screw cap closures are likely to leak at high pressures and should not be assumed to seal unless tested at appropriate pressures. Pressure can be reduced by having larger head-gas volumes and using less concentrated nutrient solutions. It is important that pressure changes be considered for both safety and closure, and if total O₂ is used as the measure of net photosynthesis and respiration, the O₂ in the gas phase must be added to the dissolved O₂.     

Mesospheric H2O and H2O2 densities inferred from in situ positive ion composition measurement

The measurements of positive ion composition in the high latitude D-region have revealed an excess of 34⁺ under distrubed conditions which has been interpreted as H₂O₂⁺. At the same altitude range near the transition height oxonium ions were measured as well. This paper presents a new model for the production and loss of oxonium ions with their production from H₂O₂⁺ + H₂O → H₃O⁺ + HO₂ and their loss by attachment of N₂ and/or CO₂. A reaction constant of 8.5×10^?28 (300/T)⁴ cm⁶s^?1 has been obtained for the three body attachment H₃O⁺ + CO₂ + M → H₃O⁺.CO₂ + M from the measured density profile of 63⁺ in flight 18.1020. Mesospheric H₂O and H₂O₂ densities are inferred from measurements of four high latitude ion compositions based on the oxonium model. The mixing ratios of hydrogen peroxide are up to two orders of magnitude higher compared to previous model calculations. In order to explain the missing production of odd hydrogen, we consider larger O(¹D) densities, surface reactions of O(³P) on particles, and cathalytic photodissociation of water vapor on aerosol particles.     

The variability and predictability of the IRI B0, B1 parameters over Grahamstown,South Africa

The International Reference Ionosphere (IRI) parameters B₀ and B₁ provide a representation of the thickness and shape, respectively, of the F2 layer of the bottomside ionosphere. These parameters can be derived from electron density profiles that are determined from vertical incidence ionograms. This paper aims to illustrate the variability of these parameters for a single mid latitude station and demonstrate the ability of the Neural Network (NN) modeling technique for developing a predictive model for these parameters. Grahamstown, South Africa (33.3°S, 26.5°E) was chosen as the mid latitude station used in this study and the B₀ and B₁ parameters for an 11 year period were determined from electron density profiles recorded at that station with a University of Massachusetts Lowell Center for Atmospheric Research (UMLCAR) Digisonde. A preliminary single station NN model was then developed using the Grahamstown data from 1996 to 2005 as a training database, and input parameters known to affect the behaviour of the F2 layer, such as day number, hour, solar and magnetic indices. An analysis of the diurnal, seasonal and solar variations of these parameters was undertaken for the years 2000, 2005 and 2006 using hourly monthly median values. Comparisons between the values derived from measured data and those predicted using the two available IRI-2001 methods (IRI tables and Gulyaeva, T. Progress in ionospheric informatics based on electron density profile analysis of ionograms. Adv. Space Res. 7(6), 39–48, 1987.) and the newly developed NN model are also shown in this paper. The preliminary NN model showed that it is feasible to use the NN technique to develop a prediction tool for the IRI thickness and shape parameters and first results from this model reveal that for the mid latitude location used in this study the NN model provides a more accurate prediction than the current IRI model options.     

Annealing of Hg2Cl2 crystals — Project of the experiment

The creep of polycrystalline Hg₂X₂ (where X = Cl, Br, J) under the terrestrial and space conditions is studied in the present experiment. The authors suppose that the creep of the Hg₂X₂ cylindrical sample can be studied by the help of the theory of micropolar (non-Newtonian) fluids. In accordance with this theory we obtain the flux of fluid through any cross-section as functions of the radius, viscosity coefficients, the gradient of pressure and the gravity acceleration. In this paper a comparison of the theoretical results for normal and zero- gravity conditions is given. It is shown that the annealing of materials having a broad region of plasticity under microgravity conditions can lead to great improvement in optical as well as mechanical qualities of the crystal. Technical aspects of the experiment are also described.     

Study of satellite retrieved CO2 and CH4 concentration over India

This paper reports a study of spatial and temporal variations of columnar averaged concentration of CO₂ and CH₄ over India using SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) and Greenhouse gas Observing SATellite (GOSAT) data. Comparison of these data with the global view National Oceanic and Atmospheric Administration (NOAA) land data and also location specific flask data is made. The temporal variation in column averaged global CO₂ is similar to that over India and it is also similar to the NOAA surface flask data and global view. The variation in NOAA surface CH₄ is location dependent and its global view appears to vary seasonally in opposite phase with the column averaged CH₄ values from satellites, reflecting the limited comparability of surface and column averaged data. Over India the CO₂ maximum is in May and minimum in August/September while for CH₄ the maximum is in September and minimum in February/March. The seasonal variation of CH₄ over India is correlated with the eastern coastal rice cultivation.     

Variation of monthly mean foF2 and hmF2 over a mid latitude station during the period 1997–2006

Ionosonde data of a mid latitude station Novosibirsk (Geog. Lat. 54.6°N, Geog. Long. 83.2°E) has been analyzed for the years 1997–2006 that covers the major part of solar cycle 23. Our results show the presence of winter anomaly in the daytime F2 layer critical frequency during different phases of solar activity. Results also reveal a semiannual variation of foF₂ with two maxima and a minimum that always appears in summer. While the first maximum is in the spring equinox, the second one is found to shift from autumn to winter with the increase of solar activity. The maximum height of F2 layer during the daytime shows variation with the solar activity. It is higher during the higher activity periods and lower during the periods of low activity. Results of ionosonde observations have been compared with those obtained from IRI-2007 model and it is found that model reproduces gross features of foF₂ variation. However, the modeled hmF₂ variations during equinoxes are significantly different from the ones derived using the ionosonde data. The model also underestimates the hmF₂ values.     

On the correlation of microwave bursts with the Hα flares

High correlation between microwave bursts and H_α flares has already been reported. However, Solar Maximum Year cooperation made it possible to do simultaneous observations of selected active regions with good spatial resolution. In this paper the results of the direct comparison of solar microwave recordings at the Metsähovi Radio Research Station and H_α films at the Hvar Observatory are reported. This comparison reveals that the correlation of microwave gradual rise and fall (GRF) events (time scale tens of minutes) with H_α flares is practically 100 percent. On the other hand the correlation of the impulsive microwave bursts (time scale tens of seconds) with H_α flares is low. From this it can be concluded that the main contribution to the microwave GRF bursts comes from thermal radiation.     

氨合成-水热改性法制备氢氧化镁阻燃剂

为了解决氢氧化镁和聚合物之间的不相容问题, 对氨合成法-水热改性处理2步法制备高分散氢氧化镁阻燃剂进行了研究,分析了常温合成温度、水热改性温度和水热改性时间对制备大晶型、低比表面积氢氧化镁阻燃剂的影响.结果表明,经过水热改性处理改变了氢氧化镁晶体的生长习性,生成了形貌规则、粒径分布均匀、分散性良好的氢氧化镁六方片状颗粒.另外通过提高氯化镁浓度和氨水过量1倍,探讨了常温合成反应的转化率,认为应该在反应原料等当量下寻求提高转化率的可行方法.     

含SiO2,ZrO2微粒复合镀镍层抗高温氧化性能

通过对含有SiO₂,ZrO₂微粒复合电沉积的研究,在Cu合金表面分别获得了含量(原子数分数)为11.3％ SiO₂,5.31％ ZrO₂微粒的Ni基复合镀层.通过在800℃、900℃条件下的高温氧化和热震循环试验,研究了这种复合镀镍层的高温氧化性能和界面结合特性.结果表明:经过40?h的高温氧化,2种复合镀镍层的抗氧化性能均达到抗氧化级,而且含SiO₂微粒的复合镀镍层的抗氧化性能优于含ZrO₂微粒的复合镀镍层;经过55次冷热循环,含SiO₂微粒的复合镀镍层与铜基体结合良好.     

Hall MHD reconnection with an initial guide field By0

An uniform out-of-plane magnetic field component B_y0 is added to the equilibrium Harris sheet with plasma β = 0.5 and L_c = 0.5d_i (where L_c is the half-width of the equilibrium current layer and d_i is the ion inertial length). Driven by the continuous boundary inflows, the magnetic reconnections with the guide field B_y0/B₀ ranging from 0 to 4.0 are investigated using a 2.5D Hall magnetohydro-dynamic (MHD) code developed from a multi-step implicit scheme. The features of the reconnection field are substantially altered in the presence of the guide field. The openness of the magnetic separatrix angle is slightly reduced and the anti-symmetric quadrupolar structure of B_y field and the symmetric distribution of plasma pressure P are replaced by an asymmetric B_y four-wing structure and an asymmetric P plot as a non-zero B_y0 is added. The decoupling of electrons and ions also occurs near the X line in the case with a finite B_y0, but the effect of initial B_y0 on the electron flow is greater than that on the ion flow. The reconnection rates at the X-line drops from 0.151 to 0.06, namely, ∂A/∂t is reduced by a factor of 2.5 as B_y0/B₀ increases from 0 to 4.0. The reduction of reconnection rate might be related to the reducing openness of reconnection layer with the increasing B_y0.     

Study on O2 generation and CO2 absorption capability of four co-cultured salad plants in an enclosed system

The ability to generate O₂ and absorb CO₂ of several co-cultured vegetable plants in an enclosed system was studied to provide theoretical reference for the future man-plant integrated tests. Four kinds of salad plants (Lactuca sativa L. var. Dasusheng, Lactuca sativa L. var. Youmaicai, Gynura bicolor and Cichorium endivia L.) were grown in the CELSS Integration Test Platform (CITP). The environmental factors including O₂ and CO₂ concentration were continuously monitored on-line and the plant biomass was measured at the end of the test. The changing rules of O₂ and CO₂ concentration in the system were basically understood and it was found that the O₂ generated by the plants could satisfy the respiratory needs of 1.75 persons by calculation. It was also found that the plants could absorb the CO₂ breathed out by 2 persons when the light intensity was raised to 550 mmol m⁻² s⁻¹ PPF. The results showed that the co-cultured plants hold good compatibility and excellent O₂-generating and CO₂-absorbing capability. They could also supply some fresh edible vegetable for a 2-person crew.     

Symmetry,reduction and relative equilibria of a rigid body in the J2 problem

The J₂ problem is an important problem in celestial mechanics, orbital dynamics and orbital design of spacecraft, as non-spherical mass distribution of the celestial body is taken into account. In this paper, the J₂ problem is generalized to the motion of a rigid body in a J₂ gravitational field. The relative equilibria are studied by using geometric mechanics. A Poisson reduction process is carried out by means of the symmetry. Non-canonical Hamiltonian structure and equations of motion of the reduced system are obtained. The basic geometrical properties of the relative equilibria are given through some analyses on the equilibrium conditions. Then we restrict to the zeroth and second-order approximations of the gravitational potential. Under these approximations, the existence and detailed properties of the relative equilibria are investigated. The orbit–rotation coupling of the rigid body is discussed. It is found that under the second-order approximation, there exists a classical type of relative equilibria except when the rigid body is near the surface of the central body and the central body is very elongated. Another non-classical type of relative equilibria can exist when the central body is elongated enough and has a low average density. The non-classical type of relative equilibria in our paper is distinct from the non-Lagrangian relative equilibria in the spherically-simplified Full Two Body Problem, which cannot exist under the second-order approximation. Our results also extend the previous results on the classical type of relative equilibria in the spherically-simplified Full Two Body Problem by taking into account the oblateness of the primary body. The results on relative equilibria are useful for studies on the motion of many natural satellites, whose motion are close to the relative equilibria.