Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

Solar and Solar-Wind Composition Results from the Genesis Mission

The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and ¹⁵N/¹⁴N and ¹⁸O/¹⁷O/¹⁶O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.     

Isotopic Composition of the Solar Wind Inferred from In-Situ Spacecraft Measurements

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gyr ago from the protosolar nebula. Data from space missions and theoretical models indicate that the solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. In anticipation of results from the Genesis mission’s solar-wind implanted samples, we revisit solar wind isotopic abundance data from the high-resolution CELIAS/MTOF spectrometer on board SOHO. In particular, we evaluate the isotopic abundance ratios ¹⁵N/¹⁴N, ¹⁷O/¹⁶O, and ¹⁸O/¹⁶O in the solar wind, which are reference values for isotopic fractionation processes during the formation of terrestrial planets as well as for the Galactic chemical evolution. We also give isotopic abundance ratios for He, Ne, Ar, Mg, Si, Ca, and Fe measured in situ in the solar wind.     

The Genesis Solar Wind Concentrator Target: Mass Fractionation Characterised by Neon Isotopes

The concentrator on Genesis provided samples of increased fluences of solar wind ions for precise determination of the oxygen isotopic composition. The concentration process caused mass fractionation as a function of the radial target position. This fractionation was measured using Ne released by UV laser ablation and compared with modelled Ne data, obtained from ion-trajectory simulations. Measured data show that the concentrator performed as expected and indicate a radially symmetric concentration process. Measured concentration factors are up to ∼30 at the target centre. The total range of isotopic fractionation along the target radius is 3.8%/amu, with monotonically decreasing ²⁰Ne/²²Ne towards the centre, which differs from model predictions. We discuss potential reasons and propose future attempts to overcome these disagreements.     

The Solar Noble Gas Record in Lunar Samples and Meteorites

Lunar soil and certain meteorites contain noble gases trapped from the solar wind at various times in the past. The progress in the last decade to decipher these precious archives of solar history is reviewed. The samples appear to contain two solar noble gas components with different isotopic composition. The solar wind component resides very close to grain surfaces and its isotopic composition is identical to that of present-day solar wind. Experimental evidence seems by now overwhelming that somewhat deeper inside the grains there exists a second, isotopically heavier component. To explain the origin of this component remains a challenge, because it is much too abundant to be readily reconciled with the known present day flux of solar particles with energies above those of the solar wind. The isotopic composition of solar wind noble gases may have changed slightly over the past few Ga, but such a change is not firmly established. The upper limit of ~5% per Ga for a secular increase of the 3He/4He ratio sets stringent limits on the amount of He that may have been brought from the solar interior to the surface (cf. Bochsler, 1992). Relative abundances of He, Ne, and Ar in present-day solar wind are the same as the long term average recorded in metallic Fe grains in meteorites within error limits of some 15-20%. Xe, and to a lesser extent Kr, are enriched in the solar wind similar to elements with a first ionisation potential < 10 eV, although Kr and Xe have higher FIPs. This can be explained if the ionisation time governs the FIP effect (Geiss and Bochsler, 1986). This revised version was published online in June 2006 with corrections to the Cover Date.     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.     

The solar WIND and suprathermal ion composition investigation on the WIND spacecraft

The Solar Wind and Suprathermal Ion Composition Experiment (SMS) on WIND is designed to determine uniquely the elemental, isotopic, and ionic-charge composition of the solar wind, the temperatures and mean speeds of all major solar-wind ions, from H through Fe, at solar wind speeds ranging from 175 kms^–1 (protons) to 1280 kms^–1 (Fe⁺⁸), and the composition, charge states as well as the 3-dimensional distribution functions of suprathermal ions, including interstellar pick-up He⁺, of energies up to 230 keV/e. The experiment consists of three instruments with a common Data Processing Unit. Each of the three instruments uses electrostatic analysis followed by a time-of-flight and, as required, an energy measurement. The observations made by SMS will make valuable contributions to the ISTP objectives by providing information regarding the composition and energy distribution of matter entering the magnetosphere. In addition SMS results will have an impact on many areas of solar and heliospheric physics, in particular providing important and unique information on: (i) conditions and processes in the region of the corona where the solar wind is accelerated; (ii) the location of the source regions of the solar wind in the corona; (iii) coronal heating processes; (iv) the extent and causes of variations in the composition of the solar atmosphere; (v) plasma processes in the solar wind; (vi) the acceleration of particles in the solar wind; and (vii) the physics of the pick-up process of interstellar He as well as lunar particles in the solar wind, and the isotopic composition of interstellar helium.     

The Genesis Solar Wind Concentrator

The primary goal of the Genesis Mission is to collect solar wind ions and, from their analysis, establish key isotopic ratios that will help constrain models of solar nebula formation and evolution. The ratios of primary interest include ¹⁷O/¹⁶O and ¹⁸O/¹⁶O to ±0.1%, ¹⁵N/¹⁴N to ±1%, and the Li, Be, and B elemental and isotopic abundances. The required accuracies in N and O ratios cannot be achieved without concentrating the solar wind and implanting it into low-background target materials that are returned to Earth for analysis. The Genesis Concentrator is designed to concentrate the heavy ion flux from the solar wind by an average factor of at least 20 and implant it into a target of ultra-pure, well-characterized materials. High-transparency grids held at high voltages are used near the aperture to reject >90% of the protons, avoiding damage to the target. Another set of grids and applied voltages are used to accelerate and focus the remaining ions to implant into the target. The design uses an energy-independent parabolic ion mirror to focus ions onto a 6.2 cm diameter target of materials selected to contain levels of O and other elements of interest established and documented to be below 10% of the levels expected from the concentrated solar wind. To optimize the concentration of the ions, voltages are constantly adjusted based on real-time solar wind speed and temperature measurements from the Genesis ion monitor. Construction of the Concentrator required new developments in ion optics; materials; and instrument testing and handling. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Genesis Discovery Mission: Return of Solar Matter to Earth

The Genesis Discovery mission will return samples of solar matter for analysis of isotopic and elemental compositions in terrestrial laboratories. This is accomplished by exposing ultra-pure materials to the solar wind at the L1 Lagrangian point and returning the materials to Earth. Solar wind collection will continue until April 2004 with Earth return in Sept. 2004. The general science objectives of Genesis are to (1) to obtain solar isotopic abundances to the level of precision required for the interpretation of planetary science data, (2) to significantly improve knowledge of solar elemental abundances, (3) to measure the composition of the different solar wind regimes, and (4) to provide a reservoir of solar matter to serve the needs of planetary science in the 21st century. The Genesis flight system is a sun-pointed spinner, consisting of a spacecraft deck and a sample return capsule (SRC). The SRC houses a canister which contains the collector materials. The lid of the SRC and a cover to the canister were opened to begin solar wind collection on November 30, 2001. To obtain samples of O and N ions of higher fluence relative to background levels in the target materials, an electrostatic mirror (‘concentrator’) is used which focuses the incoming ions over a diameter of about 20 cm onto a 6 cm diameter set of target materials. Solar wind electron and ion monitors (electrostatic analyzers) determine the solar wind regime present at the spacecraft and control the deployment of separate arrays of collector materials to provide the independent regime samples. This revised version was published online in August 2006 with corrections to the Cover Date.     

OB Associations, Wolf–Rayet Stars, and the Origin of Galactic Cosmic Rays

We have measured the isotopic abundances of neon and a number of other species in the galactic cosmic rays (GCRs) using the Cosmic Ray Isotope Spectrometer (CRIS) aboard the ACE spacecraft. Our data are compared to recent results from two-component (Wolf–Rayet material plus solar-like mixtures) Wolf–Rayet (WR) models. The three largest deviations of galactic cosmic ray isotope ratios from solar-system ratios predicted by these models, ¹²C/¹⁶O, ²²Ne/²⁰Ne, and ⁵⁸Fe/⁵⁶Fe, are very close to those observed. All of the isotopic ratios that we have measured are consistent with a GCR source consisting of ∼20% of WR material mixed with ∼80% material with solar-system composition. Since WR stars are evolutionary products of OB stars, and most OB stars exist in OB associations that form superbubbles, the good agreement of our data with WR models suggests that OB associations within superbubbles are the likely source of at least a substantial fraction of GCRs. In previous work it has been shown that the primary ⁵⁹Ni (which decays only by electron-capture) in GCRs has decayed, indicating a time interval between nucleosynthesis and acceleration of >10⁵ y. It has been suggested that in the OB association environment, ejecta from supernovae might be accelerated by the high velocity WR winds on a time scale that is short compared to the half-life of ⁵⁹Ni. Thus the ⁵⁹Ni might not have time to decay and this would cast doubt upon the OB association origin of cosmic rays. In this paper we suggest a scenario that should allow much of the ⁵⁹Ni to decay in the OB association environment and conclude that the hypothesis of the OB association origin of cosmic rays appears to be viable.     

The Genesis Solar Wind Concentrator: Flight and Post-Flight Conditions and Modeling of Instrumental Fractionation

The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.     

Johannes Geiss’ Investigations of Solar, Heliospheric and Interstellar Matter

Johannes Geiss is a world leader and foremost expert on measurements and interpretation of the composition of matter that reveals the history, present state, and future of astronomical objects. With his Swiss team he was first to measure the composition of the noble gases in the solar wind when in the late 1960s he flew the brilliant solar wind collecting foil experiments on the five Apollo missions to the moon. Always at the forefront of the art of composition measurements, he with his colleagues determined the isotopic and elemental composition of the solar wind using instruments characterized by innovative design that have provided the most comprehensive record of the solar wind composition under all solar wind conditions at all helio-latitudes. He discovered heavy interstellar pickup ions, from which the composition of the neutral gas of the Local Interstellar Cloud is determined, and the “Inner Source” of pickup ions. Johannes Geiss played a key role both in the in-situ measurements and modeling of molecular ions in comets, and the interpretation of these data. He and co-workers measured the composition of plasmas in the magnetospheres of Earth and Jupiter. Here we highlight Johannes Geiss’ many discoveries and seminal contributions to our knowledge of the composition of matter of the Sun, solar wind, interstellar gas, early universe, comets and magnetospheres.     

The Plasma Ion and Electron Instruments for the Genesis Mission

The Genesis Ion Monitor (GIM) and the Genesis Electron Monitor (GEM) provide 3-dimensional plasma measurements of the solar wind for the Genesis mission. These measurements are used onboard to determine the type of plasma that is flowing past the spacecraft and to configure the solar wind sample collection subsystems in real-time. Both GIM and GEM employ spherical-section electrostatic analyzers followed by channel electron multiplier (CEM) arrays for detection and angle and energy/charge analysis of incident ions and electrons. GIM is of a new design specific to Genesis mission requirements whereas the GEM sensor is an almost exact copy of the plasma electron sensors currently flying on the ACE and Ulysses spacecraft, albeit with new electronics and programming. Ions are detected at forty log-spaced energy levels between ∼ 1 eV and 14 keV by eight CEM detectors, while electrons with energies between ∼ 1 eV and 1.4 keV are measured at twenty log-spaced energy levels using seven CEMs. The spin of the spacecraft is used to sweep the fan-shaped fields-of-view of both instruments across all areas of the sky of interest, with ion measurements being taken forty times per spin and samples of the electron population being taken twenty four times per spin. Complete ion and electron energy spectra are measured every ∼ 2.5 min (four spins of the spacecraft) with adequate energy and angular resolution to determine fully 3-dimensional ion and electron distribution functions. The GIM and GEM plasma measurements are principally used to enable the operational solar wind sample collection goals of the Genesis mission but they also provide a potentially very useful data set for studies of solar wind phenomena, especially if combined with other solar wind data sets from ACE, WIND, SOHO and Ulysses for multi-spacecraft investigations. This revised version was published online in August 2006 with corrections to the Cover Date.     

Solar Wind Conditions and Composition During the Genesis Mission as Measured by in situ Spacecraft

We describe the Genesis mission solar-wind sample collection period and the solar wind conditions at the L1 point during this 2.3-year period. In order to relate the solar wind samples to solar composition, the conditions under which the samples were collected must be understood in the context of the long-term solar wind. We find that the state of the solar wind was typical of conditions over the past four solar cycles. However, Genesis spent a relatively large fraction of the time in coronal-hole flow as compared to what might have been expected for the declining phase of the solar cycle. Data from the Solar Wind Ion Composition Spectrometer (SWICS) on the Advanced Composition Explorer (ACE) are used to determine the effectiveness of the Genesis solar-wind regime selection algorithm. The data collected by SWICS confirm that the Genesis algorithm successfully separated and collected solar wind regimes having distinct solar origins, particularly in the case of the coronal hole sample. The SWICS data also demonstrate that the different regimes are elementally fractionated. When compared with Ulysses composition data from the previous solar cycle, we find a similar degree of fractionation between regimes as well as fractionation relative to the average photospheric composition. The Genesis solar wind samples are under long-term curation at NASA Johnson Space Center so that as sample analysis techniques evolve, pristine solar wind samples will be available to the scientific community in the decades to come. This article and a companion paper (Wiens et al. 2013, this issue) provide post-flight information necessary for the analysis of the Genesis array and foil solar wind samples and the Genesis solar wind ion concentrator samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Fractionation of SI, NE, and MG Isotopes in the Solar Wind as Measured by Soho/Celias/MTOF

Using the high-resolution mass spectrometer CELIAS/MTOF on board SOHO we have measured the solar wind isotope abundance ratios of Si, Ne, and Mg and their variations in different solar wind regimes with bulk velocities ranging from 330 km/s to 650 km/s. Data indicate a small systematic depletion of the heavier isotopes in the slow solar wind on the order of (1.4±1.3)% per amu (2σ-error) compared to their abundances in the fast solar wind from coronal holes. These variations in the solar wind isotopic composition represent a pure mass-dependent effect because the different isotopes of an element pass the inner corona with the same charge state distribution. The influence of particle mass on the acceleration of minor solar wind ions is discussed in the context of theoretical models and recent optical observations with other SOHO instruments. This revised version was published online in June 2006 with corrections to the Cover Date.     

The isotopic composition of anomalous cosmic rays from sampex

Measurements of the anomalous cosmic ray (ACR) isotopic composition have been made in three regions of the magnetosphere accessible from the polar Earth orbit of SAMPEX, including the interplanetary medium at high latitudes and geomagnetically trapped ACRs. At those latitudes where ACRs can penetrate the Earth's magnetic field while fully stripped galactic cosmic rays (GCRs) of similar energies are excluded, a pure ACR sample is observed to have the following composition: ¹⁵N/N < 0.023, ¹⁸O/¹⁶O < 0.0034, and ²²Ne/²⁰Ne = 0.077(+0.085, –0.023). We compare our values with those found by previous investigators and with those measured in other samples of solar and galactic material. In particular, a comparison of ²²Ne/²⁰Ne measurements from various sources implies that GCRs are not simply an accelerated sample of the local interstellar medium.     

Structure of the Solar Wind and Compositional Variations

The composition of the solar wind is largely determined by the composition of the source material, i.e. the present-day composition of the outer convective zone. It is then modified by the processes which operate in the transition region and in the inner corona. In situ measurements of the solar wind composition give a unique opportunity to obtain information on the isotopic and elemental composition of the Sun. However, elemental — and to some degree also isotopic — fractionation can occur in the flow of matter from the outer convective zone into the interplanetary space. The most important examples of elemental fractionation are the well-known FIP/FIT effect (First Ionization Potential/Time) and the sometimes dramatic variations of the helium abundance relative to hydrogen in the solar wind. A thorough investigation of fractionation processes which cause compositional variations in different solar wind regimes is necessary to make inferences about the solar source composition from solar wind observations. Our understanding of these processes is presently improving thanks to the detailed diagnostics offered by the optical instrumentation on SOHO. Correlated observations of particle instruments on Ulysses, WIND, and SOHO, together with optical observations will help to make inferences for the solar composition. Continuous in situ observations of several isotopic species with the particle instruments on WIND and SOHO are currently incorporated into an experimental database to infer isotopic fractionation processes which operate in different solar wind regimes between the solar surface and the interplanetary medium. Except for the relatively minor effects of secular gravitational sedimentation which works at the boundary between the outer convective zone and the radiative zone, refractory elements such as Mg can be used as faithful witnesses to monitor the magnitude of these processes. With theoretical considerations it is possible to make inferences about the importance of isotopic fractionation in the solar wind from a comparison of optical and in situ observations of elemental fractionation with the corresponding models. Theoretical models and preliminary results from particle observations indicate that the combined isotope effects do not exceed a few percent per mass unit. In the worst case, which concerns the astrophysically important 3He/4He ratio, we expect an overall effect of at most several percent in the sense of a systematic depletion of the heavier isotope. Continued observations with WIND, SOHO, and ACE, and, with the revival of the foil technique, with the upcoming Genesis mission will further consolidate our knowledge about the relation between solar wind dynamics and solar wind composition. This revised version was published online in June 2006 with corrections to the Cover Date.     

HF-W Chronometry and Inner Solar System Accretion Rates

Models for the mechanisms of accretion of the terrestrial planets are re-examined using the experimental technique of high-precision isotope ratio mass spectrometry of tungsten (W). The decay of ¹⁸²Hf to ¹⁸²W (via ¹⁸²Ta) provides a new kind of radiometric chronometer of planet formation processes. Hafnium and W, the parent and daughter trace elements, are highly refractory; however, Hf is lithophile and strongly partitioned into the silicate portion of a planet, whereas W is moderately siderophile and preferentially partitioned into a coexisting metallic phase. More than 90% of terrestrial W has gone into the Earth's core during its formation. The residual silicate portion, the Earth's primitive mantle, has a Hf/W ratio in the range 10−40, an order of magnitude higher than chondritic (∼1.3). Tungsten isotopic data for the Earth and the Moon suggest that we can date a major event of planet formation: The Moon formed about 50 Myrs after the start of the solar system, providing strong support for the Giant Impact Theory of lunar origin. Recent simulations of this event imply that the Earth was probably only half formed at the time. From this we can deduce the planetary accretion rate. Tungsten isotope data for Mars provide evidence of a much shorter accretion interval, perhaps as little as 10 Myrs, but the rates for the Earth over the same time interval could have been comparable. The large W isotopic heterogeneities on Mars could only have been produced within the first 30 Myrs of the solar system. Large-scale mixing, e.g. from convective overturn, as is thought to drive the Earth's plates, must be absent from Mars. Limitations of the method such as 1) cosmogenic ¹⁸²Ta effects on lunar samples, 2) incomplete mixing of debris to cause W isotope heterogeneity on the Moon, and 3) initial ¹⁸²Hf/¹⁸⁰Hf heterogeneities of the early solar system are critically discussed. This revised version was published online in June 2006 with corrections to the Cover Date.