Solar Elemental Composition Based on Studies of Solar Energetic Particles

Solar abundances can be derived from the composition of the solar wind and solar energetic particles (SEPs) as well as obtained through spectroscopic means. Past comparisons have suggested that all three samples agree well, when rigidity-related fractionation effects on the SEPs were accounted for. It has been known that such effects vary from one event to the next and should be addressed on an event-by-event basis. This paper examines event variability more closely, particularly in terms of energy-dependent SEP abundances. This is now possible using detailed SEP measurements spanning several decades in energy from the Ultra Low Energy Isotope Spectrometer (ULEIS) and the Solar Isotope Spectrometer (SIS) on the ACE spacecraft. We present examples of the variability of the elemental composition with energy and suggest they can be understood in terms of diffusion from the acceleration region near the interplanetary shock. By means of a spectral scaling procedure, we obtain energy-independent abundance ratios for 14 large SEP events and compare them to reported solar wind and coronal abundances as well as to previous surveys of SEP events.     

An Update on Ultra-Heavy Elements in Solar Energetic Particles above 10 MeV/Nucleon

Measurements below several MeV/nucleon from Wind/LEMT and ACE/ULEIS show that elements heavier than Zn (Z=30) can be enhanced by factors of ∼100 to 1000, depending on species, in ³He-rich solar energetic particle (SEP) events. Using the Solar Isotope Spectrometer (SIS) on ACE we find that even large SEP (LSEP) shock-accelerated events at energies from ∼10 to >100 MeV/nucleon are often very iron rich and might contain admixtures of flare seed material. Studies of ultra-heavy (UH) SEPs (with Z>30) above 10 MeV/nucleon can be used to test models of acceleration and abundance enhancements in both LSEP and ³He-rich events. We find that the long-term average composition for elements from Z=30 to 40 is similar to standard solar system values, but there is considerable event-to-event variability. Although most of the UH fluence arrives during LSEP events, UH abundances are relatively more enhanced in ³He-rich events, with the (34<Z<40)/O ratio on average more than 50 times higher in ³He-rich events than in LSEP events. At energies >10 MeV/nucleon, the most extreme event in terms of UH composition detected so far took place on 23 July 2004 and had a (34<Z<40)/O enhancement of ∼250–300 times the standard solar value.     

Evidence for a Two-Stage Acceleration Process in Large Solar Energetic Particle Events

Using high-resolution mass spectrometers on board the Advanced Composition Explorer (ACE), we surveyed the event-averaged ∼0.1–60 MeV/nuc heavy ion elemental composition in 64 large solar energetic particle (LSEP) events of cycle 23. Our results show the following: (1) The Fe/O ratio decreases with increasing energy up to ∼10 MeV/nuc in ∼92% of the events and up to ∼60 MeV/nuc in ∼64% of the events. (2) The rare isotope ³He is greatly enhanced over the corona or the solar wind values in 46% of the events. (3) The heavy ion abundances are not systematically organized by the ion’s M/Q ratio when compared with the solar wind values. (4) Heavy ion abundances from C–Fe exhibit systematic M/Q-dependent enhancements that are remarkably similar to those seen in ³He-rich SEP events and CME-driven interplanetary (IP) shock events. Taken together, these results confirm the role of shocks in energizing particles up to ∼60 MeV/nuc in the majority of large SEP events of cycle 23, but also show that the seed population is not dominated by ions originating from the ambient corona or the thermal solar wind, as previously believed. Rather, it appears that the source material for CME-associated large SEP events originates predominantly from a suprathermal population with a heavy ion enrichment pattern that is organized according to the ion’s mass-per-charge ratio. These new results indicate that current LSEP models must include the routine production of this dynamic suprathermal seed population as a critical pre-cursor to the CME shock acceleration process.     

Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.     

Composition of Light Solar Wind Noble Gases in the Bulk Metallic Glass flown on the Genesis Mission

We discuss data of light noble gases from the solar wind implanted into a metallic glass target flown on the Genesis mission. Helium and neon isotopic compositions of the bulk solar wind trapped in this target during 887 days of exposure to the solar wind do not deviate significantly from the values in foils of the Apollo Solar Wind Composition experiments, which have been exposed for hours to days. In general, the depth profile of the Ne isotopic composition is similar to those often found in lunar soils, and essentially very well reproduced by ion-implantation modelling, adopting the measured velocity distribution of solar particles during the Genesis exposure and assuming a uniform isotopic composition of solar wind neon. The results confirm that contributions from high-energy particles to the solar wind fluence are negligible, which is consistent with in-situ observations. This makes the enigmatic “SEP-Ne” component, apparently present in lunar grains at relatively large depth, obsolete. ²⁰Ne/ ²²Ne ratios in gas trapped very near the metallic glass surface are up to 10% higher than predicted by ion implantation simulations. We attribute this superficially trapped gas to very low-speed, current-sheet-related solar wind, which has been fractionated in the corona due to inefficient Coulomb drag.     

Solar Energetic Particle Isotopic Composition

We discuss isotopic abundance measurements of heavy (6 ≤ Z ≤ 14) solar energetic particles with energies from ∼15 to 70 MeV/nucleon, focusing on new measurements made on SAMPEX during two large solar particle events in late 1992. These measurements are corrected for charge/mass dependent acceleration effects to obtain estimates of coronal isotopic abundances and are compared with terrestrial and solar wind isotope abundances. An example of new results from the Advanced Composition Explorer is included. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.     

On the Differences in Composition between Solar Energetic Particles and Solar Wind

Although the average composition of solar energetic particles (SEPs) and the bulk solar wind are similar in a number of ways, there are key differences which imply that solar wind is not the principal seed population for SEPs accelerated by coronal mass ejection (CME) driven shocks. This paper reviews these composition differences and considers the composition of other possible seed populations, including coronal material, impulsive flare material, and interplanetary CME material.     

Solar Energetic Particle Composition, Energy Spectra, and Space Weather

Recent progress in measuring the composition and energy spectra of solar energetic particles (SEPs) accelerated by CME-driven shocks is reviewed, including a comparison of the observed charge-to-mass dependence of breaks in SEP spectra with model predictions. Also discussed is a comparison of SEP and CME kinetic energies in seventeen large SEP events, and estimates of the SEP radiation dose that astronauts would be subject to once they venture outside the protective cover of Earth’s magnetosphere.     

Determination of Sulfur Abundance in the Solar Wind

Solar chemical abundances are determined by comparing solar photospheric spectra with synthetic ones obtained for different sets of abundances and physical conditions. Although such inferred results are reliable, they are model dependent. Therefore, one compares them with the values for the local interstellar medium (LISM). The argument is that they must be similar, but even for LISM abundance determinations models play a fundamental role (i.e., temperature fluctuations, clumpiness, photon leaks). There are still two possible comparisons—one with the meteoritic values and the second with solar wind abundances. In this work we derive a first estimation of the solar wind element ratios of sulfur relative to calcium and magnesium, two neighboring low-FIP elements, using 10 years of CELIAS/MTOF data. We compare the sulfur abundance with the abundance determined from spectroscopic observations and from solar energetic particles. Sulfur is a moderately volatile element, hence, meteoritic sulfur may be depleted relative to non-volatile elements, if compared to its original solar system value.     

The Solar Isotope Spectrometer for the Advanced Composition Explorer

The Solar Isotope Spectrometer (SIS), one of nine instruments on the Advanced Composition Explorer (ACE), is designed to provide high- resolution measurements of the isotopic composition of energetic nuclei from He to Zn (Z=2 to 30) over the energy range from ∼10 to ∼100 MeV nucl−1. During large solar events SIS will measure the isotopic abundances of solar energetic particles to determine directly the composition of the solar corona and to study particle acceleration processes. During solar quiet times SIS will measure the isotopes of low-energy cosmic rays from the Galaxy and isotopes of the anomalous cosmic-ray component, which originates in the nearby interstellar medium. SIS has two telescopes composed of silicon solid-state detectors that provide measurements of the nuclear charge, mass, and kinetic energy of incident nuclei. Within each telescope, particle trajectories are measured with a pair of two-dimensional silicon-strip detectors instrumented with custom, very large-scale integrated (VLSI) electronics to provide both position and energy-loss measurements. SIS was especially designed to achieve excellent mass resolution under the extreme, high flux conditions encountered in large solar particle events. It provides a geometry factor of ∼40 cm2 sr, significantly greater than earlier solar particle isotope spectrometers. A microprocessor controls the instrument operation, sorts events into prioritized buffers on the basis of their charge, range, angle of incidence, and quality of trajectory determination, and formats data for readout by the spacecraft. This paper describes the design and operation of SIS and the scientific objectives that the instrument will address. This revised version was published online in June 2006 with corrections to the Cover Date.     

3He-Rich Solar Energetic Particle Events

³He-rich solar energetic particle (SEP) events show huge enrichments of ³He and association with kilovolt electrons and Type-III radio bursts. Observations from a new generation of high resolution instruments launched on the Wind, ACE, Yohkoh, SOHO, TRACE, and RHESSI spacecraft have revealed many new properties of these events: the particle energy spectra are found to be either power-law or curved in shape, with the ³He spectrum often being distinctly different from other species. Ultra-heavy nuclei up to >200 amu are found to be routinely present at average enrichments of >200 times solar-system abundances. The high ionization states previously observed near ∼1 MeV/nucleon have been found to decrease towards normal solar coronal values in these events. The source regions have been identified for many events, and are associated with X-ray jets and EUV flares that are associated with magnetic reconnection sites near active regions. This paper reviews the current experimental picture and theoretical models, with emphasis on the new insights found in the last few years.     

The composition of heavy ions in solar energetic particle events

We review recent advances in determining the elemental, charge-state, and isotopic composition of 1 to 20 MeV per nucleon ions in solar energetic particle (SEP) events and outline our current understanding of the nature of solar and interplanetary processes which may explain the observations.The composition within individual SEP events may vary both with time and energy, and will in general be different from that in other SEP events. Average values of relative abundances measured in a large number of SEP events, however, are found to be roughly energy independent in the 1 to 20 MeV per nucleon range, and show a systematic deviation from photospheric abundances which seems to be organized in terms of the first ionization potential of the ion.Direct measurements of the charge states of SEPs have revealed the surprisingly common presence of energetic He⁺ along with heavy ions with typically coronal ionization states. High-resolution measurements of isotopic abundance ratios in a small number of SEP events show these to be consistent with the universal composition except for the puzzling overabundance of the SEP ²²Ne/²⁰Ne relative to this isotopes ratio in the solar wind. The broad spectrum of observed elemental abundance variations, which in their extreme result in composition anomalies characteristic of ³He-rich, heavy-ion rich and carbon-poor SEP events, along with direct measurements of the ionization states of SEPs provide essential information on the physical characteristics of, and conditions in the source regions, as well as important constraints to possible models for SEP production.It is concluded that SEP acceleration is a two-step process, beginning with plasma-wave heating of the ambient plasma in the lower corona, which may include pockets of cold material, and followed by acceleration to the observed energies by either flare-generated coronal shocks or Fermi-type processes in the corona. Interplanetary propagation as well as acceleration by interplanetary propagating shock will often further modify the composition of SEP events, especially at lower energies.     

Long-Term Fluences of Solar Energetic Particles from H to Fe

Data from ACE and GOES have been used to measure Solar Energetic Particle (SEP) fluence spectra for H, He, O, and Fe, over the period from October 1997 to December 2005. The measurements were made by four instruments on ACE and the EPS sensor on three GOES satellites and extend in energy from ∼0.1 MeV/nuc to ∼100 MeV/nuc. Fluence spectra for each species were fit by conventional forms and used to investigate how the intensities, composition, and spectral shapes vary from year to year.     

Abundances,Ionization States,Temperatures, and FIP in Solar Energetic Particles

The relative abundances of chemical elements and isotopes have been our most effective tool in identifying and understanding the physical processes that control populations of energetic particles. The early surprise in solar energetic particles (SEPs) was 1000-fold enhancements in \({}^{3}\mbox{He}/{}^{4}\mbox{He}\) from resonant wave-particle interactions in the small “impulsive” SEP events that emit electron beams that produce type III radio bursts. Further studies found enhancements in Fe/O, then extreme enhancements in element abundances that increase with mass-to-charge ratio \(A/Q\), rising by a factor of 1000 from He to Au or Pb arising in magnetic reconnection regions on open field lines in solar jets. In contrast, in the largest SEP events, the “gradual” events, acceleration occurs at shock waves driven out from the Sun by fast, wide coronal mass ejections (CMEs). Averaging many events provides a measure of solar coronal abundances, but \(A/Q\)-dependent scattering during transport causes variations with time; thus if Fe scatters less than O, Fe/O is enhanced early and depleted later. To complicate matters, shock waves often reaccelerate impulsive suprathermal ions left over or trapped above active regions that have spawned many impulsive events. Direct measurements of ionization states \(Q\) show coronal temperatures of 1–2 MK for most gradual events, but impulsive events often show stripping by matter traversal after acceleration. Direct measurements of \(Q\) are difficult and often unavailable. Since both impulsive and gradual SEP events have abundance enhancements that vary as powers of \(A/Q\), we can use abundances to deduce the probable \(Q\)-values and the source plasma temperatures during acceleration, ≈3 MK for impulsive SEPs. This new technique also allows multiple spacecraft to measure temperature variations across the face of a shock wave, measurements otherwise unavailable and provides a new understanding of abundance variations in the element He. Comparing coronal abundances from SEPs and from the slow solar wind as a function of the first ionization potential (FIP) of the elements, remaining differences are for the elements C, P, and S. The theory of the fractionation of ions by Alfvén waves shows that C, P, and S are suppressed because of wave resonances during chromospheric transport on closed magnetic loops but not on open magnetic fields that supply the solar wind. Shock waves can accelerate ions from closed coronal loops that easily escape as SEPs, while the solar wind must emerge on open fields.     

Johannes Geiss’ Investigations of Solar, Heliospheric and Interstellar Matter

Johannes Geiss is a world leader and foremost expert on measurements and interpretation of the composition of matter that reveals the history, present state, and future of astronomical objects. With his Swiss team he was first to measure the composition of the noble gases in the solar wind when in the late 1960s he flew the brilliant solar wind collecting foil experiments on the five Apollo missions to the moon. Always at the forefront of the art of composition measurements, he with his colleagues determined the isotopic and elemental composition of the solar wind using instruments characterized by innovative design that have provided the most comprehensive record of the solar wind composition under all solar wind conditions at all helio-latitudes. He discovered heavy interstellar pickup ions, from which the composition of the neutral gas of the Local Interstellar Cloud is determined, and the “Inner Source” of pickup ions. Johannes Geiss played a key role both in the in-situ measurements and modeling of molecular ions in comets, and the interpretation of these data. He and co-workers measured the composition of plasmas in the magnetospheres of Earth and Jupiter. Here we highlight Johannes Geiss’ many discoveries and seminal contributions to our knowledge of the composition of matter of the Sun, solar wind, interstellar gas, early universe, comets and magnetospheres.     

Ionic Charge States of Solar Energetic Particles: A Clue to the Source

The ionic charge of solar energetic particles (SEP) as observed in interplanetary space is an important parameter for the diagnostic of the plasma conditions at the source region and provides fundamental information about the acceleration and propagation processes at the Sun and in interplanetary space. In this paper we review the new measurements of ionic charge states with advanced instrumentation onboard the SAMPEX, SOHO, and ACE spacecraft that provide for the first time ionic charge measurements over the wide energy range of ∼0.01 to 70 MeV/nuc (for Fe), and for many individual SEP events. These new measurements show a strong energy dependence of the mean ionic charge of heavy ions, most pronounced for iron, indicating that the previous interpretation of the mean ionic charge being solely related to the ambient plasma temperature was too simplistic. This energy dependence, in combination with models on acceleration, charge stripping, and solar and interplanetary propagation, provides constraints for the temperature, density, and acceleration time scales in the acceleration region. The comparison of the measurements with model calculations shows that for impulsive events with a large increase of Q _Fe(E) at energies ≤1 MeV/nuc the acceleration occurs low in the corona, typically at altitudes ≤0.2 R _S .     

The Two Sources of Solar Energetic Particles

Evidence for two different physical mechanisms for acceleration of solar energetic particles (SEPs) arose 50 years ago with radio observations of type III bursts, produced by outward streaming electrons, and type II bursts from coronal and interplanetary shock waves. Since that time we have found that the former are related to “impulsive” SEP events from impulsive flares or jets. Here, resonant stochastic acceleration, related to magnetic reconnection involving open field lines, produces not only electrons but 1000-fold enhancements of ³He/⁴He and of (Z>50)/O. Alternatively, in “gradual” SEP events, shock waves, driven out from the Sun by coronal mass ejections (CMEs), more democratically sample ion abundances that are even used to measure the coronal abundances of the elements. Gradual events produce by far the highest SEP intensities near Earth. Sometimes residual impulsive suprathermal ions contribute to the seed population for shock acceleration, complicating the abundance picture, but this process has now been modeled theoretically. Initially, impulsive events define a point source on the Sun, selectively filling few magnetic flux tubes, while gradual events show extensive acceleration that can fill half of the inner heliosphere, beginning when the shock reaches ～2 solar radii. Shock acceleration occurs as ions are scattered back and forth across the shock by resonant Alfvén waves amplified by the accelerated protons themselves as they stream away. These waves also can produce a streaming-limited maximum SEP intensity and plateau region upstream of the shock. Behind the shock lies the large expanse of the “reservoir”, a spatially extensive trapped volume of uniform SEP intensities with invariant energy-spectral shapes where overall intensities decrease with time as the enclosing “magnetic bottle” expands adiabatically. These reservoirs now explain the slow intensity decrease that defines gradual events and was once erroneously attributed solely to slow outward diffusion of the particles. At times the reservoir from one event can contribute its abundances and even its spectra as a seed population for acceleration by a second CME-driven shock wave. Confinement of particles to magnetic flux tubes that thread their source early in events is balanced at late times by slow velocity-dependent migration through a tangled network produced by field-line random walk that is probed by SEPs from both impulsive and gradual events and even by anomalous cosmic rays from the outer heliosphere. As a practical consequence, high-energy protons from gradual SEP events can be a significant radiation hazard to astronauts and equipment in space and to the passengers of high-altitude aircraft flying polar routes.     

A Comparison of Ground Level Event e/p and Fe/O Ratios with Associated Solar Flare and CME Characteristics

Solar energetic particle (SEP) events reaching rigidities >1 GV are observed at 1?AU as ground-level events (GLEs). They are considered to be extreme cases of gradual SEP events, produced by shocks driven by wide and fast CMEs that are usually associated with long-duration (>1 hour) soft X-ray (SXR) flares. However, some large gradual SEP events, including GLEs, are associated with flares of short-duration (<1 hour) timescales comparable to those of flares seen with impulsive, low-energy SEP events with enhanced charge states, heavy-element abundances, and e/p ratios. The association of some GLEs with short-duration SXR events challenges us to understand the GLE event-to-event variation with SXR durations and whether it truly reflects the nature of the particle acceleration processes or simply the characteristics of the solar regions from which large, fast CMEs arise. We examine statistically the associated flare, active region (AR), and CME characteristics of ～40?GLEs observed since 1976 to determine how the GLE e/p and Fe/O ratios, each measured in two energy ranges, depend on those characteristics. The abundance ratios trend weakly to lower, more coronal, and less scattered values with increasing flare timescales, thermal and nonthermal peak fluxes, and measures of source AR sizes. These results and the wide range of solar longitude connections for GLEs with high abundance ratios argue against a significant role for flare effects in the GLEs. We suggest that GLE SEPs are accelerated predominately in CME-driven shocks and that a coupling of flare size and timescales with CME properties could explain the SEP abundance correlations with flare properties.     

Particle Acceleration by the Sun: Electrons, Hard X-rays/Gamma-rays

Observations of hard X-ray (HXR)/γ-ray continuum and γ-ray lines produced by energetic electrons and ions, respectively, colliding with the solar atmosphere, have shown that large solar flares can accelerate ions up to many GeV and electrons up to hundreds of MeV. Solar energetic particles (SEPs) are observed by spacecraft near 1 AU and by ground-based instrumentation to extend up to similar energies, but it appears that a different acceleration process, one associated with fast Coronal Mass Ejections (CMEs) is responsible. Much weaker SEP events are observed that are generally rich in electrons, ³He, and heavy elements. The energetic particles in these events appear to be similar to those accelerated in flares. The Ramaty High Energy Solar Spectroscopic Imager (RHESSI) mission provides high-resolution spectroscopy and imaging of flare HXRs and γ-rays. The observations of the location, energy spectra, and composition of the flare accelerated energetic particles at the Sun strongly imply that the acceleration is closely related to the magnetic reconnection that releases the energy in solar flares. Here preliminary comparisons of the RHESSI observations with observations of both energetic electrons and ions near 1 AU are reviewed, and the implications for the particle acceleration and escape processes are discussed.