Effect of sodium tartrate concentrations on morphology and characteristics of anodic oxide film on titanium alloy Ti–10V–2Fe–3Al

The effect of sodium tartrate concentrations on morphology and characteristics of ano-dic oxide film on titanium alloy was investigated. The alloy substrates were anodized in different concentration solutions of sodium tartrate with the addition of PTFE emulsion and their morphol-ogy and characteristics were analyzed. The anodic oxide film presented a uniform petaloid drums and micro-cracks morphology. Additionally, micro-cracks dramatically swelled with the increase of the tartrate concentrations. The thickness of the anodic oxide film increased with the concentra-tions until the concentration reached 15 g/L. The results of Raman analysis illustrate that all sam-ples have similarity in the crystal structure, consisting of mainly amorphous TiO2, some anatase TiO2 and a small amount of rutile TiO2. And the ratios of anatase TiO2 and rutile TiO2 increase with the concentrations until it reaches 15 g/L. Furthermore, the intensity of the peaks increases with enhanced concentrations until the concentration reaches 15 g/L. The corrosion resistance of the anodic oxide film is increased by the sodium tartrate with higher concentrations before 15 g/L. The coefficient of friction of the anodic oxide film reduces with the concentrations until the concentration reaches 15 g/L, then the coefficient of friction of the anodic oxide film increases with the concentrations.     

Magnetic and Optical Properties of the TiO2-Co-TiO2 Composite Films Grown by Magnetron Sputtering

The TiO2-Co-TiO2 sandwich films were successfully grown on glass and silicon substrata making alternate use of radio frequency reactive magnetron sputtering and direct current magnetron sputtering. The structures and properties of these films were identified with X-ray diffraction (XRD), Raman spectra and X-ray photoemission spectra (XPS). It is shown that the sandwich film consists of two anatase TiO2 films with an embedded Co nano-film. The fact that, when the Co nano-film thickens, varied red shifts appear in optical absorption spectra may well be explained by the quantum confinement and tunnel effects. As for magnetic properties, the saturation magnetization, remnant magnetic induction and coercivity vary with the thickness of the Co nano-films. Moreover, the Co nano-film has a critical thickness of about 8.6 nm, which makes the coercivity of the composite film reach the maximum of about 1413 Oe.     

玻璃纤维芯铅丝(网)/橡胶动态性能影响因素研究

设计并制备了以不同橡胶为基体、具有不同界面结合强度的玻璃纤维芯铅丝(网)增强橡胶复合材料(GF/Pb/R),通过比较它们的动态压缩模量和阻尼损耗因子,研究了复合方式、橡胶基体性能和界面结合强度对于GF/Pb/R动态性能的影响。     

铜团簇 (Cu)(n =2~7)的密度泛函理论研究

应用密度泛函理论的B3LYP方法,在6-31G(d)和6-31++G(d)基组水平上对铜团簇(Cu)n(n=2~7)进行了研究,计算得到了铜团簇的各种稳定构型、总能量、团簇束缚能,以及n=4时铜团簇的红外振动光谱。通过能量最小化原理,确定了各尺寸铜团簇的最稳定构型,并利用二阶差分和分裂能理论,讨论了6种最稳定结构的生长规律,结果表明,n=4时的团簇结构最为稳定,具有明显的幻数特征,n=5时的团簇结构出现区域不稳定的特性。     

阳极氧化膜厚度对TB8钛合金表面特性及其粘结性能的影响

采用以酒石酸钠为主盐的电解体系对TB8钛合金进行阳极氧化,研究阳极氧化膜厚度对TB8钛合金表面特性及其与环氧树脂粘结性能的影响。采用SEM、XRD和EDS分析了阳极氧化膜的微观形貌和晶体结构,采用角接触测量仪和三维视频显微镜分别对阳极氧化膜的表面润湿性和粗糙度进行测量。研究了不同厚度TB8钛合金阳极氧化膜的粘结性能与表面形貌、相组成、润湿性及粗糙度的关系。结果表明:采用以酒石酸钠为主盐的电解体系对TB8钛合金进行阳极氧化处理,氧化时间为15 min,电压为1~30 V时,能够在钛合金表面形成一层1~4μm厚的阳极氧化膜;氧化膜主要由金红石型和锐钛型TiO₂混合晶体组成,其表面具有微纳多孔的粗糙结构;随着厚度的增加,阳极氧化膜对水的润湿性能逐渐增强。当氧化膜厚度为3μm时,可获得最大粘结强度为19.6 MPa,相对于母材提高了88.5%,同时,水接触角为43.2°,相对于其母材减少了56.1%;粗糙度为2.14μm,相对于母材提高了137.8%。     

Compound Ceramic Coatings Grown by Micro-plasma Oxidation on Ti-6Al-4V Alloy

Compound ceramics coatings on the Ti-6Al-4V alloy were prepared by the direct current micro-plasma oxidation (MPO) in NaAlO2 solution. The composition and morphology of the coatings were studied with the X-ray diffraction (XRD) and the scanning electron microscopy (SEM), respectively. Inductively coupled plasma atomic emission spectrometer technique was used to analyze the solution features of Ti-6Al-4V alloy in the process of preparation. The results reveal that Al2TiO5 forms in the coatings at the initial stages of MPO reaction, and its content changes rapidly with the reaction continuing: after 20 min, the ceramics coatings are composed of α-Al2O3, γ-Al2O3 and Al2TiO5, but after 40 min, its main composition is of α-Al2O3. The content of Ti in the solution will increase when the MPO time extends, and as will Al in the anode area until, after 30 min, it reaches the maximum and keeps constant from then on. Both substrata of Ti and Al in the electrolyte join the MPO reaction at the initial stage, where the formation of Al2TiO5 happens; but as the MPO reaction prolongs, more and more Al in the electrolyte will take part in the reaction, leading to the appearance of a large amount of Al2O3.     

CVI反应器气体流动可视化发烟系统

CVI反应器内气体的输运对基体的沉积速度与沉积质量有重要的影响.本文介绍了一种基于TiCl4与H2O反应产生TiO2烟雾而设计的发烟系统,能使模拟CVI反应器内复杂的与不可观察的气体流动现象可视化.该系统结构简单,可操作性强,形成的烟流总流量与密度可调且长时间可视、均匀.流场照片表明其发烟效果很好,能满足CVI反应器内气体流场的显示研究.     

飞机座舱有机玻璃透明导电膜的制备及透光和微波散射性能

研究了用溅射法在飞机座舱有机玻璃上镀制金属-介质组合透明导电膜的工艺 ;测试和分析了金膜、银膜、氧化钛膜的光学特性、导电性及形貌结构 ;按薄膜光学原理进行膜系匹计算 ,并分别镀制了 Ti O2-Au-Ti O2 、 Ti O2-Ag-Ti O2 组合透明导电膜。在 40 0～ 760 nm可见光波段内 ,透光率分别达到了 74%和 81 % ,在 8～ 1 2 GHz频段内对垂直入射的微波 ,反射率分别达到-1 .1 d B和-0 .8d B。     

采用线膨胀系数可控ZrO2-TiO2陶瓷模具的钛合金高精度超塑成形

对线膨胀系数可控的ZrO2-TiO2陶瓷模具及钛合金高精度超塑成形进行了系统研究。探讨了TiO2体积分数和相对密度对ZrO2-TiO2陶瓷的线膨胀系数的影响规律,并引入相对密度修正模型——Turner模型来准确预测复合陶瓷材料的线膨胀系数。采用压痕法检测了与TC4钛合金等膨胀系数的ZrO2-TiO2陶瓷模具的超塑成形精度。在925℃下,利用ZrO2-TiO2陶瓷模具进行超塑成形,其使用性能良好。结果表明:ZrO2-TiO2陶瓷的线膨胀系数随TiO2体积分数的增加而减小,随相对密度的增加而增加。采用线膨胀系数优化的ZrO2-TiO2陶瓷模具,成形精度误差大幅降低,不超过0.1%,且陶瓷模具具有足够的热机械性能进行超塑成形,使用性能优良。     

咪唑促进的含溴环氧树脂／氰酸酯体系共固化反应及其抗氧化阻燃性能研究

通过傅立叶红外光谱和差热分析手段探讨了咪唑2E4MZ对于环氧树脂E51/氰酸酯BCE/溴环氧EX48共固化体系的反应机理和反应动力学。结果表明,2E4MZ对于共固化体系具有良好的促进作用:促进环氧基团和氰酸酯基团的共聚反应,加快固化反应速度,并且提高共固化反应的选择性,增大了固化产物结构中噁唑啉及其异构体噁唑烷酮的比例。氧化热增重、热重分析结果以及闪点、氧指数等测试结果表明,采用2E4MZ促进的共固化体系固化产物抗氧化和阻燃性能获得改善。     

纳米TiO2/Fe2O3复合材料的制备及其红外吸收性能研究

用溶胶-凝胶法制备了纳米TiO2／Fe2O3复合材料，并用XRD、TEM等方法对其进行了表征，给出了相关的工艺参数。研究了不同组分的纳米TiO2／Fe2O3的红外吸收特性。结果表明，纳米TiO2／Fe2O3复合材料在400cm^-1～1000cm^-1内随Fe2O3含量的增加，吸收峰明显宽化。     

TiAl合金高温循环氧化行为及其表面改性研究

研究了TiAl金属间化合物及表面涂层在空气中的高温循环氧化行为。结果表明:在800℃时TiAl合金具有较好的抗高温氧化行为,但当温度高于800℃时,TiAl合金表面未能形成单一的Al2O3保护层,而是形成外3层为疏松的TiO2层,内层为TiO2+Al2O3的混合氧化物层,因而使得TiAl合金的抗高温循环氧化性能严重蜕化。TiAl合金经过Cr改性铝化处理后,表面形成了具有立方Ll2结构的Al67Ti26Cr7层,立方Ll2结构的Al67Ti26Cr7不仅具有较高的铝含量,而且具有优良的韧性,因而使得处理后的TiAl合金具有良好的抗高温循环氧化性能。铝化物涂层尽管有很高的铝含量,但由于铝化得到的TiAl3相具有四方形结构,涂层非常脆,故该涂层抗高温循环氧化性能有待进一步提高。     

系列嵌套圆环系统的能量吸收特性

能量吸收结构的性能对航空、航天等领域的人员和结构防护非常重要。针对一种系列嵌套圆环系统的能量吸收特性进行了理论、数值和实验研究。首先建立了考虑应变强化效应的系列嵌套圆环系统受刚性平板横向准静态压缩时的刚塑性理论模型;然后对双环和三环嵌套圆环系统进行了准静态压缩实验及有限元数值模拟,理论预测、数值模拟和实验测得的系列嵌套圆环系统的载荷-挠度曲线吻合很好;最后对将系列嵌套圆环系统应用到航空领域进行了探讨,以应用至航空座椅为例,建立了人体、座椅、能量吸收结构的数学模型,参照美国航空联邦局航空座椅动态实验标准,基于该模型计算得到了人体所受的腰椎负荷,并与不装备能量吸收结构时的腰椎负荷进行了比较,结果表明应用系列嵌套圆环系统可以有效地对人体进行防护。     

钛合金阳极氧化膜的XPS研究

利用XPS分析了TCA钛合金经阳极氧化处理后,表面氧化膜的成分和结构及其随深度的变化.研究表明,钛合金阳极氧化膜表面为单一的TiO_2,并以晶态和非晶态的形式存在于氧化膜中.随着氧化膜厚度的增加,内部氧化越来越不充分,TiO_2的含量减少,并逐渐出现Ti:O_3、TiO;并且阳极氧化处理明显增厚了表面氧化膜.     

STUDY ON ACTIVE CONTROL FOR A FLEXIBLE BEAM UNDER THE CONDITION OF ZERO GRAVITY

The structure/controlling coupling system is akind of dynamic feedback system in which the me-chanical load and the actuator/controller interact.Because of the influence of inertia,while the com-mon elastic structure is in rigid motion ( or largemotion) ,there inevitably exists a kind of elastic vi-bration ( or small motion) superimposed on thelarge motion.This is the phenomenon of rigid- e-lastic coupling of the motion of an elastic body.Consequently,to study the problem of the motionstabilit…     

电动大巴车用永磁电机转子结构分析

针对大巴车用永磁电动机,通过有限元法分析了V型和V一型两种不同转子结构电机的转矩、交直轴电感、弱磁扩速能力及铁耗等性能,仿真不同转子结构的效率云图。通过对比分析不同转子结构的特点,最终选择出适合电动大巴车用驱动电机的转子磁路采用V型结构。     

钛蜂窝体制备及压缩性能研究

采用融熔沉积快速成形法制备钛金属蜂窝结构材料,对粉浆制备、钛金属蜂窝结构蜡坯固化、脱蜡等工艺以及所制备的钛蜂窝体的压缩性能进行了研究.结果表明,采用融熔沉积快速成形可以制备钛金属蜂窝结构,工艺简单、尺寸可控,钛蜂窝结构的相对密度在9%～12.6%范围内,屈服强度和弹性模量的增加不大;相对密度超过12.6%后,屈服强度显著增加,但弹性模量增加的幅度不大.通过改变蜂窝体正六边形的边长或改变蜂窝体的壁厚均达到相同的相对密度条件下,蜂窝体的压缩强度差别不大,但对蜂窝体的弹性模量却有显著影响.     

Global Response of the Ionosphere to Atmospheric Tides Forced from Below: Recent Progress Based on Satellite Measurements

This paper provides an overview on the recent progress in studying the ionospheric response to atmospheric tides forced from below. The global spatial structure and temporal variability of the atmospheric temperature tides and their ionospheric responses are considered on the basis of modern satellite-board data (COSMIC and TIMED). The tidal waves from the two data sets have been extracted by one and the same data analysis method. The similarity between the lower thermospheric temperature tides and their ionospheric responses provides evidence for confirming the new paradigm of atmosphere-ionosphere coupling. This paper provides also new experimental results which give an explanation why the WN4 and partly WN3 longitude structures are so prominent pattern in the ionosphere. These results present evidence indicating that the WN4 (WN3) structure is not generated only by the DE3 (DE2) tide as it has been often assumed. The DE3 (DE2) tide remains the leading contributor, but the SPW4 and SE2 (SPW3, DW4 and SE1) waves have their effects as well in a way that the ionospheric response becomes almost double (1.5 time stronger). The paper presents also the global distribution and temporal variability of the sun-synchronous 24-h (DW1), 12-h (SW2) and 8-h (TW3) electron density oscillations. It has been shown that while the latitude and altitude structure of the ionospheric SW2 response is predominantly shaped by the migrating SW2 tide forced from below the DW1 response is mainly due to daily variability of the photo-ionization. The peculiar vertical structure of the ionospheric TW3 response, that shows downward/upward phase progression, calls for further study of the physical processes shaping this ionospheric response.     

运用区域法模型计算燃烧室内一维辐射换热

采用一种机理严密,精度高的区域法辐射换热模型用于燃烧室壁温计算.采用Lefebvre模型和区域法模型计算了一个圆筒型不冷却火焰筒结构的换热;对比分析了两种方法计算的壁面辐射热流密度和壁面温度分布情况.结果表明,使用Lefebvre模型计算时,由于将燃气按一维划分为定向辐射,在燃烧室前后壁面辐射热流密度较小,存在一定不足;而使用区域法模型计算时,辐射热流密度分布更趋合理.      

Effect of cooling strategies on performance and mechanism of helical milling of CFRP/Ti-6Al-4V stacks

Hole-making for Carbon Fiber Reinforced Plastics(CFRP)/Ti-6Al-4V stacks is crucial for the assembling strength of aircraft structure parts. This work carried out experimental work for helical milling(HM) of the stacks with sustainable cooling/lubrication(dry, MQL and cryogenic)conditions. Cutting forces and temperatures at the CFRP layer, Ti-6Al-4V layer and the interface of stacks were obtained by a developed measuring system. The temperatures in CFRP machining at cryogenic condition varied fro...