热退火对溅射法Al-Sn共掺ZnO薄膜光电性能的影响

利用射频磁控溅射方法,采用AZO靶和Sn靶共溅射的方法在钠钙玻璃衬底上制备了Al与Sn共掺杂的ZnO (ATZO) 薄膜样品,再对样品进行300,350,370,400,500 ℃ 5种不同温度和1,2,4 h 3种不同时间的退火处理。采用X射线衍射仪(X-ray diffraction, XRD)和扫描电子显微镜(Scanning electron microscope, SEM)对其相结构及形貌进行了表征和分析。结果表明,所制备的ATZO薄膜都是六角纤锌矿结构,在（002）方向上表现出择优生长且表面都较为均匀。采用UV vis分光光度计测试薄膜样品的透过率,结果显 示370 ℃退火2 h的样品在400~760 nm处有87.09%的最高平均透过率,对应的光学带隙为3.40 eV;同时,此样品具有最低的电阻率为4.22×10-2 Ω·cm和最高的载流子浓度和迁移率,分别为6.44×1020 cm-3和4.30 cm2/(V·s)。     

Influence of Gd2O3 and Yb2O3 Co-doping on Phase Stability,Thermo-physical Properties and Sintering of 8YSZ

The role of multicomponent rare earth oxides in phase stability, thermophysical properties and sintering for ZrO2-based thermal barrier coatings (TBCs) materials is investigated. 8YSZ codoped with 3 mol% Gd2O3 and 3 mol% Yb2O3 (GYb-YSZ) powders are synthesized by solid state reaction for 24 h at various temperatures. As temperature increases, stabilizers are dissolved into zirconia matrix gradually. Synthesized at 1 500 °C, GYb-YSZ is basically composed of cubic phase. GYb-YSZ exhibits excellent phase stability and sinters lower than 8YSZ by nearly three times. The thermal conductivity of GYb-YSZ is much lower than that of 8YSZ, and the thermal expansion coefficient of GYb-YSZ is comparable to that of 8YSZ. The influence of Gd2O3 and Yb2O3 co-doping on phase stability, thermal conductivity and sintering of 8YSZ is discussed.     

面向太空环境应用的抗辐照有源光纤特性研究

针对太空恶劣辐射环境会造成光器件的光学性能降低或失效的问题。本文利用改良化学气相沉积法（MCVD）结合原子层沉积（ALD）掺杂技术制备铋铒共掺光纤（BEDF）,经不同辐照剂量的伽马射线处理,与掺铒光纤（EDF）的光谱特性进行对比研究。光纤样品分别经0.3 kGy、0.5 kGy、0.8 kGy 和 1.5 kGy辐照处理,对比光谱发现 BEDF的辐照诱导损耗（RIA）的增加明显低于EDF, 特别是经1.5 kGy 的辐照处理,EDF的RIA比BEDF增加1.93 dB/m。EDF的荧光强度随辐照剂量的增加而降低,并低于未辐照前的荧光强度,而对于BEDF而言,其荧光强度随辐照剂量增加先增加后减弱,且均高于未辐照的荧光强度。实验结果表明,BEDF光纤具有一定抗辐照特性,对应用于太空环境具有重要研究意义。