Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl–ion concentrations. The results demonstrate that the Cl–ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples pas-sivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those pas-sivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti:Ni=9.01:1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

镀银抗硫防变色性能研究

介绍防止零件镀银层变色的试验过程，包括工艺配方、试片准备及钝化工艺等。     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl^- ion concentrations. The results demonstrate that the Cl^- ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples passivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those passivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti：Ni = 9.01：1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

铜钝化废液的再生回收与循环利用

本文提出了一种铜钝化废液再生回收与循环利用的工艺方法隔膜电解法，这种方法把电解和膜分离技术融为一体。论文对方案选择、再生回收原理、工艺条件的确立等都进行了认真地讨论。     

刀具钝化对铣削GH4169表面粗糙度的影响

针对GH4169难加工材料,采用单因素实验法,研究了不同切削参数下刀具钝化对面粗糙度的影响,实验表明:使用钝化刀具加工形成的表面粗糙度较未钝化刀具有所下降,表面质量得以提高;切削深度由刃口半径的0.5倍变化到4倍时,表面粗糙度呈先减小后增大趋势,当切削深度是刃口半径的2倍时表面粗糙度最低.     

S-03钢渗氮面点蚀机理与钝化工艺优化

针对S-03钢(022Cr12Ni10MoTi)渗氮后表面出现点腐蚀现象,进行深入机理分析,发现渗氮后表面生成CrN,造成渗氮表面贫Cr,不能形成致密完整的钝化膜,导致材料耐蚀性能降低,易发生点蚀。并对原有磷酸体系钝化工艺进行改进优化,提出了复合钝化工艺。利用循环极化、电化学阻抗谱(EIS)等技术手段,研究了复合钝化后S-03钢渗氮表面的腐蚀行为,并与未钝化和磷酸体系钝化进行对比。结果表明,经复合钝化处理的S-03钢渗氮表面点蚀电位E b最高,腐蚀速率最小,且钝化膜修复能力最强。说明复合钝化工艺能在S-03渗氮表面形成x Cr 2 O 3·y CrOOH稳定的非晶态氧化膜,增强了表面抗点蚀能力,其耐蚀性能要远高于磷酸体系钝化和未钝化表面。同时复合钝化工艺可有效提高S-03钢渗氮表面钝化膜厚度,增强钝化膜修复能力。     

航天器用氢镍蓄电池钝化技术研究

为了减缓蓄电池组爆炸产生的空间碎片,文章对常在航天器上应用的氢镍蓄电池的钝化技术进行了研究。首先分析了氢镍蓄电池的爆炸机理,然后针对氢镍蓄电池组提出了安全性设计方法;进行了过充电、过放电等蓄电池爆炸试验;研制了一台氢镍蓄电池钝化装置,进行了蓄电池钝化消能试验。     

考虑passivation的备件库存时变凸优化

考虑到passivation现象,利用时变库存平衡方程构建时变备件短缺数函数,根据扩展帕姆定理将当前时刻之前时段的累积需求率糅合入泊松分布的形状参数,建立考虑备件累积需求率的凸优化算法。以费用约束下的时变可用度为目标函数,利用凸优化算法,得到每一时段的最优配置方案。利用众数法,选择适当的全局库存策略。最后,构建了优化案例来阐释本文提出的方法,同时通过对比几种库存策略,证明了所提方法的优越性。      

腐蚀环境对LC4CS铝合金疲劳裂纹闭合的影响

采用透射电子显微镜观察了３．５％ＮａＣｌ溶液中的ＬＣ４ＣＳ薄膜试样裂纹扩展，并用俄歇能谱仪对ＬＣ４ＣＳ铝合金边缺口试件在３．５％ＮａＣｌ溶液中腐蚀疲劳裂纹面进行了测试。结果表明，腐蚀介质使薄膜试样理解纹扩展，裂纹面有腐蚀产物生成；腐蚀疲劳裂纹面生成的致密的钝化膜抑制了腐蚀产物的进一步发展，分析认为，３．５％ＮａＣｌ溶液中ＬＣ４ＣＳ铝合金裂纹闭合与干燥空气中相同。     

热镀锌钢板钼酸盐—单宁酸钝化研究

采用钼酸盐—单宁酸复合钝化工艺对热镀锌钢板进行了钝化处理。硫酸铜点滴实验表明,采用钼酸盐—单宁酸复合钝化的镀锌钢板的耐蚀性与单一钼酸盐钝化的耐蚀性相当。测试了镀锌钢板在0.5mol/L的NaCl溶液中钝化前后的极化曲线、电化学交流阻抗谱。结果表明:经钼酸盐、单宁酸、钼酸盐—单宁酸钝化的样品腐蚀电流密度分别为4.95×10-5、9.80×10-5和1.47×10-4A cm-2。电化学阻抗谱表明,单宁酸加入钼酸盐中,其钝化样品耐蚀性能有所下降。简要探讨了钼酸盐—单宁酸复合钝化机理。