APC—2／AS4热塑性带材火焰辅助缠绕研究——火焰温度对成形质量的影响

通过对ＡＰＣ－２／ＡＳ４带材火焰辅助缠绕过程的研究，分析了工艺条件对制件成形质量的影响和制件的断面显微特征，认为火焰辅助缠绕制件的孔隙主要是由于基体和纤维的降解失重产生的，而不是空气夹杂产生的。     

计算机模拟高温下温度波动对简化环氧分子结构参数的影响

对４００Ｋ下简化环氧分子结构的键长、键角、四原子扭转角及非键合原子间距离等结构参数在微小温度波动时进行动态模拟，分析了这些结构参数在该条件下的变形刚性。     

Calcification and silicification: fossilization potential of cyanobacteria from stromatolites of Niuafo'ou's Caldera Lakes (Tonga) and implications for the early fossil record

Calcification and silicification processes of cyanobacterial mats that form stromatolites in two caldera lakes of Niuafo'ou Island (Vai Lahi and Vai Si'i) were evaluated, and their importance as analogues for interpreting the early fossil record are discussed. It has been shown that the potential for morphological preservation of Niuafo'ou cyanobacteria is highly dependent on the timing and type of mineral phase involved in the fossilization process. Four main modes of mineralization of cyanobacteria organic parts have been recognized: (i) primary early postmortem calcification by aragonite nanograins that transform quickly into larger needle-like crystals and almost totally destroy the cellular structures, (ii) primary early postmortem silicification of almost intact cyanobacterial cells that leave a record of spectacularly well-preserved cellular structures, (iii) replacement by silica of primary aragonite that has already recrystallized and obliterated the cellular structures, (iv) occasional replacement of primary aragonite precipitated in the mucopolysaccharide sheaths and extracellular polymeric substances by Al-Mg-Fe silicates. These observations suggest that the extremely scarce earliest fossil record may, in part, be the result of (a) secondary replacement by silica of primary carbonate minerals (aragonite, calcite, siderite), which, due to recrystallization, had already annihilated the cellular morphology of the mineralized microbiota or (b) relatively late primary silicification of already highly degraded and no longer morphologically identifiable microbial remains.     

Biogenesis and early life on Earth and Europa: favored by an alkaline ocean?

Recent discoveries about Europa--the probable existence of a sizeable ocean below its ice crust; the detection of hydrated sodium carbonates, among other salts; and the calculation of a net loss of sodium from the subsurface--suggest the existence of an alkaline ocean. Alkaline oceans (nicknamed "soda oceans" in analogy to terrestrial soda lakes) have been hypothesized also for early Earth and Mars on the basis of mass balance considerations involving total amounts of acids available for weathering and the composition of the early crust. Such an environment could be favorable to biogenesis since it may have provided for very low Ca2+ concentrations mandatory for the biochemical function of proteins. A rapid loss of CO2 from Europa's atmosphere may have led to freezing oceans. Alkaline brine bubbles embedded in ice in freezing and impact-thawing oceans could have provided a suitable environment for protocell formation and the large number of trials needed for biogenesis. Understanding these processes could be central to assessing the probability of life on Europa.     

Carbon-Epoxy圆管件的静态吸能特征

Carbon/Epoxy复合材料可以用作理想的吸能材料。为了考察材料体系对结构吸能性能的影响,对一系列Carbon/Epoxy圆管件进行了静态吸能性能试验。试验结果表明,在基体种类相同的条件下,结构的压溃失效模式有很大的区别。材料的吸能性能不仅同材料性能关系密切,而且也受材料纤维方式影响。     

用共固结和热变形成型技术制造热塑性复合材料加筋结构

报导了碳纤维增强聚醚醚酮基热塑性复合材料的带L型加强筋结构件的一体化制造过程。强调了加强筋的热变形成型制造技术。实验发现,用编织布直接铺层模压成型加强筋时,难于精确控制碳纤维的定位;成型固结后,边缘区空隙率高。而用对合模模压热变形成型技术制造时,这些问题则可以解决。采用共固结技术制备了平板加筋结构。后两项技术在制造复杂制件方面具有一定的优势,大批量生产时可以降低制造成本。     

柔性混编预浸料制造热塑性复合材料加筋结构

PEEK树脂基复合材料具有突出的韧性和高损伤容限,但因成型工艺条件较为苛刻,且铺覆性能差,影响了曲面成型能力.利用柔性混编预浸料技术则可解决这一难题,高质量、高效率地实现复杂曲面结构件的制备.分别带有"L"型加强筋和帽型材的加筋口盖的制造,对此进行了充分的验证.     

APC—2／AS4预浸料带热芯缠绕的显微特征

通过对ＡＰＣ－２／ＡＳ４热塑性预浸带缠绕过程的研究，分析了缠绕管件的断面显微特征，认为热塑性预浸带热芯缠绕成形过程中，形成孔隙的主要原因是层间的不良浸渍而非基体的降解。提高缠绕张力和树脂含量有利于孔隙的消除，但又对制件中树脂的均匀性及外表面尺寸稳定性有影响。     

T800/5228A 层合板I 型断裂韧性优化

冷场发射扫描电镜表明,固化5228A/ PAEK 共混体系发生了反应诱导相分离,相形貌依次经历
了海岛-双连续-相反转的演化过程; DMA 试验表明,PAEK 的引入对5228A 基体树脂Tg 略有影响,但基本不
会改变原有树脂体系的使用温度;T800/5228A 经韧化后,在层间内形成了典型的相反转结构,裂纹扩展路径呈
现出波纹状,明显区别于原有的光滑平直裂纹路径,玉型层间断裂韧度(GIC)大幅度提高。     

T800/5228E复合材料层合板动态冲击力学响应

研究了宽冲击能量范围(12.8、25.5、34.2、42.3与51 J)内T800/5228E复合材料层合板动态冲击力学响应历程.结果表明,复合材料层合板损伤历程依次为裂纹引发→分层扩展→最大损伤→二次损伤等,冲击能量基本不会对其发展演化历程产生影响;力学损伤参数研究发现,赫兹失效载荷Fh与冲击能量成线性关系,而最大作用载荷Fmax与冲击能量为特定指数函数关系.不可逆能量Lw与能量吸收率η研究表明,两者均与冲击能量保持单调递增关系,反映复合材料板的损伤程度在加重,但损伤面积基本趋于稳定,纤维断裂等二次损伤可能成为新型能量吸收方式.