排序方式: 共有34条查询结果,搜索用时 147 毫秒
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为改善相稳定硝酸铵(PSAN)的吸湿性和表面极性,选择乙二胺、二乙胺和三乙胺,分别代表伯、仲和叔胺化合物,与PSAN颗粒表面反应,制备反应型包覆PSAN。FTIR证实,乙二胺、二乙胺和三乙胺与AN均能发生化学反应。通过吸湿率、接触角测量和推进剂拉伸实验,对包覆效果进行了表征。结果表明,二乙胺反应型包覆的PSAN吸湿性和表面极性改善效果最好,相对湿度为75.3%和92.5%两种环境下,8 h吸湿率分别下降了60.5%和63.6%,表面自由能极性分量下降了约91%,非极性分量增加了约145%;而乙二胺反应型包覆PSAN对BAMO-THF/PSAN推进剂力学性能改善效果最好,乙二胺包覆量为0.2%时,推进剂的最大应力σm取得最大值,σm提高了约46%,最大应力下延伸率εm提高了约83%。 相似文献
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本文在分析硝胺复合推进剂燃烧特点的基础上,对有关硝胺复合推进剂的燃速特性和燃烧模型进行了全面的述评,并指出了进一步模化的方向. 相似文献
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采用傅立叶红外光谱和核磁共振技术,研究了硝化甘油(NG)和1,2,4-丁三醇三硝酸酯(BTTN)两种硝酸酯增塑后的聚醚聚氨酯在空气中90°C下的热氧降解。结果表明:NG,BTTN在聚氨酯粘合剂中的分解产物主要为醇类。这些小分子醇参与了聚氨酯硬段的重聚合反应,形成氨基甲酸酯结构;硝酸酯对聚氨酯粘合剂的热氧降解表现出某种稳定作用,并改变了软段产物结构,使甲酸酯和叔碳结构相对增加;硝酸酯分解产生的NO2自由基可能与软段降解产生的过氧化氢反应形成硝酸,从而加速了硝酸酯的水解。 相似文献
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Yuan Xiao Yongding Liu Gaohong Wang 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2012
Simulated microgravity (SMG) can inhibit proliferation and enhance microcystin production of Microcystis aeruginosa. We investigated the role of nitric oxide (NO) in regulating the SMG induced changes of proliferation, photochemical system II photochemical activity, pigment, soluble protein and microcystin production in M. aeruginosa. M. aeruginosa was exposed to 0.1 mM sodium nitroprusside (SNP, NO donor) or 0.02 mM 2-(4-carboxyphenyl)-4, 4, 5, 5-tetramethylimidazoline-1-oxyl-3-oxide (c-PTIO, NO scavenger) alone or in combination with SMG for 48 h. SMG and SNP inhibited the growth of M. aeruginosa while c-PTIO had no effect on cell number. As to yield, the negative effect of SMG was augmented by SNP and suppressed by c-PTIO. The intracellular concentrations of chlorophyll a, carotenoid, phycocyanin, soluble protein and microcystin were increased by SMG after 48 h. The effects of SMG on these metabolic processes could be enhanced by SNP and be partly eliminated by c-PTIO. Moreover, SNP and c-PTIO only functioned in these biochemical processes under SMG, unlike in the regulation of cell proliferation and yield. These results showed that the effects of SMG could be enhanced by adding exogenous NO and be mitigated by scavenging endogenous NO, revealing the involvement of NO in the changes in biochemistry processes induced by SMG in M. aeruginosa. 相似文献
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概述了GAP/AN推进剂的特性,研制状况及发展潜力,针对目前该推进剂的各项性能水平(能量性能,燃烧性能,力学性能)提出了该推进剂存在的问题及改善方法。 相似文献
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