机载中空纤维膜组件壳程气体流动数值模拟

机载惰化用中空纤维膜组件具有分离效率高、安全稳定、结构紧凑等优点,是目前较为经济高效的飞机燃油箱惰化设备。采用计算流体力学(CFD)方法对某中空纤维膜组件壳程气体流动进行数值模拟,通过更改膜丝束间距、膜丝束入口速度、膜丝束流量、膜丝束排布方式及飞行高度,得到了不同工况下的组件轴向各截面的气体流动分布,并提出无量纲参数截面平均速度比来描述气体流动分布规律。仿真结果表明:在保持入口气体流动速度一定时,平均速度比值随着膜丝束间距的减小先减小后增大,在膜丝束间距为1.5倍膜丝半径时达到最小值, 在保持入口流量一定时,壳程气体流动有着相同的规律;在保持膜丝束填充数量不变时,均匀排布比不均匀排布的平均速度比值更小;保持膜丝束间距不变时,入口速度对平均速度比值影响不大;飞行高度对组件壳程气体分布的影响作用主要体现在膜组件内壁处。      

LIP与PTB真空计量标准的比对

1987～1989年,采用我国生产的DL-2型热阴极电离规为传递规,分别对LIP的新型标准压缩式真空计标准装置与PTB的静态膨胀标准装置进行了两轮比对。比对中,使用He、Ar、N_2三种气体。比对结果,最大偏差为1.48％,DL-2规的重复性为+0.49％(PTB)和-0.88％(LIP)。LIP从美国MKS公司购买的SRG-2规,在PTB进行了校准。运到我国后,LIP进行了认真的校准。双方的数据偏差小于013％。     

超临界压力RP-3在竖直细圆管内混合对流研究

研究了超临界压力下碳氢燃料航空煤油RP-3在竖直细圆管内混合对流,分析了浮升力及热物性对碳氢燃料在垂直管中对流换热的影响。实验中控制热流密度从200~500 kW/m2变化,进口压力变化范围为3~5 MPa,进口雷诺数从5 000~10 500范围内变化。研究表明:在向上流动情况中进口段存在较为明显的入口效应,换热出现恶化现象,而在向下流动中未出现;对于向上和向下流动,由于热物性的综合影响,换热系数沿流动方向增大;在较低进口雷诺数(Re=5 700)时,对于向下流动,随着浮升力影响的增大,浮升力改变了流体径向速度分布,出现了换热强化;在较高进口雷诺数(Re=10 500)时,浮升力对换热的影响依然显著;判别式Bo*数小于5.6×10-7未能预测浮升力对碳氢燃料换热影响。      

微颗粒表面磁控溅射镀金属膜实验

采用磁控溅射方法,成功地在微颗粒表面沉积了金属铜膜和金属镍膜.利用光学显微镜(OM)、场发射扫描电子显微镜(FESEM)、能谱仪(EDS)、多功能扫描探针显微镜(SPM)、电感耦合等离子体发射光谱仪(ICP-AES)和光电子能谱仪(XPS)等测试仪器对其表面形貌、膜厚和组份进行了表征.重点讨论了不同的沉积条件对薄膜结晶的影响,并用X射线衍射仪(XRD)对其进行了表征.结果表明,溅射镀膜时,通过控制微颗粒的运动方式,可以在微颗粒表面镀上均匀性好、附着力强和致密性好的金属膜.溅射时间越长或溅射功率越大或装载量越少,都有利于薄膜结晶.      

吸热碳氢燃料热沉测量实验装置的设计与性能测试

为了测定吸热碳氢燃料在不同温度条件下的总吸热量(热沉),以便于对吸热碳氢燃料进行筛选,研制了一套适合于高温下热沉测量的实验装置。该装置主要由进样计量、载气输送、加热控温、反应量热和产物分析五部分组成。对反应管轴向温度分布进行了测定,实验装置的工作温度范围在500℃-900℃,各温度下恒温区域长达440 mm,恒温区内温度梯度不大于3℃;利用电能标定的方法测定了装置的量热常数,并用纯物质(N2)作为样品对装置的准确度进行了校准,求解仪器量热常数的工作曲线的线性相关系数在0.999 7以上,氮气热沉测定值与理论值基本吻合,表明该装置测定结果可靠、测量准确度高,装置的设计符合T ian’s方程,可用于吸热碳氢燃料热沉的实验测定,为吸热碳氢燃料的研究提供了较可靠的热化学数据。     

铝合金阳极化膜上铈转化膜沉积的电化学研究

阳极氧化膜在含1g/L CeCl₃和2.7 g/L H₂O₂的水溶液中阴极电解可以在其表面沉积富铈转化膜.用循环伏安、φ-t和j-t曲线等电化学测试方法对转化膜成膜反应进行了研究,以期获得对成膜机理的深入了解和证实根据其它工作提出的成膜机理.研究结果表明铈转化膜的生成包括阳极氧化膜的化学溶解和4价铈化合物的电化学还原两个过程;在阴极电位达到析氢电位之前,这两个过程主要是由H₂O₂在阴极的电还原改变了阴极表面附近溶液的局部pH值引起的,而O₂的还原通常不能引起这两个过程的发生.      

AZ91D镁合金低压交流氧化成膜机制

基于一种低的交流电压条件(10 V),在NaOH和Na₂SiO₃的混合溶液体系中,对AZ91D镁合金进行电化学阳极氧化处理.利用扫描电镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)、电化学测试技术等手段研究了AZ91D镁合金表面阳极氧化的成膜过程、膜层生长的特点以及氧化工艺参数对膜层性能的影响规律.试验结果表明:在10 V这样低的交流电压下,在镁合金表面获得的氧化膜层表面均匀,为无孔洞的平层状膜层,其生长过程呈叠加式特点;获得的氧化膜层的主要成分为Mg₂SiO₄;在质量分数为3.5%的NaCl溶液中,经过电化学阳极氧化的镁合金的耐蚀性优于未经处理的镁合金.      

汞-199离子储存频率标准近期的理论进展和实验结果

储存在射频四极陷阱(Trap)中的199Hg离子在4O.5GHz频率时的超精细谐振,证明具有极窄的相对线宽,因而被选作为高精密的频率标准。引起该类频标频率变化的主要因素是因储存离子运动产生的二阶多普勒频移,采用少量低压气体作为背景,使运动的离子被致冷至300K所形成的离子云的密度几乎完全决定于伪电势与空间电荷力的平衡。我们发现在这种情况下,根据陷阱参数、温度和储存离子的总数和质量可以准确地计算出二阶多普勒频移。用氦作为致冷气体所进行的大量实验表明,由射频脉冲宽度限制的谱线宽度为0.85Hz。根据所观测到的谱线形状可以预计自然线宽将小于0.1Hz。采用闭环稳定储存离子数的方法,已能使测得的二阶多普勒频移达n×10~(-13)量级。     

RCA通信卫星的进展

美国无线电通信公司(RCA公司)是第一个研制双频段通信卫星和第一个使用全固态通信卫星(Satcoms)的公司,该公司因一直采用三轴稳定而闻名世界。第一个RCA通信卫星Satcom-1是用德尔它(Delta)火箭送入轨道的。 Satcom-1有24个信道,每个信道有单波饱和功率为5瓦的行波管放大器,行波管放大器采用单收集极,直流转换到射频的效率为36％,射频功率为120瓦。天线采     

高垂直度和低沉积的MEMS陀螺梳齿结构释放工艺

梳齿型微机电系统（MEMS）陀螺的释放要求结构具有垂直度高、释放过程沉积聚合物少的特点,通过优化深硅刻蚀的工艺参数,包括钝化气体八氟环丁烷（C4F8）的流量、衬底温度、刻蚀气体六氟化硫（SF6）的流量和钝化气体C4F8的压力,实现了结构垂直度为90.0°、支撑层表面沉积物厚度为87.1nm的梳齿结构释放工艺。深硅刻蚀工艺的优化为高性能MEMS陀螺的加工提供了基础。     

Structure and NIR feature of QCC: a laboratory analog of carbon dust.

We have produced thin films of quenched carbonaceous composite (QCC) by hydrocarbon plasma deposition. The effect of thermal annealing on QCC has been investigated to understand how QCC, as a laboratory analog of carbon dust, is transformed in the warm environment around evolved stars. Spectroscopic measurements have indicated that, by heating, the proportion of aromatic sp2 CH bonds increases relative to sp3 CH bonds. Carbon onion-like spherules of approximately 10 nm in diameter are found with electron microscopic images after "graphitization" of thermal annealing.     

超外差接收相敏检波在电磁超声检测中的应用

为了提高电磁超声检测接收信号的信噪比,研究和设计了基于超外差接收正交相敏检波技术的电磁超声检测系统.应用该系统分别对铝合金、碳钢和不锈钢试样进行了检测,对接收信号进行了正交相敏检波处理,将处理后的信号同原始接收射频信号进行了对比,分析了中频放大器和相敏检波器中低通滤波器的带宽设置对检测结果的影响.研究结果表明:超外差接收正交相敏检波技术在铝合金、碳钢和不锈钢等非铁磁性或铁磁性金属材料的电磁超声检测中可以起到去噪、提高信噪比的作用.      

An all-sky survey at 230 GHz by MLS on Aura

The Microwave Limb Sounder (MLS) instrument is a small satellite-borne radio telescope. Its purpose is to make limb-scanning measurements of atmospheric composition. One of the gases to which it is sensitive is carbon monoxide (CO), detected via the J = 2 → 1 rotational transition at 230 GHz. CO is present in molecular gas clouds in the Milky Way. Although it was not designed for the purpose, MLS can detect emissions from galactic CO, allowing a map of the 230 GHz radio sky to be constructed. We report the MLS measurements of galactic radio emission and discuss their effect on the atmospheric mission of MLS. The region of the Milky Way with emissions strong enough to significantly affect MLS observations of atmospheric CO is identified. Ground-based radio astronomers have been mapping the sky using CO emission for many years. However, the MLS data are the first such survey to be carried out from space. The MLS survey covers a larger area of the sky than any other 230 GHz survey, but no previously unknown gas clouds are observed.     

Hot atoms in cosmic chemistry

High energy chemical reactions and atom molecule interactions might be important for cosmic chemistry with respect to the accelerated species in solar wind, cosmic rays, colliding gas and dust clouds and secondary knock-on particles in solids. “Hot” atoms with energies ranging from a few eV to some MeV can be generated via nuclear reactions and consequent recoil processes. The chemical fate of the radioactive atoms can be followed by radiochemical methods (radio GC or HPLC). Hot atom chemistry may serve for laboratory simulation of the reactions of energetic species with gaseous or solid interstellar matter. Due to the effective measurement of 10⁸–10¹⁰ atoms only it covers a low to medium dose regime and may add to the studies of ion implantation which due to the optical methods applied are necessarily in the high dose regime.

Experimental results are given for the systems: C/H₂O (gas), C/H₂O (solid, 77 K), N/CH₄ (solid, 77K) and C/NH₃ (solid, 77 K). Nuclear reactions used for the generation of 2 to 3 MeV atoms are: ¹⁴N(p, ) ¹¹C, ¹⁶O(p, pn) ¹¹C and ¹²C(d,n) ¹³N with 8 to 45 MeV protons or deuterons from a cyclotron. Typical reactions products are: CO, CO₂, CH₄, CH₂O, CH₃OH, HCOOH, NH₃, CH₃NH₂, cyanamide, formamidine, guanidine etc. Products of hot reactions in solids are more complex than in corresponding gaseous systems, which underlines the importance of solid state reactions for the build-up of precursors for biomolecules in space. As one of the major mechanisms for product formation, the simultaneous or fast consecutive reactions of a hot carbon with two target molecules (reaction complex) is discussed.     

暴时密度增强区附近电离层不均匀体研究

基于IGS提供的TEC数据, 研究了2003年10月大磁暴期间的暴时密度增强(Storm Enhanced Density, SED)现象; 利用GPS观测数据, 计算出ROTI (Standard deviations of ROT)指数, 分析了SED边界附近电离层小尺度不均匀体结构的时间和空间演变. 研究表明, 在磁暴主相期间SED边界附近不均匀体随着磁暴的发展逐渐增多; 在主相的中后期不均匀体的分布密集度达到最大; 在恢复相期间, 不均匀体分布很少; 随着磁暴的发展, 不均匀体开始主要集中在40~45oN范围内, 随后向高纬漂移, 主要集中在45~55oN范围内.      

掺杂纳米硅薄膜的生长特性

采用等离子增强化学气相沉积(PECVD)方法成功的沉积出掺杂(主要是磷、硼)纳米硅薄膜.探讨了各种生长工艺条件对掺杂纳米硅薄膜的结构与性能的影响及其规律.利用高分辨电镜(HREM)、Raman散射等手段对掺入不同杂质后的纳米硅薄膜的微结构进行初步研究,并从实验和理论上对掺杂纳米硅薄膜的生长特性进行了探讨.得出掺杂纳米硅薄膜具有与掺杂非晶硅薄膜和掺杂微晶硅薄膜不同的生长特性,即杂质原子绝大部分是非活性的,只有很少一部分在薄膜中起施主作用.大部分非活性的杂质原子存在于晶粒间界.     

Exploring for natural gas using reflectance spectra of surface soils

Reflectance spectra in the visible and near-infrared wavelengths provide a rapid and inexpensive means for determining the mineralogy of samples and obtaining information on chemical composition. Hydrocarbon microseepage theory establishes a cause-and-effect relation between oil and gas reservoirs and some special surface anomalies, which mainly include surface hydrocarbon microseepage and related alterations. Therefore, we can explore for oil, gas by determining reflectance spectra of surface anomalies. This idea has been applied to the R&D project of exploring for natural gas in Qinghai province of China using NASA EO-1 satellite with the Hyperion sensor (June 2005 to June 2006). In this project, in order to improve the accuracy of exploration targets of natural gas mapped in the field studied, an integrated practical system of exploration of oil and gas was built by the analysis of not only hyperspectral remote sensing data but also data provided from field work. In this paper, our efforts were focused on the analysis of the 799 reflectance spectra provided from the field work. In order to properly define the typical form of hydrocarbon microseepage with spectroscopy and fulfill the data analysis, it was necessary to build a spectral model. In this spectral model the most important features of hydrocarbon microseepage in the surface of our study area, i.e., diagnostic spectral macroscopic features and diagnostic spectral absorption features, were proposed and extracted, respectively. The distribution of coexisting anomalies, which results from both alteration minerals and hydrocarbons, is estimated by the diagnostic macroscopic features mainly using Spectral Angle Mapper (SAM) classifier. On the other hand, the diagnostic absorption features of two main absorption bands presented abundant local information, based on deep analysis of which, we are able to map the anomalies of alteration minerals and hydrocarbons, respectively. Additionally, a general framework of analysis and key classification algorithms applied to the Hyperion data have been introduced briefly. In our work, three exploration targets of natural gas were identified from the study area which covers 2100 km². In the three exploration targets, three wildcats have been drilled by China National Petroleum Corporation (CNPC) since July 2006, and all the three wells have been proven some industrial reserves.     

掺杂nc-Si:H薄膜中纳米硅晶粒的择优生长

发现PECVD生长的系列掺杂氢化纳米硅(nc-Si:H)薄膜中纳米硅晶粒(nc-Si)有择优生长的趋势.用Raman、XRD、AFM、HRTEM等方法研究其微观结构时发现:掺磷的nc-Si:H薄膜XRD 峰位的二倍衍射角约为33°.掺硼nc-Si:H薄膜的XRD峰位的二倍衍射角约为47°.用自由能密度与序参量的关系结合实验参数分析得到:较高的衬底温度引起序参量改变,使掺磷nc-Si:H薄膜中nc-Si的晶面择优生长.适当的电场作用引起序参量改变,导致掺硼nc-Si:H薄膜在一定的自由能密度范围内nc-Si的晶面择优生长.      

Incineration of biomass and utilization of product gas as a CO2 source for crop production in closed systems: gas quality and phytotoxicity.

This study addressed the recycle of carbon from inedible biomass to CO2 for utilization in crop production. Earlier work identified incineration as an attractive approach to resource recovery from solid wastes because the products are well segregated. Given the effective separation of carbon into the gaseous product stream from the incinerator in the form of CO2 we captured the gaseous stream produced during incineration of wheat inedible biomass and utilized it as the CO2 source for crop production. Injection rate was based on maintenance of CO2 concentration in the growing environment. The crop grown in the closed system was lettuce. Carbon was primarily in the form of CO2 in the incinerator product gas with less than 8% of carbon compounds appearing as CO. Nitrogen oxides and organic compounds such as toluene, xylene, and benzene were present in the product gas at lower concentrations (< 4 micromol mol-1); sulfur containing compounds were below the detection limits. Direct utilization of the gaseous product of the incinerator as the CO2 source was toxic to lettuce grown in a closed chamber. Net photosynthetic rates of the crop was suppressed more than 50% and visual injury symptoms were visible within 3 days of the introduction of the incinerator gas. Even the removal of the incinerator gas alter two days of crop exposure and replacement with pure CO2 did not eliminate the toxic effects. Both organic and inorganic components of the incinerator gas are candidates for the toxin.     

二氧化碳甲烷化在载人航天器再生式环控生保系统中的应用

二氧化碳甲烷化（Sabatier反应）是载人航天再生式环控生保系统中空气质量管理的关键技术,也是焦炉气甲烷化和煤制天然气甲烷化流程中最后一级反应器主要进行的化学反应.化工行业中的二氧化碳甲烷化,尤其是针对高纯度二氧化碳的甲烷化技术,与载人航天用Sabatier技术既有共同点又存在差异.通过对Sabatier技术工艺、催化剂和关键设计的总结,对比分析应用于两个不同领域的二氧化碳甲烷化技术在工艺流程、催化剂和反应器方面的差异,借鉴工业二氧化碳甲烷化技术经验,提出载人航天用Sabatier技术可能的优化方向.