Isotopic Composition of the Solar Wind Inferred from In-Situ Spacecraft Measurements

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gyr ago from the protosolar nebula. Data from space missions and theoretical models indicate that the solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. In anticipation of results from the Genesis mission’s solar-wind implanted samples, we revisit solar wind isotopic abundance data from the high-resolution CELIAS/MTOF spectrometer on board SOHO. In particular, we evaluate the isotopic abundance ratios ¹⁵N/¹⁴N, ¹⁷O/¹⁶O, and ¹⁸O/¹⁶O in the solar wind, which are reference values for isotopic fractionation processes during the formation of terrestrial planets as well as for the Galactic chemical evolution. We also give isotopic abundance ratios for He, Ne, Ar, Mg, Si, Ca, and Fe measured in situ in the solar wind.     

Solar Wind Conditions and Composition During the Genesis Mission as Measured by in situ Spacecraft

We describe the Genesis mission solar-wind sample collection period and the solar wind conditions at the L1 point during this 2.3-year period. In order to relate the solar wind samples to solar composition, the conditions under which the samples were collected must be understood in the context of the long-term solar wind. We find that the state of the solar wind was typical of conditions over the past four solar cycles. However, Genesis spent a relatively large fraction of the time in coronal-hole flow as compared to what might have been expected for the declining phase of the solar cycle. Data from the Solar Wind Ion Composition Spectrometer (SWICS) on the Advanced Composition Explorer (ACE) are used to determine the effectiveness of the Genesis solar-wind regime selection algorithm. The data collected by SWICS confirm that the Genesis algorithm successfully separated and collected solar wind regimes having distinct solar origins, particularly in the case of the coronal hole sample. The SWICS data also demonstrate that the different regimes are elementally fractionated. When compared with Ulysses composition data from the previous solar cycle, we find a similar degree of fractionation between regimes as well as fractionation relative to the average photospheric composition. The Genesis solar wind samples are under long-term curation at NASA Johnson Space Center so that as sample analysis techniques evolve, pristine solar wind samples will be available to the scientific community in the decades to come. This article and a companion paper (Wiens et al. 2013, this issue) provide post-flight information necessary for the analysis of the Genesis array and foil solar wind samples and the Genesis solar wind ion concentrator samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Genesis Solar Wind Concentrator: Computer Simulations of Performance Under Solar Wind Conditions

The design and operation of the Genesis Solar-Wind Concentrator relies heavily on computer simulations. The computer model is described here, as well as the solar wind conditions used as simulation inputs, including oxygen charge state, velocity, thermal, and angular distributions. The simulation included effects such as ion backscattering losses, which also affect the mass fractionation of the instrument. Calculations were performed for oxygen, the principal element of interest, as well as for H and He. Ion fluences and oxygen mass fractionation are determined as a function of radius on the target. The results were used to verify that the instrument was indeed meeting its requirements, and will help prepare for distribution of the target samples upon return of the instrument to earth. The actual instrumental fractionation will be determined at that time by comparing solar-wind neon isotope ratios measured in passive collectors with neon in the Concentrator target, and by using a model similar to the one described here to extrapolate the instrumental fractionation to oxygen isotopes. This revised version was published online in August 2006 with corrections to the Cover Date.     

Solar and Solar-Wind Composition Results from the Genesis Mission

The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and ¹⁵N/¹⁴N and ¹⁸O/¹⁷O/¹⁶O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.     

The Genesis Solar Wind Concentrator

The primary goal of the Genesis Mission is to collect solar wind ions and, from their analysis, establish key isotopic ratios that will help constrain models of solar nebula formation and evolution. The ratios of primary interest include ¹⁷O/¹⁶O and ¹⁸O/¹⁶O to ±0.1%, ¹⁵N/¹⁴N to ±1%, and the Li, Be, and B elemental and isotopic abundances. The required accuracies in N and O ratios cannot be achieved without concentrating the solar wind and implanting it into low-background target materials that are returned to Earth for analysis. The Genesis Concentrator is designed to concentrate the heavy ion flux from the solar wind by an average factor of at least 20 and implant it into a target of ultra-pure, well-characterized materials. High-transparency grids held at high voltages are used near the aperture to reject >90% of the protons, avoiding damage to the target. Another set of grids and applied voltages are used to accelerate and focus the remaining ions to implant into the target. The design uses an energy-independent parabolic ion mirror to focus ions onto a 6.2 cm diameter target of materials selected to contain levels of O and other elements of interest established and documented to be below 10% of the levels expected from the concentrated solar wind. To optimize the concentration of the ions, voltages are constantly adjusted based on real-time solar wind speed and temperature measurements from the Genesis ion monitor. Construction of the Concentrator required new developments in ion optics; materials; and instrument testing and handling. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Genesis Solar-Wind Collector Materials

Genesis (NASA Discovery Mission #5) is a sample return mission. Collectors comprised of ultra-high purity materials will be exposed to the solar wind and then returned to Earth for laboratory analysis. There is a suite of fifteen types of ultra-pure materials distributed among several locations. Most of the materials are mounted on deployable panels (‘collector arrays’), with some as targets in the focal spot of an electrostatic mirror (the ‘concentrator’). Other materials are strategically placed on the spacecraft as additional targets of opportunity to maximize the area for solar-wind collection. Most of the collection area consists of hexagonal collectors in the arrays; approximately half are silicon, the rest are for solar-wind components not retained and/or not easily measured in silicon. There are a variety of materials both in collector arrays and elsewhere targeted for the analyses of specific solar-wind components. Engineering and science factors drove the selection process. Engineering required testing of physical properties such as the ability to withstand shaking on launch and thermal cycling during deployment. Science constraints included bulk purity, surface and interface cleanliness, retentiveness with respect to individual solar-wind components, and availability. A detailed report of material parameters planned as a resource for choosing materials for study will be published on a Genesis website, and will be updated as additional information is obtained. Some material is already linked to the Genesis plasma data website (genesis.lanl.gov). Genesis should provide a reservoir of materials for allocation to the scientific community throughout the 21st Century. This revised version was published online in August 2006 with corrections to the Cover Date.     

Fractionation of SI, NE, and MG Isotopes in the Solar Wind as Measured by Soho/Celias/MTOF

Using the high-resolution mass spectrometer CELIAS/MTOF on board SOHO we have measured the solar wind isotope abundance ratios of Si, Ne, and Mg and their variations in different solar wind regimes with bulk velocities ranging from 330 km/s to 650 km/s. Data indicate a small systematic depletion of the heavier isotopes in the slow solar wind on the order of (1.4±1.3)% per amu (2σ-error) compared to their abundances in the fast solar wind from coronal holes. These variations in the solar wind isotopic composition represent a pure mass-dependent effect because the different isotopes of an element pass the inner corona with the same charge state distribution. The influence of particle mass on the acceleration of minor solar wind ions is discussed in the context of theoretical models and recent optical observations with other SOHO instruments. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Genesis Solar Wind Concentrator Target: Mass Fractionation Characterised by Neon Isotopes

The concentrator on Genesis provided samples of increased fluences of solar wind ions for precise determination of the oxygen isotopic composition. The concentration process caused mass fractionation as a function of the radial target position. This fractionation was measured using Ne released by UV laser ablation and compared with modelled Ne data, obtained from ion-trajectory simulations. Measured data show that the concentrator performed as expected and indicate a radially symmetric concentration process. Measured concentration factors are up to ∼30 at the target centre. The total range of isotopic fractionation along the target radius is 3.8%/amu, with monotonically decreasing ²⁰Ne/²²Ne towards the centre, which differs from model predictions. We discuss potential reasons and propose future attempts to overcome these disagreements.     

Isotopic Fractionation by Plasma Processes

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gy ago from the protosolar nebula. The solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. Data from space missions and theoretical models indicate that the isotopes of the volatile elements N, O, Ne, and Ar are fractionated by at most a few percent per atomic mass unit in different solar wind regimes. In contrast, isotopic abundances of solar and heliospheric energetic particles at energies larger than about 100 keV/amu are observed to strongly vary relative to solar abundances. Processes such as resonant acceleration or pre-acceleration by plasma waves, first-order Fermi acceleration, or propagation in the interplanetary plasma are discussed as causes for charge-to-mass dependent fractionation. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Genesis Discovery Mission: Return of Solar Matter to Earth

The Genesis Discovery mission will return samples of solar matter for analysis of isotopic and elemental compositions in terrestrial laboratories. This is accomplished by exposing ultra-pure materials to the solar wind at the L1 Lagrangian point and returning the materials to Earth. Solar wind collection will continue until April 2004 with Earth return in Sept. 2004. The general science objectives of Genesis are to (1) to obtain solar isotopic abundances to the level of precision required for the interpretation of planetary science data, (2) to significantly improve knowledge of solar elemental abundances, (3) to measure the composition of the different solar wind regimes, and (4) to provide a reservoir of solar matter to serve the needs of planetary science in the 21st century. The Genesis flight system is a sun-pointed spinner, consisting of a spacecraft deck and a sample return capsule (SRC). The SRC houses a canister which contains the collector materials. The lid of the SRC and a cover to the canister were opened to begin solar wind collection on November 30, 2001. To obtain samples of O and N ions of higher fluence relative to background levels in the target materials, an electrostatic mirror (‘concentrator’) is used which focuses the incoming ions over a diameter of about 20 cm onto a 6 cm diameter set of target materials. Solar wind electron and ion monitors (electrostatic analyzers) determine the solar wind regime present at the spacecraft and control the deployment of separate arrays of collector materials to provide the independent regime samples. This revised version was published online in August 2006 with corrections to the Cover Date.     

Structure of the Solar Wind and Compositional Variations

The composition of the solar wind is largely determined by the composition of the source material, i.e. the present-day composition of the outer convective zone. It is then modified by the processes which operate in the transition region and in the inner corona. In situ measurements of the solar wind composition give a unique opportunity to obtain information on the isotopic and elemental composition of the Sun. However, elemental — and to some degree also isotopic — fractionation can occur in the flow of matter from the outer convective zone into the interplanetary space. The most important examples of elemental fractionation are the well-known FIP/FIT effect (First Ionization Potential/Time) and the sometimes dramatic variations of the helium abundance relative to hydrogen in the solar wind. A thorough investigation of fractionation processes which cause compositional variations in different solar wind regimes is necessary to make inferences about the solar source composition from solar wind observations. Our understanding of these processes is presently improving thanks to the detailed diagnostics offered by the optical instrumentation on SOHO. Correlated observations of particle instruments on Ulysses, WIND, and SOHO, together with optical observations will help to make inferences for the solar composition. Continuous in situ observations of several isotopic species with the particle instruments on WIND and SOHO are currently incorporated into an experimental database to infer isotopic fractionation processes which operate in different solar wind regimes between the solar surface and the interplanetary medium. Except for the relatively minor effects of secular gravitational sedimentation which works at the boundary between the outer convective zone and the radiative zone, refractory elements such as Mg can be used as faithful witnesses to monitor the magnitude of these processes. With theoretical considerations it is possible to make inferences about the importance of isotopic fractionation in the solar wind from a comparison of optical and in situ observations of elemental fractionation with the corresponding models. Theoretical models and preliminary results from particle observations indicate that the combined isotope effects do not exceed a few percent per mass unit. In the worst case, which concerns the astrophysically important 3He/4He ratio, we expect an overall effect of at most several percent in the sense of a systematic depletion of the heavier isotope. Continued observations with WIND, SOHO, and ACE, and, with the revival of the foil technique, with the upcoming Genesis mission will further consolidate our knowledge about the relation between solar wind dynamics and solar wind composition. This revised version was published online in June 2006 with corrections to the Cover Date.     

Genesis on-board determination of the solar wind flow regime

Some of the objectives of the Genesis mission require the separate collection of solar wind originating in different types of solar sources. Measurements of the solar wind protons, alpha particles, and electrons are used on-board the spacecraft to determine whether the solar-wind source is most likely a coronal hole, interstream flow, or a coronal mass ejection. A simple fuzzy logic scheme operating on measurements of the proton temperature, the alpha-particle abundance, and the presence of bidirectional streaming of suprathermal electrons was developed for this purpose. Additional requirements on the algorithm include the ability to identify the passage of forward shocks, reasonable levels of hysteresis and persistence, and the ability to modify the algorithm by changes in stored constants rather than changes in the software. After a few minor adjustments, the algorithm performed well during the initial portion of the mission. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.     

The Plasma Ion and Electron Instruments for the Genesis Mission

The Genesis Ion Monitor (GIM) and the Genesis Electron Monitor (GEM) provide 3-dimensional plasma measurements of the solar wind for the Genesis mission. These measurements are used onboard to determine the type of plasma that is flowing past the spacecraft and to configure the solar wind sample collection subsystems in real-time. Both GIM and GEM employ spherical-section electrostatic analyzers followed by channel electron multiplier (CEM) arrays for detection and angle and energy/charge analysis of incident ions and electrons. GIM is of a new design specific to Genesis mission requirements whereas the GEM sensor is an almost exact copy of the plasma electron sensors currently flying on the ACE and Ulysses spacecraft, albeit with new electronics and programming. Ions are detected at forty log-spaced energy levels between ∼ 1 eV and 14 keV by eight CEM detectors, while electrons with energies between ∼ 1 eV and 1.4 keV are measured at twenty log-spaced energy levels using seven CEMs. The spin of the spacecraft is used to sweep the fan-shaped fields-of-view of both instruments across all areas of the sky of interest, with ion measurements being taken forty times per spin and samples of the electron population being taken twenty four times per spin. Complete ion and electron energy spectra are measured every ∼ 2.5 min (four spins of the spacecraft) with adequate energy and angular resolution to determine fully 3-dimensional ion and electron distribution functions. The GIM and GEM plasma measurements are principally used to enable the operational solar wind sample collection goals of the Genesis mission but they also provide a potentially very useful data set for studies of solar wind phenomena, especially if combined with other solar wind data sets from ACE, WIND, SOHO and Ulysses for multi-spacecraft investigations. This revised version was published online in August 2006 with corrections to the Cover Date.     

Elemental Abundances of the Bulk Solar Wind: Analyses from Genesis and ACE

Analysis of the Genesis samples is underway. Preliminary elemental abundances based on Genesis sample analyses are in good agreement with in situ-measured elemental abundances made by ACE/SWICS during the Genesis collection period. Comparison of these abundances with those of earlier solar cycles indicates that the solar wind composition is relatively stable between cycles for a given type of flow. ACE/SWICS measurements for the Genesis collection period also show a continuum in compositional variation as a function of velocity for the quasi-stationary flow that defies the simple binning of samples into their sources of coronal hole (CH) and interstream (IS).     

Composition of Light Solar Wind Noble Gases in the Bulk Metallic Glass flown on the Genesis Mission

We discuss data of light noble gases from the solar wind implanted into a metallic glass target flown on the Genesis mission. Helium and neon isotopic compositions of the bulk solar wind trapped in this target during 887 days of exposure to the solar wind do not deviate significantly from the values in foils of the Apollo Solar Wind Composition experiments, which have been exposed for hours to days. In general, the depth profile of the Ne isotopic composition is similar to those often found in lunar soils, and essentially very well reproduced by ion-implantation modelling, adopting the measured velocity distribution of solar particles during the Genesis exposure and assuming a uniform isotopic composition of solar wind neon. The results confirm that contributions from high-energy particles to the solar wind fluence are negligible, which is consistent with in-situ observations. This makes the enigmatic “SEP-Ne” component, apparently present in lunar grains at relatively large depth, obsolete. ²⁰Ne/ ²²Ne ratios in gas trapped very near the metallic glass surface are up to 10% higher than predicted by ion implantation simulations. We attribute this superficially trapped gas to very low-speed, current-sheet-related solar wind, which has been fractionated in the corona due to inefficient Coulomb drag.     

The Heliospheric Magnetic Field and Its Extension to the Inner Heliosheath

The general structure of the heliospheric magnetic field is well known and has been extensively studied, mostly in the inner heliosphere, out to the orbit of Saturn. Beyond 10 AU, the Pioneer and now the Voyager spacecraft have provided a view of the outer heliosphere. Its structure is strongly affected by large-scale phenomena originating in the Sun’s activity, such as the pattern of fast and slow solar wind streams around solar minimum that lead to Corotating Interaction Regions, and the increased frequency and strength of Coronal Mass Ejections around solar maximum. The large current sheet that separates the dominant magnetic polarities in the heliospheric medium, the Heliospheric Current Sheet, provides a variable structure that evolves from a relatively simple geometry close to the solar equatorial plane to what is likely to be a highly complex and dynamic surface reaching to high heliolatitudes at high levels of solar activity. The magnetic field observed in a fluctuating, dynamical heliosheath differs considerably from that in a static heliosheath. In particular, the time between current-sheet crossings (sectors) is quite sensitive to the radial speed of the solar-wind termination shock. If an inwardly moving termination shock moves past an observer on a slowly moving spacecraft, the time between current-sheet crossings in the heliosheath becomes larger, and can become very large, for reasonably expected inward shock speeds. This effect may help to explain recent observations of the magnetic field from the Voyager 1 spacecraft, where, in the heliosheath, the magnetic field remained directed outward from the Sun for several months without a current-sheet crossing. The crossings finally resumed and now occur somewhat regularly. In addition, the magnetic fluctuations in the heliosheath are observed to be quite different from those in the supersonic upstream solar wind.     

Direct observations of solar-wind particles

Direct observations of solar-wind particles are discussed in detail. A well-defined quiet state of the solar wind is indicated by observations made from 1962 to 1967. The plasma properties in this quiet state are compared with those predicted by hydrodynamic models of the coronal expansion. While the basic flow parameters are predicted with reasonable accuracy by these models, the thermal properties of the solar-wind particles remain largely unexplained. As the interplanetary plasma is not in thermodynamic equilibrium, the thermal properties are determined by the specific energy-transfer mechanisms operative in the plasma. The observed magnitude of the magnetic-field-aligned anisotropy of proton random motions is interpreted as evidence for the presence of instability-generated waves; the effect of these waves on the thermal properties is examined. The observed chemical compositon of the solar wind is discussed and related to the solar origin of the inter-planetary material. Finally, the spatial and temporal structure of the medium is investigated through consideration of patterns of variation in the plasma properties.     

CIR Associated Energetic Particles in the Inner and Middle Heliosphere

Energetic particles associated with Corotating Interaction Regions (CIRs) are observed throughout the inner and middle heliosphere, showing large positive (>100%/AU) radial intensity gradients. Their appearance at 1 AU is associated with the appearance of fast, recurrent solar wind streams. At several AU, CIR energetic particles are accelerated at shocks which propagate away from the interface of fast and slow solar wind streams. CIR energy spectra at 1 AU cover the range >35 keV to several MeV/amu; the spectra steepen above ∼1 MeV/amu, and show no turnover even at the lowest energies. The ion composition of CIRs is similar to solar material, but with significant differences that might be due to properties of the seed population and/or the acceleration process. This paper summarizes properties of energetic particles in CIRs as known through the early 1990s, prior to the launch of the Ulysses, and WIND spacecraft, whose new results are presented in Kunow, Lee et al. (1999) in this volume. This revised version was published online in August 2006 with corrections to the Cover Date.     

Nickel Isotopic Composition and Nickel/Iron Ratio in the Solar Wind: Results from SOHO/CELIAS/MTOF

Using the Mass Time-of-Flight Spectrometer (MTOF)—part of the Charge, Elements, Isotope Analysis System (CELIAS)—onboard the Solar Heliospheric Observatory (SOHO) spacecraft, we derive the nickel isotopic composition for the isotopes with mass 58, 60 and 62 in the solar wind. In addition we measure the elemental abundance ratio of nickel to iron. We use data accumulated during ten years of SOHO operation to get sufficiently high counting statistics and compare periods of different solar wind velocities. We compare our values with the meteoritic ratios, which are believed to be a reliable reference for the solar system and also for the solar outer convective zone, since neither element is volatile and no isotopic fractionation is expected in meteorites. Meteoritic isotopic abundances agree with the terrestrial values and can thus be considered to be a reliable reference for the solar isotopic composition. The measurements show that the solar wind elemental Ni/Fe-ratio and the isotopic composition of solar wind nickel are consistent with the meteoritic values. This supports the concept that low-FIP elements are fed without relative fractionation into the solar wind. Our result also confirms the absence of substantial isotopic fractionation processes for medium and heavy ions acting in the solar wind.