The carbonaceous chondrites

The carbonaceous chondrites are a group of stony meteorites characterized by the presence of an appreciable amount of carbonaceous material other than free carbon (diamond and graphite). They have been divided into three subgroups known respectively as Type I, Type II, and Type III. Analyses of Type I meteorites show about 3–5% of carbon and 20% of combined water; they consist largely of hydrated magnesium-iron silicate, magnetite, and magnesium sulfate, contain no chondrules, and have a density about 2.2. Analyses of Type II meteorites show about 2–3% of carbon and 10–15% of combined water; they consist of a groundmass of hydrated magnesium-iron silicate enclosing chondrules of olivine and pyroxene which are almost iron-free, and have a density of 2.6–2.9. Analyses of Type III meteorites show about 0.5–2% of carbon and 2% combined water; they consist largely of olivine (often variable in composition, but averaging 30–40 mole per cent Fe₂SiO₄), with accessory pigeonite and sulfide minerals, and have a density about 3.4.The carbonaceous material and combined water in these meteorites are clearly of extraterrestrial origin, but their significance is not well understood. A biological origin has been claimed for some of the organic compounds on the basis of their composition, but this claim is the subject of considerable dispute. Microscopic objects with regular outline (organized elements) have been recognized in some of these meteorites; some investigators have claimed these to be extraterrestrial fossils, others have ascribed them to terrestrial contamination or considered them to be crystals or crystal aggregates of non-biological origin.     

Hydrocarbons in terrestrial samples and the Orgueil meteorite

Meteorites contain extraterrestrial carbonaceous materials. The Alais, Orgueil, Tonk, and Ivuna meteorites resemble in their carbon, free sulfur, and non-metamorphosed mineral contents, densities, and general appearances certain organic-rich terrestrial sediments. Structural and isotopic determinations of carbon compounds in the Orgueil chondrite indicate that these compounds are primarily indigenous. Physically and chemically the benzene extractable carbonaceous materials from the Orgueil and certain near-surface terrestrial sediments are similar. Mass spectrometric type analyses of the alkanes from an Orgueil fragment, terrestrial sediments and organisms are statistically indistinguishable at the 95 per cent confidence level. Theoretical considerations and experimental data are presented, and these permit an assessment of the potential and reliability of hydrocarbons as biological indicators. Based on the production and preservation or organic substances in terrestrial environments, alkanes in the Alais, Orgueil, Tonk, and Ivuna (Type I) carbonaceous chondrites could retain the best evidence of organisms that may have lived on a parent body of meteorites.A portion of the research reported in this article was supported by the National Aeronautics and Space Administration under Contract No. NASw 508.     

The Mighei meteorite

The Mighei meteorite is generally considered to be unique amongst the group of stony meteorites known as the carbonaceous chondrites in a number of scientifically interesting aspects. The meteorite, which is related to the type II carbonaceous chondrites of Wiik's classification (or type C2 according to van Schmus and Wood), contains extraterrestrial organic compounds (general C content = 2.6%), and extraterrestrial water associated with iron-magnesium silicate crystals (general H₂O content=12%).The meteorite fall occurred in 1889, over a region in the Ukraine. In structure it was found to be a chondritic meteorite, having chondrules of order 0.5 mm in size. The composition of the meteorite is inhomogeneous. In mineralogical terms the meteorite is composed of two paragenetic associations, described as high and low temperature, which are generally distributed in equal proportions. The low temperature associations are a characteristic only of carbonaceous chondrites: the minerals involved are chlorites or the serpentine group, carbonates, free sulphur, sulphates and low temperature glass. In chemical terms the Mighei meteorite is somewhat enriched in the volatile elements S, C, H, N, O in comparison to the usual chondrites. These elements are found in different forms and the isotopic composition of the elements S, C, O, is different for different phases. The meteorite is also rich in a number of other fairly volatile element admixtures such as: B, F, Cl, Cu, Zn, Ga, Ge, Br, In, Te, I, Hg, Tl, Pb, Bi, and contains somewhat enhanced initial quantities of rare gases.The organic compounds are of an abiological nature in the meteorite and are located in finely dispersed distributions between the chondrules. They are present in the main, as polymerized organic compounds. Among these polymers there are gaseous hydrocarbons (saturated and non-saturated) and extractable organic compounds. In the latter condition the following organic compounds have been identified: aliphatic hydrocarbons, aromatic hydrocarbons, amino acids and others. The meteorite contains free organic radicals (10¹⁷ centres g^–1), uncoupled -electrons which are delocalized in the aromatic structure of the polymeric matter.The radiogenic age of the meteorite has been determined as from 2.4 to 3.2 × 10⁹ yr (by the K-Ar method) and up to 4.54 × 10⁹ yr (by the Rb-Sr method), while the radiation age is put at 0.5 to 2.4 × 10⁶ yr. Details of the meteorite structure give evidence of at least two processes in its formation; the accretion of the meteoritic matter, together with the simultaneous formation of organic compounds could have taken place at temperatures between 450 and 300 K.Reported on the XIV Meteoritic Conference, December 17, 1970, Moscow.     

Rosina – Rosetta Orbiter Spectrometer for Ion and Neutral Analysis

The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) will answer important questions posed by the mission’s main objectives. After Giotto, this will be the first time the volatile part of a comet will be analyzed in situ. This is a very important investigation, as comets, in contrast to meteorites, have maintained most of the volatiles of the solar nebula. To accomplish the very demanding objectives through all the different phases of the comet’s activity, ROSINA has unprecedented capabilities including very wide mass range (1 to >300 amu), very high mass resolution (m/Δ m > 3000, i.e. the ability to resolve CO from N₂ and ¹³C from ¹²CH), very wide dynamic range and high sensitivity, as well as the ability to determine cometary gas velocities, and temperature. ROSINA consists of two mass spectrometers for neutrals and primary ions with complementary capabilities and a pressure sensor. To ensure that absolute gas densities can be determined, each mass spectrometer carries a reservoir of a calibrated gas mixture allowing in-flight calibration. Furthermore, identical flight-spares of all three sensors will serve for detailed analysis of all relevant parameters, in particular the sensitivities for complex organic molecules and their fragmentation patterns in our electron bombardment ion sources.     

Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Organic constituents of the carbonaceous chondrites

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers.Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded that most of the organic constituents are indigenous to the meteorites and are extra terrestial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin.A brief review on studies of organized elements contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some micro-structures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.Contribution from the Chemistry Section, Space Science Division of Jet Propulsion Laboratory.     

Isotopic analysis of cometary organic matter

Carbon isotope ratios have been measured for CN in the coma of comet Halley and for several CHON particles emitted by Halley. Of these, only the CHON-particle data may be reasonably related to organic matter in the cometary nucleus, but the true range of ¹³C/¹²C values in those particles is quite uncertain. The D/H ratio in H₂O in the Halley coma resembles that in Titan/Uranus. The next decade should substantially improve our understanding of the distribution of C, H, N, and O isotopes in cometary organics. The isotopic composition of meteoritic organic matter is better understood and can serve as a useful analog for the cometary case.     

Core Formation and Mantle Differentiation on Mars

Geochemical investigation of Martian meteorites (SNC meteorites) yields important constraints on the chemical and geodynamical evolution of Mars. These samples may not be representative of the whole of Mars; however, they provide constraints on the early differentiation processes on Mars. The bulk composition of Martian samples implies the presence of a metallic core that formed concurrently as the planet accreted. The strong depletion of highly siderophile elements in the Martian mantle is only possible if Mars had a large scale magma ocean early in its history allowing efficient separation of a metallic melt from molten silicate. The solidification of the magma ocean created chemical heterogeneities whose ancient origin is manifested in the heterogeneous ¹⁴²Nd and ¹⁸²W abundances observed in different meteorite groups derived from Mars. The isotope anomalies measured in SNC meteorites imply major chemical fractionation within the Martian mantle during the life time of the short-lived isotopes ¹⁴⁶Sm and ¹⁸²Hf. The Hf-W data are consistent with very rapid accretion of Mars within a few million years or, alternatively, a more protracted accretion history involving several large impacts and incomplete metal-silicate equilibration during core formation. In contrast to Earth early-formed chemical heterogeneities are still preserved on Mars, albeit slightly modified by mixing processes. The preservation of such ancient chemical differences is only possible if Mars did not undergo efficient whole mantle convection or vigorous plate tectonic style processes after the first few tens of millions of years of its history.     

On the Isotopic Composition of Primordial Xenon in Terrestrial Planet Atmospheres

Xenon plays a crucial role in models of atmospheric evolution in which noble gases are fractionated from their initial compositions to isotopically heavier distributions by early hydrodynamic escape of primordial planetary atmospheres. With the assumption that nonradiogenic Xe isotope ratios in present-day atmospheres were generated in this way, backward modeling from these ratios through the fractionating process can in principle identify likely parental Xe compositions and thus the probable sources of noble gases in pre-escape atmospheres. Applied to Earth, this approach simultaneously establishes the presence of an atmospheric Xe component due principally to fission of extinct ²⁴⁴Pu and identifies a composition called U-Xe as primordial Xe. Pu-Xe comprises 4.65±0.30% of atmospheric ¹³⁶Xe, and 6.8±0.5% of the present abundance of ¹²⁹Xe derives from decay of extinct ¹²⁹I. U-Xe is identical to the measured composition of solar-wind Xe except for deficits of the two heaviest isotopes – an unexpected difference since the modeling otherwise points to solar wind compositions for the lighter noble gases in the primordial terrestrial atmosphere. Evidence for the presence of U-Xe is not restricted to the early Earth; modeling based on a purely meteoritic data set defines a parental component in chondrites and achondrites with the same isotopic distribution. Results of experimental efforts to measure this composition directly in meteorites are promising but not yet conclusive. U-Xe also appears as a possible base component in interstellar silicon carbide, here with superimposed excesses of ¹³⁴Xe and ¹³⁶Xe six-fold larger than those in the solar wind. These compositional differences imply mixing of U-Xe with a nucleogenetic heavy-isotope component whose relative abundance in the solar accretion disk and in pre-solar environments varied both spatially and temporally. In contrast to Earth, the U-Xe signature on Mars was apparently overwhelmed by local accretion of materials rich in either chondritic Xe or solar-wind Xe. Data currently in hand from SNC meteorites on the composition of the present atmosphere are insufficiently precise to constrain a modeling choice between these two candidates for primordial martian Xe. They likewise do not permit definitive resolution of a ²⁴⁴Pu component in the atmosphere although its presence is allowed within current measurement uncertainties. This revised version was published online in June 2006 with corrections to the Cover Date.     

Origin,age, and composition of meteorites

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites.The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstätten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstätten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe₄C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four.The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. Hybrid meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt.Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one.The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body.As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with 10¹⁷ protons/cm² at a very early stage of its history.There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Öpik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites.The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km).Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

The Beginning: Swift and Violent

Radiometric dating shows that the earliest steps in forming the substance of meteorites and assembling it into planetesimals occurred in a very short interval of time, 1–2 Ma. This study shows that rapid formation is also dictated by the need to use short-lived ²⁶Al (half-life T _1/2=0.74 Ma) as a heat source to metamorphose and in some cases melt the meteorite parent bodies after they accreted. The earliest events in solar system history dated by cosmochemists, formation at high temperatures of the Ca,Al-rich inclusions that occur in chondritic meteorites, probably occurred during the most energetic stage of protosolar disk evolution, as the protosun neared its present mass and infall drew to a close. This revised version was published online in June 2006 with corrections to the Cover Date.     

Ureilites

Ureilites are a rare group of five stony meteorites — feldsparless achondrites containing diamonds of preterrestrial origin the total weight of them being 315 carats. The whole carbon content in ureilites makes up 1.5–4.1%. Ureilites substantially differ from the other stony meteorites. In comparison with chondrites they are enriched in Mg but depleted in metal, troilite, alkaline elements. All ureilites are very similar by their structure. They contain elongated cavities generally stretched in the same direction. The structure of ureilites is an achondritic porphyric one. These meteorites consist of large olivine grains, there is less clinopyroxene (pigeonite). They contain kamacite (Ni content being 1.5–4%), troilite FeS, chromite. Carbon material is represented by diamond, graphite and organic material being present in a disequilibrium state. Two ureilites (North Haig and Dingo Pup Donga) were considerably oxidized during terrestrial weathering and contain secondary iron oxides.Diamonds are present in ureilites in thin intergrowths with graphite being disposed between silicate grains more or less evenly in the meteorite. The sizes of such black diamond-graphite aggregates are 0.3–0.9 mm. The sizes of the micromonocrystals of diamond and graphite are less than 1. The diamond-graphite aggregates contain dispersed particles of kamacite, troilite, chromite, nickelchrome, being present in very thin intergrowths with one another. Besides the usual diamond there is an admixture of lonsdaleite in the aggregates representing a hexagonal diamond with a würtzite-like structure. Lonsdaleite has been identified in the ureilites Novo Urei, Goalpara, North Haig. The diamonds of ureilites are characterized by inhomogeneities in the crystalline structure which are at least partly caused by the presence of donor nitrogen. According to the isotopic carbon composition the diamond in the meteorite Novo Urei has the value C¹³ = -5.7.The structure peculiarities of ureilites bear witness of the fact that these meteorites had been subject to the action of dynamic pressure about 300–600 kbar. The impact had taken place in cosmic space. All ureilites subdivide into two types: the first type are Novo Urei, Dyalpur, Dingo Pup Donga, the second type are Goalpara, North Haig according to the following signs: (1) olivine grains are finer in ureilites of the second type; (2) twinning is more typical of clinopyroxenes of ureilites belonging to the first type; (3) in ureilites of the first type a net-like iron distribution is observed, in ureilites of the second type kamacite plates are chiefly present between silicate grains; (4) the size of diamondgraphite intergrowths in ureilites of the first type does not exceed 0.3 mm, in ureilites of the second type it reaches 0.9 mm. Ureilites of the first type have undergone a less intensive impact than ureilites of the second type. Certain similarity of the material composition of ureilites and of the material composition of carbonaceous chondrites, the distinction of these two groups of meteorites from all other meteorites bear witness of the fact that ureilites have formed from carbonaceous chondrites during a collision of asteroid bodies in cosmic space, diamonds having been formed from the carbon material of carbonaceous chondrites.     

The D/H Ratio in Chondrites

The statistical distribution of all available published D/H ratios of carbonaceous chondrites is presented. The possible interpretations of this distribution are reviewed at the global scale of the solar system planetary objects and at the scale defined by the carbonaceous meteorites. New issues concerning the chemical origin of the deuterium enrichment in solar system water and organic molecules are put into light by this exercise. This distribution is a robust constraint on the origin of water on Earth. This revised version was published online in August 2006 with corrections to the Cover Date.     

OB Associations, Wolf–Rayet Stars, and the Origin of Galactic Cosmic Rays

We have measured the isotopic abundances of neon and a number of other species in the galactic cosmic rays (GCRs) using the Cosmic Ray Isotope Spectrometer (CRIS) aboard the ACE spacecraft. Our data are compared to recent results from two-component (Wolf–Rayet material plus solar-like mixtures) Wolf–Rayet (WR) models. The three largest deviations of galactic cosmic ray isotope ratios from solar-system ratios predicted by these models, ¹²C/¹⁶O, ²²Ne/²⁰Ne, and ⁵⁸Fe/⁵⁶Fe, are very close to those observed. All of the isotopic ratios that we have measured are consistent with a GCR source consisting of ∼20% of WR material mixed with ∼80% material with solar-system composition. Since WR stars are evolutionary products of OB stars, and most OB stars exist in OB associations that form superbubbles, the good agreement of our data with WR models suggests that OB associations within superbubbles are the likely source of at least a substantial fraction of GCRs. In previous work it has been shown that the primary ⁵⁹Ni (which decays only by electron-capture) in GCRs has decayed, indicating a time interval between nucleosynthesis and acceleration of >10⁵ y. It has been suggested that in the OB association environment, ejecta from supernovae might be accelerated by the high velocity WR winds on a time scale that is short compared to the half-life of ⁵⁹Ni. Thus the ⁵⁹Ni might not have time to decay and this would cast doubt upon the OB association origin of cosmic rays. In this paper we suggest a scenario that should allow much of the ⁵⁹Ni to decay in the OB association environment and conclude that the hypothesis of the OB association origin of cosmic rays appears to be viable.     

Shear Flow Instabilities in Low-Beta Space Plasmas

We study instabilities driven by a sheared plasma flow in the low-frequency domain. Two unstable branches are found: the ion-sound mode and the kinetic Alfvén mode. Both instabilities are aperiodic. The ion-sound instability does not depend on the plasma β (gas/magnetic pressure ratio) and has a maximum growth rate of about 0.1 of the velocity gradient dV ₀/dx. On the other hand, the kinetic Alfvén instability is stronger for larger β and dominates the ion-sound instability for β > 0.05. Possible applications for space plasmas are shortly discussed.     

Evidence for a Two-Stage Acceleration Process in Large Solar Energetic Particle Events

Using high-resolution mass spectrometers on board the Advanced Composition Explorer (ACE), we surveyed the event-averaged ∼0.1–60 MeV/nuc heavy ion elemental composition in 64 large solar energetic particle (LSEP) events of cycle 23. Our results show the following: (1) The Fe/O ratio decreases with increasing energy up to ∼10 MeV/nuc in ∼92% of the events and up to ∼60 MeV/nuc in ∼64% of the events. (2) The rare isotope ³He is greatly enhanced over the corona or the solar wind values in 46% of the events. (3) The heavy ion abundances are not systematically organized by the ion’s M/Q ratio when compared with the solar wind values. (4) Heavy ion abundances from C–Fe exhibit systematic M/Q-dependent enhancements that are remarkably similar to those seen in ³He-rich SEP events and CME-driven interplanetary (IP) shock events. Taken together, these results confirm the role of shocks in energizing particles up to ∼60 MeV/nuc in the majority of large SEP events of cycle 23, but also show that the seed population is not dominated by ions originating from the ambient corona or the thermal solar wind, as previously believed. Rather, it appears that the source material for CME-associated large SEP events originates predominantly from a suprathermal population with a heavy ion enrichment pattern that is organized according to the ion’s mass-per-charge ratio. These new results indicate that current LSEP models must include the routine production of this dynamic suprathermal seed population as a critical pre-cursor to the CME shock acceleration process.     

On The 53Mn Heterogeneity In The Early Solar System

It is well established that the prolonged and thorough mixing of numerous nucleosynthetic components that constitutes the matter in the solar nebula resulted in an essential isotopic homogeneity of the solar system material. This may or may not be true for the short-lived radionuclides which were injected into or formed within the solar nebula just prior to or during solar system formation. Distinguishing between their heterogeneous or homogeneous distribution is important because the short- lived radionuclides are now widely used for the relative chronology of various objects and processes in the early solar system and as constraints for models of nucleosynthesis. The recent studies of the ⁵³Mn-⁵³Cr isotope system (half life of ⁵³Mn is 3.7 Ma) in various solar system objects have shown that the relative abundance of radiogenic ⁵³Cr is consistent with essentially homogeneous distribution of ⁵³Mn in the asteroid belt. Thus, the relative ⁵³Mn-⁵³Cr chronometer can be directly used for dating samples which originated in the asteroid belt. Importantly, however, all meteorite groups studied so far indicate a clear excess of ⁵³Cr as compared to Earth and to a lunar sample, which exhibits also a terrestrial ⁵³Cr/⁵²Cr ratio. The results from the Martian (SNC) meteorites show that their ⁵³Cr excesses are less than half of those found in the asteroid belt bodies. Thus, the characteristic ⁵³Cr/⁵²Cr ratio of Mars is intermediate between that of the Earth-Moon system and those of the other meteorites. If these ⁵³Cr variations are viewed as a function of the heliocentric distance, the radial dependence of the relative abundances of radiogenic ⁵³Cr is indicated. This observed gradient can be explained by either an early, volatility controlled, Mn/Cr fractionation within the nebula or by an initial radial heterogeneous distribution of ⁵³Mn. Although model calculations of the Mn/Cr ratios in the bulk terrestrial planets seem to be inconsistent with the volatility driven scenario, the precision of these calculations is inadequate for eliminating this possibility. In contrast, recent studies of the ⁵³Mn-⁵³Cr system in the enstatite chondrites indicate that, while their bulk Mn/Cr ratios are essentially the same as in ordinary chondrites, the ⁵³Cr excess in bulk enstatite chondrites is three times lower than that in the bulk ordinary chondrites. This difference cannot be explained by a Mn/Cr fractionation and, thus, strongly suggests that a radial heterogeneous distribution of ⁵³Mn must have existed in at least the early inner solar system. Using the observed gradient and the ⁵³Cr/⁵²Cr ratio of the bulk enstatite chondrites, their parent body(ies) formed at ∼1.4 AU or somewhat closer to the Sun. This revised version was published online in June 2006 with corrections to the Cover Date.     

EXOSAT observations of the bright X-ray source GX9+1

We present the results of the spectral and timing analysis of an observation of GX9+1/4U1758-205 performed with the Medium Energy Experiment aboard EXOSAT. During our observation the source flux varied irregularly in time scales from minutes to hours. No periodic emission in the period range from 16 msec to 2000 sec was found with an upper limit of around 1% (3 ) for the pulsed fraction. The hardness ratio shows a correlated change with the flux intensity (Sco X-1 behaviour). The spectrum could be fitted by a double component model, a black body component (kT=1.16–1.26 keV) together with a thermal bremsstrahlung law (kT=13–15keV). The black-body temperature-black-body flux relation follows a Stefan Boltzmann law with R_BB=15.3 km^*D/10 kpc. No iron line was detected. The upper limit for the line equivalent width of a 6.7 keV iron emission line is 40 eV (1). The X-ray spectral behaviour of GX9+1 indicates, that this source belongs to the class of Low-Mass X-ray Binaries (LMXB).