Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

Solar and Solar-Wind Composition Results from the Genesis Mission

The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and ¹⁵N/¹⁴N and ¹⁸O/¹⁷O/¹⁶O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.     

On Noble Gas Processing in the Solar Accretion Disk

Two fractionation models are applied to the problem of generating the widely distributed “Q-component” noble gases in meteorites from the solar-like isotopic and elemental compositions that presumably characterized the early solar accretion disk. Noble gas fractionation by mass-dependent dissipation of the solar nebula, as suggested by Ozima et al. (1998), is examined in the context of a model developed by Johnstone et al. (1998) for accretion disk photoevaporation driven by intense UV radiation from a neighboring giant star. Hydrodynamic escape of heavier species entrained in hydrogen outflow from the UV-heated outer regions of the disk can generate substantial noble gas fractionations, but they do not match the observed Q-component isotopic pattern and moreover require the physically unrealistic assumption that the fractionated gases are confined to the heated disk boundary zone, without mixing with the interior nebula, for long periods of time. It seems more likely that hydrodynamic outflow is actually established below this zone, in the body of the disk. In this case fractionations are governed by Rayleigh distillation of the entire remaining nebula, and are negligible at the time when disk erosion is halted by the gravitational potential of the young sun embedded in the disk. A “local” model of noble gas fractionation by hydrodynamic blowoff of transient, methane-rich atmospheres outgassed from the interiors of large primitive planetesimals (Pepin, 1991) is updated and assessed against current data. Degassed atmospheres are assumed to contain isotopically solar noble gases except for an additional nucleogenic Xe component that contributes primarily to the two heaviest isotopes; there is evidence that this same component is present at varying levels in other solar-system volatile reservoirs, possibly reflecting a compositional change with time in the solar nebula. Single fixed values for the two free parameters in the blowoff modeling equations can generate fractionated Xe, Kr, Ar and Ne compositions in the residual atmosphere that closely match observed meteoritic isotopic distributions, and Q-gas elemental ratios are approximated by adsorption of fractionated gases on planetesimal surface grains using plausible values of relative Henry Law constants. Additional requirements for adsorption of sufficient absolute amounts of Q-gases on carrier grains, and their subsequent ejection to space, mixing in the nebula, and dispersal into meteorite bodies, are examined in the context of current models for body sizes and dynamical evolution in an early mass-rich asteroid belt (Chambers and Wetherill, 2001). Despite its ability to replicate isotopic compositions, uncertainties about the environments in which the blowoff model can successfully operate suggest that there is, as yet, no entirely satisfactory understanding of how the Q-component noble gases might have evolved from solar-like precursor compositions. This revised version was published online in August 2006 with corrections to the Cover Date.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Solar Noble Gas Record in Lunar Samples and Meteorites

Lunar soil and certain meteorites contain noble gases trapped from the solar wind at various times in the past. The progress in the last decade to decipher these precious archives of solar history is reviewed. The samples appear to contain two solar noble gas components with different isotopic composition. The solar wind component resides very close to grain surfaces and its isotopic composition is identical to that of present-day solar wind. Experimental evidence seems by now overwhelming that somewhat deeper inside the grains there exists a second, isotopically heavier component. To explain the origin of this component remains a challenge, because it is much too abundant to be readily reconciled with the known present day flux of solar particles with energies above those of the solar wind. The isotopic composition of solar wind noble gases may have changed slightly over the past few Ga, but such a change is not firmly established. The upper limit of ~5% per Ga for a secular increase of the 3He/4He ratio sets stringent limits on the amount of He that may have been brought from the solar interior to the surface (cf. Bochsler, 1992). Relative abundances of He, Ne, and Ar in present-day solar wind are the same as the long term average recorded in metallic Fe grains in meteorites within error limits of some 15-20%. Xe, and to a lesser extent Kr, are enriched in the solar wind similar to elements with a first ionisation potential < 10 eV, although Kr and Xe have higher FIPs. This can be explained if the ionisation time governs the FIP effect (Geiss and Bochsler, 1986). This revised version was published online in June 2006 with corrections to the Cover Date.     

Galileo Probe Mass Spectrometer experiment

The Galileo Probe Mass Spectrometer (GPMS) is a Probe instrument designed to measure the chemical and isotopic composition including vertical variations of the constituents in the atmosphere of Jupiter. The measurement will be performed by in situ sampling of the ambient atmosphere in the pressure range from approximately 150 mbar to 20 bar. In addition batch sampling will be performed for noble gas composition measurement and isotopic ratio determination and for sensitivity enhancement of non-reactive trace gases.The instrument consists of a gas sampling system which is connected to a quadrupole mass analyzer for molecular weight analysis. In addition two sample enrichment cells and one noble gas analysis cell are part of the sampling system. The mass range of the quadrupole analyzer is from 2 amu to 150 amu. The maximum dynamic range is 10⁸. The detector threshold ranges from 10 ppmv for H₂O to 1 ppbv for Kr and Xe. It is dependent on instrument background and ambient gas composition because of spectral interference. The threshold values are lowered through sample enrichment by a factor of 100 to 500 for stable hydrocarbons and by a factor of 10 for noble gases. The gas sampling system and the mass analyzer are sealed and evacuated until the measurement sequence is initiated after the Probe enters into the atmosphere of Jupiter. The instrument weighs 13.2 kg and the average power consumption is 13 W.The instrument follows a sampling sequence of 8192 steps and a sampling rate of two steps per second. The measurement period lasts appropriately 60 min through the nominal pressure and altitude range.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Composition of Light Solar Wind Noble Gases in the Bulk Metallic Glass flown on the Genesis Mission

We discuss data of light noble gases from the solar wind implanted into a metallic glass target flown on the Genesis mission. Helium and neon isotopic compositions of the bulk solar wind trapped in this target during 887 days of exposure to the solar wind do not deviate significantly from the values in foils of the Apollo Solar Wind Composition experiments, which have been exposed for hours to days. In general, the depth profile of the Ne isotopic composition is similar to those often found in lunar soils, and essentially very well reproduced by ion-implantation modelling, adopting the measured velocity distribution of solar particles during the Genesis exposure and assuming a uniform isotopic composition of solar wind neon. The results confirm that contributions from high-energy particles to the solar wind fluence are negligible, which is consistent with in-situ observations. This makes the enigmatic “SEP-Ne” component, apparently present in lunar grains at relatively large depth, obsolete. ²⁰Ne/ ²²Ne ratios in gas trapped very near the metallic glass surface are up to 10% higher than predicted by ion implantation simulations. We attribute this superficially trapped gas to very low-speed, current-sheet-related solar wind, which has been fractionated in the corona due to inefficient Coulomb drag.     

New Horizons: Anticipated Scientific Investigations at the Pluto System

The New Horizons spacecraft will achieve a wide range of measurement objectives at the Pluto system, including color and panchromatic maps, 1.25–2.50 micron spectral images for studying surface compositions, and measurements of Pluto’s atmosphere (temperatures, composition, hazes, and the escape rate). Additional measurement objectives include topography, surface temperatures, and the solar wind interaction. The fulfillment of these measurement objectives will broaden our understanding of the Pluto system, such as the origin of the Pluto system, the processes operating on the surface, the volatile transport cycle, and the energetics and chemistry of the atmosphere. The mission, payload, and strawman observing sequences have been designed to achieve the NASA-specified measurement objectives and maximize the science return. The planned observations at the Pluto system will extend our knowledge of other objects formed by giant impact (such as the Earth–moon), other objects formed in the outer solar system (such as comets and other icy dwarf planets), other bodies with surfaces in vapor-pressure equilibrium (such as Triton and Mars), and other bodies with N₂:CH₄ atmospheres (such as Titan, Triton, and the early Earth).     

The Genesis Solar Wind Concentrator: Flight and Post-Flight Conditions and Modeling of Instrumental Fractionation

The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Noble Gas Isotopes on the Moon

We discuss some of the major noble gas components on the Moon and their implications on the history of Moon and Sun. He, Ar, and Rn have been detected in the tenuous lunar atmosphere. The Ar and Rn abundances suggest that a sizeable fraction of the lunar interior presently loses all its freshly produced radiogenic noble gases. Part of the radiogenic Ar and Xe (the latter from now extinct radioactive isotopes of I and Pu) outgassed from the lunar interior later became retrapped in the dust grains on the lunar surface. These “parentless” gases may also be used to constrain the degassing history of the Moon, although a quantitative understanding is lacking. The dust layer on the lunar surface contains large amounts of noble gases implanted by the solar wind. The lunar regolith therefore constitutes the best available archive of the solar history of the past four billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

Origin of planetary atmospheres

The near absence of noble gases on earth, other than those of radioactive origin, indicates that the earth was formed by the accumulation of planetesimals; this process systematically excluded all constituents that did not enter into the solid phase. The atmosphere and the ocean with many of its dissolved salts have arisen from gases emitted from the earth's interior, a process that continues today. The oxygen in the earth's atmosphere plus a greater quantity that has been removed from the atmosphere to oxidize geologic materials, has arisen mainly from a small excess of photosynthesis over decay of organic material. The atmospheres of Mars and Venus have probably arisen in a manner similar to the atmosphere on earth, by emission from the planetary interiors. However, they have not received any oxygen from photosynthesis and so are nearly oxygen free. Mars has very little water in its atmosphere, and this can be explained by its lower than freezing average surface temperature. Venus also has very little water, and this requires an ad hoc explanation; one possibility is that Venus was formed from much drier planetesimals than was the earth. Mercury and the moon are virtually without atmospheres. Although some gases may be emitted from their interiors, they are presumably rapidly lost by escape. Whatever atmosphere they possess is probably due to the neutralized solar wind that impinges upon them. The outer planets retained volatiles, including hydrogen and helium, to a much greater extent than did the terrestrial planets.     

Atmosphere Impact Losses

Determining the origin of volatiles on terrestrial planets and quantifying atmospheric loss during planet formation is crucial for understanding the history and evolution of planetary atmospheres. Using geochemical observations of noble gases and major volatiles we determine what the present day inventory of volatiles tells us about the sources, the accretion process and the early differentiation of the Earth. We further quantify the key volatile loss mechanisms and the atmospheric loss history during Earth’s formation. Volatiles were accreted throughout the Earth’s formation, but Earth’s early accretion history was volatile poor. Although nebular Ne and possible H in the deep mantle might be a fingerprint of this early accretion, most of the mantle does not remember this signature implying that volatile loss occurred during accretion. Present day geochemistry of volatiles shows no evidence of hydrodynamic escape as the isotopic compositions of most volatiles are chondritic. This suggests that atmospheric loss generated by impacts played a major role during Earth’s formation. While many of the volatiles have chondritic isotopic ratios, their relative abundances are certainly not chondritic again suggesting volatile loss tied to impacts. Geochemical evidence of atmospheric loss comes from the \({}^{3}\mathrm{He}/{}^{22}\mathrm{Ne}\), halogen ratios (e.g., F/Cl) and low H/N ratios. In addition, the geochemical ratios indicate that most of the water could have been delivered prior to the Moon forming impact and that the Moon forming impact did not drive off the ocean. Given the importance of impacts in determining the volatile budget of the Earth we examine the contributions to atmospheric loss from both small and large impacts. We find that atmospheric mass loss due to impacts can be characterized into three different regimes: 1) Giant Impacts, that create a strong shock transversing the whole planet and that can lead to atmospheric loss globally. 2) Large enough impactors (\(m_{\mathit{cap}} \gtrsim \sqrt{2} \rho_{0} (\pi h R)^{3/2}\), \(r_{\mathit{cap}}\sim25~\mbox{km}\) for the current Earth), that are able to eject all the atmosphere above the tangent plane of the impact site, where \(h\), \(R\) and \(\rho_{0}\) are the atmospheric scale height, radius of the target, and its atmospheric density at the ground. 3) Small impactors (\(m_{\mathit{min}}>4 \pi\rho_{0} h^{3}\), \(r_{\mathit {min}}\sim 1~\mbox{km}\) for the current Earth), that are only able to eject a fraction of the atmospheric mass above the tangent plane. We demonstrate that per unit impactor mass, small impactors with \(r_{\mathit{min}} < r < r_{\mathit{cap}}\) are the most efficient impactors in eroding the atmosphere. In fact for the current atmospheric mass of the Earth, they are more than five orders of magnitude more efficient (per unit impactor mass) than giant impacts, implying that atmospheric mass loss must have been common. The enormous atmospheric mass loss efficiency of small impactors is due to the fact that most of their impact energy and momentum is directly available for local mass loss, where as in the giant impact regime a lot of energy and momentum is ’wasted’ by having to create a strong shock that can transverse the entirety of the planet such that global atmospheric loss can be achieved. In the absence of any volatile delivery and outgassing, we show that the population of late impactors inferred from the lunar cratering record containing 0.1% \(M_{\oplus }\) is able to erode the entire current Earth’s atmosphere implying that an interplay of erosion, outgassing and volatile delivery is likely responsible for determining the atmospheric mass and composition of the early Earth. Combining geochemical observations with impact models suggest an interesting synergy between small and big impacts, where giant impacts create large magma oceans and small and larger impacts drive the atmospheric loss.     

The solar WIND and suprathermal ion composition investigation on the WIND spacecraft

The Solar Wind and Suprathermal Ion Composition Experiment (SMS) on WIND is designed to determine uniquely the elemental, isotopic, and ionic-charge composition of the solar wind, the temperatures and mean speeds of all major solar-wind ions, from H through Fe, at solar wind speeds ranging from 175 kms^–1 (protons) to 1280 kms^–1 (Fe⁺⁸), and the composition, charge states as well as the 3-dimensional distribution functions of suprathermal ions, including interstellar pick-up He⁺, of energies up to 230 keV/e. The experiment consists of three instruments with a common Data Processing Unit. Each of the three instruments uses electrostatic analysis followed by a time-of-flight and, as required, an energy measurement. The observations made by SMS will make valuable contributions to the ISTP objectives by providing information regarding the composition and energy distribution of matter entering the magnetosphere. In addition SMS results will have an impact on many areas of solar and heliospheric physics, in particular providing important and unique information on: (i) conditions and processes in the region of the corona where the solar wind is accelerated; (ii) the location of the source regions of the solar wind in the corona; (iii) coronal heating processes; (iv) the extent and causes of variations in the composition of the solar atmosphere; (v) plasma processes in the solar wind; (vi) the acceleration of particles in the solar wind; and (vii) the physics of the pick-up process of interstellar He as well as lunar particles in the solar wind, and the isotopic composition of interstellar helium.     

Johannes Geiss’ Investigations of Solar, Heliospheric and Interstellar Matter

Johannes Geiss is a world leader and foremost expert on measurements and interpretation of the composition of matter that reveals the history, present state, and future of astronomical objects. With his Swiss team he was first to measure the composition of the noble gases in the solar wind when in the late 1960s he flew the brilliant solar wind collecting foil experiments on the five Apollo missions to the moon. Always at the forefront of the art of composition measurements, he with his colleagues determined the isotopic and elemental composition of the solar wind using instruments characterized by innovative design that have provided the most comprehensive record of the solar wind composition under all solar wind conditions at all helio-latitudes. He discovered heavy interstellar pickup ions, from which the composition of the neutral gas of the Local Interstellar Cloud is determined, and the “Inner Source” of pickup ions. Johannes Geiss played a key role both in the in-situ measurements and modeling of molecular ions in comets, and the interpretation of these data. He and co-workers measured the composition of plasmas in the magnetospheres of Earth and Jupiter. Here we highlight Johannes Geiss’ many discoveries and seminal contributions to our knowledge of the composition of matter of the Sun, solar wind, interstellar gas, early universe, comets and magnetospheres.     

Atmospheric/Exospheric Characteristics of Icy Satellites

The atmospheres/exospheres of icy satellites greatly vary from one to the next in terms of density, composition, structure or steadiness. Titan is the only icy satellite with a dense atmosphere comparable in many ways to that of the Earth’s atmosphere. Titan’s atmosphere prevents the surface from direct interaction with the plasma environment, but gives rise to Earth-like exchanges of energy, matter and momentum. The atmospheres of other satellites are tenuous. Enceladus’ atmosphere manifests itself in a large water vapor plume emanating from surface cracks near the south pole. Io’s SO₂ atmosphere originates from volcanoes. Europa’s tenuous O₂ atmosphere is produced by intense radiation bombardment. This chapter reviews the characteristics of the atmospheres of Titan, Enceladus, Io and Europa based on observations.     

Plasma-induced sputtering of an atmosphere

Magnetospheric ions, solar wind ions, and locally produced pick-up ions can impact the atmospheres of objects in the solar system, transferring energy by collisions with atmospheric atoms and molecules. This can result in an expansion of the atmospheric corona with a fraction of the energetic atoms or molecules being lost (sputtered) from the atmosphere. The expanded corona presents a larger target to the incident plasma, which in turn enhances pick-up ion formation and collisional ejection. In this manner a significant flux of atoms or molecules can be lost from an atmosphere, affecting its long-term evolution. This has been shown to be an important process for the dynamics and evolution of the atmosphere of lo, which is bombarded by the Jovian magnetospheric plasma, and for loss of atmosphere from Titan. Sputtering by pick-up ion bombardment has been shown to remove material from the atmosphere of Mars affecting the observed isotope ratios, and energetic O⁺ precipitation affects the Earth's thermosphere. The physics of ion bombardment of a gas which leads to atmospheric sputtering is described here. Analytic expressions derived from transport equations are shown to be useful for estimating the sputtering rate. These are compared to results from transport and Monte-Carlo calculations.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

Venus Atmospheric Thermal Structure and Radiative Balance

From the discovery that Venus has an atmosphere during the 1761 transit by M. Lomonosov to the current exploration of the planet by the Akatsuki orbiter, we continue to learn about the planet’s extreme climate and weather. This chapter attempts to provide a comprehensive but by no means exhaustive review of the results of the atmospheric thermal structure and radiative balance since the earlier works published in Venus and Venus II books from recent spacecraft and Earth based investigations and summarizes the gaps in our current knowledge. There have been no in-situ measurements of the deep Venus atmosphere since the flights of the two VeGa balloons and landers in 1985 (Sagdeev et al., Science 231:1411–1414, 1986). Thus, most of the new information about the atmospheric thermal structure has come from different remote sensing (Earth based and spacecraft) techniques using occultations (solar infrared, stellar ultraviolet and orbiter radio occultations), spectroscopy and microwave, short wave and thermal infrared emissions. The results are restricted to altitudes higher than about 40 km, except for one investigation of the near surface static stability inferred by Meadows and Crisp (J. Geophys. Res. 101:4595–4622, 1996) from 1 \(\upmu\)m observations from Earth. Little information about the lower atmospheric structure is possible below about 40 km altitude from radio occultations due to large bending angles. The gaps in our knowledge include spectral albedo variations over time, vertical variation of the bulk composition of the atmosphere (mean molecular weight), the identity, properties and abundances of absorbers of incident solar radiation in the clouds. The causes of opacity variations in the nightside cloud cover and vertical gradients in the deep atmosphere bulk composition and its impact on static stability are also in need of critical studies. The knowledge gaps and questions about Venus and its atmosphere provide the incentive for obtaining the necessary measurements to understand the planet, which can provide some clues to learn about terrestrial exoplanets.