垂直对天顶测量的紫外前向散射探测臭氧总量的可行性研究

选用SBDART模式作为大气辐射传输计算模式,通过模拟计算和结果分析探讨无云的晴天、垂直对天顶观测的紫外前向散射反演大气臭氧总量的可行性.计算表明,穿透能力与探测灵敏度之间的复杂联系使得探测波长应随着sΩ0的增大而波长变长,若用波长对探测,则波长对中较短的波长也应随着sΩ0的增大而增大.另外大气的臭氧总量越少,反演结果受下垫面反照率、气压和仪器精度的影响越大,因而反演误差越大.当强度Ii的测量精度为±1%时,下垫面反照率R和气压P0的分辨率分别达到±0.05和±50 hPa,若用单波长探测,则在大气臭氧总量Ω0和s都较小时,反演结果大于5%;若选用波长对进行探测,由于R和P0的误差对反演结果的影响降低,故精度大大提高.Ii,R和P0在上述精度下,选取适当的波长对进行探测,精度至少可达±4%,当臭氧总量高于350 DU时,可达±2%.      

紫外后向散射探测臭氧总量的反演误差研究

通过探测紫外后向散射获取臭氧总量目前已经成为臭氧总量探测的主要方法之一. 本文以模拟计算为主要方法, 从模式计算误差, 反演算法误差和仪器误差三方面着手, 对影响臭氧总量反演精度的各个参数进行分析研究, 并对由其引起的臭氧总量反演误差进行定量计算, 研究结果对臭氧总量反演精度的提高和实际观测资料的处理有着重要的指导意义.      

中国不同地区剩余臭氧及臭氧探空订正因子

根据中国不同地点臭氧探空数据，研究气球炸点臭氧浓度定值（CMR）法、卫星（SBUV和MLS）纬向平均法确定的剩余臭氧Ω_res及其对订正因子C_ref的影响，同时检验臭氧垂直分布对C_ref的贡献.结果显示: CMR法对气球炸点高度依赖性明显，且易高估Ω_res使C_ref整体低于100%；卫星纬向平均Ω_res对气球炸点高度不敏感，但在中国东部的臭氧总量高值区或青藏高原及低纬度臭氧低值地区，Ω_res呈现近10DU以上低值，这是经向臭氧总量及其垂直分布差异在卫星遥感数据上的反映.地面到100hPa的对流层臭氧（Ω_tro），100~10hPa的平流层臭氧（Ω_str）以及10hPa以上的Ω_res对C_ref贡献平均分别为（16±3.4）%，（65±2.3）%，（19±3.3）%.表明基于C_ref评估或订正探空仪平流层臭氧测值时，需考虑对流层臭氧及确定Ω_res方法的影响.卫星纬向平均法，特别是近似实测的SBUV臭氧廓线的值适用于确定Ω_res.      

气溶胶光学特性偏振遥感反演算法

陆地上空大气顶的辐射主要由大气散射和地表反射组成,一般地表反射的贡献要大于大气散射的贡献,使得陆地上空气溶胶的特性提取非常困难,而偏振信息只强烈依赖于散射粒子的特性,发展基于偏振信息的气溶胶反演方法是非常有效的. 通过对矢量辐射传输方程求解进行研究,基于倍加累加法矢量辐射传输模式分析影响气溶胶反演的主要因素,确定多维参数查找表建立方法,利用POLDER(Polarization and Directionality of the Earth-s Reflectances)提供的反射率和偏振反射率数据,发展了一种利用反射率和偏振反射率查找表迭代查找反演气溶胶光学参数和地表反射率的算法,实现了对北京、香河、Dalanzadgad观测站上空气溶胶光学厚度、粒子半径、折射指数和地表反射率的反演.用AERONET(Aerosol Robotic Network)地基数据对反演结果进行了验证.     

日全食期间中间层大气臭氧光化过程试验

利用包括活O_x、HO_x、和NO_x等成份在内的一维时变光化模式,研究了日全食时上中层大气臭氧和O₂(1△g)的变化特性,并通过与观测资料的比较进行了光化模式的试验.结果表明,日全食时太阳辐照变化对1.27μm气晖影响的高度比曙暮期间明显偏低,利用1.27μm气晖光度计测量大气臭氧的高度范围约为52-67km.1997年3月9日漠河日全食时测量的大气臭氧含量变化幅度为50％.这与考虑O_x、HO_x、和NO_x等成份的光化模式理论模拟结果基本一致.它表明在52-67km高度范围不存在臭氧亏损现象.      

观测路径和光谱分辨率对吸收性气溶胶指数的影响

吸收性气溶胶指数（AAI）在监测污染物方面有较好的应用,其反演结果受边界层高度、云高、相对湿度以及仪器指标和观测几何路径等因素影响.利用大气辐射传输模型MODTRAN,对辐射传输方程中多次散射计算的不同近似方法和不同观测几何角度下的AAI进行模拟,研究这些因素对AAI结果的作用,并分析仪器光谱分辨率对AAI探测结果的影响.结果表明,折衷考虑计算效率与精度的情况下,应选择8流近似的离散坐标法进行带有多次散射计算的辐射方程解析.AAI在不同浓度和不同类型气溶胶下随观测角度变化的趋势相同:相对方位角<120°时,AAI误差在太阳天顶角和卫星方位角均为40°～60°时最大;相对方位角在120°～180°时误差均较小;光谱分辨率对AAI反演结果无明显影响.      

对流层顶变化对上对流层/下平流层臭氧分布的影响

上对流层和下平流层(UT／LS)，位于8-25km高度之间，是大气中一个很特殊的区域．大部分的臭氧分布在下平流层，在下平流层臭氧的含量发生一个很小的变化，就会对气候和地面的紫外辐射产生很大的影响．而作为气象参数的对流层顶，是充分混合、缺乏臭氧的上对流层和层结稳定、臭氧丰富的下平流层之间的边界或过渡层，其变化对臭氧总量和分布有直接和明显的影响．本文使用二维模式模拟研究对流层顶变化对臭氧在UT／LS分布的影响．模拟结果表明对流层顶的季节变化对UT/LS的臭氧分布有明显的影响，臭氧的局地变化可以超过10％在冬季北半球中纬度对流层顶高度升高1km时，模式结果表明对臭氧分布的影响比较显著，局地变化可超过6％，但是对臭氧总量的影响较小，变化不超过5DU，小于观测资料统计分析的结果。     

大气臭氧地基遥感反演的退卷积方法

本文提出了一种大气臭氧地基遥感信息处理的新方法,它利用非线性退卷积方法和等效仪器函数提高光谱分辨率,利用非线性最小二乘法进行大气臭氧反演计算,可以显着提高大气臭氧遥感的可探测高度和精度。      

高层大气臭氧对于太阳紫外辐射27天波动的响应

本文利用Ｓｏｌａｒ Ｍｅｓｏｓｐｈｅｒｅ Ｅｘｐｌｏｒｅｒ（ＳＭＥ）卫星１９８２年和１９８３年太阳紫外辐射和赤道地区５０－９０ｋｍ臭氧分布的红外观测资料，对臭氧地太阳紫外辐射２７天振荡的响应进行了研究，并且利用大气光化波动模式对其进行了理论计算，计算结果与实测结果基本一致。     

利用曙暮气晖反演中层臭氧的可行性

利用1.27μm曙暮气晖反演大气O₃是中间层03含量的重要测量方法.本文研究了1.27μm地面曙暮气晖所包含的独立信息参量、可测量高度和垂直分辨率;讨论了光化学参量、大气参量不定性的影响和对中间层O₃含量变化的灵敏度.结果指出,利用这一方法可以给出60－90km高度的大气O₃含量,光化模式参量不定性的影响约为10％.      

Prediction of clear-sky biologically effective erythematic radiation (EER) From global solar radiation (250–2800 nm) at Cairo,Egypt

The hourly and daily measured clear-sky global solar radiation (G) and biologically important effective erythematic radiation (EER) incident on a horizontal surface at Cairo, Egypt (latitude 30° 05′ N & Longitude 31° 15′ E), during the period from January 1995 to December 2005 are used in this paper. The relationship between daily integrated totals of EER and the daily totals of broadband global solar radiation (250–2800 nm) is established. The temporal variability of the percentage ratio of the total daily erythema to total daily broadband solar global irradiation (EER/G) is determined. The monthly and the seasonal averages of the extraterrestrial UVB solar radiation, Mesurad and estímated UVB solar radiation and clearness index K_tUVB of UVB radiation are discussed. The average monthly mean variation of slant ozone (Z) and UVB transmission (K_tUVB) at the present work are found. The two variables show an opposite seasonal behavior, and the average monthly of slant ozone column and UVB transmission values shows the relationship between them in a clearer way than those of daily values. The estimated values of UVB solar radiation a good agreement with the measured values of the UVB solar radiation, the difference between the estimated and measured values of UVB solar radiation varies from 1.2% to 2.8%. The effect of the annual cycles of solar zenith angle (SZA) and total column ozone (TCO) on the ratios (EER/G) are presented and the correction factors are determined for removal of the ozone cycle. The seasonal variability of EER/G is also discussed. The effect of the annual cycles of solar zenith angle (SZA) and total column ozone (TCO) on the ratios (EER/G) is presented and the correction factors are determined for removal of the ozone cycle.     

Quasi-biennial oscillation (QBO) of tropical total ozone under alternative QBO scenarios of equatorial stratospheric wind

Equatorial total column ozone variations with quasi-biennial periodicity are described by paying attention to their coupling with the quasi-biennial oscillation (QBO) of zonal wind in equatorial stratosphere. Analysis is made for the 35-year time interval from 1978 to 2013 using the zonal mean total ozone (TOZ) data in latitude band from 5° S to 5° N derived from satellite measurements by means of Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI). The study was performed using strong seasonal regularities of the wind QBO and the discrete variation of the QBO-period revealed earlier. The forecast of the wind QBO evolution made in Gabis (2012) is fully justified. The comparison between predicted and actually observed changes of the height wind structure shows the prominent accordance, which confirms the forecast validity. It is shown that variations of deseasonalized TOZ are in strong coupling with changes of equatorial wind QBO that coincides with the numerous previous researches. However our results contradict the assumption about quite complicated ozone response in the equatorial region due to continuously varying with time relationship between annual and quasi-biennial cycles and irregularly variable wind QBO-period. The total ozone changes actually observed clearly corresponds to the mean ozone variations calculated for different QBO scenarios and aligned according to the sequence of QBO scenarios already occurred in fact. This close association indicates the possibility of forecasting the equatorial total ozone QBO based on the predicted wind QBO.     

Comparison of OClO nadir measurements from SCIAMACHY and GOME

The scanning imaging absorption spectrometer for atmospheric chartography was launched successfully onboard ENVISAT on March 1, 2002. It observes the solar radiation transmitted and backscattered from the atmosphere and reflected from the ground in nadir, limb and occultation viewing modes. Chlorine dioxide (OClO), an important indicator for stratospheric chlorine activation, can be measured in the UV spectral range by differential optical absorption spectroscopy (DOAS).

First results of the DOAS retrieval of OClO slant column densities from the SCIAMACHY nadir measurements are presented and compared to measurements of the global ozone monitoring experiment (GOME), which has successfully measured OClO since 1995. While SCIAMACHY operates in the same orbit, it measures ≈30 min earlier than GOME and has an increased spatial resolution (30 × 60 km² compared to 40 × 320 km² for GOME).     

Global pictures of the ozone field,from high altitudes,from DE-I

Using the imaging instrumentation aboard the Dynamics Explorer spacecraft (DE-I), total column ozone densities are obtained in the sunlit hemisphere by measuring the intensities of backscattered solar ultraviolet radiation with multiple filters and multiple photometers. The high apogee altitude (23,000 km) of the eccentric polar orbit allows high resolution global-scale images of the terrestrial ozone field to be obtained within 12 minutes. Previous ozone-monitoring spacecraft have required much longer time periods for comparable spatial coverage because of their lower altitudes (<1200 km). The much higher altitude of DE-I also provides hours of continuous imaging of features compared to minutes or seconds with previous spacecraft. Near perigee, high resolution images can be gained with pixel size as small as 3 km to view mesoscale atmospheric variations. Utilizing these data, the effects of planetary-scale, synoptic-scale, and mesoscale dynamical processes, which control the distribution of ozone near the tropopause, can be studied. Preliminary results show short-term (less than one day) variations in the synoptic ozone field and these variations appear to be in accord with meteorological data. Spatial variations in the ozone field are found to be highly negatively correlated with tropopause altitude.     

太阳光谱辐射强度变化对地球能量平衡的影响分析

目前太阳对地球能量平衡影响的研究大都是以太阳总辐射通量密度作为输入参数的. 本文以美国航空航天局（National Aeronautics and Space Administration,NASA）太阳辐射与气候实验项目的卫星实测数据为基础,对太阳上升相（2010年上半年）和下降相（2007年12月）期间太阳光谱变化对地球能量平衡的影响进行了研究. 结果表明,2010年上半年较强的太阳总辐射通量密度主要是由紫外及红外波段的能量增强引起的,其在200～400nm 和760～4000nm波段内的平均能量分别增加了0.11%和0.05%,而在 400～760nm可见光区的能量却呈减小趋势,平均减小量为0.05%. 通过对MLS2.2全球臭氧日数据进行再分析后发现,相对于2007年12月,2010年上半年平流层臭氧浓度也有所增加,其中在太阳紫外辐射呈现较大增强的2月和3月,其臭氧增量也相对较大,最大值分别出现在33km和40km处,值为0.6mL·m-3和0.62mL·m-3. 因此,可见光区能量减弱与平流层臭氧浓度增加的双重削弱作用致使虽然2010年上半年的太阳总辐射通量密度较大,但是到达对流层顶的太阳辐射却有所减小,最大减小量出现在3月,值为0.15W·m-2. 这一结果说明,太阳活动或总辐射通量密度的增强也有可能对地球对流层系统起到冷却作用.      

Observations of the ozone and nitrogen dioxide profiles in the TROICA-4 experiment

To investigate the vast area of Russia, a mobile scientific facility based in a railway carriage was developed. It is capable to perform continues measurements being coupled in a passenger train traveling along railroads. It was first equipped with a spectrometer for remote sensing of ozone and nitrogen dioxide in the atmosphere for the transcontinental observations into the chemistry of the atmosphere-4 expedition performed from February 18 to March 5, 1998. A twilight DOAS method, which was applied for retrieval of the nitrogen dioxide profiles basing on spectral measurements at the visible wavelengths (434–451 nm), is described in the paper. Main features of a new algorithm for retrieval of the ozone profile and total content using the differential structure of the UV spectrum (310–335 nm) are presented. The ozone and nitrogen dioxide contents are obtained and shortly validated against available alternative data.     

Ozone destruction by solar electrons in relation to solar variability and the terrestrial latitude

Precipitating electrons from the radiation belts with energies greater than from 150 keV to 5 MeV have been correlated with ozone data of a large number of stations located within 40–70° N. Energetic electrons have been collected by the low altitude polar Russian satellite METEOR while ozone data have been compiled from almost ninety (90) stations located all over the world within the latitude zone 40–70° N.     

High vertical resolution water vapour profiles in the upper troposphere and lower stratosphere retrieved from MAESTRO solar occultation spectra

An algorithm has been developed that retrieves water vapour profiles in the upper troposphere and lower stratosphere from optical depth spectra obtained by the Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (MAESTRO) instrument onboard the SCISAT satellite as part of the Atmospheric Chemistry Experiment (ACE) mission. The retrieval relies on ro-vibrational absorption of solar radiation by water vapour in the 926–970 nm range. During the iterative inversion process, the optical depth spectra are simulated at the spectral resolution and sampling frequency of MAESTRO using the correlated-k approximation. The Chahine inversion updates the water vapour volume mixing ratio (VMR), adjusting all retrieval layers simultaneously, to match the observed differential optical depth due to absorption by water vapour and ozone at each tangent height. This approach accounts for significant line saturation effects. Profiles are typically obtained from ∼22 km down to the cloud tops or to 5 km, with relative precision as small as 3% in the troposphere. In the lower stratosphere, the precision on water vapour VMR is ∼1.3 μmol/mol in an individual retrieval layer (∼1 km thick). The spectral capability of MAESTRO allows for the clear separation of extinction due to water vapour and aerosol, and for the fitting quality to be quantified and used to determine an altitude-dependent convergence criterion for the retrieval. In the middle troposphere, interhemispheric differences in water vapour VMR are driven by oceanic evaporation whereas in the upper troposphere, deep convection dominates and a strong seasonal cycle is observed at high latitudes.