Segmented battery charger for high energy 28 V lithium ion battery

Since they were first introduced in the early 1990s, lithium ion batteries have enjoyed unprecedented growth and success in the consumer marketplace. Combining excellent performance with affordability, they have become the product of choice for portable computers and cellular phones. Building on the same energy and life cycle attributes, which marked their consumer market success, but adding new high power storage capability, lithium ion technology is now poised to play a similar role in the transportation, military, and space sectors. With major program in various aspects of electric and hybrid electric vehicles, Saft has developed a family of battery products that address the power and energy storage where lightweight, long life, and excellent energy or power storage capabilities are needed. Significant progress in the packaging and control of high power, yet compact, batteries has been accomplished for a variety of vehicle applications. This paper discusses the charger and balancing strategies of one of this family of products     

Bipolar nickel-metal hydride batteries for aerospace applications

Electro Energy Inc. (EEI) is developing high power, long life, bipolar nickel-metal hydride batteries for aerospace applications. Bipolar nickel-metal hydride designs allow for high energy and high power designs with a 25 percent reduction in both weight and volume as compared to prismatic and/or cylindrical Ni-MH designs. Utilizing a sealed wafer cell design EEI has demonstrated a 1.2 kW/kg power capability. Prototype designs have achieved 70 Wh/kg. Designs studies show 80 Wh/kg are achievable with EEI's state-of-the-art technology. The sealed wafer cell is the building block for EEI's high power and high voltage bipolar batteries making the assembly easy and significantly lower in cost. Satellite and aircraft batteries are being developed which provide high power and long life. Sealed cells now show excellent rate capability and life. Cells tested in a low earth orbit (LEO) cycle have reached 9000 cycles and continue on test. High power, bipolar battery designs are ideal in applications where using conventional aerospace battery technology would require excessive capacity; weight and volume, thereby reducing usable payload on the vehicle     

Heating and cooling battery electric vehicles-the final barrier

Battery electric vehicles (EVs) present a particular challenge to the development of more efficient and effective heating and cooling systems for automotive applications. Because heating-ventilating-air-conditioning (HVAC) systems are electrically powered, vehicle range is reduced when the HVAC system is operating. The alternative solutions to HVAC battery electric vehicles are identified and evaluated. These include a basis for determining HVAC boundary design assumptions and showing mathematical methods for estimating the HVAC load and energy requirements, and evaluation of the new European and Japanese approaches to wintertime heating, such as NaS battery, motor and component waste heat recovery, electric seat warmer, radiant foot warmer, electric windshield and backlight defrost, molten salt latent heat storage, metal hydride hydrogen storage and catalytic heater, and liquid fueled heater     

富锂锰基正极材料研究进展

随着社会发展,电动汽车、消费类(3C)电子产品、储能装置等对锂离子电池的能量密度提出了更高要求。富锂锰基正极材料具有高比容量(≈250 mAh/g)、高工作电压(≈3.6 V)及低成本等优势,有望成为下一代商用高比能电池正极材料。首次库仑效率低、倍率性能差、电压/容量衰减快等问题限制了富锂锰基正极材料的工程化应用。本文综述了富锂锰基正极材料的最新研究进展,重点从材料结构、电化学反应机理、失效机制和改性方法等几方面进行了阐述。研究表明,采用离子掺杂、表面包覆、晶体结构调控等技术,可显著改善富锂锰基正极材料的电化学性能。最后,对富锂锰基正极材料的发展方向进行了展望。     

飞机碱性电瓶最佳充电方式研究及其实现

应用电瓶最佳受电原理，对常用飞机碱性电瓶的充电方式进行了分析和比较，提出了脉冲恒流二阶段充电法是电瓶的最佳充电方法之一的设想，其可行性已被试验证实。利用该充电方法，研制成了飞机碱性电瓶专用充电器．实验结果表明该充电方法能大大提高电瓶的充电效率，延长电瓶的使用寿命。     

Sealed nickel cadmium and nickel metal hydride cell advances

Nickel cadmium cells have almost doubled in capacity since 1980 after being stagnated in performance for twenty years. Nickel metal hydride cells, introduced in 1992, have shown a 170 percent increase in energy density to be competitive on a volume basis with lithium ion. Other characteristics, such as charge retention, charge rate, high temperature operation, and rate capability have also advanced with improvements in materials and constructions. These two cell types account for roughly one half of the value of the small secondary battery market     

Design and integration of a solar AMTEC power system with anadvanced global positioning satellite

A 1,200-W solar AMTEC (alkali metal thermal-to-electric conversion) power system concept was developed and integrated with an advanced global positioning system (GPS) satellite. The critical integration issues for the SAMTEC with the GPS subsystems included: (1) packaging within the Delta II launch vehicle envelope; (2) deployment and start-up operations for the SAMTEC; (3) SAMTEC operation during all mission phases; (4) satellite field of view restrictions with satellite operations; and (5) effect of the SAMTEC requirements on other satellite subsystems. The SAMTEC power system was compared with a conventional planar solar array/battery power system to assess the differences in system weight, size, and operations, Features of the design include the use of an advanced multitube, vapor anode AMTEC cell design with 24% conversion efficiency, and a direct solar insolation receiver design with integral LiF salt canisters for energy storage to generate power during the maximum solar eclipse cycle, The modular generator design consists of an array of multitube AMTEC cells arranged into a parallel/series electrical network with built-in cell redundancy. Our preliminary assessment indicates that the solar generator design is scaleable over a 500 to 2,500-W range. No battery power is required during the operational phase of the GPS mission. SAMTEC specific power levels greater than 5 We/kg and 160 We/m² are anticipated for a mission duration of 10 to 12 years in orbits with high natural radiation backgrounds     

Performance characteristics of lithium-ion cells for NASA's Mars2001 Lander application

NASA requires lightweight rechargeable batteries for future missions to Mars and the outer planets that are capable of operating over a wide range of temperatures, with high specific energy and energy densities. Due to the attractive performance characteristics, lithium-ion batteries have been identified as the battery chemistry of choice for a number of future applications, including Mars rovers and landers. The Mars 2001 Lander (Mars Surveyor Program MSP 01) will be one of the first missions which will utilize lithium-ion technology. This application will require two lithium-ion batteries, each being 28 V (eight cells), 25 Ah and 8 kg. In addition to the requirement of being able to supply at least 200 cycles and 90 days of operation on the surface of Mars, the battery must be capable of operation (both charge and discharge) at temperatures as low as -20°C. To assess the viability of lithium-ion cells for these applications, a number of performance characterization tests have been performed, including: assessing the room temperature cycle life, low temperature cycle life (-20°C), rate capability as a function of temperature, pulse capability, self-discharge and storage characteristics, as well as mission profile capability. This paper describes the Mars 2001 Lander mission battery requirements and contains results of the cell testing conducted to-date in support of the mission,     

Bipolar nickel-metal hydride battery for hybrid vehicles

Hybrid electric vehicles are receiving increased interest as an approach to decrease vehicle pollution, dependence, and consumption of liquid petroleum and meet forthcoming Government vehicle emission standards. A number of schemes are under consideration (heat engine battery, fuel cell battery, peaking battery, inner-city battery, etc.). The success of any of the approaches will be dependent on battery capabilities, i.e., power, density, life, and cost. The nickel-metal hydride system appears to be the most promising of the candidate battery chemistries. Preliminary designs and analysis have been prepared and are presented for various configurations. Initial performance characterization tests are presented. It is concluded that a bipolar package arrangement for the Ni-MH chemistry appears most suited for the hybrid vehicle application considered     

Hybrid power sources for Land Warrior scenario

Hybrid systems utilizing a zinc-air battery or a Proton Exchange Membrane Fuel Cell (PEMFC) as the high energy density component coupled with a rechargeable battery (lead-acid or nickel-metal hydride) or electrochemical capacitor (EC) bank as the high power density component were tested under a high-pulse application load, Land Warrior (LW). The hybrid power sources successfully operated the LW cyclic load beyond the capabilities of the specific single chemistry systems studied. The zinc-air battery hybrids allowed approximately triple the operation time of PEMFC hybrids. The best performing hybrid system was the zinc-air battery/lead-acid battery. It provided the greatest operating voltage and longest operating time     

基于直流微电网的混合储能协调控制策略仿真研究

针对直流微电网中光伏发电单元出力的波动性和间歇性造成系统内部功率不平衡的问题,混合储能系统可以同时发挥蓄电池高能量密度和超级电容高功率密度的优势,根据直流母线电压进行混合储能单元间的协调控制策略。该策略将直流母线电压进行分层控制,采用四个电压阈值共分成五个控制区域,以直流母线电压为信息载体,决定储能系统的运行状态,实现对混合储能单元的充电、放电模式间自主切换。电压分层控制有效地避免了蓄电池由于电压波动而频繁进行充放电切换,从而延长了电池的使用寿命。最后,MATLAB/Simulink的仿真结果验证了所提控制策略的可行性。     

Global avionics in the future

The following topics are discussed: new batteries for old airplanes; new charge controls for lengthening battery life; fast methods for batteries charging; AC conductance measurement based battery testing; pulse power; bipolar lead-acid batteries vs supercapacitors; Ni electrode cells for spacecraft; worn-out battery disposal; recycling technology; vehicle batteries cost; high energy content batteries; and energy storage for electric utilities     

Advanced materials for next generation NiMH portable, HEV and EVbatteries

While Ovonic NiMH batteries are already in high volume commercial production for portable applications, advances in materials technology have enabled performance improvements in specific energy (100 Wh/kg), specific power (600-1000 W/kg), high temperature operation, charge retention, and voltage stability. Concurrent with technology advances, Ovonic NiMH batteries have established performance and commercial milestones in electric vehicles, hybrid electric vehicles, as well as scooter, motorcycle and bicycle applications. As important as these advances, significant manufacturing cost reductions have also occurred which allow continued growth of NiMH technology. In this paper, advances in performance, applications and cost reduction are discussed with particular emphasis on the improved proprietary metal hydride and nickel hydroxide materials that make such advances possible     

Electric-vehicle batteries

Electric vehicles that can't reach trolley wires need batteries. In the early 1900's electric cars disappeared when owners found that replacing the car's worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today's electric cars are still propelled by lead-acid batteries. General Motors in their prototype Impact, for example, used starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon's new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda traveled 260 km on a single charge of its zinc-bromine battery. A German 3.5-ton postal truck traveled 300 km with a single charge in its 650-kg (146 Wh/kg) zinc-air battery. Its top speed was 110 km per hour     

涡轮叶片复合疲劳特性曲线及其规律的试验

为了解高周振动载荷对于涡轮叶片高温疲劳性能的影响,对某型涡轮叶片进行高低周复合疲劳试验.试验结果表明,在低周载荷基础上叠加高频振动载荷,显著缩短了叶片的疲劳寿命;复合疲劳的分散性很大,且不存在疲劳极限,当叶片高周循环次数超过107时,继续试验叶片仍会发生断裂;在双对数坐标下,叶片的振动应力与其高周循环寿命成线性关系,即复合疲劳特性曲线(应力-寿命曲线、概率-应力-寿命曲线)服从双对数线性规律,进一步研究发现该规律对于高温合金材料的复合疲劳特性曲线具有普遍性.      

Effect of KOH concentration on LEO cycle life of IPVnickel-hydrogen flight cell-update II

For update I see Energy and Environment: A Continuing Partnership, vol.3, American Nuclear Society (1991). An update of validation test results confirming the breakthrough in the low-Earth-orbit (LEO) cycle life of nickel-hydrogen cells containing 26% KOH electrolyte is presented. The results are part of an investigation of the effect of KOH concentration on life cycle. The cycle life of boiler plate cells was about 40000 LEO cycles compared to 3500 cycles for cells containing 31% KOH. The cycle regime was a stressful accelerated LEO, which consisted of a 27.5 min charge followed by a 17.5 min discharge (2×normal rate). The depth-of-discharge (DOD) was 80%. The cell temperature was maintained at 23°C. Results for six 48-Ah recirculation design IPV nickel-hydrogen flight battery cells currently being evaluated to validate the above findings are reported. Three of the cells contain 26% KOH (test cells), and three contain 31% KOH (control cells). They are undergoing real-time LEO cycle life testing. The 31% KOH cells failed at cycles 3729, 4165, and 11355. One of the 26% KOH cells failed at cycle 15314. The other two 26% KOH cells have been cycled for over 16600 cycles without failure     

Demonstration of a zinc bromine battery in an electric vehicle

The zinc bromine battery is a high energy density battery that utilizes low cost materials. The battery is of unique construction utilizing plastic storage tanks for the zinc bromide electrolyte and plastic bipolar electrode stacks. This paper briefly describes the zinc bromine battery technology and the experience gained in installing and operating an electric vehicle with this advanced system. The described electric vehicle (The “T-Star”) was tested in March 1993 on the Chrysler Proving Grounds in Phoenix, Arizona and it participated in the May 1993 American Tour de Sol capturing second place over all and first place in the student division     

Hubble Space Telescope at twelve years of age

The Hubble Space Telescope was deployed from the Space Shuttle Discovery into a 380-mile high Earth orbit on April 25, 1990. It subsequently made outstanding astronomical discoveries with its 8-foot (2.4-meter) telescope and other scientific instruments. Critical to the successful observations was continuous availability of power from its solar arrays during sunlit periods, and from nickel-hydrogen batteries when the satellite was in the Earth's shadow. The adopted nickel-hydrogen batteries were carefully selected and tested to confirm their depth-of-discharge and operating temperature that delivered the longest life in charge/discharge cycling service. These batteries had a design life of 7 years. At 12 years after launch the Hubble batteries have delivered more charge/discharge cycles than any other batteries in low-Earth orbit. However, the Hubble batteries have been subjected to many unexpected stresses, and peculiar reductions in battery capacity have been observed. Battery replacement requires a costly trip to the Hubble Space Telescope by astronauts, so the remaining useful life of the batteries must be predicted. Already in four servicing missions, astronauts have replaced or modified optics, solar arrays, a power control unit, and various science packages. A fifth servicing mission is scheduled in 2004. This paper discusses battery charging hardware and software controls, history of battery events in Hubble, cell performance model and spare battery tests, and capacity walkdown.     

Safety testing of lithium ion batteries for navy devices

Lithium ion battery technology is being introduced into power supplies used by our armed forces for a variety of applications. In many cases, the same cells and design parameters that support commercial battery packs are being used in military battery packs. This approach is expected to result in a major decrease in the total life cycle cost of the equipment these batteries support. On June 13, 1991, NAVSEA issued INST9310.1B1, which states that all lithium battery powered equipment must undergo safety evaluation and approval prior to fleet use. This safety program governs a process whereby approvals are issued for lithium batteries to be used in specific equipment on ground facilities, surface combatants, air combatants, and/or submarines. The Naval Ordnance Safety and Security Activity (NOSSA) manages the program. The chief technical advisors are Code 644 at NSWC Carderock Division and Code 609A at NSWC Crane Division. This paper describes three battery designs that incorporate lithium ion technology, and the results of battery safety tests conducted in accordance with navy requirements.     

基于组合预测模型的某型导弹贮存寿命评估方法

科学确定导弹的贮存寿命对提高部队装备保障能力和战斗力具有重要的现实意义。针对导弹贮存数据具有“少数据”和随机波动性较大特点,建立了灰色GM（1,1）评估模型和马尔可夫模型的组合预测模型,并应川此组合预测模型解决了某型导弹贮存寿命评估的问题。结果表明,该方法对现有数据拟合程度较好,预测精度较高,克服单一预测方法的不足,有效性强,使用价值大。