Isotopic Composition of the Solar Wind Inferred from In-Situ Spacecraft Measurements

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gyr ago from the protosolar nebula. Data from space missions and theoretical models indicate that the solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. In anticipation of results from the Genesis mission’s solar-wind implanted samples, we revisit solar wind isotopic abundance data from the high-resolution CELIAS/MTOF spectrometer on board SOHO. In particular, we evaluate the isotopic abundance ratios ¹⁵N/¹⁴N, ¹⁷O/¹⁶O, and ¹⁸O/¹⁶O in the solar wind, which are reference values for isotopic fractionation processes during the formation of terrestrial planets as well as for the Galactic chemical evolution. We also give isotopic abundance ratios for He, Ne, Ar, Mg, Si, Ca, and Fe measured in situ in the solar wind.     

Composition of Light Solar Wind Noble Gases in the Bulk Metallic Glass flown on the Genesis Mission

We discuss data of light noble gases from the solar wind implanted into a metallic glass target flown on the Genesis mission. Helium and neon isotopic compositions of the bulk solar wind trapped in this target during 887 days of exposure to the solar wind do not deviate significantly from the values in foils of the Apollo Solar Wind Composition experiments, which have been exposed for hours to days. In general, the depth profile of the Ne isotopic composition is similar to those often found in lunar soils, and essentially very well reproduced by ion-implantation modelling, adopting the measured velocity distribution of solar particles during the Genesis exposure and assuming a uniform isotopic composition of solar wind neon. The results confirm that contributions from high-energy particles to the solar wind fluence are negligible, which is consistent with in-situ observations. This makes the enigmatic “SEP-Ne” component, apparently present in lunar grains at relatively large depth, obsolete. ²⁰Ne/ ²²Ne ratios in gas trapped very near the metallic glass surface are up to 10% higher than predicted by ion implantation simulations. We attribute this superficially trapped gas to very low-speed, current-sheet-related solar wind, which has been fractionated in the corona due to inefficient Coulomb drag.     

Solar and Solar-Wind Composition Results from the Genesis Mission

The Genesis mission returned samples of solar wind to Earth in September 2004 for ground-based analyses of solar-wind composition, particularly for isotope ratios. Substrates, consisting mostly of high-purity semiconductor materials, were exposed to the solar wind at L1 from December 2001 to April 2004. In addition to a bulk sample of the solar wind, separate samples of coronal hole (CH), interstream (IS), and coronal mass ejection material were obtained. Although many substrates were broken upon landing due to the failure to deploy the parachute, a number of results have been obtained, and most of the primary science objectives will likely be met. These objectives include He, Ne, Ar, Kr, and Xe isotope ratios in the bulk solar wind and in different solar-wind regimes, and ¹⁵N/¹⁴N and ¹⁸O/¹⁷O/¹⁶O to high precision. The greatest successes to date have been with the noble gases. Light noble gases from bulk solar wind and separate solar-wind regime samples have now been analyzed. Helium results show clear evidence of isotopic fractionation between CH and IS samples, consistent with simplistic Coulomb drag theory predictions of fractionation between the photosphere and different solar-wind regimes, though fractionation by wave heating is also a possible explanation. Neon results from closed system stepped etching of bulk metallic glass have revealed the nature of isotopic fractionation as a function of depth, which in lunar samples have for years deceptively suggested the presence of an additional, energetic component in solar wind trapped in lunar grains and meteorites. Isotope ratios of the heavy noble gases, nitrogen, and oxygen are in the process of being measured.     

Isotopic Composition of H,HE and NE in the Protosolar Cloud

Observations and measurements in the solar wind, the Jovian atmosphere and the gases trapped in lunar surface material provide the main evidence from which the isotopic composition of H, He and Ne in the Protosolar Cloud (PSC) is derived. These measurements and observations are reviewed and the corrections are discussed that are needed for obtaining from them the PSC isotopic ratios. The D/H, ³He/⁴He (D+³He)/H, ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios adopted for the PSC are presented. Protosolar abundances provide the basis for the interpretation of isotopic ratios measured in the various solar system objects. In this article we discuss constraints derived from the PSC abundances on solar mixing, the origin of atmospheric neon, and the nature of the “SEP” component of neon trapped at the lunar surface. We also discuss constraints on the galactic evolution provided by the isotopic abundances of H and He in the PSC. This revised version was published online in August 2006 with corrections to the Cover Date.     

The isotopic composition of anomalous cosmic rays from sampex

Measurements of the anomalous cosmic ray (ACR) isotopic composition have been made in three regions of the magnetosphere accessible from the polar Earth orbit of SAMPEX, including the interplanetary medium at high latitudes and geomagnetically trapped ACRs. At those latitudes where ACRs can penetrate the Earth's magnetic field while fully stripped galactic cosmic rays (GCRs) of similar energies are excluded, a pure ACR sample is observed to have the following composition: ¹⁵N/N < 0.023, ¹⁸O/¹⁶O < 0.0034, and ²²Ne/²⁰Ne = 0.077(+0.085, –0.023). We compare our values with those found by previous investigators and with those measured in other samples of solar and galactic material. In particular, a comparison of ²²Ne/²⁰Ne measurements from various sources implies that GCRs are not simply an accelerated sample of the local interstellar medium.     

OB Associations, Wolf–Rayet Stars, and the Origin of Galactic Cosmic Rays

We have measured the isotopic abundances of neon and a number of other species in the galactic cosmic rays (GCRs) using the Cosmic Ray Isotope Spectrometer (CRIS) aboard the ACE spacecraft. Our data are compared to recent results from two-component (Wolf–Rayet material plus solar-like mixtures) Wolf–Rayet (WR) models. The three largest deviations of galactic cosmic ray isotope ratios from solar-system ratios predicted by these models, ¹²C/¹⁶O, ²²Ne/²⁰Ne, and ⁵⁸Fe/⁵⁶Fe, are very close to those observed. All of the isotopic ratios that we have measured are consistent with a GCR source consisting of ∼20% of WR material mixed with ∼80% material with solar-system composition. Since WR stars are evolutionary products of OB stars, and most OB stars exist in OB associations that form superbubbles, the good agreement of our data with WR models suggests that OB associations within superbubbles are the likely source of at least a substantial fraction of GCRs. In previous work it has been shown that the primary ⁵⁹Ni (which decays only by electron-capture) in GCRs has decayed, indicating a time interval between nucleosynthesis and acceleration of >10⁵ y. It has been suggested that in the OB association environment, ejecta from supernovae might be accelerated by the high velocity WR winds on a time scale that is short compared to the half-life of ⁵⁹Ni. Thus the ⁵⁹Ni might not have time to decay and this would cast doubt upon the OB association origin of cosmic rays. In this paper we suggest a scenario that should allow much of the ⁵⁹Ni to decay in the OB association environment and conclude that the hypothesis of the OB association origin of cosmic rays appears to be viable.     

Cosmic-ray Composition as Observed by Ulysses

The cosmic ray isotopic composition measurements from the High Energy Telescope (HET) on the Ulysses spacecraft are reviewed. The source isotopic composition of key elements is found to be surprisingly like the Solar system abundances with the notable exception of ²²Ne. The average density of interstellar material cosmic rays traverse is found to be 0.25 atom cm^–3, corresponding to a confinement time of 20 Myr. Vanadium isotopic abundances are shown to be consistent with weak cosmic-ray reacceleration. The implications of these measurements are discussed.     

Isotopic Fractionation by Ion-Molecule Reactions

Isotopic fractionation in interstellar clouds can occur by ion-molecule reactions at low temperatures. The major effect is not kinetic but thermodynamic in origin in that it arises from the difference in rate coefficients between forward and backward directions in reactions which exchange isotopic atoms. In this article, we concentrate on deuterium fractionation in interstellar clouds; this effect enhances the relative abundances of deuterated isotopomers to their normal counterparts by up to four orders of magnitude as compared with the basic D/H elemental abundance ratio. We also discuss the fractionation of ¹⁵N and ¹³C. This revised version was published online in August 2006 with corrections to the Cover Date.     

Martian Volatiles: Isotopic Composition, Origin, and Evolution

Information about the composition of volatiles in the Martian atmosphere and interior derives from Viking spacecraft and ground-based measurements, and especially from measurements of volatiles trapped in Martian meteorites, which contain several distinct components. One volatile component, found in impact glass in some shergottites, gives the most precise measurement to date of the composition of Martian atmospheric Ar, Kr, and Xe, and also contains significant amounts of atmospheric nitrogen showing elevated ¹⁵N/¹⁴N. Compared to Viking analyses, the ³⁶Ar/¹³²Xe and ⁸⁴Kr/¹³²Xe elemental ratios are larger in shergottites, the ¹²⁹Xe/¹³²Xe ratio is similar, and the ⁴⁰Ar/³⁶Ar and ³⁶Ar/³⁸Ar ratios are smaller. The isotopic composition of atmospheric Kr is very similar to solar Kr, whereas the isotopes of atmospheric Xe have been strongly mass fractionated in favor of heavier isotopes. The nakhlites and ALH84001 contain an atmospheric component elementally fractionated relative to the recent atmospheric component observed in shergottites. Several Martian meteorites also contain one or more Martian interior components that do not show the mass fractionation observed in atmospheric noble gases and nitrogen. The D/H ratio in the atmosphere is strongly mass fractionated, but meteorites contain a distinct Martian interior hydrogen component. The isotopic composition of Martian atmospheric carbon and oxygen have not been precisely measured, but these elements in meteorites appear to show much less variation in isotopic composition, presumably in part because of buffering of the atmospheric component by larger condensed reservoirs. However, differences in the oxygen isotopic composition between meteorite silicate minerals (on the one hand) and water and carbonates indicate a lack of recycling of these volatiles through the interior. Many models have been presented to explain the observed isotopic fractionation in Martian atmospheric N, H, and noble gases in terms of partial loss of the planetary atmosphere, either very early in Martian history, or over extended geological time. The number of variables in these models is large, and we cannot be certain of their detailed applicability. Evolutionary data based on the radiogenic isotopes (i.e., ⁴⁰Ar/³⁶Ar, ¹²⁹Xe/¹³²Xe, and ¹³⁶Xe/¹³²Xe ratios) are potentially important, but meteorite data do not yet permit their use in detailed chronologies. The sources of Mars' original volatiles are not well defined. Some Martian components require a solar-like isotopic composition, whereas volatiles other than the noble gases (C, N, and H₂O) may have been largely contributed by a carbonaceous (or cometary) veneer late in planet formation. Also, carbonaceous material may have been the source of moderate amounts of water early in Martian history.     

The Genesis Solar Wind Concentrator: Flight and Post-Flight Conditions and Modeling of Instrumental Fractionation

The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

The composition of heavy ions in solar energetic particle events

We review recent advances in determining the elemental, charge-state, and isotopic composition of 1 to 20 MeV per nucleon ions in solar energetic particle (SEP) events and outline our current understanding of the nature of solar and interplanetary processes which may explain the observations.The composition within individual SEP events may vary both with time and energy, and will in general be different from that in other SEP events. Average values of relative abundances measured in a large number of SEP events, however, are found to be roughly energy independent in the 1 to 20 MeV per nucleon range, and show a systematic deviation from photospheric abundances which seems to be organized in terms of the first ionization potential of the ion.Direct measurements of the charge states of SEPs have revealed the surprisingly common presence of energetic He⁺ along with heavy ions with typically coronal ionization states. High-resolution measurements of isotopic abundance ratios in a small number of SEP events show these to be consistent with the universal composition except for the puzzling overabundance of the SEP ²²Ne/²⁰Ne relative to this isotopes ratio in the solar wind. The broad spectrum of observed elemental abundance variations, which in their extreme result in composition anomalies characteristic of ³He-rich, heavy-ion rich and carbon-poor SEP events, along with direct measurements of the ionization states of SEPs provide essential information on the physical characteristics of, and conditions in the source regions, as well as important constraints to possible models for SEP production.It is concluded that SEP acceleration is a two-step process, beginning with plasma-wave heating of the ambient plasma in the lower corona, which may include pockets of cold material, and followed by acceleration to the observed energies by either flare-generated coronal shocks or Fermi-type processes in the corona. Interplanetary propagation as well as acceleration by interplanetary propagating shock will often further modify the composition of SEP events, especially at lower energies.     

The Genesis Solar Wind Concentrator

The primary goal of the Genesis Mission is to collect solar wind ions and, from their analysis, establish key isotopic ratios that will help constrain models of solar nebula formation and evolution. The ratios of primary interest include ¹⁷O/¹⁶O and ¹⁸O/¹⁶O to ±0.1%, ¹⁵N/¹⁴N to ±1%, and the Li, Be, and B elemental and isotopic abundances. The required accuracies in N and O ratios cannot be achieved without concentrating the solar wind and implanting it into low-background target materials that are returned to Earth for analysis. The Genesis Concentrator is designed to concentrate the heavy ion flux from the solar wind by an average factor of at least 20 and implant it into a target of ultra-pure, well-characterized materials. High-transparency grids held at high voltages are used near the aperture to reject >90% of the protons, avoiding damage to the target. Another set of grids and applied voltages are used to accelerate and focus the remaining ions to implant into the target. The design uses an energy-independent parabolic ion mirror to focus ions onto a 6.2 cm diameter target of materials selected to contain levels of O and other elements of interest established and documented to be below 10% of the levels expected from the concentrated solar wind. To optimize the concentration of the ions, voltages are constantly adjusted based on real-time solar wind speed and temperature measurements from the Genesis ion monitor. Construction of the Concentrator required new developments in ion optics; materials; and instrument testing and handling. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Isotopic Signatures of Presolar Materials in Interplanetary Dust

Interplanetary dust particles collected in the stratosphere frequently exhibit enrichments in deuterium (D) and ¹⁵N relative to terrestrial materials. These effects are most likely due to the preservation of presolar interstellar materials. While the elevated D/H ratios probably resulted from mass fractionation during chemical reactions at very low < 100 K temperatures, the origin of the N isotopic anomalies remains unresolved. The bulk of the N-bearing material may have obtained its isotopic signatures from low temperature chemistry, but a nucleosynthetic origin is also possible. This revised version was published online in August 2006 with corrections to the Cover Date.     

Solar Isotopic Composition as Determined Using Solar Energetic Particles

Solar energetic particles (SEPs) provide a sample of the Sun from which solar composition may be determined. Using high-resolution measurements from the Solar Isotope Spectrometer (SIS) onboard NASA’s Advanced Composition Explorer (ACE) spacecraft, we have studied the isotopic composition of SEPs at energies ≥20 MeV/nucleon in large SEP events. We present SEP isotope measurements of C, O, Ne, Mg, Si, S, Ar, Ca, Fe, and Ni made in 49 large events from late 1997 to the present. The isotopic composition is highly variable from one SEP event to another due to variations in seed particle composition or due to mass fractionation that occurs during the acceleration and/or transport of these particles. We show that various isotopic and elemental enhancements are correlated with each other, discuss the empirical corrections used to account for the compositional variability, and obtain estimated solar isotopic abundances. We compare the solar values and their uncertainties inferred from SEPs with solar wind and other solar system abundances and find generally good agreement.     

The Accretion, Composition and Early Differentiation of Mars

The early development of Mars is of enormous interest, not just in its own right, but also because it provides unique insights into the earliest history of the Earth, a planet whose origins have been all but obliterated. Mars is not as depleted in moderately volatile elements as are other terrestrial planets. Judging by the data for Martian meteorites it has Rb/Sr 0.07 and K/U 19,000, both of which are roughly twice as high as the values for the Earth. The mantle of Mars is also twice as rich in Fe as the mantle of the Earth, the Martian core being small (20% by mass). This is thought to be because conditions were more oxidizing during core formation. For the same reason a number of elements that are moderately siderophile on Earth such as P, Mn, Cr and W, are more lithophile on Mars. The very different apparent behavior of high field strength (HFS) elements in Martian magmas compared to terrestrial basalts and eucrites may be related to this higher phosphorus content. The highly siderophile element abundance patterns have been interpreted as reflecting strong partitioning during core formation in a magma ocean environment with little if any late veneer. Oxygen isotope data provide evidence for the relative proportions of chondritic components that were accreted to form Mars. However, the amount of volatile element depletion predicted from these models does not match that observed — Mars would be expected to be more depleted in volatiles than the Earth. The easiest way to reconcile these data is for the Earth to have lost a fraction of its moderately volatile elements during late accretionary events, such as giant impacts. This might also explain the non-chondritic Si/Mg ratio of the silicate portion of the Earth. The lower density of Mars is consistent with this interpretation, as are isotopic data. ⁸⁷Rb-⁸⁷Sr, ¹²⁹I-¹²⁹Xe, ¹⁴⁶Sm-¹⁴²Nd, ¹⁸²Hf-¹⁸²W, ¹⁸⁷Re-¹⁸⁷Os, ²³⁵U-²⁰⁷Pb and ²³⁸U-²⁰⁶Pb isotopic data for Martian meteorites all provide evidence that Mars accreted rapidly and at an early stage differentiated into atmosphere, mantle and core. Variations in heavy xenon isotopes have proved complicated to interpret in terms of ²⁴⁴Pu decay and timing because of fractionation thought to be caused by hydrodynamic escape. There are, as yet, no resolvable isotopic heterogeneities identified in Martian meteorites resulting from ⁹²Nb decay to ⁹²Zr, consistent with the paucity of perovskite in the martian interior and its probable absence from any Martian magma ocean. Similarly the longer-lived ¹⁷⁶Lu-¹⁷⁶Hf system also preserves little record of early differentiation. In contrast W isotope data, Ba/W and time-integrated Re/Os ratios of Martian meteorites provide powerful evidence that the mantle retains remarkably early heterogeneities that are vestiges of core metal segregation processes that occurred within the first 20 Myr of the Solar System. Despite this evidence for rapid accretion and differentiation, there is no evidence that Mars grew more quickly than the Earth at an equivalent size. Mars appears to have just stopped growing earlier because it did not undergo late stage (>20 Myr), impacts on the scale of the Moon-forming Giant Impact that affected the Earth.     

On Noble Gas Processing in the Solar Accretion Disk

Two fractionation models are applied to the problem of generating the widely distributed “Q-component” noble gases in meteorites from the solar-like isotopic and elemental compositions that presumably characterized the early solar accretion disk. Noble gas fractionation by mass-dependent dissipation of the solar nebula, as suggested by Ozima et al. (1998), is examined in the context of a model developed by Johnstone et al. (1998) for accretion disk photoevaporation driven by intense UV radiation from a neighboring giant star. Hydrodynamic escape of heavier species entrained in hydrogen outflow from the UV-heated outer regions of the disk can generate substantial noble gas fractionations, but they do not match the observed Q-component isotopic pattern and moreover require the physically unrealistic assumption that the fractionated gases are confined to the heated disk boundary zone, without mixing with the interior nebula, for long periods of time. It seems more likely that hydrodynamic outflow is actually established below this zone, in the body of the disk. In this case fractionations are governed by Rayleigh distillation of the entire remaining nebula, and are negligible at the time when disk erosion is halted by the gravitational potential of the young sun embedded in the disk. A “local” model of noble gas fractionation by hydrodynamic blowoff of transient, methane-rich atmospheres outgassed from the interiors of large primitive planetesimals (Pepin, 1991) is updated and assessed against current data. Degassed atmospheres are assumed to contain isotopically solar noble gases except for an additional nucleogenic Xe component that contributes primarily to the two heaviest isotopes; there is evidence that this same component is present at varying levels in other solar-system volatile reservoirs, possibly reflecting a compositional change with time in the solar nebula. Single fixed values for the two free parameters in the blowoff modeling equations can generate fractionated Xe, Kr, Ar and Ne compositions in the residual atmosphere that closely match observed meteoritic isotopic distributions, and Q-gas elemental ratios are approximated by adsorption of fractionated gases on planetesimal surface grains using plausible values of relative Henry Law constants. Additional requirements for adsorption of sufficient absolute amounts of Q-gases on carrier grains, and their subsequent ejection to space, mixing in the nebula, and dispersal into meteorite bodies, are examined in the context of current models for body sizes and dynamical evolution in an early mass-rich asteroid belt (Chambers and Wetherill, 2001). Despite its ability to replicate isotopic compositions, uncertainties about the environments in which the blowoff model can successfully operate suggest that there is, as yet, no entirely satisfactory understanding of how the Q-component noble gases might have evolved from solar-like precursor compositions. This revised version was published online in August 2006 with corrections to the Cover Date.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Isotopic Fractionation by Plasma Processes

The Sun is the largest reservoir of matter in the solar system, which formed 4.6 Gy ago from the protosolar nebula. The solar wind carries a nearly unfractionated sample of heavy isotopes at energies of about 1 keV/amu from the Sun into interplanetary space. Data from space missions and theoretical models indicate that the isotopes of the volatile elements N, O, Ne, and Ar are fractionated by at most a few percent per atomic mass unit in different solar wind regimes. In contrast, isotopic abundances of solar and heliospheric energetic particles at energies larger than about 100 keV/amu are observed to strongly vary relative to solar abundances. Processes such as resonant acceleration or pre-acceleration by plasma waves, first-order Fermi acceleration, or propagation in the interplanetary plasma are discussed as causes for charge-to-mass dependent fractionation. This revised version was published online in August 2006 with corrections to the Cover Date.     

The Composition of the Solar Wind in Polar Coronal Holes

The solar wind charge state and elemental compositions have been measured with the Solar Wind Ion Composition Spectrometers (SWICS) on Ulysses and ACE for a combined period of about 25 years. This most extensive data set includes all varieties of solar wind flows and extends over more than one solar cycle. With SWICS the abundances of all charge states of He, C, N, O, Ne, Mg, Si, S, Ar and Fe can be reliably determined (when averaged over sufficiently long time periods) under any solar wind flow conditions. Here we report on results of our detailed analysis of the elemental composition and ionization states of the most unbiased solar wind from the polar coronal holes during solar minimum in 1994–1996, which includes new values for the abundance S, Ca and Ar and a more accurate determination of the ²⁰Ne abundance. We find that in the solar minimum polar coronal hole solar wind the average freezing-in temperature is ∼1.1×10⁶ K, increasing slightly with the mass of the ion. Using an extrapolation method we derive photospheric abundances from solar wind composition measurements. We suggest that our solar-wind-derived values should be used for the photospheric ratios of Ne/Fe=1.26±0.28 and Ar/Fe=0.030±0.007.