Meteoroid bombardment as a source of the lunar exosphere

The column densities of impact-produced metal atoms in the exosphere during the peaks of activity of the main meteor showers – Geminids, Quadrantids and Perseids – and during quiet periods are estimated. The Na supply rate is estimated to be 2 × 10⁴, 3 × 10³, 10⁴, and 2 × 10⁴ atoms cm⁻² s⁻¹ for sporadic meteoroids, Perseid, Geminid, and Quadrantid meteor showers, respectively. A low upper limit on Ca in the lunar exosphere is explained by the condensation of Ca into dust grains during expansion of the cooling impact-produced vapor cloud. The chemical composition of gas-phase species released to the lunar exosphere during meteoroid impacts has been estimated. Most impact-produced molecules that contain metals are destroyed by solar photons while on ballistic trajectories. Energies of Na, K, Ca, and Mg atoms produced via photolysis of the respective monoxides are estimated to be 0.4, 0.35, 0.6, and 0.45 eV, respectively. The relative content of impact-produced Na and K atoms is maximal at altitudes of about 1000–2000 km and during the main meteor showers, lunar eclipses, and passages of the Moon through the Earth’s magnetosphere.     

Synthesis,chemistry and photochemistry of cyanobutadiyne (HCCCCCN)

Cyanobutadiyne has been synthesized starting from the mono or bistributylstannyl derivative of 1,3-butadiyne and p-toluenesulfonyl cyanide. The UV spectrum of HC₅N and the ¹³C NMR spectrum of the deuterocyanobutadiyne DC₅N have been recorded for the first time. Cyanobutadiyne has been detected in the photolysis of mixtures of gases observed on Titan. Its formation starting from cyanoacetylene and acetylene also occurs in the presence of huge amounts of dinitrogen, the major constituent of the Titan’s atmosphere. The application of these findings to the atmosphere of Titan is discussed. The chemistry and photochemistry of cyanobutadiyne have been investigated. A photoadduct has been observed in the photolysis of cyanoacetylene and ethanethiol and, a univocal synthesis of this compound was performed by a nucleophilic addition reaction.     

Heterogeneous solid/gas chemistry of organic compounds related to comets,meteorites, Titan,and Mars: Laboratory and in lower Earth orbit experiments

To understand the evolution of organic molecules involved in extraterrestrial environments and with exobiological implications, many experimental programs in the laboratory are devoted to photochemical studies in the gaseous phase as well as in the solid state. The validity of such studies and their applications to extraterrestrial environments can be questioned as long as experiments conducted in space conditions, with the full solar spectrum, especially in the short wavelength domain, have not been implemented. The experiments that are described here will be carried out on a FOTON capsule, using the BIOPAN facility, and on the International Space Station, using the EXPOSE facility. Vented and sealed exposition cells will be used, which will allow us to study the chemical evolution in the gaseous phase as well as heterogeneous processes, such as the degradation of solid compounds and the release of gaseous fragments.     

Photo-alteration of hydantoins against UV light and its relevance to prebiotic chemistry

Aqueous solutions of 5-substituted hydantoins were irradiated with ultraviolet (UV) light, to investigate their structural stability against UV radiation as well as the possible photolysis products. The photolysis products were identified and the degree of photolysis was measured using reversed-phase and ion-exchange high-performance liquid chromatography. Hydantoin (2,4-imidazolidinedione) was dominantly detected as a photolysis product of 5-substituted hydantoins. With hydrolysis of UV-irradiated 5-substituted hydantoins, glycine and alanine were dominantly detected. These experimental results are important for the prebiotic photochemistry of 5-substituted hydantoins in the formation of hydantoin since they have been detected in Solar System materials.