球形ZnS纳米粒子的制备和光学性质

用快速均匀沉淀法制备了平均粒径3nm左右的球形ZnS纳米粒子。并且讨论了成长时间，反应温度，体系pH值，反应物浓度和配比对ZnS纳米粒子尺寸的影响。通过XRD，BET，紫外可见吸收光谱表征了ZnS纳米粒子的尺寸、结构和表面态性质。通过红外吸收光谱证明了吸附在ZnS纳米颗粒上的乙酸基起到控制粒子长大和防止团聚的作用。研究了ZnS纳米晶粒的荧光光谱，证实其在425nm处的蓝色发光峰是来源于表面硫空位与锌空位之间的电子-空穴复合跃迁发光。     

Earth as an extrasolar planet: Earth model validation using EPOXI earth observations

The EPOXI Discovery Mission of Opportunity reused the Deep Impact flyby spacecraft to obtain spatially and temporally resolved visible photometric and moderate resolution near-infrared (NIR) spectroscopic observations of Earth. These remote observations provide a rigorous validation of whole-disk Earth model simulations used to better understand remotely detectable extrasolar planet characteristics. We have used these data to upgrade, correct, and validate the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional line-by-line, multiple-scattering spectral Earth model. This comprehensive model now includes specular reflectance from the ocean and explicitly includes atmospheric effects such as Rayleigh scattering, gas absorption, and temperature structure. We have used this model to generate spatially and temporally resolved synthetic spectra and images of Earth for the dates of EPOXI observation. Model parameters were varied to yield an optimum fit to the data. We found that a minimum spatial resolution of ～100 pixels on the visible disk, and four categories of water clouds, which were defined by using observed cloud positions and optical thicknesses, were needed to yield acceptable fits. The validated model provides a simultaneous fit to Earth's lightcurve, absolute brightness, and spectral data, with a root-mean-square (RMS) error of typically less than 3% for the multiwavelength lightcurves and residuals of ～10% for the absolute brightness throughout the visible and NIR spectral range. We have extended our validation into the mid-infrared by comparing the model to high spectral resolution observations of Earth from the Atmospheric Infrared Sounder, obtaining a fit with residuals of ～7% and brightness temperature errors of less than 1?K in the atmospheric window. For the purpose of understanding the observable characteristics of the distant Earth at arbitrary viewing geometry and observing cadence, our validated forward model can be used to simulate Earth's time-dependent brightness and spectral properties for wavelengths from the far ultraviolet to the far infrared. Key Words: Astrobiology-Extrasolar terrestrial planets-Habitability-Planetary science-Radiative transfer. Astrobiology 11, 393-408.     

An Overview of the Instrument Suite for the Deep Impact Mission

A suite of three optical instruments has been developed to observe Comet 9P/Tempel 1, the impact of a dedicated impactor spacecraft, and the resulting crater formation for the Deep Impact mission. The high-resolution instrument (HRI) consists of an f/35 telescope with 10.5 m focal length, and a combined filtered CCD camera and IR spectrometer. The medium-resolution instrument (MRI) consists of an f/17.5 telescope with a 2.1 m focal length feeding a filtered CCD camera. The HRI and MRI are mounted on an instrument platform on the flyby spacecraft, along with the spacecraft star trackers and inertial reference unit. The third instrument is a simple unfiltered CCD camera with the same telescope as MRI, mounted within the impactor spacecraft. All three instruments use a Fairchild split-frame-transfer CCD with 1,024× 1,024 active pixels. The IR spectrometer is a two-prism (CaF₂ and ZnSe) imaging spectrometer imaged on a Rockwell HAWAII-1R HgCdTe MWIR array. The CCDs and IR FPA are read out and digitized to 14 bits by a set of dedicated instrument electronics, one set per instrument. Each electronics box is controlled by a radiation-hard TSC695F microprocessor. Software running on the microprocessor executes imaging commands from a sequence engine on the spacecraft. Commands and telemetry are transmitted via a MIL-STD-1553 interface, while image data are transmitted to the spacecraft via a low-voltage differential signaling (LVDS) interface standard. The instruments are used as the science instruments and are used for the optical navigation of both spacecraft. This paper presents an overview of the instrument suite designs, functionality, calibration and operational considerations.     

Properties of an Earth-like planet orbiting a Sun-like star: Earth observed by the EPOXI mission

NASA's EPOXI mission observed the disc-integrated Earth and Moon to test techniques for reconnoitering extrasolar terrestrial planets, using the Deep Impact flyby spacecraft to observe Earth at the beginning and end of Northern Hemisphere spring, 2008, from a range of ～1/6 to 1/3 AU. These observations furnish high-precision and high-cadence empirical photometry and spectroscopy of Earth, suitable as "ground truth" for numerically simulating realistic observational scenarios for an Earth-like exoplanet with finite signal-to-noise ratio. Earth was observed at near-equatorial sub-spacecraft latitude on 18-19 March, 28-29 May, and 4-5 June (UT), in the range of 372-4540?nm wavelength with low visible resolving power (λ/Δλ=5-13) and moderate IR resolving power (λ/Δλ=215-730). Spectrophotometry in seven filters yields light curves at ～372-948?nm filter-averaged wavelength, modulated by Earth's rotation with peak-to-peak amplitude of ≤20%. The spatially resolved Sun glint is a minor contributor to disc-integrated reflectance. Spectroscopy at 1100-4540?nm reveals gaseous water and carbon dioxide, with minor features of molecular oxygen, methane, and nitrous oxide. One-day changes in global cloud cover resulted in differences between the light curve beginning and end of ≤5%. The light curve of a lunar transit of Earth on 29 May is color-dependent due to the Moon's red spectrum partially occulting Earth's relatively blue spectrum. The "vegetation red edge" spectral contrast observed between two long-wavelength visible/near-IR bands is ambiguous, not clearly distinguishing between the verdant Earth diluted by cloud cover versus the desolate mineral regolith of the Moon. Spectrophotometry in at least one other comparison band at short wavelength is required to distinguish between Earth-like and Moon-like surfaces in reconnaissance observations. However, measurements at 850?nm alone, the high-reflectance side of the red edge, could be sufficient to establish periodicity in the light curve and deduce Earth's diurnal period and the existence of fixed surface units.