Regolith-derived ferrosilicon as a potential feedstock material for wire-based additive manufacturing

Ferrosilicon is a primary metallic alloy produced during the reduction of metal oxides contained in lunar and Martian regolith by a variety of techniques. This study examines the usefulness of ferrosilicon as a candidate feedstock material for wire-based 3D printers designed for in-space manufacturing. Alloys of composition ranging from pure iron to 12?wt% Si were synthesized and their electrical and mechanical properties characterized. The melts were cast into rods for mechanical testing to determine ultimate strength and ductility. It was determined that the samples above 3?wt% Si were too brittle to be pulled into wire and ruptured at low strain values. The 3?wt% Si sample and iron had comparable mechanical properties relative to samples of higher silicon content but with differences in ductility and ultimate strength. Microstructure and compositional studies revealed the differences between the ductile and brittle samples as being the complete ferrite phase presence on the iron and low-Si content samples. This study establishes an upper limit on the Si content at 3?wt% in ferrosilicon materials to be used in wire feedstock in additive manufacturing for in-space applications.     

Bolometric luminosities and brightness temperatures of BL Lac Objects and FR I radio galaxies

To understand the connection among the subclasses of BL Lac Objects, FR I radio galaxies and Flat spectrum radio quasars (FSRQs), here the correlations of the bolometric luminosities with redshifts and brightness temperatures of these objects are studied. The bolometric luminosities vary linearly with redshifts, but few objects are scattered at high redshift. The bolometric luminosity versus brightness temperature distribution shows a correlation between these two components, except a few scattered objects, mostly RBLs. The bolometric luminosities and brightness temperatures of FR I radio galaxies with low redshift (<0.1) and low spectral index (α_rx < 0.75) are comparable to those of XBLs and those characteristics of FR I radio galaxies, with relatively high redshift (>0.2) and high spectral index, can be comparable with RBLs with low redshift (z < 0.5) and low bolometric luminosity. Those scattered RBLs with high redshifts (z > 0.5) are believed to be in complex environment with companion galaxies, most of these RBLs are still unresolved. The bolometric luminosity and brightness temperature of these scattered RBLs are comparable to those of quasars. The FSRQs are at high redshifts and bolometric luminosities and the brightness temperatures are also high relative to BL Lac Objects. These results support the FRI/BL Lac unification scheme. It suggests that, the FR I radio galaxies may be the parent populations of the BL Lac Objects, but it needs more investigation to confirm the unification of FR I radio galaxies, XBLs and RBLs.     

Determination of epsomite-hexahydrite equilibria by the humidity-buffer technique at 0.1 MPa with implications for phase equilibria in the system MgSO4-H2O

Epsomite (MgSO(4).7H(2)O) and hexahydrite (MgSO(4).6H(2)O) are common minerals found in marine evaporite deposits, in saline lakes as precipitates, in weathering zones of coal and metallic deposits, in some soils and their efflorescences, and possibly on the surface of Europa as evaporite deposits. Thermodynamic properties of these two minerals reported in the literature are in poor agreement. In this study, epsomite-hexahydrite equilibria were determined along four humidity-buffer curves at 0.1 MPa and between 25 and 45 degrees C. Results obtained for the reaction epsomite = hexahydrite + H(2)O, as demonstrated by very tight reversals along each humidity buffer, can be represented by ln K(+/- 0.012) = 20.001 - 7182.07/T, where K is the equilibrium constant, and T is temperature in Kelvin. The derived standard Gibbs free energy of reaction is 10.13 +/- 0.07 kJ/mol, which is essentially the same value as that calculated from vapor pressure measurements reported in the literature. However, this value is at least 0.8 kJ/mol lower than those calculated from the data derived mostly from calorimetric measurements.