燃烧室热力计算的一种新方法

本文根据燃气轮机燃烧室热力计算的“非迭代精确法”原理,推导了使用液体或气体燃料的燃气轮机.蒸气轮机联合循环研究中几种燃烧室热力计算的通用公式,并从两个不同角度,将其与国内常用的“等温焓差法”进行对比分析,揭示了它们之间的内在联系.     

Sugar synthesis from a gas-phase formose reaction

Prebiotic possibilities for the synthesis of interstellar ribose through a protic variant of the formose reaction under gas-phase conditions were studied in the absence of any known catalyst. The ion-molecule reaction products, diose and triose, were sought by mass spectrometry, and relevant masses were observed. Ab initio calculations were used to evaluate protic formose mechanism possibilities. A bilateral theoretical and experimental effort yielded a physical model for glycoaldehyde generation whereby a hydronium cation can mediate formaldehyde dimerization followed by covalent bond formation leading to diose and water. These results advance the possibility that ion-molecule reactions between formaldehyde (CH(2)O) and H(3)O(+) lead to formose reaction products and inform us about potential sugar formation processes in interstellar space.