Volatile Trapping in Martian Clathrates

Thermodynamic conditions suggest that clathrates might exist on Mars. Despite observations which show that the dominant condensed phases on the surface of Mars are solid carbon dioxide and water ice, clathrates have been repeatedly proposed to play an important role in the distribution and total inventory of the planet’s volatiles. Here we review the potential consequences of the presence of clathrates on Mars. We investigate how clathrates could be a potential source for the claimed existence of atmospheric methane. In this context, plausible clathrate formation processes, either in the close subsurface or at the base of the cryosphere, are reviewed. Mechanisms that would allow for methane release into the atmosphere from an existing clathrate layer are addressed as well. We also discuss the proposed relationship between clathrate formation/dissociation cycles and how potential seasonal variations influence the atmospheric abundances of argon, krypton and xenon. Moreover, we examine several Martian geomorphologic features that could have been generated by the dissociation of extended subsurface clathrate layers. Finally we investigate the future in situ measurements, as well as the theoretical and experimental improvements that will be needed to better understand the influence of clathrates on the evolution of Mars and its atmosphere.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Infrared Spectroscopy of Solar-System Planets

Most of our knowledge regarding planetary atmospheric composition and structure has been achieved by remote sensing spectroscopy. Planetary spectra strongly differ from one planet to another. CO₂ signatures dominate on Mars, and even more on Venus (where the thermal component is detectable down to 1 μm on the dark side). Spectroscopic monitoring of Venus, Earth and Mars allows us to map temperature fields, wind fields, clouds, aerosols, surface mineralogy (in the case of the Earth and Mars), and to study the planets’ seasonal cycles. Spectra of giant planets are dominated by H₂, CH₄ and other hydrocarbons, NH₃, PH₃ and traces of other minor compounds like CO, H₂O and CO₂. Measurements of the atmospheric composition of giant planets have been used to constrain their formation scenario.     

Experimental and theoretical burning of solid rocket propellants near the pressure deflagration limit

Burning of composite solid rocket propellants near the pressure deflagration limit (PDL) was studied experimentally in two different test chambers. The propellant tested was a nonmetallized ammonium perchlorate-based composite propellant (AP 84/CTPB 16). Measurements were taken of the regression rate, oscillations frequency and flame luminosity. Self-sustained oscillations were detected near the PDL that matched reasonably well the predictions of the analytical nonlinear stability theory and of the numerically solved nonlinear mathematical model. Both experimental and numerical results show the burning rate oscillations near the PDL due to statically unstable burning, that is the only combustion regime possible below a certain pressure. When pressure is further reduced the amplitude of the oscillations increases and their frequency decreases, until extinction follows abruptly below a pressure that corresponds to the PDL.     

Analyse du fonctionnement d'un propulseur a éjection modulée

ONERA developed, for studying the response of a propellant to a pressure or velocity fluctuation, an experimental rocket engine whose nozzle throat area can be modulated by a toothed disk.The paper presents a linearized theory of the functioning of this engine in the low frequency domain, i.e. when there is no wave propagation within the combuster.To describe the functioning of this motor, the Ryazantsev-Novozhilov method, which assumes that the gas response is instantaneous, is used. This analysis takes into account the erosion and radiation effects, the combustion efficiency and the thermal losses through the walls.Two particular cases are described, for two values of the Damköhler parameter $\text{D}{}_1\text{=}\text{t}{}_{\mathrm{c}}\text{t}{}_{\mathrm{th}}$, where t_c is the residence time in the combuster and t_th the characteristic thermal time of the heat penetration into the solid propellant. These two cases correspond, one to a classical propellant D₁ > 1, the other to a particular propellant of low burning rate ($\text{J}{}_{\mathrm{b}}\text{? 0.2}\text{to}\text{0.4}\text{mm s}{}^{\mathrm{?1}}$) D₁ < 1. The stability conditions are analysed as well as the pressure amplitute and phase as a function of the nozzle throat modulation frequency.Still in linearized theory, the complete solutions of the problem are presented, using a method of numerical resolution.     

Prebiotic significance of extraterrestrial ice photochemistry: detection of hydantoin in organic residues

The delivery of extraterrestrial organic materials to primitive Earth from meteorites or micrometeorites has long been postulated to be one of the origins of the prebiotic molecules involved in the subsequent apparition of life. Here, we report on experiments in which vacuum UV photo-irradiation of interstellar/circumstellar ice analogues containing H(2)O, CH(3)OH, and NH(3) led to the production of several molecules of prebiotic interest. These were recovered at room temperature in the semi-refractory, water-soluble residues after evaporation of the ice. In particular, we detected small quantities of hydantoin (2,4-imidazolidinedione), a species suspected to play an important role in the formation of poly- and oligopeptides. In addition, hydantoin is known to form under extraterrestrial, abiotic conditions, since it has been detected, along with various other derivatives, in the soluble part of organic matter of primitive carbonaceous meteorites. This result, together with other related experiments reported recently, points to the potential importance of the photochemistry of interstellar "dirty" ices in the formation of organics in Solar System materials. Such molecules could then have been delivered to the surface of primitive Earth, as well as other telluric (exo-) planets, to help trigger first prebiotic reactions with the capacity to lead to some form of primitive biomolecular activity.