Element Abundances and Isotope Ratios in the Giant Planets and Titan

This paper reviews our present knowledge about elemental and isotopic ratios in the Giant Planets and Titan. These parameters can provide key information about the formation and evolution of these objects. Element abundances, especially after the results of the Galileo Probe Mass Spectrometer in Jupiter, strongly support the formation model invoking an initial core formation (Mizuno, 1980; Pollack et al., 1996). They also suggest that solar composition icy planetesimals (SCIPs) brought the heavy elements to Jupiter. The Jupiter value of D/H appears to be representative of the protosolar value, while the D/H enrichment observed on Uranus and Neptune is consistent with the formation scenario of these planets. The ¹⁵N/¹⁴N measurement in Jupiter seems to be representative of its protosolar value. Future measurements are expected to come from the Cassini and Herschel space mission, as well as the ALMA submillimeter observatory. This revised version was published online in August 2006 with corrections to the Cover Date.     

Cassini Imaging Science: Instrument Characteristics And Anticipated Scientific Investigations At Saturn

The Cassini Imaging Science Subsystem (ISS) is the highest-resolution two-dimensional imaging device on the Cassini Orbiter and has been designed for investigations of the bodies and phenomena found within the Saturnian planetary system. It consists of two framing cameras: a narrow angle, reflecting telescope with a 2-m focal length and a square field of view (FOV) 0.35^∘ across, and a wide-angle refractor with a 0.2-m focal length and a FOV 3.5^∘ across. At the heart of each camera is a charged coupled device (CCD) detector consisting of a 1024 square array of pixels, each 12 μ on a side. The data system allows many options for data collection, including choices for on-chip summing, rapid imaging and data compression. Each camera is outfitted with a large number of spectral filters which, taken together, span the electromagnetic spectrum from 200 to 1100 nm. These were chosen to address a multitude of Saturn-system scientific objectives: sounding the three-dimensional cloud structure and meteorology of the Saturn and Titan atmospheres, capturing lightning on both bodies, imaging the surfaces of Saturn’s many icy satellites, determining the structure of its enormous ring system, searching for previously undiscovered Saturnian moons (within and exterior to the rings), peering through the hazy Titan atmosphere to its yet-unexplored surface, and in general searching for temporal variability throughout the system on a variety of time scales. The ISS is also the optical navigation instrument for the Cassini mission. We describe here the capabilities and characteristics of the Cassini ISS, determined from both ground calibration data and in-flight data taken during cruise, and the Saturn-system investigations that will be conducted with it. At the time of writing, Cassini is approaching Saturn and the images returned to Earth thus far are both breathtaking and promising.This revised version was published online in July 2005 with a corrected cover date.     

Organic Chemistry and Exobiology on Titan

Exobiology is not only the study of the origin, distribution and evolution of life in the universe, but also of structures — including at the molecular level, and processes — including organic chemical transformations — related to life. In that respect, with its dense nitrogen atmosphere, which includes a noticeable fraction of methane, and the many organic compounds which are present in the gas and aerosols phases, Titan appears to be a planetary object of prime interest for exobiology in the Solar system, allowing the study of chemical organic evolution in a planetary environment over a long time scale. We describe here some aspects of this extraterrestrial organic chemistry which involves many physical and chemical couplings in the different parts of what can be called ‘Titan's geofluid’ (gas phase, aerosol phases and surface solid and maybe liquid phases). The three complementary approaches which can be followed to study such chemistry of exobiological interest are considered. Those are experimental simulations in the laboratory, chemical and photochemical modeling and of course observation, using both remote sensing and in situ measurements, which is an essential approach. The Cassini-Huygens mission, that offers a unique opportunity to study in detail the many aspects of Titan's organic chemistry, is discussed and the many expected exobiological returns from the different instruments of the Cassini orbiter and the Huygens probe are considered. This revised version was published online in August 2006 with corrections to the Cover Date.     

The 2.5 to 5 microns spectrum of comet Halley from the IKS instrument of Vega

Results of the 2.5–5 micron spectroscopic channel of the IKS instrument on Vega are reported and the data reduction process is described. H₂O and CO₂ molecules have been detected with production rates of 10³⁰ s⁻¹ and 1.5 10²⁸ s⁻¹ respectively. Emission features between 3.3 and 3.7 microns are tentatively attributed to CH - bearing compounds - CO is marginally detected with a mixing ratio CO/H₂O 0.2. OH emission and H₂O - ice absorption might also be present in the spectra.     

Galileo Probe Measurements of D/H and 3He/4He in Jupiter's Atmosphere

The Galileo Probe Mass Spectrometer measurements in the atmosphere of Jupiter give D/H = (2.6 ± 0.7) × 10-5 3He/4He = (1.66 ± 0.05) × 10-4These ratios supercede earlier results by Niemann et al. (1996) and are based on a reevaluation of the instrument response at high count rates and a more detailed study of the contributions of different species to the mass peak at 3 amu. The D/H ratio is consistent with Voyager and ground based data and recent spectroscopic and solar wind (SW) values obtained from the Infrared Spectroscopic Observatory (ISO) and Ulysses. The 3He/4He ratio is higher than that found in meteoritic gases (1.5 ± 0.3) × 10-4. The Galileo result for D/H when compared with that for hydrogen in the local interstellar medium (1.6 ± 0.12) × 10-5 implies a small decrease in D/H in this part of the universe during the past 4.55 billion years. Thus, it tends to support small values of primordial D/H - in the range of several times 10-5 rather than several times 10-4. These results are also quite consistent with no change in (D+3He)/H during the past 4.55 billion years in this part of our galaxy.     

Dark matter in the outer solar system.

There are now a large number of small bodies in the outer solar system that are known to be covered with dark material. Attempts to identify that material have been thwarted by the absence of discrete absorption features in the reflection spectra of these planetesimals. An absorption at 2.2 micrometers that appeared to be present in several objects has not been confirmed by new observations. Three absorptions in the spectrum of the unusually red planetesimal 5145 Pholus are well-established, but their identity remains a mystery.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Haze aerosols in the atmosphere of early Earth: manna from heaven

An organic haze layer in the upper atmosphere of Titan plays a crucial role in the atmospheric composition and climate of that moon. Such a haze layer may also have existed on the early Earth, providing an ultraviolet shield for greenhouse gases needed to warm the planet enough for life to arise and evolve. Despite the implications of such a haze layer, little is known about the organic material produced under early Earth conditions when both CO(2) and CH(4) may have been abundant in the atmosphere. For the first time, we experimentally demonstrate that organic haze can be generated in different CH(4)/CO(2) ratios. Here, we show that haze aerosols are able to form at CH(4) mixing ratios of 1,000 ppmv, a level likely to be present on early Earth. In addition, we find that organic hazes will form at C/O ratios as low as 0.6, which is lower than the predicted value of unity. We also show that as the C/O ratio decreases, the organic particles produced are more oxidized and contain biologically labile compounds. After life arose, the haze may thus have provided food for biota.     

The Contributions of Comets to Planets, Atmospheres, and Life: Insights from Cassini-Huygens, Galileo, Giotto, and Inner Planet Missions

Comets belong to a group of small bodies generally known as icy planetesimals. Today the most primitive icy planetesimals are the Kuiper Belt objects (KBOs) occupying a roughly planar domain beyond Neptune. KBOs may be scattered inward, allowing them to collide with planets. Others may move outward, some all the way into the Oort cloud. This is a spherical distribution of comet nuclei at a mean distance of ～50,000 AU. These nuclei are occasionally perturbed into orbits that intersect the paths of the planets, again allowing collisions. The composition of the atmosphere of Jupiter—and thus possibly all outer planets—shows the effects of massive early contributions from extremely primitive icy bodies that must have been close relatives of the KBOs. Titan may itself have a composition similar to that of Oort cloud comets. The origin and early evolution of its atmosphere invites comparison with that of the early Earth. Impacts of comets must have brought water and other volatile compounds to the Earth and the other inner planets, contributing to the reservoir of key ingredients for the origin of life. The magnitude of these contributions remains unknown but should be accessible to measurements by instruments on spacecraft.