聚苯胺中空微球的改性与电磁特性

 用分散聚合法制备单分散的聚苯乙烯（PS）微球，并用浓硫酸对PS微球进行表面改性。将改性后的PS微球作为制备聚苯胺（PANI）中空微球的模板，在一定浓度HCl掺杂条件下，苯胺单体在PS模板表面聚合，然后将PS模板通过N，N 二甲基甲酰胺(DMF)溶解，得到了粒径在0.8~1.2 μm的PANI中空微球。若在PANI聚合过程中加入适量的Fe₃O₄,可获得由Fe₃O₄与PANI构成的复合中空微球。2~18 GHz的波导法测试结果表明，经HCl和Fe₃O₄掺杂后的复合中空微球与本征态PANI中空微球的电磁参数存在很大变化；吸波性能研究表明，8~12 GHz范围内，PANI中空微球的吸波效果要好于其实心微球的吸波效果。     

Electromagnetism and Absorptivity of the Modified Micro-coiled Chiral Carbon Fibers

Micro-coiled chiral carbon fibers are modified by nano-Ni. X-ray diffraction （XRD） and scanning electron microscopy （SEM） are used to compare the composition and morphology of the unmodified and the modified fibers. The results show that electromagnetism parameters of the modified are different from those of the unmodified. After modification by nano-Ni, the micro-coiled chiral carbon fibers have decreased permittivity and electrical loss. The permeability and magnetic loss of the modified carbon fibers become larger than those of the unmodified ones. Moreover, the modification of unmodified chiral carbon fibers into the modified is much like changing hollow electric windings into those with magnetic cores inside. The modifier intensifies the cross polarization of the chiral carbon fibers and makes the permittivity and the permeability get closer to each other which improves the matching performance and enhances absorbability of coatings. In the range of 6-18 GHz, the reflectivity of the coating is 6-8dB and the bandwidth is 12 GHz. The area density of the coating is below 3 kg/m^2.     

雷达波吸波涂层理想电磁参数的计算机模拟分析

目前吸波涂层计算机模拟分析多是从现有材料出发,研究厚度、排布次序等参数对于涂层吸波性能的影响.本文介绍了一种通过预先设定雷达吸波涂层的厚度、反射率等多个参数,反推得到一定入射频率下达到预定反射率所需理想电磁参数区域的研究方法,并通过实验进行了验证.结果表明这种分析方法能够较好的预测吸波剂在不同频段的吸波性能并明确指出吸波剂的改性方向,对于吸波涂层的设计具有重要的作用和意义.