1,5-二氨基四唑含能配合物的制备、表征及其催化性能研究

合成出2种以1,5-二氨基四唑(DAT)为配体,苦味酸根为外界,钴和铜为中心离子的含能配合物,并对其结构进行了表征.运用示差扫描热分析(DSC)方法,就目标化合物对高氯酸铵(AP)、奥克托金(HMX)和六硝基六氮杂异伍兹烷(HNIW)热分解的影响进行了研究.利用电荷耦合器件(CCD)燃速测定系统,研究了目标化合物对缩水...     

超高速撞击下PTFE/Al含能材料薄板的载荷特性分析

不同于传统惰性材料的空间碎片防护结构,含能材料防护结构在超高速撞击下的冲击起爆特性是其防护能力得以提高的根本原因。PTFE/Al含能材料防护结构的冲击起爆特性改变了弹丸强冲击载荷下的破碎机制,弹丸内部的冲击压力对于分析含能材料在超高速撞击下的防护机理具有重要意义。对超高速撞击试验中回收的PTFE/Al防护结构后板进行损伤特性分析,获得了对应速度条件下弹丸的破碎特性。基于一维冲击波理论,分析PTFE/Al靶板在超高速撞击条件下的冲击响应过程,结合考虑化学反应效率的热化学反应模型,获得了弹丸在碰撞与爆炸联合作用下的载荷特性,通过与试验结果对比验证,获得该材料完全反应的临界撞击速度约为1800 m/s,弹丸的临界破碎速度为2875 m/s,小于铝防护结构中对应的临界破碎速度。给出了弹丸在PTFE/Al、铝两种防护结构中产生相同冲击压力时对应的临界速度,分别为弹道段的800 m/s和破碎段的3580 m/s。     

高能电子辐照下介质-导体相间结构深层充电特性研究

为研究影响介质-导体相间结构深层充电特性的内在因素,设计了不同构型的试验样品,利用90Sr放射源模拟空间高能电子环境对样品进行深层充电辐照试验,测量了充电电位的差异。并借助深层充电三维仿真软件计算介质-导体相间结构在不同几何构型情况下的深层充电电位、电场分布。试验和仿真结果表明,介质最高表面电位以及介质内部最大电场均与介质宽度和高度呈正相关。其他条件不变时,介质越宽,或越高于导体表面,发生放电的风险就越高。在介质与导体侧面存在微小缝隙情况下,介质内最大电场显著增强,易发生内部击穿。而在介质与导体之间的真空间隙内,电场很容易超过击穿阈值,放电风险很大。航天工程应用中为降低此种结构深层充放电的风险,在满足绝缘性能及其他要求的前提下应尽量减小介质的宽度,降低介质与导体间的高度差,并确保介质与导体侧面接触良好。     

Antideuterons as an indirect dark matter signature: Si(Li) detector development and a GAPS balloon mission

The General AntiParticle Spectrometer (GAPS) is a novel approach for indirect dark matter searches that exploits cosmic antideuterons. GAPS complements existing and planned direct dark matter searches as well as other indirect techniques, probing a different and unique region of parameter space in a variety of proposed dark matter models. The GAPS method involves capturing antiparticles into a target material with the subsequent formation of an excited exotic atom. The exotic atom decays with the emission of atomic X-rays and pions from the nuclear annihilation, which uniquely identifies the captured antiparticle. This technique has been verified through the accelerator testing at KEK in 2004 and 2005. The prototype flight is scheduled from Hokkaido, Japan in 2011, preparatory for a long duration balloon flight from the Antarctic in 2014.     

The hydroxyl radical as an indicator of SEP fluxes in the high-latitude terrestrial atmosphere

The low background values at nighttime of the mesospheric hydroxyl (OH) radical make it easier to single out the atmospheric response to the external solar forcing in Polar Regions. Because of the short lifetime of HO_x, it is possible to follow the trails of Solar Energetic Particle (SEP) events in the terrestrial atmosphere, as shown by Storini and Damiani (2008). The sensitivity of this indicator makes discernible not only extreme particle events with a flux peak of several thousand pfu [1 pfu = 1 particle/(cm² s sr)] at energies >10 MeV, but also those with lower flux up to about 300 pfu. Using data from the Microwave Limb Sounder (MLS) on board the EOS AURA satellite, we examined the correlation of OH abundance vs. solar proton flux for almost all the identified SEP events spanning from November 2004 to December 2006 (later on no more SEP events occurred during Solar Cycle no. 23). The channels at energies greater than 5 MeV and 10 MeV showed the best correlation values (r ∼ 0.90–0.95) at altitudes around 65–75 km whereas, as expected, the most energetic channels were most highly correlated at lower altitudes. Therefore, it is reasonably possible to estimate the solar proton flux from values of mesospheric OH (and viceversa) and it could be useful in studying periods with gaps in the records of solar particles.     

Al/Ni含能多层膜在Al2O3陶瓷/不锈钢焊接中的应用

采用磁控溅射设备,生长AuSn合金做焊料层、Al/Ni含能多层膜做热量提供层,实现了不锈钢和Al_2O_3间的异质材料自蔓延高温扩散焊。利用SEM、XRD和DSC等测试手段表征AuSn合金和Al/Ni含能多层膜的微观形貌、相成分和放热量;用万能试验机测试焊接接头的力学性能。结果表明,AuSn合金的质量比基本达到80∶20,而多层膜的层状结构清晰,反应热达到1 239 J/g。焊接实验结果表明,仅使用AuSn焊料时,剪切强度仅为46 MPa,在增加Al/Ni含能多层膜后,其剪切强度可达90 MPa,强度提高了约一倍。焊接接头的界面显微形貌和相结构研究表明,剪切强度的增强主要是Al/Ni多层膜提供了额外能量使得界面处的反应剧烈,陶瓷金属化层与中间层的反应加剧,形成了新的反应生成物。     

冷原子干涉陀螺研究进展

近年来,基于激光冷却与俘获的冷原子干涉技术得到了飞速的发展,这为精密转动测量提供了新的研究方向。相比于传统陀螺,冷原子干涉陀螺具有更高的灵敏度,是新一代的惯性测量仪器。从冷原子干涉陀螺的测量原理出发,介绍了近几年国内外干涉型冷原子陀螺的实现技术路线和研究现状,对比了各技术路线的优缺点,提炼出了最佳的研制冷原子干涉陀螺的总体技术方案,为高精度和高动态测量的陀螺样机研制提供了技术基础。     

基于蒙特卡罗方法的冷原子干涉仪物理仿真

由于现有的噪声分析方法无法很好地评估在复杂环境下冷原子干涉仪的输出特性,本文提出了一种新的冷原子干涉仪仿真方法,可以模拟大动态条件下各项噪声及其之间的耦合对冷原子干涉仪的影响。利用单粒子波包演化的处理方式对冷原子干涉仪进行全过程物理建模,并采取蒙特卡罗方法对大量确定初态的原子进行全过程统计,最终得到冷原子干涉仪在多种噪声同时存在的情况下的响应。该方法主要优势体现在能够对噪声耦合情形进行高精度仿真,并且可以根据实际数据对干涉仪输出进行实时处理,以提升冷原子干涉仪的性能指标。     

Viewing radiation signatures of solar energetic particles in interplanetary space

A current serious limitation on the studies of solar energetic particle (SEP) events is that their properties in the inner heliosphere are studied only through in situ spacecraft observations. Our understanding of spatial distributions and temporal variations of SEP events has come through statistical studies of many such events over several solar cycles. In contrast, flare SEPs in the solar corona can be imaged through their radiative and collisional interactions with solar fields and particles. We suggest that the heliospheric SEPs may also interact with heliospheric particles and fields to produce signatures which can be remotely observed and imaged. A challenge with any such candidate signature is to separate it from that of flare SEPs. The optimum case for imaging high-energy (E > 100 MeV) heliospheric protons may be the emission of π⁰-decay γ-rays following proton collisions with solar wind (SW) ions. In the case of E > 1 MeV electrons, gyrosynchrotron radio emission may be the most readily detectible remote signal. In both cases we may already have observed one or two such events. Another radiative signature from nonthermal particles may be resonant transition radiation, which has likely already been observed from solar flare electrons. We discuss energetic neutrons as another possible remote signature, but we rule out γ-ray line and 0.511 MeV positron annihilation emission as observable signatures of heliospheric energetic ions. We are already acquiring global signatures of large inner-heliospheric SW density features and of heliosheath interactions between the SW and interstellar neutral ions. By finding an appropriate observable signature of remote heliospheric SEPs, we could supplement the in situ observations with global maps of energetic SEP events to provide a comprehensive view of SEP events.     

基于中性层偏移的Z型材滚弯成形回弹预测

以提高大截面Z型材四轴滚弯成形精度为目的，通过综合考虑材料属性、几何特征和成形半径等因素对回弹的影响，建立了引入中性层偏移的大截面Z型材弯曲回弹解析模型，研究了7075-O和7475-O铝合金Z型材在不同滚弯成形半径下的回弹规律，并进行滚弯成形实验验证。结果表明，与忽略中性层偏移影响的型材回弹预测经验模型相比，基于中性层偏移的回弹预测模型能够准确预测大截面Z型材的回弹量，在相同的曲率半径下，预测回弹变形的最大相对误差从11.681%减小到3.347%。