| 1,5-二氨基四唑含能配合物的制备、表征及其催化性能研究 |
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| 引用本文： | 李志敏,张建国,刘俊伟,翟进贤,张同来,杨利.1,5-二氨基四唑含能配合物的制备、表征及其催化性能研究[J].固体火箭技术,2011,34(1):79-85. |
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| 作者姓名： | 李志敏 张建国 刘俊伟 翟进贤 张同来 杨利 |
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| 作者单位： | 1. 北京理工大学,爆炸科学与技术国家重点实验室,北京,100081
2. 北京理工大学,材料学院,北京,100081 |
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| 基金项目： | 国家自然科学基金(10776002和20911120033); 爆炸科学与技术国家重点实验室(北京理工大学)自主课题(ZD-KT08-01和YBKT10-03); 教育部新世纪优秀人才资助计划项目(NCET-10-00051) |
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| 摘 要： | 合成出2种以1,5-二氨基四唑(DAT)为配体,苦味酸根为外界,钴和铜为中心离子的含能配合物,并对其结构进行了表征.运用示差扫描热分析(DSC)方法,就目标化合物对高氯酸铵(AP)、奥克托金(HMX)和六硝基六氮杂异伍兹烷(HNIW)热分解的影响进行了研究.利用电荷耦合器件(CCD)燃速测定系统,研究了目标化合物对缩水...
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| 关 键 词： | 1 5-二氨基四唑 含能配合物 热分解 催化作用 |
Synthesis,characterization and catalytic activity of energetic complexes based on 1,5-diaminotetrazole |
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| LI Zhi-min,ZHANG Jian-guo,LIU Jun-wei,ZHAI Jin-xian,ZHANG Tong-lai,YANG Li.Synthesis,characterization and catalytic activity of energetic complexes based on 1,5-diaminotetrazole[J].Journal of Solid Rocket Technology,2011,34(1):79-85. |
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| Authors: | LI Zhi-min ZHANG Jian-guo LIU Jun-wei ZHAI Jin-xian ZHANG Tong-lai YANG Li |
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| Institution: | LI Zhi-min1,ZHANG Jian-guo1,LIU Jun-wei1,ZHAI Jin-xian2,ZHANG Tong-lai1,YANG Li1(1.State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing 100081,China,2.Schoole of Material Science and Engineering,China) |
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| Abstract: | Two novel energetic coordination compounds using 1,5-diaminotetrazole as ligand,Co or Cu as the central cation and picric acid as outer ion were synthesized and characterized by elemental analysis,FT-IR spectroscopy.The effects of the two complexes on thermal decomposition of AP,HMX and HNIW were investigated by DSC and TG-DTG technologies.The CCD burning-rate determinate system was used to study the catalysis of the two complexes on the combustion of the GAP/HNIW propellant.The results show the two novel e... |
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| Keywords: | 1 5-diaminotetrazole energetic complexes thermal decomposition catalysis |
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