WC/C复合涂层海水环境的耐蚀性与摩擦性能

采用非平衡磁控溅射技术在304L不锈钢和单晶硅基底上沉积WC/C多层复合涂层,利用扫描电镜、Raman光谱仪、X射线衍射仪等研究WC/C复合涂层的微观结构,采用纳米压痕仪、划痕测试系统测试涂层的力学性能,利用电化学测试系统和摩擦磨损试验机分别研究涂层在人工配置的海水环境的耐蚀性能和摩擦性能。结果表明:WC/C复合涂层内含有较多类石墨sp2键结构,存在WC1-x相并镶嵌在非晶碳基质中。较之于304L不锈钢基底,WC/C复合涂层在海水环境中表现出更好的耐蚀性与更优异的摩擦适应性。     

Effect of sodium tartrate concentrations on morphology and characteristics of anodic oxide film on titanium alloy Ti–10V–2Fe–3Al

The effect of sodium tartrate concentrations on morphology and characteristics of ano-dic oxide film on titanium alloy was investigated. The alloy substrates were anodized in different concentration solutions of sodium tartrate with the addition of PTFE emulsion and their morphol-ogy and characteristics were analyzed. The anodic oxide film presented a uniform petaloid drums and micro-cracks morphology. Additionally, micro-cracks dramatically swelled with the increase of the tartrate concentrations. The thickness of the anodic oxide film increased with the concentra-tions until the concentration reached 15 g/L. The results of Raman analysis illustrate that all sam-ples have similarity in the crystal structure, consisting of mainly amorphous TiO2, some anatase TiO2 and a small amount of rutile TiO2. And the ratios of anatase TiO2 and rutile TiO2 increase with the concentrations until it reaches 15 g/L. Furthermore, the intensity of the peaks increases with enhanced concentrations until the concentration reaches 15 g/L. The corrosion resistance of the anodic oxide film is increased by the sodium tartrate with higher concentrations before 15 g/L. The coefficient of friction of the anodic oxide film reduces with the concentrations until the concentration reaches 15 g/L, then the coefficient of friction of the anodic oxide film increases with the concentrations.     

泡沫铝合金镀镍工艺研究

本文研究了在高硅铸铝制备的泡沫铝合金样品上镀镍工艺，提出了一种确定泡沫铝合金表面积的方法。讨论了主盐、还原剂、络合剂、缓冲剂等配方主要成份和ｐＨ 值、温度等工艺条件对化学镀镍的沉积速度和镀层质量的影响，优化了前处理方法，从而得到了适合于泡沫铝合金的镀镍工艺。     

机械镀锌锡铝合金工艺研究

研究了机械镀锌锡铝合金工艺及性能。结果表明;机械镀锌合金的抗性优于电镀锌层,镀层与基体结合力良好,镀覆工艺不会使基材产生氢脆。     

SiC/Al复合丝的耐蚀性和高温稳定性研究

本研究结果表明,SiC/L_6和SiC/LF_6复合丝在真空中加热至600℃和在空气中400℃暴露144小时,以及在蒸馏水和5%NaCl水溶液中浸泡15天后,其强度保留率大于87%,证明SiC/Al复合丝具有良好的耐蚀性和高温稳定性,用气相层析仪和发射光谱分析了腐蚀气体、溶液和白色沉淀,初步确定其反应机理是电化学腐蚀。与C/Al复合丝相比,SiC/Al腐蚀速度缓慢,纤维—基体界面损伤极小。     

研究原子氧对空间材料效应的氧等离子体试验装置

介绍我所研制成的一台评价原子氧对空间材料效应的高频放电氧等离子体试验装置的结构和性能.对Kapton试样的测试表明:用这种装置试验的结果与美国洛克希德公司装置的测试结果相当.其作用强度相当于200km高度轨道中原子氧作用强度的4倍以上.     

Preparation of bimodal grain size 7075 aviation aluminum alloys and their corrosion properties

The bimodal grain size metals show improved strength and ductility compared to traditional metals; however, their corrosion properties are unknown. In order to evaluate the corrosion properties of these metals, the bimodal grain size 7075 aviation aluminum alloys containing different ratios of coarse(100 μm in diameter) and fine(10 μm in diameter) grains were prepared by spark plasma sintering(SPS). The effects of grain size as well as the mixture degree of coarse and fine grains on general corrosion were estimated by immersion tests, electrochemical measurements and complementary techniques such as scanning electron microscope(SEM) and transmission electron microscope-energy disperse spectroscopy(TEM-EDS). The results show that, compared to fine grains, the coarse grains have a faster dissolution rate in acidic NaCl solution due to the bigger size,higher alloying elements content and larger area fraction of second phases in them. In coarse grains,the hydrogen ions have a faster reduction rate on cathodic second phases, therefore promoting the corrosion propagation. The mixture of coarse and fine grains also increases the electrochemical heterogeneity of alloys in micro-scale, and thus the increased mixture degree of these grains in metal matrix accelerates the corrosion rate of alloys in acidic NaCl solution.     

海洋环境下天线腐蚀机理与防腐技术研究

针对海洋环境下测控天线腐蚀引起的性能劣化和失效,在分析天线腐蚀机理、危害及影响因素的基础上,为设备的工程设计提供了采用耐腐蚀材料、隔断环境影响、表面防护技术、密封等防腐蚀措施的指导原则与设计方法,并首次探讨了海洋强腐蚀环境中,测控天线防腐蚀采用重装氟防腐涂料保护法和牺牲阳极的阴极保护法的可行性和实施细节。     

涡轮盘榫齿高温复合疲劳载荷、寿命由试验向外场的换算

针对某型发动机二级涡轮盘榫齿裂纹故障,进行了轻、重两种腐蚀状态的涡轮盘榫齿高温复合疲劳寿命试验。并由试验寿命推算出其外场使用寿命,为此,本文提出了复合疲劳载荷、寿命由试验向外场的双频比换算方法。换算结果可用于制定涡轮盘的腐蚀判废标准。     

滑轨防高温高速烧粘技术的应用研究及进展

对防高温高速燃气烧粘技术在工程应用中的环境条件，清洗、设计变更或配件更换、发动机改进、脂／干膜类润滑防护涂层、无机和有机防热／烧蚀材料、纳米功能涂层和技术的应用研究状况和进展进行了概述；介绍了冷／热模拟、发动机试车台模拟等防烧粘—腐蚀试验评估技术以及在这些技术领域取得的最新进展。