Competing effects of surface catalysis and ablation in hypersonic reentry aerothermodynamic environment

Under hypersonic flow conditions, the complicated gas-graphene interactions including surface catalysis and surface ablation would occur concurrently and intervene together with the thermodynamic response induced by spacecraft reentry. In this work, the competing effects of surface heterogeneous catalytic recombination and ablation characteristics at elevated temperatures are investigated using the Reactive Molecular Dynamics (RMD) simulation method. A Gas-Surface Interaction (GSI) model is established to simulate the collisions of hyper-enthalpy atomic oxygen on graphene films in the temperature range of 500–2500 K. A critical temperature T_c around 900 K is identified to distinguish the graphene responses into two parts: at T < T_c, the heterogeneous surface catalysis dominates, while the surface ablation plays a leading role at T > T_c. Contradicting to the traditional Arrhenius expression that the recombination coefficient increases with the increase of surface temperature, the value is found to be relatively uniform at T < T_c but declines sharply as the surface temperature increases further due to the competing ablation effect. The occurrence of surface ablation decreases the amounts of active sites on the graphene surface for oxygen adsorption, leading to reduced recombination coefficient from both Langmuir-Hinshelwood (L-H) and Eley-Rideal (E-R) mechanisms. It suggests that the traditional Computational Fluid Dynamics (CFD) simulation method, which relies on the Arrhenius-type catalysis model, would result in large discrepancies in predicting aerodynamic heat for carbon-based materials during reentry into strong aerodynamic thermal environment.     

批产航天器自测试系统设计

集成快检、存储快检与射前快检成为批产航天器亟待解决的问题。传统航天器综合测试模式存在测试效率低、测试改装部署繁琐、测试成本高、测试周期长和难以深入产品内部探查的问题,不能很好地适应批产研制与测发需求。针对该问题,从航天器可测试性与自测试设计出发,研究航天器自测试功能单元的设计方法、自测试通信交互模式、基于结构模型与行为模型的自测试诊断模型设计方法,设计了分层的自测试系统架构,通过总线快速调度自测试流程,提升快速检修能力,满足批产航天器快检需求。     

复合材料胶粘修复界面的载荷传递仿真优化

胶接修复工艺是飞机结构修理的重要工艺之一,为了研究胶黏工艺对修复效果的影响规律,探索最佳的工艺参数,本文建立胶粘修复的三维模型,利用ANSYS Workbench有限元软件对胶粘修复界面载荷传递进行分析,讨论补片材料、补片厚度、胶层剪切模量和胶层厚度对胶接修复的影响。仿真结果证明补片材料为硼/环氧树脂时,胶粘失效风险最小;补片较厚时,胶接修复效果好,但补片过厚会削弱胶接修复的效果;胶黏剂剪切模量越大越有助于损伤区域的修复,工程应用中建议选用剪切模量较高的胶黏剂;胶层较厚时会增大胶层发生缺陷的概率从而减弱修复效果,建议合理选取厚度较小的胶层。最后提出修复界面的表面处理、复合材料端部的溢胶以及倒角处理均有益于修复结构的载荷传递,缓和胶粘界面应力水平,降低胶层失效的风险。     

C/ C 复合材料CVD 过程中气相反应分析

以整体毡为预制体,丙烷为碳源,以沉积温度和气体滞留时间为考察变量,采用CVD 法制备了 C/ C 复合材料,并用偏光显微镜分析了热解碳结构,用气相色谱仪分析了尾气成分,并采用商用COMSOL 软件 分析了1 250 K 以上成碳过程的中间气相产物和气相反应路径。结果表明:试样上下表面热解碳均为光滑层 结构,高温下主要中间产物有H2、C2H2、C2H4、CH4,其中大分子结构、H2、C2H2 浓度,随着温度的升高而增大, C2H4 浓度随着温度的升高迅速减小,CH4 浓度略有减小;具有较低C—H 结合能而容易形成稳定的自由基的 大分子浓度随滞留时间延长而先增加后下降,具有高不饱和结构的大分子随滞留时间的延长浓度变化不大;热 解碳形成的复杂过程中C2H4 具有重要的作用。     

天然气氧化特性的实验与数值计算

在流动管反应器中对压力为0.1 MPa、温度范围为500~1 850 K、当量比分别为0.5、1.0与3.5的工况条件下天然气（90%甲烷/7%乙烷/3%丙烷，体积分数）的氧化过程进行了实验测试。同时，通过全局敏感性分析方法，构建了天然气的简化反应动力学机理（38组分和149反应），并对天然气的氧化特性进行了数值计算。结果表明：随着当量比增大，燃料发生氧化反应的起始温度与终止温度逐渐升高，CO生成与消耗完全对应的反应温度逐渐升高，NO的生成量逐渐降低。天然气的简化反应机理可以很好地预测天然气氧化过程中主要组分摩尔分数随温度变化的整体趋势；但是在C₃H₈、C₂H₂、NO、NO₂的起始反应温度或摩尔分数峰值的预测上与相应实验值存在差异。     

民用飞机驾驶舱人机界面评估方法研究

驾驶舱人机界面(Human Machine Interface,以下简称HMI)是连接飞行员和飞机的重要桥梁,人机界面的好坏直接关系到飞机的使用效率及运行安全。以民用飞机为例,分析研究了在飞机的设计过程中驾驶舱领域的人机界面设计评估相关问题和理论,并结合实际,建立了人机界面评价指标,提出了以适航规章为基础的驾驶舱人机界面评估方法。该方法有助于设计过程中的设计评估验证活动,可提高评估效率,促进设计更为合理的符合适航规章和使用需求的驾驶舱人机界面。     

真空条件下液滴闪蒸的非均温建模与分析

为深入揭示液滴在真空环境下的闪蒸机理，建立了真空闪蒸全过程、非均温的传热传质数学模型，获得了各时刻液滴温度场及半径，并能够追踪结冰阶段的相变界面位置.通过开展液滴闪蒸的实验研究，观察了相变前后液滴的形态变化，并对数值模型进行了验证.基于数学模型，研究了液滴初始半径、初始温度、真空舱压力和结冰过冷度对闪蒸过程的影响规律.结果表明:真空舱压力是影响闪蒸过程的主要因素，且会影响最终平衡温度；初始半径主要影响预冷和冻结时间，而初始温度和结冰过冷度主要只影响预冷时间.      

旋流流动对水冲压发动机性能影响

基于某药柱式水冲压发动机,建立粉末式水冲压发动机模型.利用Fluent软件模拟研究旋流流动对水冲压发动机流动与燃烧反应性能的影响.选择k ε双方程模型作为湍流模型,有限速率/涡耗散模型作为燃烧模型,基于密度隐式耦合求解进行计算.结果表明:添加旋流叶片并增大旋流角度,燃烧室最高燃烧温度、平均燃烧温度、出口速度和比冲均增大.研究证明添加旋流叶片对水冲压发动机流动与燃烧反应性能有很大改进,且旋流角度越大,效果越明显.      

化学法处理大批量导弹液体推进剂废液废水

通过对导弹液体推进剂废液废水的组成和化学性质的分析,确定废液废水的处理方法。根据化学反应和实验结果确定处理剂的用量,分别对氧化剂和燃料废液废水的处理工艺进行了设计,并提出了防止大气污染、安全快速的有效处理措施。     

Effects of chemical energy accommodation on nonequilibrium flow and heat transfer to a catalytic wall

The accurate prediction of the aeroheating performance of hypersonic vehicles requires more detailed modeling of the catalysis process, rather than merely employing a catalytic coefficient. In this paper, the theoretical modeling, as well as the direct simulation Monte Carlo method, is used to preliminarily study the incomplete chemical energy accommodation effects, that is, only a part of the potential energy released in the heterogenous recombination reaction is transferred to the surface, while the remaining is retained as the vibrational energy of the desorbed molecule. An integrated model is proposed to describe the contribution of each energy mode in the rarefied nonequilibrium heat and mass transfer process. Based on the model and several Damköhler numbers, an analytical formula is derived, and is also shown to compare well with the numerical results. On account of the incomplete accommodations of the chemical and vibrational energy on the wall, a variation up to 20% is observed in predicting the stagnation point heat flux under typical nonequilibrium flow conditions. This study could enrich our understanding of the nonequilibrium heat transfer phenomenon and also shows a potential practical value.