高效湿法缠绕用环氧树脂配方及其复合材料性能

针对高质固体火箭发动机壳体高效的生产要求对不同官能度环氧树脂复配体系的工艺性进行研究,重点开展了多官能团环氧树脂复配体系配方设计及力学性能研究,分别采用DSC(差示扫描分析)、黏度测试进行固化特征温度、固化反应动力学及工艺适用期研究,并最终制备单向层合板及NOL(the Naval Ordnance Laboratory)环进行复合材料性能的测试分析。研究结果表明:三官能度复配的环氧树脂能满足高效湿法缠绕要求。当三官能度的TDE-85质量分数为25%时,综合性能达到最优,适用期仅为120 min,拉伸强度为973 MPa,弯曲强度为115 MPa,玻璃化转变温度高达466 K,较最低值分别提高363%、159%、258%。该树脂体系与纤维匹配性好,复合材料性能优良,NOL环拉伸强度与层间剪切强度分别为256 GPa、744 MPa,纤维强度利用率达766%,适用于固体火箭发动机湿法缠绕成形。     

不同酚醛树脂对芳纶纸蜂窝性能的影响

为研究酚醛树脂对芳纶纸蜂窝性能的影响,本文采用两种不同的酚醛树脂制备芳纶纸蜂窝芯材,对所制备蜂窝芯材的压缩性能和剪切性能进行测试,同时结合蜂窝端面树脂分布观察、树脂与芳纶纸接触角测量等方法,分析了两种树脂所制备蜂窝芯材性能出现差异的原因,结果表明：树脂中溶剂水的挥发速度、树脂与芳纶纸之间的表面张力会影响树脂在蜂窝壁上的树脂分布;蜂窝芯材树脂含量相同时,其节点两侧的树脂胶柱有利于提高蜂窝芯材压缩强度,但树脂堆积在节点后会降低蜂窝壁厚,造成蜂窝的剪切强度和模量下降。     

空间三轴激光陀螺现状与展望

空间三轴激光陀螺作为激光陀螺技术集成创新的典型代表,已充分展现出优越的综合性能。为全面了解和掌握空间三轴激光陀螺技术发展现状,本文梳理了空间三轴激光陀螺原理与组成、主要特点、关键技术和研究历程,分析了国外主要研究机构、典型产品型谱及应用现状,从中可见空间三轴激光陀螺在国外已经非常成熟和广泛应用。针对国内发展现状和存在的差距,提出了后续发展建议,为我国激光陀螺技术发展及产业化提供了参考。     

Controlling factors of Region 2 field-aligned current and its relationship to the ring current: Model results

One essential component of magnetosphere and ionosphere coupling is the closure of the ring current through Region 2 field-aligned current (FAC). Using the Comprehensive Ring Current Model (CRCM), which includes magnetosphere and ionosphere coupling by solving the kinetic equation of ring current particles and the closure of the electric currents between the two regions, we have investigated the effects of high latitude potential, ionospheric conductivity, plasma sheet density and different magnetic field models on the development of Region 2 field-aligned currents, and the relationship between R2 FACs and the ring current. It is shown that an increase in high latitude potential, ionospheric conductivity or plasma sheet density generally results in an increase in Region 2 FACs’ intensity, but R2 FACs display different local time and latitudinal distributions for changes in each parameter due to the different mechanisms involved. Our simulation results show that the magnetic field configuration of the inner magnetosphere is also an important factor in the development of Region 2 field-aligned current. More numerical experiments and observational results are needed in further our understanding of the complex relationship of the two current systems.     

新型环氧树脂潜伏性促进剂的合成、表征及性能研究

合成了新型环氧树脂潜伏性促进剂三(乙酰乙酸十八酯)铝,采用DSC,FT-IR,H-NMR、元素分析分别对其热分解机理、化学结构、物质纯度进行了表征.研究了以环氧ZH92-21∶双酚S∶三(乙酰乙酸十八酯)铝=l00∶3∶0.5为配比的树脂体系的固化制度、潜伏性和力学性能,树脂体系的表观粘度在室温储藏7个月后基本没有变化,相分离是其具有优异潜伏性的主要原因.     

Leakage performance of floating ring seal in cold/hot state for aero-engine

Rotating experimental investigations were carried out to study the oil sealing capability of two different floating ring seals in cold/hot state for aero-engine. High-speed Floating Ring Seal(HFRS) is a seal with the inner diameter of 83.72 mm and maximum speed of 38000 r/min, and Low-speed Floating Ring Seal(LFRS) is another seal with the inner diameter of 40.01 mm and maximum speed of 18000 r/min. In hot state, sealing air with the temperature of 371 K and oil with the temperature of 343 K was employed to model the working conditions of an aero-engine. Comparisons between floating ring seal and labyrinth seal were done to inspect the leakage performance.More attention was paid to the critical pressure ratio where the oil leakage began. Results show that the critical pressure ratio in cold state is obviously larger than that in hot state for both seals. An underlying sealing mechanism for floating ring seal is clarified by the fluid film, which closely associates with the dimensionless parameter of clearance over rotating diameter(2 c/Dr). Another fantastic phenomenon is that the leakage coefficient in hot state, not the leakage magnitude, is unexpectedly larger than that in cold state. Overall, the leakage performance of the floating ring seal is better than the labyrinth seal.     

Storage life of silicone rubber sealing ring used in solid rocket motor

It is urgent to carry out detailed research on storage performance of rubber sealing ring to get the criterion for its storage life. This paper acquires material ageing regularity by theoretical analysis and experimental confirmation. On this condition, failure mode and failure criterion of typical sealing structure is studied, and the failure mechanism is found. Thus by analyzing the stress distribution, the relationship between ageing state and sealing condition is established. Rationalization proposal is put forward and storage life of sealing ring is evaluated. The research mentionedabove has special reference to the design of sealing structures and can provide reference for prolonging their service life.     

轻质隔热纳米孔结构耐烧蚀酚醛材料

在一定温度下,通过改性剂组分与热固性钡酚醛树脂之间热共聚反应,制备了改性酚醛树脂。采
用模压工艺制备出具有目标尺寸和形状的改性酚醛树脂固化物,对该样品分别进行了400 和700℃的炭化处
理,得到了相应的酚醛炭化样品,并测试其密度、失重率、收缩率等特征参数。研究改性剂用量对碳化物特征参
数和性能的影响,如密度、失重率形貌、比表面积、隔热性能、压缩强度等。SEM 研究表明,700℃炭化后样品形
成了“珊瑚状”碳结构,形成了30 ~150 nm 纳米孔。比表面积测试(BET)结果表明其比表面积可达464 m2 / g。
隔热性能与力学性能的测试结果表明,相对于未改性酚醛树脂碳化物,改性酚醛碳化物的热导率降低了
45． 57%,并且保持了较好的压缩强度。     

环氧树脂基形状记忆复合材料的制备与性能

以自制的形状记忆环氧树脂为基体,CCF300级碳纤维U-3160织物为增强材料,采用真空袋成型工艺制备形状记忆复合材料,分析碳纤维含量对复合材料的形状记忆性能的影响。结果表明,当碳纤维含量为0%~50%时,随着增强体碳纤维含量的增加,复合材料的形状固定率由98%降至91%,形状回复率也由98%降至91%。在有限次的循环实验中,循环次数对形状固定率和形状回复率没有明显的影响。     

中介机匣典型故障排除及深度修理

航空发动机中介机匣组件因各种故障而需修理或导致报废的现象时有发生。针对发动机中介机匣分流环裂纹掉块、上部衬套磨损松动、弹性环磨损、同心度检测不合格等故障进行分析研究,提出解决措施,制定满足发动机使用要求的合理技术标准和修理方法。在修理技术方法中,采用挖补补焊方法解决分流环裂纹掉块故障;采用极坐标定位与专用模板衬套相结合的方法提高新品衬套加工精度以解决上部衬套更换新品后装配准确性难题;采用装配过盈销钉和扩口工艺以保证零件的堵孔质量等。结果表明:这些修理措施提高了中介机匣零部件的利用率,延长了其使用寿命,降低了发动机修理成本。