Synthesis,chemistry and photochemistry of cyanobutadiyne (HCCCCCN)

Cyanobutadiyne has been synthesized starting from the mono or bistributylstannyl derivative of 1,3-butadiyne and p-toluenesulfonyl cyanide. The UV spectrum of HC₅N and the ¹³C NMR spectrum of the deuterocyanobutadiyne DC₅N have been recorded for the first time. Cyanobutadiyne has been detected in the photolysis of mixtures of gases observed on Titan. Its formation starting from cyanoacetylene and acetylene also occurs in the presence of huge amounts of dinitrogen, the major constituent of the Titan’s atmosphere. The application of these findings to the atmosphere of Titan is discussed. The chemistry and photochemistry of cyanobutadiyne have been investigated. A photoadduct has been observed in the photolysis of cyanoacetylene and ethanethiol and, a univocal synthesis of this compound was performed by a nucleophilic addition reaction.     

XANES analysis of organic residues produced from the UV irradiation of astrophysical ice analogs

Organic residues formed in the laboratory from the ultraviolet (UV) photo-irradiation or ion bombardment of astrophysical ice analogs have been extensively studied for the last 15 years with a broad suite of techniques, including infrared (IR) and UV spectroscopies, as well as mass spectrometry. Analyses of these materials show that they consist of complex mixtures of organic compounds stable at room temperature, mostly soluble, that have not been fully characterized. However, the hydrolysis products of these residues have been partly identified using chromatography techniques, which indicate that they contain molecular precursors of prebiotic interest such as amino acids, nitrile-bearing compounds, and amphiphilic compounds. In this study, we present the first X-ray absorption near-edge structure (XANES) spectroscopy measurements of three organic residues made from the UV irradiation of ices having different starting compositions. XANES spectra confirm the presence of different chemical functions in these residues, and indicate that they are rich in nitrogen- and oxygen-bearing species. These data can be compared with XANES measurements of extraterrestrial materials. Finally, this study also shows how soft X rays can alter the chemical composition of samples.     

Interpretation of the SOHO/UVCS observations of two CME-driven shocks

We report on the analysis of two fast CME-driven shocks observed with the UltraViolet Coronagraph Spectrometer (UVCS) on board the Solar and Heliospheric Observatory (SOHO). The first event, detected on 2002 March 22 at 4.1 R_⊙ with the UVCS slit placed in correspondence with the flank of the expanding CME surface, represents the highest UV detection of a shock obtained so far with the UVCS instrument in the corona. The second one, detected on 2002 July 23 at 1.6 R_⊙ with the UVCS slit placed in correspondence with the front of the expanding CME surface, shows an anomalous deficiency of ion heating with respect to what observed in previous CME/shocks observed by UVCS, possibly reflecting the effect of different coronal plasma conditions over the solar cycle. From the two different sets of observations we derived an estimate for the shock compression ratio X, which turns out to be X = 2.4 ± 0.2 and X = 2.2 ± 0.1, respectively, for the first and second event. Comparison between the two events provides complementary perspectives on the dynamical evolution of CME-driven shocks.     

大功率LED混光照明恒流驱动电路的设计

在分析了大功率LED混光照明中LED光源特性的基础上,提出了三色LED恒流驱动电路的设计方案。驱动电路分别采用升压和降压拓扑结构,利用具有PWM实时调光功能的RT8452作为驱动控制芯片,通过改变外接PWM占空比即可调节LED亮度。实验证明,此驱动电路工作可靠,效率高,实现简单。     

Recent ozone investigations over Bulgaria by remote sensing: Ground-based and satellite data

This presentation deals with the recent investigations of the dynamics of the total ozone content (TOC) and of the lower troposphere ozone over Bulgaria, South-Eastern Europe.     

Working Group 4 Report: Composition and Elemental Abundance Variations in the Solar Atmosphere and Solar Wind

This paper contains a summary of the topics treated in the working group on abundance variations in the solar atmosphere and in the solar wind. The FIP bias (overabundance of particles with low First Ionization Potentials over photospheric abundances) in coronal holes and coronal hole associated solar wind amounts to values between 1 and 2. The FIP bias in the slow solar wind is typically a factor 4, consistent with optical observations in streamers. In order to distinguish between different theoretical models which make an attempt to explain the FIP bias, some observable parameters must be provided. Unfortunately, many models are deficient in this respect. In addition to FIP fractionation, gravitational settling of heavy elements has been found in the core of long lived streamers. The so-called electron 'freeze in' temperatures derived from in situ observed ionization states of minor ions in the fast wind are significantly higher than the electron temperatures derived from diagnostic line ratios observed in polar coronal holes. The distinction between conditions in plumes and interplume lanes needs to be further investigated. The 'freeze in' temperatures for the slow solar wind are consistent with the electron temperatures derived for streamers. This revised version was published online in June 2006 with corrections to the Cover Date.     

Constraints on Coronal Outflow Velocities Derived from UVCS Doppler Dimming Measurements and in-Situ Charge State Data

We constrain coronal outflow velocity solutions, resolved along the line-of-sight, by using Doppler dimming models of H I Lyman alpha and O VI 1032/1037 Å emissivities obtained with data from the Ultraviolet Coronagraph Spectrometer (UVCS) on SOHO. The local emissivities, from heliocentric heights of 1.5 to 3.0 solar radii, were determined from 3-D reconstructions of line-of-sight intensities obtained during the first Whole Sun Month Campaign (10 August to 8 September 1996). The models use electron densities derived from polarized brightness measurements made with the visible light coronagraphs on UVCS and LASCO, supplemented with data from Mark III at NCAR/MLSO. Electron temperature profiles are derived from 'freezing-in' temperatures obtained from an analysis of charge state data from SWICS/Ulysses. The work concentrates on neutral hydrogen outflow velocities which depend on modeling the absolute coronal H I Lyα emissivities. We use an iterative method to determine the neutral hydrogen outflow velocity with consistent values for the electron temperatures derived from a freezing-in model.     

基于绿色光源LED的开关型恒流驱动电路设计

针对LED的特点提出开关型恒流驱动电路,通过电流与电压负反馈技术的采用,将LED的输入电流控制在一个稳定的电流数值下,同时使电路防止过电压的能力提高,可靠性大为增强.     

用Ce~(3+):YVO_4晶体荧光粉与蓝光LED制造自然白光LED

本文报导了通过结合自行制备的掺铈钒酸钇晶体(Ce3 :YVO4)荧光粉与InGaN／GaN蓝光发光二极管(LED)结合而得的白光发光二极管(W-LED)。在室温、正向电压3.5V、正向电流20mA时W-LED的CIE色坐标为(0．32,0．37),接近纯白色(0．33,0．33)。     

Observation of Transition Region Fine Structures with Soho/Sumer

We present a preliminary analysis of two quiet Sun transition region areas observed with the SOHO/SUMER spectrometer, using lines from oxygen, nitrogen and silicon. The average quiet Sun physical parameters are studied as a function of line intensity. Systematic variations of line position and width with increasing intensity are found. A large number of small-scale active points have been observed, and preliminary analysis of the physical properties and dynamics of these active features is presented. A jet-like structure, found in an active point, is also investigated and its velocity along the line of sight determined. This revised version was published online in June 2006 with corrections to the Cover Date.