纺丝工艺参数对初生PBO纤维性能的影响

采用干喷-湿法液晶纺丝技术制得初生PBO纤维,对纺丝原液浓度、纺丝温度、纺丝压力、拉伸比等几个主要工艺参数的选择进行了讨论,分析了这些工艺参数对初生PBO纤维性能的影响。研究结果表明,随着聚合物浓度的升高,PBO的分子量增大,制得纤维的拉伸强度增大;最佳纺丝温度为160~180℃;纺丝压力提高,有利于纺丝;拉伸比增大,有利于提高纤维的性能。     

超低温处理对T700碳纤维/环氧复合材料拉—压疲劳性能的影响

对T700碳纤维/环氧复合材料在超低温处理前后的拉—压疲劳性能进行了的研究。采用真空袋—热压罐成型工艺,制备了T700碳纤维/环氧复合材料单向板,在液氮中对试样进行超低温浸泡和超低温/室温循环处理,利用光学显微镜观测了试样在超低温处理过程中产生的微裂纹情况,并测试了超低温处理后试样的静强度和拉—压疲劳1000次、10000次及130000次后的剩余强度。对T700碳纤维/环氧复合材料超低温损伤机理进行了分析,并讨论了超低温处理和拉—压疲劳对复合材料剩余强度的影响。结果表明,超低温处理和拉—压疲劳处理都会使试样产生微裂纹,并引起试样内的残余应力释放和试样的剩余强度降低;经历不同的超低温处理之后,试样的剩余强度达到最高值时所对应的拉—压疲劳次数不同;随着超低温处理和拉—压疲劳的作用,试样的剩余强度会经历先升高—再降低的过程。     

Alpha Particle X-Ray Spectrometer (APXS) on-board Chandrayaan-2 rover

Alpha Particle X-ray Spectrometer (APXS) payload configuration for Chandrayaan-2 rover has been completed recently and fabrication of mechanical assembly, PCB layout design and fabrication are in progress. Here we present the design and performance evaluation of various subsystems developed for APXS payload. The low energy threshold of <1 keV and the energy resolution of ∼150 eV at 5.9 keV, for the Silicon Drift Detector (SDD), as measured from the developed APXS electronics is comparable to the standard spectrometers available off-the-shelf. We have also carried out experiments for measuring fluorescent X-ray spectrum from various standard samples from the USGS catalog irradiated by the laboratory X-ray source ²⁴¹Am with 1 mCi activity. It is shown that intensities of various characteristic X-ray lines are well correlated with the respective elemental concentrations.     

Random copolymer membrane coated PBO fibers with significantly improved interfacial adhesion for PBO fibers/cyanate ester composites

Poly(p-phenylene-2,6-benzobisoxazole) (PBO) fibers possess excellent dielectric, mechanical properties and heat resistance. However, the surface of PBO fibers is smooth and highly chemical inert, resulting in poor interfacial compatibility to polymer matrix, which severely limits its wider application in high-performance fiber-reinforced resin matrix composites. In this work, random copolymers (P(S-co-BCB-co-MMA)) containing benzocyclobutene in the side-chain were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, which were then utilized to form dense random copolymer membrane on the surface of PBO fibers by thermally cross-linking at 250 °C (PBO@P fibers). Four kinds of synthesized P(S-co-BCB-co-MMA) with different number-average molar mass (M_n) were well controlled and possessed narrow dispersity. When the M_n was 32300, the surface roughness of PBO@P fibers was increased from 11 nm (PBO fibers) to 39 nm. In addition, PBO@P fibers presented the optimal interfacial compatibility with bisphenol A cyanate (BADCy) resins. And the single fiber pull-out strength of PBO@P fibers/BADCy micro-composites was 4.5 MPa, increasing by 45.2% in comparison with that of PBO fibers/BADCy micro-composites (3.1 MPa). Meantime, PBO@P fibers still retained excellent tensile strength (about 5.1 GPa). Overall, this work illustrates a simple and efficient surface functionalization method, which would provide a strong theoretical basis and technical support for controlling the surface structure & chemistry of inert substrates.     

空芯光子晶体光纤熔接技术研究

空芯光子晶体光纤(HC-PCF)因其利用纤芯的空气导光而具有高损伤阈值、低损耗、低色散、低非线性等优点。此外,HC-PCF纤芯中空气的折射率温度系数、Verdet系数、Kerr系数远小于石英,在光纤陀螺中有独特的优势。但是在向实际应用迈进的过程中,必须要解决HC-PCF与普通单模光纤以及自身简便、低损耗的熔接问题。基于热致扩芯技术和过渡光纤两种模场匹配方法,研究了HC-PCF和普通单模光纤之间的熔接问题,将两者的熔接损耗由直接熔接的1.4dB降至0.73dB。此外,研究了HC-PCF与其自身的熔接,通过两步放电熔接法,得到高强度低损耗的熔点,熔接损耗为0.52dB。     

光栅光纤组合探头在油料液位检测中的应用

提出了一种利用光栅光纤组合探头技术对航空油料液位进行检测的方法。该方法是将钢带浮子式液位计检测到了液位信息转换为光栅位移量,通过光纤探头探测,由光缆远距离传送至中央控制室,利用微处理机对信号进行实时处理,实现对液位的自动采集和监测,具有体积小、重量轻、精度高、可靠性好、本安防爆等优点。     

面向宇航应用光传输微系统集成技术

为了满足宇航系统对高速、宽带数据和图像传输产品小体积、轻质化的需求，研究光传输高速高密度集成技术。基板采用带状差分线设计和叠层组装工艺，提高集成密度、缩小体积提升了系统组装的空间，并通过建模仿真设计分析高速信号完整性；将光器件设计在外壳底板上，实现高效散热结构设计，同时提高了光器件使用可靠性；采用混合集成微组装工艺，硅转接基板实现芯片级三维立体集成，采用二次封装技术解决了光纤高效耦合与气密共实现的难题。微系统模块体积≤27 mm×24 mm×5 mm，气密封装漏率≤5×10–9Pa·m3/s(He)。     

Review on monolayer CBN superabrasive wheels for grinding metallic materials

A state-of-the-art review on monolayer electroplated and brazed cubic boron nitride (CBN) superabrasive wheels for grinding metallic materials has been provided in this article. The fabrication techniques and mechanisms of the monolayer CBN wheels are discussed. Grain distri-bution, wheel dressing, wear behavior, and wheel performance are analyzed in detail. Sample appli-cations of monolayer CBN wheel for grinding steels, titanium alloys, and nickel-based superalloys are also provided. Finally, this article highlights opportunities for further investigation of mono-layer CBN grinding wheels.     

Metrology on-board PROBA-3: The shadow position sensors subsystem

PROBA-3 is an ESA mission aimed at the demonstration of formation flying performance of two satellites that will form a giant coronagraph in space. The first spacecraft will host a telescope imaging the solar corona in visible light, while the second, the external occulter, will produce an artificial eclipse. This instrument is named ASPIICS (Association of Spacecraft for Polarimetric and Imaging Investigation of the Corona of the Sun). To accomplish the payload's scientific tasks, PROBA-3 will ensure sub-millimeter reciprocal positioning of its two satellites using closed-loop on-board metrology. Several metrology systems will be used and the Shadow Position Sensor (SPS) subsystem senses the penumbra around the instrument aperture and returns the 3-D displacement of the coronagraph satellite, with respect to its nominal position, by running a dedicated algorithm. In this paper, we describe how the SPS works and the choices made to accomplish the mission objectives.     

纤维/树脂浸润测试仪的研制与应用

针对复合材料成型工艺的特点,依据毛细原理,研制了浸润性能测试仪.该测试仪包括浸润质量测试系统与温度控制系统,能够定量测试在较宽的温度范围内发生浸润的速率和浸润程度.对该测试仪的准确性与稳定性进行了校准与标定,并运用该仪器研究了纤维种类、树脂粘度和纤维体积含量对树脂/纤维浸润性能的影响规律.研究结果表明该设备为研究各类复合材料中增强材料与基体间的浸润性能提供了方便的测试手段,对指导复合材料制备工艺具有较高的参考价值.