3,6-二硝基吡唑[4,3-c]并吡唑(DNPP)有机双胺盐的合成及热性能

以有机胺和自制的3,6-二硝基吡唑[4,3-c]并吡唑(DNPP)为原料,合成了DNPP的肼盐(DH-DNPP)、胍盐(DGDNPP)、三氨基胍盐(DTAG-DNPP)、脒基脲盐(DGU-DNPP)、4-氨基-1,2,4-三唑盐(DAT-DNPP)、氨基脲盐(DS-DNPP)、缩二胍盐(DBG-DNPP)、氨基胍盐(DAG-DNPP)、二氨基胍盐(DBAG-DNPP)、二氨基呋咱盐(DAF-DNPP)等10种有机双胺盐化合物,收率分别为95.7%、58.5%、56.9%、80.5%、59.5%、71.1%、47.0%、81.6%、86.9%、69.7%;采用红外光谱、核磁共振、质谱及元素分析等方法,表征了目标化合物的结构;利用差示扫描量热(DSC)、热重(TG)等热分析手段,研究了10种化合物的热性能。结果表明,此类化合物具有较好的热稳定性。     

超燃发动机燃烧室三维化学反应流场的数值模拟

采用ＬＵ隐式方法强耦合求解有限体积法离散的完全N-S方程及组份方程,数值模拟超燃发动机燃烧室内的化学反应流场。计算中采用了AUSM通量分裂格式,两方程及八方程的化学反应模型。计算得到了流场的结构与组份分布,并对两种化学反应模型的结果进行了比较与分析。     

高分子纳米复合材料研究进展(II)--高分子纳米复合材料的结构和性能

综述了高分子纳米复合材料的发展研究现状,包括纳米粒子的结构和性能,及其在聚合物基体中聚集形成高次结构的特征和协同性能     

纤维吸水对F-12环氧复合材料性能影响

采用ＮＯＬ环拉伸与剪切实验,研究了纤维吸水对Ｆ－１２／胺环氧体系性能影响,结果表明,纤维吸水后,ＮＯＬ环拉伸强度和模量分别下降了７．２％和２．５％,而剪切强度提高了３６．４％,ＳＥＭ照片显示,干态纤维复合材料和湿态纤维材料破坏模式有一定的差别。     

高频基片复合材料的研究进展

介绍了电路组装技术对基片的性能要求、性能影响因素及基片设计原则，评述了高频基片复合材料的发展现状，并提出未来研究工作的重点。     

复合固体推进剂燃烧性能模拟计算的神经网络方法

在总结已有燃烧模型的基础上，重点考虑压强、氧化剂的重均粒径、氧化剂的质量浓度三种主要影响因素，提出了一种基于误差反传（ＢＰ）神经网络的复合固体推进剂燃烧性能模拟计算方法，计算结果和实验值吻合较好，这为推进剂配方的计算机辅助设计提供了一种新方法。     

聚合物基电子封装复合材料研究进展

综述了聚合物基电子封装材料的基本性能要求并分析了其影响因素,阐述了聚合物基电子封装材料的复合原理和结构设计思想,展望了聚合物基电子封装材料的发展趋势。     

Exo-Astrobiological Aspects of Europa and Titan: From Observations to Speculations

By extrapolating what we know on the origins of life on Earth, and in particular on the chemical processes which gave rise to the first living system, Europa and Titan appear as two major targets for studies of exo/astrobiology in the outer solar system. With the likely presence of water oceans relatively close to its surface, coupled to possible sources of organics, the emergence and sustaining of life on Europa seems possible. On Titan, it cannot be ruled out. But the main exobiological interest of the largest satellite of Saturn is the presence of a complex organic chemistry which shows many similarities with the prebiotic chemistry which allowed the emergence of life on Earth.     

自愈合机敏复合材料综述

综述了中空纤维释放黏结剂的裂纹愈合及近期开发的机敏裂纹自愈合复合材料的研究进展。对后者微胶囊促使的机敏裂纹自愈合进行了详尽的阐述。其中包括愈合剂和催化剂的结构、微胶囊的形成和外表连接催化剂、愈合剂系统原位聚合反应、纯环氧树脂基体和复合材料中的裂纹自愈合、愈合效率及愈合复合材料微观表征等方面。一个典型的双相自愈合系统是包含于微胶囊中的二聚环戊二烯（DCPD），通过埋于环氧基体中的钌络合物催化剂进行开环转位聚合反应（ROMP），形成新的聚合物来愈合裂纹。在纯环氧树脂基体中，上述自愈合系统在室温下的愈合效率可高达90％，而在碳纤维复合材料中室温下的愈合效率大致是45％，在80℃可提高到80％。降冰片烯（Norbomene）及其衍生物具有同以上系统相似的自愈合功能。三聚呋喃和四聚马来酰亚胺可在无催化剂作用下，进行热可逆的、无终止的交联聚合反应，自动愈合裂纹。同时，对以上三种自愈合剂系统及复合材料的特点进行了比较。     

Effect of severe geomagnetic storm conditions on atomic oxygen greenline dayglow emission in mesosphere

Severe geomagnetic storms and their effects on the 557.7 nm dayglow emission are studied in mesosphere. This study is primarily based on photochemical model with the necessary input obtained from a combination of experimental observations and empirical models. The model results are presented for a low latitude station Tirunelveli (8.7°N, 77.8°E). The volume emission rates are calculated using MSISE-90 and NRLMSISE-00 neutral atmospheric models. A comparison is made between the results obtained from these two models. A positive correlation amongst volume emission rate (VER), O, O₂ number densities and Dst index has been found. The present results indicate that the variation in emission rate is more for MSISE-90 than in NRLMSISE-00 model. The maximum depletion in the VER of greenline dayglow emission is found to be about 30% at 96 km during the main phase of the one of the geomagnetic storms investigated in the case of MSISE-90 (which is strongest with Dst index −216 nT). The O₂ density decreases about 22% at 96 km during the main phase of the same geomagnetic storm.The NRLSMSISE-00 model does not show any appreciable change in the number density of O during any of the two events. The present study also shows that the altitude of peak emission rate is unaffected by the geomagnetic storms. The effect of geomagnetic storm on the greenline nightglow emission has also been studied. It is found that almost no correlation can be established between the Dst index and variations in the volume emission rates using the NRLMSISE-00 neutral model atmosphere. However, a positive correlation is found in the case of MSISE-90 and the maximum depletion in the case of nightglow is about 40% for one of the storms. The present study shows that there are significant differences between the results obtained using MSISE-90 and NRLMSISE-00.