高性能M40J/BADCy复合材料的研究

对E51环氧树脂改性双酚A型氰酸酯(BADCy)体系的力学性能及热性能进行了研究,发现当E51环氧树脂的质量含量为5%时,改性体系的弯曲强度和冲击强度分别由原来的95.6MPa和9.24kJ/m²提高到了117.8MPa和12.6kJ/m²,而热变形温度仅下降8℃。以该改性体系为基体制作的M40J复合材料,其弯曲强度、模量和剪切强度分别高达:1270MPa,172GPa,68 9MPa。消泡剂BYK141能提高M40J/BADCy复合材料的力学性能,层间剪切强度可提高到77.1MPa。M40J/BADCy复合材料还具有良好的耐环境能力,是一种理想的航空航天结构材料。     

Effect of condensation agents and minerals for oligopeptide formation under mild and hydrothermal conditions in related to chemical evolution of proteins

The role of condensation agents and minerals for oligopeptide formation was inspected to see whether minerals possess catalytic activity under mild and hydrothermal conditions. Under mild conditions, oligopeptide formation from negatively charged amino acids (Asp and Glu) using different minerals and the elongation of alanine oligopeptides ((Ala)₂–(Ala)₅) were attempted using apatite minerals. Oligo(Asp) up to 10 amino acid units from Asp were observed in the presence of 1-ethyl-3-(3-dimethylaminopropyl carbodiimide (EDC). Notable influence of minerals was not detected for the oligo(Asp) formation. Oligo(Asp) was gradually degraded by the further incubation in the presence of EDC in both the absence and presence of minerals. The formation of oligo(Glu) was less efficient in the presence of carbonyldiimidazole. The elongation from (Ala)₃, (Ala)₄, and (Ala)₅ and the formation of diketopiperazine from (Ala)₂ proceeded immediately in the presence of EDC in the meantime of the sample preparations. In addition, it was unexpected that the disappearance of the products and the reformation of the reactants occurred by the further incubation for 24 h; for instance, (Ala)₅ decreased but (Ala)₄ increased with increasing the reaction time in the reaction of (Ala)₄ with EDC. These facts suggest that the activation of the reactant amino acids or peptides immediately occurs. Under the simulated hydrothermal conditions, EDC did not enhance the formation of oligopeptides from Asp, Glu or Ala nor the spontaneous formation of (Ala)₅ from (Ala)₄.     

酸性铬兰k褪色指示反应动力学光度法测定微量铬

本文研究了在硫酸介质中，微量铬催化过硫酸钾氧化酸性铬兰K裉色的指示反应，确立了催化动力学测定铬（Ⅵ）的新方法。该法检出极限为7．79％10^-6g.L^-1，测定线性范围0－8．0μg／50mL Cr（Ⅵ），本法已用于电镀废水中铬（Ⅵ）的测定。     

高温树脂基复合材料在超声速导弹弹体上的应用

描述了超声速导弹弹体的热环境，高温树脂基复合材料基体候选树脂，重点介绍了双马来酰亚胺，聚酰亚胺树脂和氰酸酯的性能及最新进展，最后描述了高温树脂基复合材料在超声速度导弹弹体上的应用研究。     

氰酸酯／环氧树脂体系的研究

采用环氧树脂(E 51)与氰酸酯树脂共聚以改善氰酸酯树脂的韧性,研究了环氧树脂的加入量、后处理温度、湿热老化、紫外光老化等条件对改性后树脂体系的力学性能和介电性能的影响规律,采用扫描电子显微镜对断口形貌进行了分析。结果表明环氧树脂可以明显改善氰酸酯树脂的韧性,环氧树脂含量为30wt%的体系的冲击强度和弯曲强度分别比改性前提高了100%和50%。随环氧树脂用量的增加,改性树脂的冲击强度和弯曲强度增大,树脂表现为明显的韧性断裂;改性体系经200℃后处理2h的介电性能最佳,环氧树脂用量的增加、湿热老化和紫外光老化都使介电常数和介电损耗增加,但当环氧树脂用量低于30wt%时仍属于优异的介电材料。     

焦磷酸锰引发丙烯酸——丙烯酰胺——淀粉接枝共聚反应研究

以〔Mn(H2 P2 O7) 3〕3- 作为引发剂 ,引发丙烯酸、丙烯酰胺与淀粉接枝共聚反应 ,研究了引发剂浓度、单体浓度配比、反应时间、反应温度等因素对接枝共聚反应的影响 ,结果表明 :引发剂浓度为 2 .7× 10 - 3mol/L ,单体浓度配比 (丙烯酸 :丙烯酰胺 )为 1∶1,反应温度为 5 0℃左右 ,反应时间为 5h时 ,接枝效率较高     

壳聚糖硫酸盐的制备及其催化作用的研究

本文阐述利用虾蟹壳为原料制备壳聚糖硫酸盐，探索以其为催化剂的多相由化反应催化体系的影响因素。通过研究，得出催化剂的催化效能与壳聚糖的分子量和脱乙酞度的关系，以及壳聚糖硫酸盐为催化剂的酯化反应多相催化体系的应用范围和主要影响因素。     

T cell regulation in microgravity – The current knowledge from in vitro experiments conducted in space,parabolic flights and ground-based facilities

Dating back to the Apollo and Skylab missions, it has been reported that astronauts suffered from bacterial and viral infections during space flight or after returning to Earth. Blood analyses revealed strongly reduced capability of human lymphocytes to become active upon mitogenic stimulation. Since then, a large number of in vitro studies on human immune cells have been conducted in space, in parabolic flights, and in ground-based facilities. It became obvious that microgravity affects cell morphology and important cellular functions. Observed changes include cell proliferation, the cytoskeleton, signal transduction and gene expression. This review gives an overview of the current knowledge of T cell regulation under altered gravity conditions obtained by in vitro studies with special emphasis on the cell culture conditions used. We propose that future in vitro experiments should follow rigorous standardized cell culture conditions, which allows better comparison of the results obtained in different flight- and ground-based experiment platforms.     

聚[2,5-二羟基-1,4-苯撑吡啶并二咪唑]单体的合成优化及提纯研究

研究了液晶高分子聚[2,5-二羟基-1,4-苯撑吡啶并二咪唑](PIPD)的2个单体2,5-二羟基对苯二甲酸(DHTA)和2,3,5,6-四氨基吡啶(TAP)盐酸盐的制备与提纯,并通过对比实验确定出最优的合成与提纯路线.通过IR、~1H NMR、~(13)C NMR、HPLC、DSC和元素分析确定了产物为目的产物.     

盐酸清洗缓蚀剂的研究进展

本文介绍了我国九十年代盐酸酸洗缓蚀剂的研究现状。盐酸酸洗缓蚀剂研究的重点是开发新型的高效、低毒、低成本缓蚀剂，并充分利用工业生产的副产品进行深加工，或利用天然植物进行加工、改性制备缓蚀剂，扩展原材料的来源。