Synthesis of Iron-containing Carbon Microparticles from Deoiled Asphalt and Ferrocene

The deoiled asphalt as the carbon source and the ferrocene as the metal source and the catalyst precursor were chosen to synthesize iron-containing carbon microparticles through co-carbonization at the temperature of about 450℃ for 3 h. The resulting products were treated at 2 000 ℃ for 2 h. All samples were examined by high resolution transmission electron microscopy （HRTEM） and X-ray diffraction （XRD）. The results show that the iron particles in the heat-treated material are completely coated by carbon. In addition to the fully filled carbon microparticles as well as hollow carbon ones, also form carbon fibers with hollow centers. The formation mechanism of the as-prepared products was discussed briefly.     

Change of Electronic Structure and Magnetic Properties with MgO and Fe Thicknesses in Fe/MgO/Fe Magnetic Tunnel Junction

The effects of the thickness of MgO and Fe on the electronic structure and magnetic properties of Fe/MgO/Fe magnetic tunnel junction was studied using the first principle method. Two series of models with MgO of different thicknesses： Fe（3）MgO（t）Fe（3） （t-=1,3,5,7） and with Fe of varied thicknesses： Fe（t）MgO（3）Fe（t） （t=3,4,5,6,7） were established. Calculated results show that in all the models the magnetic moment of Fe increases at the Fe/MgO interface and surface as compared with that of the inner layers. The mag- netic moment of each Fe layer was found to be independent of MgO thicknesses, while the spin-polarization of Fe layer at the interface shows a slight change in function of the MgO thicknesses. The tunneling magnetoresistance （TMR） ratio estimated by the Julliere model has the same change tendency as the spin-polarization has, and the largest value is obtained at the MgO thickness of 5 atomic layers. When the Fe thickness increases, the spin-polarization of interface Fe layer follows up an increase with a decrease. The highest TMR value is achieved when the Fe thickness is of 4 atomic layers.     

以色列计划部署第4套铁穹火箭弹防御系统

日前，以色列宣布已作好在其北部港口城市海法部署第4套由拉法尔先进防务系统公司研发的铁穹火箭弹防御系统的准备，以保护其炼油厂及氨水池。     

天然水体中Fe和草酸根分布与水体净化的关系

采用电感耦合等离子体光谱仪(ICP)和UV-2100双光束紫外/可见分光光度计分析不同水体中溶解态铁和草酸根的分布,研究其与水体净化的关系.结果表明,河流、湖泊及雨水中普遍存在溶解态铁,雨水中的溶解态铁约0.6.0.8 X10-2mg/L,比湖泊水体小1个数量级,比赣江水体小2个数量级.研究的水体中都含有草酸根,其浓度范围为0.200.0.400ms/L.在光照条件和时间相同的情况下,水样中总铁浓度与草酸根浓度的比值[Fe]/[C2 O42-]与光照后水样CODcr减小量△C0Dcr具有相关性.[Fe]/[C2042-]较大,则△CODer也较大,反之,[Fe]/[C2042-]较小则△CODcr较小.     

铁（Ⅲ）—苯芴酮—Tritonx—100体系测定铬若美中的铁

本文研究了铁 (Ⅲ ) -苯芴酮—Tritonx -1 0 0体系测定铬若美中的微量铁。铁与苯芴酮的二元配合物的摩尔吸光系数值可达 6 4× 1 0 4 ·L·mol- 1·cm- 1,加入表面活性剂Tritonx -1 0 0后 ,铁与苯芴酮、Tritonx -1 0 0生成三元配合物 ,摩尔吸光系数值提高到 2 4× 1 0 5·L·mol- 1·cm- 1,Fe含量在 1 4 5～ 2 8μg/2 0ml范围内服从耳定律 ,回收率 97%～ 99% ,反应选择性好 ,用拟定的方法测定铬若美 (铬和镍合金 )中的微量铁 ,测试结果令人满意     

高锁螺栓干涉配合安装工艺参数对凸瘤的影响分析

 干涉配合螺栓连接是提高飞机结构疲劳寿命的一种有效方法,干涉安装中产生的凸瘤对结构强度极为不利。分析了凸瘤产生的原因,对M8钛合金高锁螺栓进行了静态压入试验,同时建立了有限元模型进行数值模拟,通过对比压入力和凸瘤大小,验证了有限元模型。对影响凸瘤产生的工艺参数进行了分析。有限元模拟结果表明:最佳干涉量为1.5%,顶铁中孔直径略小于螺栓2倍时产生的凸瘤较小,钉孔间摩擦因数须小于0.15,孔出口0.2×120°倒角可减小凸瘤和降低此处的应力集中效应。