The Gas Chromatograph Mass Spectrometer for the Huygens Probe

The Gas Chromatograph Mass Spectrometer (GCMS) on the Huygens Probe will measure the chemical composition of Titan's atmosphere from 170 km altitude (∼1 hPa) to the surface (∼1500 hPa) and determine the isotope ratios of the major gaseous constituents. The GCMS will also analyze gas samples from the Aerosol Collector Pyrolyser (ACP) and may be able to investigate the composition (including isotope ratios) of several candidate surface materials. The GCMS is a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns. The mass spectrometer employs five ion sources sequentially feeding the mass analyzer. Three ion sources serve as detectors for the GC columns and two are dedicated to direct atmosphere sampling and ACP gas sampling respectively. The instrument is also equipped with a chemical scrubber cell for noble gas analysis and a sample enrichment cell for selective measurement of high boiling point carbon containing constituents. The mass range is 2 to 141 Dalton and the nominal detection threshold is at a mixing ratio of 10^{− 8}. The data rate available from the Probe system is 885 bit/s. The weight of the instrument is 17.3 kg and the energy required for warm up and 150 minutes of operation is 110 Watt-hours. This revised version was published online in August 2006 with corrections to the Cover Date.     

Chemical composition measurements of the atmosphere of Jupiter with the Galileo Probe mass spectrometer.

The Galileo Probe entered the atmosphere of Jupiter on December 7, 1995. Measurements of the chemical and isotopic composition of the Jovian atmosphere were obtained by the mass spectrometer during the descent over the 0.5 to 21 bar pressure region over a time period of approximately 1 hour. The sampling was either of atmospheric gases directly introduced into the ion source of the mass spectrometer through capillary leaks or of gas, which had been chemically processed to enhance the sensitivity of the measurement to trace species or noble gases. The analysis of this data set continues to be refined based on supporting laboratory studies on an engineering unit. The mixing ratios of the major constituents of the atmosphere hydrogen and helium have been determined as well as mixing ratios or upper limits for several less abundant species including: methane, water, ammonia, ethane, ethylene, propane, hydrogen sulfide, neon, argon, krypton, and xenon. Analysis also suggests the presence of trace levels of other 3 and 4 carbon hydrocarbons, or carbon and nitrogen containing species, phosphine, hydrogen chloride, and of benzene. The data set also allows upper limits to be set for many species of interest which were not detected. Isotope ratios were measured for 3He/4He, D/H, 13C/12C, 20Ne/22Ne, 38Ar/36Ar and for isotopes of both Kr and Xe.     

In situ results on the variation of neutral atmospheric hydrogen at venus

The concentrations of neutral hydrogen within the atmosphere of Venus are investigated for the period 1979–1980. During this period, the planet made nearly three orbits about the Sun, so that nearly three complete diurnal cycles were observed from the Pioneer Venus Orbiter (PVO). Values of n(H) are derived from in-situ ion and neutral composition measurements from the Orbiter Ion Mass Spectrometer (OIMS) and the Orbiter Neutral Mass Spectrometer (ONMS) using a charge exchange relationship involving O⁺, H⁺, O and CO₂. The dawn bulge in the diurnal distribution of n(H), reported from the first diurnal cycle by Brinton et al., is found to persist with n(H) peaking at levels near 2 - 5 × 10⁷/cm³ at altitudes below 165 km. At peak levels, the bulge exhibits a concentration ratio up to 400/1 relative to dayside values. Large day to day variations of up to a factor of five in n(H) are frequently encountered, and are attributed to perturbations induced by the solar wind interaction. These short term variations, plus a suggestion of some local time variation in the bulk location, make precise assessment of interannual variations in the n(H) difficult. Between the first diurnal cycle in early 1979 and the third in mid 1980, the decline in solar euv flux was of the order of 10% or less. Allowing for uncertainties due to short term variations, no clear evidence is found for an interannual variation in the hydrogen concentrations.     

Composition and structure of the atmosphere of Venus

Although in recent years much has been learned about the atmospheric composition and structure of Venus, there are many key questions which remain unanswered. The Pioneer Venus set of experiments is designed to provide information both individually and collectively to help understand and explain first of all the present state of the atmosphere (the composition and distribution in both the lower and upper parts, the state property profiles, the cloud compositions, the role of phase in the thermal structure, the planet's surface and interior composition, the high surface temperature, the stability of CO₂, the ionosphere — its chemistry and thermal structure, the existence of superrotation, the response of the upper atmosphere to changes in solar EUV and the solar wind) and secondly the origin and evolution of the atmosphere. This paper discusses these questions and the degree to which the Pioneer Venus instruments will respond to them.