Raman imagery: a new approach to assess the geochemical maturity and biogenicity of permineralized precambrian fossils

Laser-Raman imagery is a non-intrusive, non-destructive analytical technique, recently introduced to Precambrian paleobiology, that can be used to demonstrate a one-to-one spatial correlation between the optically discernible morphology and kerogenous composition of permineralized fossil microorganisms. Made possible by the submicron-scale resolution of the technique and its high sensitivity to the Raman signal of carbonaceous matter, such analyses can be used to determine the chemical-structural characteristics of organic-walled microfossils and associated sapropelic carbonaceous matter in acid-resistant residues and petrographic thin sections. Here we use this technique to analyze kerogenous microscopic fossils and associated carbonaceous sapropel permineralized in 22 unmetamorphosed or little-metamorphosed fine-grained chert units ranging from approximately 400 to approximately 2,100 Ma old. The lineshapes of the Raman spectra acquired vary systematically with five indices of organic geochemical maturation: (1) the mineral-based metamorphic grade of the fossil-bearing units; (2) the fidelity of preservation of the fossils studied; (3) the color of the organic matter analyzed; and both the (4) H/C and (5) N/C ratios measured in particulate kerogens isolated from bulk samples of the fossil-bearing cherts. Deconvolution of relevant spectra shows that those of relatively well-preserved permineralized kerogens analyzed in situ exhibit a distinctive set of Raman bands that are identifiable also in hydrated organic-walled microfossils and particulate carbonaceous matter freed from the cherts by acid maceration. These distinctive Raman bands, however, become indeterminate upon dehydration of such specimens. To compare quantitatively the variations observed among the spectra measured, we introduce the Raman Index of Preservation, an approximate measure of the geochemical maturity of the kerogens studied that is consistent both with the five indices of organic geochemical alteration and with spectra acquired from fossils experimentally heated under controlled laboratory conditions. The results reported provide new insight into the chemical-structural characteristics of ancient carbonaceous matter, the physicochemical changes that accompany organic geochemical maturation, and a new criterion to be added to the suite of evidence by which to evaluate the origin of minute fossil-like objects of possible but uncertain biogenicity.     

Surreal estate: addressing the issue of ‘Immovable Property Rights on the Moon’

At a time when scientific and commercial interest in the Moon is being reinvigorated it is becoming fashionable for ordinary individuals to ‘buy’ plots on the lunar surface, with the ‘vendors’ arguing that an absence of specific prohibition of individual private activity in space makes such action legal. It is therefore time for the legal community to address this situation by investigating just how legal such activity is—and bringing their findings to the attention of governments. This can be done through an examination of the relationship between national law and international space law, of the provisions of international space law—especially Article 2 of the Outer Space Treaty—and by answering any claims to private ownership of immovable property. Aside from the fact that individuals appear to be being duped, the pursuit of property claims on the Moon could impede future activities aimed at benefiting society.     

Energy Spectrum of Galactic 10–100 MeV Protons in Quiet Sun Periods

The dynamics of the proton energy spectrum during the solar cycle is studied. The spectra were determined by 1–100 MeV particle fluxes measured by different instruments mounted aboard the Earth's IMP-8 satellite for more than one hundred quiet-time intervals in the period between 1974 and 1991. The galactic branch of the spectra (E _p > 10 MeV) constructed for every quiet interval was fitted by a power law function, J =CE . The theory predicts that in the 1–100 MeV energy range, where the adiabatic cooling of particles is dominant, = 1, while we have derived a double-peak distribution. The main maximum has the mean value = 1.35. The mean value of the second, much weaker maximum, is = 0.95. Within the main maximum, values are distributed in accordance with the Gaussian law with a standard deviation D/ = 0.12. The substantial difference of from unity requires the elaboration of a new model of modulation processes in the inner heliosphere. The values corresponding to the second maximum show that modulation processes correspond sometimes to theoretical conceptions. It is shown that correlates weakly with parameters A and describing the solar branch of the spectrum (J(E) = AE ^–). At the same time, a more significant correlation is observed between and the solar activity index, R _z, the counting rate of the Deep River neutron monitor, and the energy value in the minimum of the energy spectrum flux, E _min.     

Electrostatic Instability and Plasma Irregularities in the Topside Ionosphere above the South-Atlantic Geomagnetic Anomaly

The data of measuring the plasma density in the topside ionosphere for the South-Atlantic geomagnetic anomaly region are presented. It is shown that irregular plasma structures with a wide spectrum of irregularity scale (including large-scale structures with a dimension of order of some hundred kilometers) can be generated in the fields of electrostatic turbulence in inhomogeneous plasma.     

Convective Motions in Near-Critical Fluids under Real Zero-Gravity Conditions

The results of processing and interpreting the data of joint Russian–French experiments for studying the heat and mass transfer in near-critical fluids are presented. The experiments were carried out with the ALICE-1 instrument during an orbital flight of the Mirstation from September 30 to October 2, 1995 [1]. For such fluids with a point-like source of heat, when they are placed in the field of uncontrolled inertial accelerations of the spacecraft, the influence of thermovibrational and thermogravitational mechanisms of convection on the propagation of the region of optical irregularity is investigated. It is shown that, near the thermodynamic critical point, local heating of the medium leads to generation of either intense thermogravitational convection or averaged vibroconvective flow, depending on the frequency of variations of the microaccelerations. The structure and characteristics of discovered motions are studied. The results of numerical simulations are presented that confirm the conclusion about a possibility of generation of an averaged convective flow of a vibrational type by the high-frequency component of microaccelerations.     

Cave biosignature suites: microbes,minerals, and Mars

Earth's subsurface offers one of the best possible sites to search for microbial life and the characteristic lithologies that life leaves behind. The subterrain may be equally valuable for astrobiology. Where surface conditions are particularly hostile, like on Mars, the subsurface may offer the only habitat for extant lifeforms and access to recognizable biosignatures. We have identified numerous unequivocally biogenic macroscopic, microscopic, and chemical/geochemical cave biosignatures. However, to be especially useful for astrobiology, we are looking for suites of characteristics. Ideally, "biosignature suites" should be both macroscopically and microscopically detectable, independently verifiable by nonmorphological means, and as independent as possible of specific details of life chemistries--demanding (and sometimes conflicting) criteria. Working in fragile, legally protected environments, we developed noninvasive and minimal impact techniques for life and biosignature detection/characterization analogous to Planetary Protection Protocols. Our difficult field conditions have shared limitations common to extraterrestrial robotic and human missions. Thus, the cave/subsurface astrobiology model addresses the most important goals from both scientific and operational points of view. We present details of cave biosignature suites involving manganese and iron oxides, calcite, and sulfur minerals. Suites include morphological fossils, mineral-coated filaments, living microbial mats and preserved biofabrics, 13C and 34S values consistent with microbial metabolism, genetic data, unusual elemental abundances and ratios, and crystallographic mineral forms.     

ESA's Biopan 1--"Vitamin" experiment preliminary results

The purpose of “Vitamin” experiment is to study the efficiency of protective substances on three biological acellular systems aqueous solutions exposed to cosmic radiation in space. The first system “LDL”is a low density lipoprotein. The second is “E2-TeBG complexe” in which estradiol (E2) is bound to its plasmatic carrier protein, testosterone-estradiol binding globulin (TeBG). The third is “pBR 322”, a plasmid. “Vitamin” experiment was accomodated in the Biopan which had been mounted on the outer surface of a Foton retrievable satellite. The experiment was exposed to space environment during 15 days. A stable temperature of about 20 °C was maintained throughout the flight. “Vitamin” experiment preliminary results are presented and discussed.     

Thermal resistance in satellite mounting plates due to conductive heat transfer

The thermal resistance due to conductive heat transfer between two heat generating boxes mounted symmetrically on a thin mounting plate, one side of which is subjected to a constant heat flux and the opposite side is convectively cooled, is considered. The other two sides are maintained at constant temperature. A numerical solution for the temperature field is obtained and the heat transfer between the boxes is found by integrating between the critical heat flow lines. Various nondimensional parameters are identified and their influence on the thermal resistance is studied.     

Electrostatic Noise Spectrum at the Electron Cyclotron Frequency and Electromagnetic Emission in the Inhomogeneous Plasma of the Topside Ionosphere

Measurements of the wave emission of the topside ionosphere made onboard the APEX satellite using the electric component of the wave field in the 0.1–10 MHz frequency band are presented. At middle latitudes a wave intensity decrease was observed in the broad-band spectrum of the electrostatic noise at the electron cyclotron frequency. It is shown that a break in the spectrum of electrostatic modes at the electron cyclotron frequency (the absence of the plasma eigen-frequencies) may be a cause of the observed effect. The increase of the intensity at the electron cyclotron frequency in the ionospheric trough and at latitudes above the trough region as compared to middle latitudes may be explained by the capture by plasma irregularities of the electromagnetic emission of the auroral electron fluxes.__________Translated from Kosmicheskie Issledovaniya, Vol. 43, No. 3, 2005, pp. 201–208.Original Russian Text Copyright © 2005 by Izhovkina, Prutensky, Pulinets, Kiraga, Klos, Rothkael.     

A new method of determining the spectral index for protons in the energy range about 10<Superscript>13</Superscript> eV

We consider a relationship between the difference in spectral indices of the spectra of single hadrons and all hadrons (_sngl – _h) and the difference in the indices of the spectra of galactic cosmic ray (GCR) protons and nuclei. It is demonstrated that at the mountain level the ratio (_p – _Z)/(_sngl – _h) is always larger than unity, if (_sngl – _h) > 0.1. From the experimental value _sngl – _h = 0.4 ± 0.05 we derive that, in the vicinity of E = 10 TeV, _p – _Z 0.49 ± 0.06 , i.e., _p 3.09 ± 0.06.__________Translated from Kosmicheskie Issledovaniya, Vol. 43, No. 2, 2005, pp. 83–87.Original Russian Text Copyright © 2005 by Grigorov, Tolstaya.