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21.
Laboratory experiments carried out under plausible prebiotic conditions (under conditions that might have occurred at primitive deep-sea hydrothermal vents) in water and involving constituents that occur in the vicinity of submarine hydrothermal vents (e.g., CO, H(2)S, NiS) have disclosed an iterative Ni-catalyzed pathway of C-C bond formation. This pathway leads from CO to various organic molecules that comprise, notably, thiols, alkylmono- and disulfides, carboxylic acids, and related thioesters containing up to four carbon atoms. Furthermore, similar experiments with organic compounds containing various functionalities, such as thiols, carboxylic acids, thioesters, and alcohols, gave clues to the mechanisms of this novel synthetic process in which reduced metal species, in particular Ni(0), appear to be the key catalysts. Moreover, the formation of aldehydes (and ketones) as labile intermediates via a hydroformylation-related process proved to be at the core of the chain elongation process. Since this process can potentially lead to organic compounds with any chain length, it could have played a significant role in the prebiotic formation of lipidic amphiphilic molecules such as fatty acids, potential precursors of membrane constituents. 相似文献
22.
The Lunar Reconnaissance Orbiter Laser Ranging Investigation 总被引:1,自引:0,他引:1
Maria T. Zuber David E. Smith Ronald S. Zellar Gregory A. Neumann Xiaoli Sun Richard B. Katz Igor Kleyner Adam Matuszeski Jan F. McGarry Melanie N. Ott Luis A. Ramos-Izquierdo David D. Rowlands Mark H. Torrence Thomas W. Zagwodzki 《Space Science Reviews》2010,150(1-4):63-80
The objective of the Lunar Reconnaissance Orbiter (LRO) Laser Ranging (LR) system is to collect precise measurements of range that allow the spacecraft to achieve its requirement for precision orbit determination. The LR will make one-way range measurements via laser pulse time-of-flight from Earth to LRO, and will determine the position of the spacecraft at a sub-meter level with respect to ground stations on Earth and the center of mass of the Moon. Ranging will occur whenever LRO is visible in the line of sight from participating Earth ground tracking stations. The LR consists of two primary components, a flight system and ground system. The flight system consists of a small receiver telescope mounted on the LRO high-gain antenna that captures the uplinked laser signal, and a fiber optic cable that routes the signal to the Lunar Orbiter Laser Altimeter (LOLA) instrument on LRO. The LOLA instrument receiver records the time of the laser signal based on an ultrastable crystal oscillator, and provides the information to the onboard LRO data system for storage and/or transmittal to the ground through the spacecraft radio frequency link. The LR ground system consists of a network of satellite laser ranging stations, a data reception and distribution facility, and the LOLA Science Operations Center. LR measurements will enable the determination of a three-dimensional geodetic grid for the Moon based on the precise seleno-location of ground spots from LOLA. 相似文献
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The Lunar Orbiter Laser Altimeter Investigation on the Lunar Reconnaissance Orbiter Mission 总被引:3,自引:0,他引:3
David E. Smith Maria T. Zuber Glenn B. Jackson John F. Cavanaugh Gregory A. Neumann Haris Riris Xiaoli Sun Ronald S. Zellar Craig Coltharp Joseph Connelly Richard B. Katz Igor Kleyner Peter Liiva Adam Matuszeski Erwan M. Mazarico Jan F. McGarry Anne-Marie Novo-Gradac Melanie N. Ott Carlton Peters Luis A. Ramos-Izquierdo Lawrence Ramsey David D. Rowlands Stephen Schmidt V. Stanley Scott III George B. Shaw James C. Smith Joseph-Paul Swinski Mark H. Torrence Glenn Unger Anthony W. Yu Thomas W. Zagwodzki 《Space Science Reviews》2010,150(1-4):209-241
The Lunar Orbiter Laser Altimeter (LOLA) is an instrument on the payload of NASA’s Lunar Reconnaissance Orbiter spacecraft (LRO) (Chin et al., in Space Sci. Rev. 129:391–419, 2007). The instrument is designed to measure the shape of the Moon by measuring precisely the range from the spacecraft to the lunar surface, and incorporating precision orbit determination of LRO, referencing surface ranges to the Moon’s center of mass. LOLA has 5 beams and operates at 28 Hz, with a nominal accuracy of 10 cm. Its primary objective is to produce a global geodetic grid for the Moon to which all other observations can be precisely referenced. 相似文献