含SiO2,ZrO2微粒复合镀镍层抗高温氧化性能

通过对含有SiO₂,ZrO₂微粒复合电沉积的研究,在Cu合金表面分别获得了含量(原子数分数)为11.3％ SiO₂,5.31％ ZrO₂微粒的Ni基复合镀层.通过在800℃、900℃条件下的高温氧化和热震循环试验,研究了这种复合镀镍层的高温氧化性能和界面结合特性.结果表明:经过40?h的高温氧化,2种复合镀镍层的抗氧化性能均达到抗氧化级,而且含SiO₂微粒的复合镀镍层的抗氧化性能优于含ZrO₂微粒的复合镀镍层;经过55次冷热循环,含SiO₂微粒的复合镀镍层与铜基体结合良好.     

离心力场中TiC/FeNiCr复合材料 涂层的原位反应合成

以Fe₂O₃,Cr₂O₃,CrO₃,NiO,Al,Ti粉和C粉为原料,在离心力场中在碳钢基体表面原位反应合成了TiC-FeNiCr复合材料涂层.利用X射线衍射、金相照相、扫描电镜、X射线能谱分析等手段对涂层的显微结构和组织形貌进行了研究.测试了涂层的显微硬度及干滑动磨损条件下的耐磨性能.结果表明,涂层和碳钢基体能形成冶金结合.涂层由FeNiCr奥氏体和其中弥散分布的TiC硬质相组成.TiC颗粒晶粒尺寸小于3μm,形状呈多边形或花瓣状.涂层显微硬度约为Hv 500~Hv 800,TiC含量增加,涂层的显微硬度提高.涂层较碳钢具有优异的耐磨性能.      

Si对TiAl合金高温抗氧化性能的影响

利用X射线衍射、扫描电镜、能谱仪等手段研究了TiAl-Si(原子数分数为0~20%)合金在1 173 K大气中24 h的恒温氧化.结果表明:Si元素可以有效地提高TiAl合金的高温抗氧化性能;随着Si含量的增加,氧化膜厚度依次减薄,TiO₂的含量逐渐减少,Al₂O3的含量逐渐增加,添加到10%左右时就有连续致密的Al₂O₃保护膜形成;Si在0~20%的添加过程中并没发现Si的氧化物生成.分析表明:Si对抗氧化性能的贡献可归结于Si与Ti有很好的亲和力,可以有效地降低Ti离子的活度、阻碍Ti离子的向外扩散, 相对来说增强了Al离子的活度,促进连续致密的Al₂O₃保护膜生成.      

PEEK/ZrO2固体合金的探索研究

在聚醚醚酮(PEEK)玻璃化转变温度以下,用外动式高能旋转球磨机使PEEK和二氧化锆(ZrO₂)混合物反复变形、断裂和结合,并形成新的相,即形成PEEK/ZrO₂固体合金.通过扫描电镜(SEM)、差示扫描量热仪(DSC)、红外光谱(FT-IR)和动态热力学分析装置(DMTA)对PEEK/ZrO₂=1/2和2/1固体合金的结构及性能进行研究;并与纯PEEK对比,探讨PEEK与ZrO₂形成固体合金的可能性;讨论固体合金化工艺对PEEK/ZrO₂固体合金性能的影响,分析PEEK/ZrO₂固体合金的形成机理.     

卡尔曼滤波和自相关分析方法短期预报电离层f0F2的比较

电离层参数f₀F₂的预报是电离层研究的一个重要方向.本文选取2011年北京、长春、青岛和苏州四个常规观测站的f₀F₂数据,分别采用卡尔曼滤波、自相关分析法和国际参考电离层模型（IRI）对f₀F₂实施短期预报（提前1h预报）,并通过与实际观测数据的对比,对三种方法预报f₀F₂的性能进行了比较.研究结果表明,在磁平静时期,采用卡尔曼滤波方法进行f₀F₂预报的均方误差为0.532MHz,相对误差8.11%,比国际电离层参考模型的均方误差和相对误差分别降低1.47MHz和14.58%;采用自相关分析方法进行f₀F₂预报的均方根误差为0.967MHz,相对误差11.46%,比国际电离层参考模型的均方误差和相对误差分别降低1.035MHz和11.23%.比较结果说明二者对f₀F₂短期预报的精度相对于国际电离层参考模型均有大幅提升.对磁暴期间三种方法的预测性能做了进一步比较,试验结果表明卡尔曼滤波短期预报性能总体上优于自相关分析法,这为f₀F₂短期预报的方法选择提供了一定指导.      

金合金锡铅软钎焊接头脆性行为

采用Sn63Pb37钎料对Au60AgCu合金进行钎焊试验.对钎焊接头的微观组织、显微硬度、化合物相成分、力学性能及断口形貌进行了分析,并探讨了界面化合物相对接头脆性的影响.结果表明:Au60AgCu合金接头化合物主要由AuSn₂,AuSn₄和Ag₃Sn组成.金属间化合物的硬度很高,其厚度随钎焊温度的升高及保温时间的增长而增厚.钎焊接头剪切性能测试表明,断裂发生在金属间化合物层,断口形貌为脆性断裂.     

AZ91D镁合金低压交流氧化成膜机制

基于一种低的交流电压条件(10 V),在NaOH和Na₂SiO₃的混合溶液体系中,对AZ91D镁合金进行电化学阳极氧化处理.利用扫描电镜(SEM)、X射线能谱仪(EDS)、X射线衍射仪(XRD)、电化学测试技术等手段研究了AZ91D镁合金表面阳极氧化的成膜过程、膜层生长的特点以及氧化工艺参数对膜层性能的影响规律.试验结果表明:在10 V这样低的交流电压下,在镁合金表面获得的氧化膜层表面均匀,为无孔洞的平层状膜层,其生长过程呈叠加式特点;获得的氧化膜层的主要成分为Mg₂SiO₄;在质量分数为3.5%的NaCl溶液中,经过电化学阳极氧化的镁合金的耐蚀性优于未经处理的镁合金.      

贫燃型汽车尾气NOx的催化净化

用溶胶-凝胶混合法制备了Al₂O₃,Ag/Al₂O₃,Sn/Al₂O₃,Ga/Al₂O₃,Co/Al₂O₃和Pt/Al₂O₃等催化剂.在相同实验条件下,比较了C₃H₆在这些催化剂上还原NO的活性,并考察了反应条件对C₃H₆和CH₃OH在Ag/Al₂O₃上还原NO性能的影响.结果表明,Ag/Al₂O₃的还原NO活性优于其它催化剂.H₂O对Ag/Al₂O₃催化剂的NO还原具有可逆抑制作用,SO₂降低C₃H₆在Ag/Al₂O₃上还原NO的活性,但会显著提高CH₃OH还原NO的活性.     

中国空间站燃烧科学实验系统PIV单元地面试验

中国空间站燃烧科学实验系统是用于开展微重力燃烧实验研究的综合性科学实验平台，可以实现燃烧流场测量。为了验证燃烧科学实验系统粒子图像测速(PIV)单元对燃烧流场测量的功能与可行性，本文基于与在轨状态一致的连续激光器和相机的空间布局，搭建了地面层流圆孔射流试验平台，选取Al₂O_3，TiO_2，ZrO₂三种示踪粒子进行冷态试验与热态试验。试验结果表明，自主研制Nd∶YVO₄泵浦连续激光器偏光角度合适，能照亮被测流场主流区域，燃烧科学实验系统PIV单元可用于低速燃烧流场测量；相同工况下，Al₂O₃粒子在冷态试验测量的速度值更接近于理论值，速度幅值比更接近1，更适用于低速流体测量。      

释放不同化学物质对电离层扰动的比较

在电离层F区释放氢（H₂）、水（H₂O）、二氧化碳（CO₂）、六氟化硫（SF₆）、三氟溴甲烷（CF₃Br）、羰基镍（Ni（CO）₄）可以损耗局域等离子体电子密度,形成电子空洞,电离层电子密度的改变主要取决于释放物质的气态分子与电离层之间的离子化学反应.在电离层人工主动扰动实验中,应根据发射成本和扰动效果对释放物质进行选择.通过热力学原理和有限元模拟方法计算比较了上述6种物质对电离层的扰动影响.计算结果表明,6种物质中水的气化率最低,约为19%,其余5种物质都在60%以上,选择密度小的物质,例如H₂和CO₂,可以有效降低发射成本.另外,扩散较慢且化学反应较快的物质,例如SF₆和Ni（CO）₄,能够使得电离层电子密度减少得更多,并且受扰动区域更广、持续时间更长.     

强磁暴、能量粒子暴与热层大气密度涨落之间的相关关系

利用1997-2007年由GOES8, GOES11和GOES12星载高能粒子探测器在地球同步轨道高度上所探测到的高能质子和高能电子通量探测数据以及高度560km左右星载大气密度探测器所得的热层大气密度探测数据, 统计分析了强地磁扰动、高能粒子通量跃变和热层大气密度涨落之间的相关关系, 初步获得强地磁扰动期间, 地球同步轨道(外辐射带外环)均出现了增幅大于三个数量级的高能质子通量(尤其是E>1MeV)强增强现象, 随后热 层大气密度强烈上涨, 表明三者之间是正相关关系. 在时间上地球同步轨道高能质子通量强增强现象先于日均Ap值(地磁活动程度)上涨约一天左右, 而热层大气密度强涨落现象又明显滞后于强地磁扰动事件.      

Effect of ion dynamics on the evolution of electron phase-space holes

The evolution of two-dimensional (2D) electron phase-space holes (electron holes) has been previously investigated with electrostatic Particle-in-Cell (PIC) simulations, which neglect ion dynamics. The electron holes are found to be unstable to the transverse instability, and their evolution is determined by the combined action between the transverse instability and the stabilization by the background magnetic field. In this paper, the effect of ion dynamics on the evolution of an electron hole is studied. In weakly magnetized plasma (Ω_e < ω_pe, where Ω_e and ω_pe are electron gyrofrequency and plasma frequency, respectively), the electron hole is still unstable to the transverse instability. However, it evolves a little faster and is destroyed in a shorter time when ion dynamics is considered. In strongly magnetized plasma (Ω_e > ω_pe), the electron hole is broken due to the lower hybrid waves, and its evolution is much faster.      

量子点与TiO2电极参数对光阳极电子寿命及性能影响

通过对P25Ti O2光阳极薄膜厚度、敏化的量子点种类及量子点敏化方法研究,探讨了使用连续离子层吸附反应法的敏化方法(SILAR)时,P25Ti O2薄膜厚度与光阳极电子寿命的关系,以及量子点种类、共敏化工艺对光阳极光电性能的影响.采用电化学阻抗(EIS)、开路电压衰减(OCVD)及紫外-可见吸收方法,对影响光阳极光电性能的Ti O2薄膜厚度、量子点种类及共敏化工艺因素进行测试分析.实验结果表明:当光阳极薄膜厚度为12μm时,电子复合几率最小,光阳极的电子寿命相对最长;采用连续离子层吸附反应法(SILAR)对多种量子点共敏化的光阳极(Ti O2/Cd S/Cd Se/Zn S)与单一量子点敏化的光阳极(Ti O2/Cd S)相比,短路电流提高了34%,光转换效率提高了42%;合适的共敏化工艺也有助于提高光阳极的电子寿命、光谱吸收范围和吸收强度.     

Imprints of small-scale nonadiabatic particle dynamics on large-scale properties of dynamical magnetotail equilibria

We extend our large-scale kinetic (LSK) simulation of the magnetotail by including the global electrostatic effects generated by the field-aligned motion of electrons. Differences in electron and ion dynamics result in significant electrostatic fields near the current sheet (especially near X-lines) and in the auroral zone. In addition, E_ƒ and E alter the ion precipitation profile and affect particle loss from the system through the flanks and downtail. This work provides a basis for including transverse electron currents in our calculations.     

Estimation of plasma density from wave data of cold electron plasma

Based on the dispersion relation of electron plasma, one can expect, that the waves excited in the frequency band (f_p, f_u=sqrt(f_p^*f_p+f_c^*f_c)) should persist in experimental spectra. For wave data from a spacecraft immersed in a cold plasma such an assumption may be misleading. In measurements performed on board the INTERCOSMOS-19, ACTIVE, APEX satellites and VC36.064CE rocket the most prominent spectral structure is centered around frequency f_r fulfilling the relation f_crp and corresponds to resonant detection of Bernstein waves excited in the surrounding plasma by spacecraft systems. Input network mismatch at frequencies around fu significantly depresses natural plasma noise as well as that excited by the spacecraft. Plasma emissions in the band (f_p, f_u) are prominent if the electromagnetic excitation is preferential (topside sounders) or if the excitation introduces nonequilibrium components into the plasma e.g. particle beams or clouds. Experimental examples are presented and parameters of cold plasma spectra useful for electron density estimation are discussed. The application to other spacecraft-cold plasma configurations is suggested.     

Effect of HF emission of the topside sounder transmitter aboard the COSMOS-1809 satellite on the ionospheric plasma

The experiment on investigation of effect of the HF emission (300 W) by the dipole antenna on the ionospheric plasma was carried out onboard the COSMOS-1809 satellite (1987). The sounder accelerated particles (SAP) at the electron cyclotron harmonics n · ω_cs and in the frequency region of antenna resonance were detected by the charged particle spectrometer.     

Cometary atmosphere (gas and dust)

There is important progress now in the identifications and measurements of primary (parent) molecules in the inner coma of Comet Halley. H₂O, CO₂ and CO are definitely in the list, CH and some complicate organic molecules are suspected. Gas production rate for water vapor is Q_H2O 10³⁰ s⁻¹. The bulk of data doesn't contradict to the Whipple model of nucleus (with clathrate modification). Pronounced spatial structure of gaseous flow in the coma was observed, but in general measured properties of neutral gas in the coma of Comet Halley are not very different from predicted. Situation for dust is different. In situ dust measurements show that size spectrum and optical properties of particles in coma are substantively declining from predicted on the base of groundbased photometry. However there are discrepancies between Vega and Giotto dust counter data. Dust in the inner coma didn't prevent the succesful imaging of nucleus by TV on Vega 1 and 2.