LaBr3(Ce)元件破损在线监测关键核素确定及效率校准

常用的元件破损在线监测方法受外在因素影响较大，以γ能谱中关键裂变产物核素比活度进行在线定量分析是一种可靠的元件破损监测方法。针对新型LaBr₃(Ce)元件破损监测仪，设计了元件破损模拟实验，对逸出的裂变产物采用HPGe和LaBr₃(Ce)探测器进行了对比测量。通过不同冷却时间γ能谱的核素分析，确定了¹³⁵Xe，⁸⁸Kr，¹³⁸Xe，⁸⁸Rb，¹³⁸Cs等可作为LaBr₃(Ce)元件破损γ能谱监测的关键核素。同时，制备了覆盖能量范围(250～2 400)keV，含⁶⁰Co，¹³⁷Cs，¹³³Ba；²⁴¹Am，¹⁵²Eu；¹⁰⁹Cd，⁸⁸Y，⁵⁷Co及²⁴Na的4组放射性标准溶液，在建立的效率校准系统上，校准了LaBr₃(Ce)在线监测仪的效率。在反应堆一次异常情况分析中，已校准的LaBr₃(Ce)元件破损监测仪对关键核素的现场分析结果与HPGe的取样分析结果一致，表明效率校准结果准确，校准方法可靠。     

LaBr3(Ce)元件破损在线监测关键核素确定及效率校准

常用的元件破损在线监测方法受外在因素影响较大，以γ能谱中关键裂变产物核素比活度进行在线定量分析是一种可靠的元件破损监测方法。针对新型LaBr₃(Ce)元件破损监测仪，设计了元件破损模拟实验，对逸出的裂变产物采用HPGe和LaBr₃(Ce)探测器进行了对比测量。通过不同冷却时间γ能谱的核素分析，确定了¹³⁵Xe，⁸⁸Kr，¹³⁸Xe，⁸⁸Rb，¹³⁸Cs等可作为LaBr₃(Ce)元件破损γ能谱监测的关键核素。同时，制备了覆盖能量范围(250～2 400)keV，含⁶⁰Co，¹³⁷Cs，¹³³Ba；²⁴¹Am，¹⁵²Eu；¹⁰⁹Cd，⁸⁸Y，⁵⁷Co及²⁴Na的4组放射性标准溶液，在建立的效率校准系统上，校准了LaBr₃(Ce)在线监测仪的效率。在反应堆一次异常情况分析中，已校准的LaBr₃(Ce)元件破损监测仪对关键核素的现场分析结果与HPGe的取样分析结果一致，表明效率校准结果准确，校准方法可靠。     

135.6nm夜气辉峰值电子密度反演算法及误差

根据夜间135.6nm大气辉光光强与F₂层峰值电子密度N_mF₂平方成正比的物理机制,在前期夜间135.6nm气辉辐射激发模型研究的基础上建立了峰值电子密度的反演算法,把全球经纬度分成若干格点,每个格点的电离层及中性成分信息分别由IRI2000和MSISE90提供,将电离层及中性成分廓线输入夜气辉辐射激发模型,计算每个格点135.6nm气辉的辐射强度,然后将各个格点的135.6nm气辉辐射强度与电离层廓线输入的N_mF₂平方拟合得到气辉强度与N_mF₂的转换因子.利用此方法可获得不同地方时、季节和太阳活动周期的转换因子组成查算表,进而根据实际探测的135.6nm气辉辐射强度反演相应时空的N_mF₂.最后对该算法的反演误差进行了综合分析,为该算法适用的时空特性提供重要理论支撑.      

Chemical evolution of RNA under hydrothermal conditions and the role of thermal copolymers of amino acids for the prebiotic degradation and formation of RNA.

The roles of thermal copolymers of amino acids (TCAA) were studied for the prebiotic degradation of RNA. A weak catalytic ability of TCAA consisted of Glu, L-Ala, L-Val, L-Glu, L-Asp, and optionally L-His was detected for the cleavage of the ribose phosphodiester bond of a tetranucleotide (5'-dCrCdGdG) in aqueous solution at 80 degees C. The rate constants of the disappearance of 5'-dCrCdGdG were determined in aqueous solutions using different pH buffer and TCAA. The degradation rates were enhanced 1.3-3.0 times in the presence of TCAA at pH 7.5 and 8.0 at 80 degrees C, while the hydrolysis of oligoguanylate (oligo(G)) was accelerated about 1.6 times at pH 8.0. A weak inhibitory activity for the cleavage of oligo(G) was detected in the presence of 0.055 M TCAA-Std. On the other hand, our recent study on the influences of TCAA for the template-directed reaction of oligo(G) on a polycytidylic acid template showed that TCAA has an acceleration activity for the degradation of the activated nucleotide monomer and an acceleration activity for the formation of G5' ppG capped oligo(G). This series of studies suggest that efficient and selective catalytic or inhibitory activities for either the degradation or formation of RNA under hydrothermal conditions could have hardly emerged from the simple thermal condensation products of amino acids. A scenario is going to be deduced on the chemical evolution of enzymatic activities and RNA molecules concerning hydrothermal earth conditions.     

制备生物航煤山苍子果核油预处理工艺

山苍子果核油主要成分为月桂酸等,碳原子数主要分布于8~16,目前仅用于制备烷醇酰胺等低端产品,却是生物航煤的优良原料之一.通过双氧水脱色、复合吸附脱色及酶法脱胶等对山苍子果核油原料油进行预处理及参数最优化设计,脱色率可以达到 97.33%,磷脂含量由1.036 mg/g降低为0.036 mg/g.并确定双氧水脱色的最优实验参数为双氧水加入量15%,反应时间80 min,反应温度110℃;活性炭/改性活性白土复合吸附最优实验参数为活性炭用量W₁与改性活性白土用量W₂重量比W₁/W₂=1/15,反应时间40 min,反应温度80℃,吸附剂加入量4%;酶法脱胶最优实验参数为加酶量40 mg/kg,pH5.1,反应时间 2.5 h,反应温度48℃.该方法成本低、简单易行、原料油损耗率低,对山苍子果核油成分及性质影响较小,满足后续加氢实验要求,为得到高转化率生物航煤奠定了基础.     

The highly ionised absorbing material in MR2251-178

Ginga observations have suggested the presence of iron absorption edges at energies appropriate for highly ionised material in the X-ray spectra of a significant number of active galactic nuclei. Here, we present a detailed self-consistent analysis of a series of Ginga and EXOSAT observations of MR2251-178, the original prototype of this warm-absorber phenomenon. The observations do indeed support the presence of a substantial column density of highly ionised material.

The ionisation state of the material responds to changes in the the luminosity of the ionising continuum, with the ionisation state of oxygen being particularly sensitive. Analysis of this variability leads to constraints on the density and location of this material as well as its total amount.     

Integration of waste processing and biomass production systems as part of the KSC Breadboard project.

After initial emphasis on large-scale baseline crop tests, the Kennedy Space Center (KSC) Breadboard project has begun to evaluate long-term operation of the biomass production system with increasing material closure. Our goal is to define the minimum biological processing necessary to make waste streams compatible with plant growth in hydroponic systems, thereby recycling nutrients into plant biomass and recovering water via atmospheric condensate. Initial small and intermediate-scale studies focused on the recycling of nutrients contained in inedible plant biomass. Studies conducted between 1989-1992 indicated that the majority of nutrients could be rapidly solubilized in water, but the direct use of this crop "leachate" was deleterious to plant growth due to the presence of soluble organic compounds. Subsequent studies at both the intermediate scale and in the large-scale Biomass Production Chamber (BPC) have indicated that aerobic microbiological processing of crop residue prior to incorporation into recirculating hydroponic solutions eliminated any phytotoxic effect, even when the majority of the plant nutrient demand was provided from recycled biomass during long term studies (i.e. up to 418 days). Current and future studies are focused on optimizing biological processing of both plant and human waste streams.     

Validation of GOME (ERS-2) NO2 vertical column data with ground-based measurements at Issyk-Kul (Kyrgyzstan)

Here we present the results of comparison between operational NO₂ vertical column data by Global Ozone Monitoring Experiment (GOME) onboard ERS-2 satellite and ground-based measurements at Issyk-Kul station in Kyrgyzstan, northern Tien Shan. The data of GOME, taken for the period of 1996–2002, was found to be reasonably close to the results of ground-based sunrise measurements. The latter were adjusted to the time of GOME overpass nearby noon, providing direct comparison between satellite and ground-based data. According to the results, there is 0.6 × 10¹⁵ mol/cm² (18%) overestimation of NO₂ vertical column by GOME, compared to our ground-based data.     

Two new hot white dwarfs in a region of exceptionally low hi density

We report the discovery of two hot white dwarfs which have the lowest line-of-sight neutral hydrogen column densities yet measured. The stars were found independently by the ROSAT EUV, Montreal-Cambridge-Tololo, and Edinburgh-Cape surveys. Follow-up observations made using the Voyager 2 ultraviolet spectrometer reveal strong continua shortward of the 912Å Lyman limit from which we deduce that the neutral hydrogen column densities are 1.3 × 10¹⁷ and 2.0 × 10¹⁷ atoms cm⁻².     

The 2.5 to 5 microns spectrum of comet Halley from the IKS instrument of Vega

Results of the 2.5–5 micron spectroscopic channel of the IKS instrument on Vega are reported and the data reduction process is described. H₂O and CO₂ molecules have been detected with production rates of 10³⁰ s⁻¹ and 1.5 10²⁸ s⁻¹ respectively. Emission features between 3.3 and 3.7 microns are tentatively attributed to CH - bearing compounds - CO is marginally detected with a mixing ratio CO/H₂O 0.2. OH emission and H₂O - ice absorption might also be present in the spectra.     

Influence of high concentrations of mineral salts on production process and NaCl accumulation by Salicornia europaea plants as a constituent of the LSS phototroph link.

Use of halophytes (salt-tolerant vegetation), in a particular vegetable Salicornia europaea plants which are capable of utilizing NaCl in rather high concentrations, is one of possible means of NaCl incorporation into mass exchange of bioregenerative life support systems. In preliminary experiments it was shown that S. europaea plants, basically, could grow on urine pretreated with physicochemical processing and urease-enzyme decomposing of urea with the subsequent ammonia distillation. But at the same time inhibition of the growth process of the plants was observed. The purpose of the given work was to find out the influence of excessive quantities of some mineral elements contained in products of physicochemical processing of urine on the production process and NaCl accumulation by S. europaea plants. As the content of mineral salts in the human liquid wastes (urine) changed within certain limits, two variants of experimental solutions were examined. In the first variant, the concentration of mineral salts was equivalent to the minimum salt content in the urine and was: K - 1.5 g/l, P - 0.5 g/l, S - 0.5 g/l, Mg - 0.07 g/l, Ca - 0.2 g/l. In the second experimental variant, the content of mineral salts corresponded to the maximum salt content in urine and was the following: K - 3.0 g/l, P - 0.7 g/l, S - 1.2 g/l, Mg - 0.2 g/l, Ca - 0.97 g/l. As the control, the Tokarev nutrient solution containing nitrogen in the form of a urea, and the Knop nutrient solution with nitrogen in the nitrate form were used. N quantity in all four variants made up 177 mg/l. Air temperature was 24 degrees C, illumination was continuous. Light intensity was 690 micromoles/m2s of photosynthetically active radiation. NaCl concentration in solutions was 1%. Our researches showed that the dry aboveground biomass of an average plant of the first variant practically did not differ from the control and totaled 11 g. In the second variant, S. europaea productivity decreased and the dry aboveground biomass of an average plant totaled 8 g. The increase of K quantity in the experimental solutions resulted in an elevated content of the element in the plants. The increase of K uptake in the second experimental variant was accompanied by a 30-50% decrease of Na content in comparison with the other variants. Comparative Na content in the other variants was practically identical. N, Mg and P content in the control and experimental variants was also practically identical. The increase of S quantity in the second experimental variant also increased S uptake by the plants. But Ca quantity, accumulated in aboveground plants biomass in the experimental variants was lower than in the control. NaCl uptake by plants, depending on the concentration of mineral salts in the experimental solutions, ranged from 8 g (maximum salt content) up to 15 g (minimum salt content) on a plant growth area that totaled 0.032 m2. Thus, high concentrations of mineral salts simulating the content of mineral salts contained in urine did not result in a significant decrease of S. europaea productivity. The present work also considers the influence of higher light intensity concentrations on productivity and NaCl accumulation by S. europaea plants grown on experimental solutions with high salt content.     

基于CO2浓度监测的飞机火警探测方法

目前飞机普遍采用感温、感烟火警探测方法,其存在误报率高的缺陷.分析了发生火灾时气态燃烧产物的生成规律,提出了以CO_2气体为火警探测参量,通过准确监测环境中CO_2气体浓度的变化,进行飞机火警探测的方法;根据飞机飞行所处环境条件的特殊性,研究了基于非色散红外(NDIR)吸收原理的CO_2气体浓度监测的飞机火警探测方法应用于飞机上所面临的温度补偿难题;根据飞机火警探测器测量电压与环境温度、参比电压之间的关系,采用偏最小二乘(PLS)法建立飞机火警探测器温度补偿模型;根据飞机火警探测器测量电压与CO_2气体浓度之间的关系,采用PLS法建立CO_2气体浓度计算模型;研究了基于CO_2气体浓度监测的报警算法,为飞机火警探测提供了一种新的方法.     

Effects of bioreactor retention time on aerobic microbial decomposition of CELSS crop residues.

The focus of resource recovery research at the KSC-CELSS Breadboard Project has been the evaluation of microbiologically mediated biodegradation of crop residues by manipulation of bioreactor process and environmental variables. We will present results from over 3 years of studies that used laboratory- and breadboard-scale (8 and 120 L working volumes, respectively) aerobic, fed-batch, continuous stirred tank reactors (CSTR) for recovery of carbon and minerals from breadboard grown wheat and white potato residues. The paper will focus on the effects of a key process variable--bioreactor retention time--on response variables indicative of bioreactor performance. The goal is to determine the shortest retention time that is feasible for processing CELSS crop residues, thereby reducing bioreactor volume and weight requirements. Pushing the lower limits of bioreactor retention times will provide useful data for engineers who need to compare biological and physicochemical components. Bioreactor retention times were manipulated to range between 0.25 and 48 days. Results indicate that increases in retention time lead to a 4-fold increase in crop residue biodegradation, as measured by both dry weight losses and CO2 production. A similar overall trend was also observed for crop residue fiber (cellulose and hemicellulose), with a noticeable jump in cellulose degradation between the 5.3 day and 10.7 day retention times. Water-soluble organic compounds (measured as soluble TOC) were appreciably reduced by more than 4-fold at all retention times tested. Results from a study of even shorter retention times (down to 0.25 days), in progress, will also be presented.     

The search for nitrogen compounds on the surface of Mars

Nitrogen is an essential element for life. Specifically, “fixed nitrogen” (i.e., NH₃, NH₄⁺, NO_x, or N that is chemically bound to either inorganic or organic molecules and is releasable by hydrolysis to NH₃ or NH₄⁺) is the form of nitrogen useful to living organisms. To date no direct analysis of Martian soil nitrogen content, or content of fixed nitrogen compounds has been done. Consequently, the planet's total inventory of nitrogen is unknown. What is known is that the N₂ content of the present-day Martian atmosphere is 0.2 mbar. It has been hypothesized that early in Mars' history (3 to 4 billion years ago) the Martian atmosphere contained much more N₂ than it does today. The values of N₂ proposed for this early Martian atmosphere, however, are not well constrained and range from 3 to 300 mbar of N₂. If the early atmosphere of Mars did contain much more N₂ than it does today the question to be answered is, Where did it go? The two main processes that could have removed it rapidly from the atmosphere include: 1) nonthermal escape of N-atoms to space; and 2) burial within the regolith as nitrates and nitrites. Nitrate will be stable in the highly oxidized surface soil of Mars, and will tend to accumulate in the soil. Such accumulations are observed in certain desert environments on Earth. Some NH₄⁺---N may also be fixed and stabilized in the soil by inclusion as a structural cation in the crystal lattices of certain phyllosilicates replacing K. Analysis of the Martian soil for traces of NO₃⁻ and NH₄⁺ during future missions will supply important information regarding the nitrogen abundance on Mars, its past climate as well as its potential for the evolution of life.     

Comparison of OClO nadir measurements from SCIAMACHY and GOME

The scanning imaging absorption spectrometer for atmospheric chartography was launched successfully onboard ENVISAT on March 1, 2002. It observes the solar radiation transmitted and backscattered from the atmosphere and reflected from the ground in nadir, limb and occultation viewing modes. Chlorine dioxide (OClO), an important indicator for stratospheric chlorine activation, can be measured in the UV spectral range by differential optical absorption spectroscopy (DOAS).

First results of the DOAS retrieval of OClO slant column densities from the SCIAMACHY nadir measurements are presented and compared to measurements of the global ozone monitoring experiment (GOME), which has successfully measured OClO since 1995. While SCIAMACHY operates in the same orbit, it measures ≈30 min earlier than GOME and has an increased spatial resolution (30 × 60 km² compared to 40 × 320 km² for GOME).     

风云三号C星GNOS北斗掩星电离层探测初步结果

利用风云三号卫星C星GNOS掩星探测仪电离层数据,分析了2013年10月FY-3C GNOS探测的北斗掩星电离层廓线分布,将2013年10月1日至2015年10月10日期间FY-3C GNOS观测的F₂层峰值电子密度（N_mF₂）与地面电离层测高仪观测结果进行对比,验证了FY-3C GNOS北斗电离层掩星的探测精度.结果表明,FY3-C GNOS北斗电离层掩星与电离层测高仪探测的N_mF₂数据相关系数为0.96,平均偏差为10.21%,标准差为19.61%.在不同情况下其数据精度有如下特征:白天精度高于夜晚;夏季精度高于分季,分季精度高于冬季;中纬地区精度高于低纬地区,低纬地区精度高于高纬地区; BDS倾斜同步轨道（IGSO）卫星精度高于同步轨道（GEO）卫星和中轨道（MEO）卫星.FY-3C GNOS北斗电离层掩星与国际上其他掩星电离层数据精度的一致性对GNSS掩星探测资料的综合利用具有重大意义.      

Radiation stability of organic matter in liquid and frozen H2O, NH3 and water-ammonia mixtures

The redox properties of irradiated liquid and frozen H₂O, NH₃ and H₂O/NH₃ mixtures at 298 K and 77 K, resp., towards some simple organic molecules have been checked by injecting carrierfree ¹¹C atoms and analyzing their chemical state by means of radiochromatography. The reactions and the stability of organic products versus radiation dose (in this study by MeV protons) depend on temperature, phase state, mobility of radicals, their concentration and reactivity. Especially dangerous are the reactive OH and O₂H radicals which oxidize organic material to inorganic CO₂. Highest stability has been found at low temperatures (solid state, reduced mobility of radicals) and for systems containing H-donors (H₂O/NH₃ mixtures), which reduce the concentration of oxidizing radicals. The fact that many bodies in space consist of H₂O-ice with NH₃ and CH₄ additives at temperatures between 10 and 150 K is promising in view of the survival of organic matter under high doses of radiation.     

Study of the luminosity-dependent cyclotron resonance energies of the binary X-ray pulsar 4U 0115+63 with RXTE

We report on the luminosity dependent change of the cyclotron resonance energy obtained from a transient X-ray pulsar, 4U 0115+63. Using RXTE data observed on 1999 March, we found that the fundamental resonance energy stayed constant (11 keV) when the source luminosity was above 5 × 10³⁷ erg s⁻¹. As the luminosity decreased below 5 × 10³⁷ erg s⁻¹, the fundamental resonance energy gradually increased up to 16 keV at 0.16 × 10³⁷ erg s⁻¹. The luminosity dependence of the resonance energy can be understood by the change of the accretion column height.     

H2O对空间站5A分子筛CO2去除性能影响

为进一步研究分子筛CO2去除系统应用于空间站的工作可靠性和鲁棒性,针对空间站4床分子筛(4-BMS)系统中可能出现的湿度失效保护问题展开了实验研究.测试了两种载人航天分子筛材料TC-5A与PSA-5A,研究了不同相对湿度对CO2吸附性能的影响;比较了相同湿度条件下,进口气体CO2浓度、粒径及吸附温度的变化对分子筛吸附CO2性能的影响,采用不同实验方法探究了H2O和CO2在两种分子筛材料中的竞争吸附关系.结果表明:PSA-5A吸附CO2性能优于TC-5A,但对H2O的吸附率略低于TC-5A.H2O的存在对分子筛吸附CO2影响非常大,空气中相对湿度达到60%时,分子筛基本失去了吸附CO2的能力.此外,温度升高会造成CO2的吸附量显著下降,但对H2O的吸附量影响相对较小,尤其是当相对湿度较高时.这对中国未来长期运行的空间站分子筛CO2去除系统工作有效性与工作鲁棒性的评价具有指导意义.     

High resolution X-ray spectrum of AM Her

We present the analysis of archival Chandra high resolution X-ray spectra of AM Her. Emission lines from several hydrogen-like ions, helium-like ions, Fe-L shell transitions and Fe-K fluorescent are identified. Using the resonance, intercombination and forbidden lines of the few prominent helium-like ions, we infer a density greater than 2 × 10¹² cm⁻³ and a temperature of 2 MK for the oxygen and neon line emitting regions in the accretion column of AM Her.