Distributed Sources in Comets

The distribution of some molecules and radicals (H₂CO, CO, HNC, CN,?…) in the atmosphere of several comets cannot be explained only by a direct sublimation from the nucleus, or by gas phase processes in the coma. Such molecules are in part the result of a distributed source in the coma, which could be the photo and thermal degradation of dust. We present a review of the degradation processes and discuss possible interpretations of the observations in which the degradation of solid complex organic material in dust particles seems to play a major role. The knowledge of such gas production mechanisms provides important clues on the chemical nature of the refractory organic material contained in comet nuclei.     

Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

Origins of Cometary Materials

In this introductory presentation, material is categorized according to our state of knowledge: What do we know, what do we think we know but don’t know certainly, and what do we not know but often describe it as if it were a well-established fact about comets, their nuclei, their composition, and processes within comets and their nuclei. The material is presented not with the intend to criticize laboratory work simulating condition in comet nuclei, or observers analyzing their observations, nor modelers using data from both these sources to improve our understanding and make predictions. The intent is to provoke discussion and dialog between these groups to avoid overstating the results. What is a Comet? A comet is a diffuse appearing celestial phenomenon moving in an orbit about the Sun. The central body, the nucleus, is composed of ice and dust. It is the source of all cometary activity, including comae and tails. We distinguish between molecular (including atoms and ions) and dust comae. At heliocentric distances of about 1 AU and less, the hydrogen coma typically has dimensions larger than the Sun. The tails are composed of dust, neutral atoms and molecules, and plasma.     

Interstellar Reservoirs of Cometary Matter

We review the evidence for the products of interstellar chemistry in volatile cometary matter. We compare the organic inventory of star-forming cores with that measured in various comets and point out the similarities and differences. The conditions necessary to fractionate interstellar molecules in the heavier isotopes of H, C, O and N are summarised and compared to the measured fractionation ratios in cometary ices. We give a list of future measurements that would shed further light on the putative connection between cometary and interstellar molecules.     

Comets and Chemical Composition

It is commonly believed that comets are made of primordial material. As a consequence, they can reveal more information about the origin of our solar system. To interpret the coma composition measurements of comet Churyumov–Gerasimenko that will be collected by the Rosetta mission, models of the coma chemistry have to be constructed. However, programming the chemistry of a cometary coma is extremely complex due to the large number of species and reactions involved. Moreover, such a program needs to be very flexible as one may want to extend, change, or update the set of species, reactions, and reaction rates. Therefore, we developed software to manage a database of species and reactions and to generate code automatically to compute source/loss balances. This database includes the data from the UMIST database and the ion–molecule reactions collected by V.G. Anicich. To use all these databases together, a lot of practical problems need to be solved, but the result is an enormous source of information about chemical reactions that can be used in chemical models, not only for comets but also for other applications.     

Structural evolution of cometary surfaces

Comets with a high content of organics and light molecules are expected under cosmic radiation to gain a relatively unreactive crust and less volatile material to some ten metres deep. Interstellar dust impacts act to loosen and turn over 1 cm of the surface. We discuss how far this accords with observations of cometary dust halos and new versus old comets. Two key material properties have emerged from recent studies. Firstly, the source of cometary volatiles is not ice in the sense of material with a single sublimation energy. Secondly, the particulates are not simply mineral dust but include much organic material, some of which undergoes chemical processing and exchanges with the gaseous environment. Consistent with these properties, a coherent crust rather than a mantle of loose grains would build up to cover much of the nucleus of periodic comets. It would consolidate by cooking in the solar radiation, especially at peak temperatures around perihelion. There are two disjoint surface phases: one of volatile material, the other the refractory crust, the former deepening into crater-like hollows over successive apparitions. The transition to non-volatile crust is unstable, subject to competing consolidation and disruption processes, and sensitive to seasonal changes. A comet dims and becomes asteroidal as the inert crust extends over the erosion craters, and may only be rejuvenated via collision with a boulder-sized impactor or perturbation of the orbit to smaller perihelion distance.     

Mupus – A Thermal and Mechanical Properties Probe for the Rosetta Lander Philae

MUPUS, the multi purpose sensor package onboard the Rosetta lander Philae, will measure the energy balance and the physical parameters in the near-surface layers – up to about 30 cm depth- of the nucleus of Rosetta’s target comet Churyumov-Gerasimenko. Moreover it will monitor changes in these parameters over time as the comet approaches the sun. Among the parameters studied are the density, the porosity, cohesion, the thermal diffusivity and conductivity, and temperature. The data should increase our knowledge of how comets work, and how the coma gases form. The data may also be used to constrain the microstructure of the nucleus material. Changes with time of physical properties will reveal timescales and possibly the nature of processes that modify the material close to the surface. Thereby, the data will indicate how pristine cometary matter sampled and analysed by other experiments on Philae really is.     

On the Existence of Distributed Sources in Comet Comae

The main production process of species occurring in the coma of comets is the photodestruction of molecules initially present in the nucleus ices and non-refractory grains or trapped inside the nucleus "material". Grains can also be a source of molecules in the coma. Chemical reactions may occur between coma species. Consequently, although chances that an abundant coma species has not been detected are now small, the coma composition is certainly quite different from that of the nucleus. Except for the molecules released directly at the nucleus surface, all coma species are produced in an "extended region" or come from "a distributed source". Since the recent literature is rich in reports on observations of molecules and species possibly not initially present in the comet ices or not released at the nucleus, a general discussion of how coma species are stored, processed or produced is presented, based mostly on observational results. What is at stake is the proper modeling of the coma structure, hence an accurate derivation of the nucleus composition from coma observations. This revised version was published online in June 2006 with corrections to the Cover Date.     

Origin of Molecular Oxygen in Comets: Current Knowledge and Perspectives

The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) instrument onboard the Rosetta spacecraft has measured molecular oxygen (O₂) in the coma of comet 67P/Churyumov-Gerasimenko (67P/C-G) in surprisingly high abundances. These measurements mark the first unequivocal detection of O₂ in a cometary environment. The large relative abundance of O₂ in 67P/C-G despite its high reactivity and low interstellar abundance poses a puzzle for its origin in comet 67P/C-G, and potentially other comets. Since its detection, there have been a number of hypotheses put forward to explain the production and origin of O₂ in the comet. These hypotheses cover a wide range of possibilities from various in situ production mechanisms to protosolar nebula and primordial origins. Here, we review the O₂ formation mechanisms from the literature, and provide a comprehensive summary of the current state of knowledge of the sources and origin of cometary O₂.     

Dust Environment Modelling of Comet 67P/Churyumov-Gerasimenko

Dust is an important constituent of cometary emission; its analysis is one of the major objectives of ESA’s Rosetta mission to comet 67P/Churyumov-Gerasimenko (C–G). Several instruments aboard Rosetta are dedicated to studying various aspects of dust in the cometary coma, all of which require a certain level of exposure to dust to achieve their goals. At the same time, impacts of dust particles can constitute a hazard to the spacecraft. To conciliate the demands of dust collection instruments and spacecraft safety, it is desirable to assess the dust environment in the coma even before the arrival of Rosetta. We describe the present status of modelling the dust coma of 67P/C–G and predict the speed and flux of dust in the coma, the dust fluence on a spacecraft along sample trajectories, and the radiation environment in the coma. The model will need to be refined when more details of the coma are revealed by observations. An overview of astronomical observations of 67P/C–G is given, because model parameters are derived from this data if possible. For quantities not yet measured for 67P/C–G, we use values obtained for other comets, e.g. concerning the optical and compositional properties of the dust grains. One of the most important and most controversial parameters is the dust mass distribution. We summarise the mass distribution functions derived from the in-situ measurements at comet 1P/Halley in 1986. For 67P/C–G, constraining the mass distribution is currently only possible by the analysis of astronomical images. We find that both the dust mass distribution and the time dependence of the dust production rate of 67P/C–G are those of a fairly typical comet.     

Remote Observations of the Composition of Cometary Volatiles

The volatile species released in the coma are an important clue to the composition of the cometary nucleus ices. Their identification and the measurement of their abundances is possible by remote sensing. Considerable progress has been made recently using radio and infrared spectroscopy, especially with the observations of the two exceptional comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp).) 24 molecules likely to be parent molecules outgassed from the nucleus have now been identified. Significant upper limits exist for many other species, and the presence of unidentified lines suggests that further species are to be identified. In addition, isotopic varieties have been observed for hydrogen, carbon, nitrogen and sulphur. We will review these results with a special emphasis on the reliability of the identifications and of the molecular production rate determinations. A critical point is to assess whether a given species is a genuine parent molecule outgassed from nuclear ices, or is a secondary product coming from grains or from gas-phase photochemistry. Ground-based spectral imaging, such as radio interferometry, may help resolving this problem. This revised version was published online in June 2006 with corrections to the Cover Date.     

Isotopic analysis of cometary organic matter

Carbon isotope ratios have been measured for CN in the coma of comet Halley and for several CHON particles emitted by Halley. Of these, only the CHON-particle data may be reasonably related to organic matter in the cometary nucleus, but the true range of ¹³C/¹²C values in those particles is quite uncertain. The D/H ratio in H₂O in the Halley coma resembles that in Titan/Uranus. The next decade should substantially improve our understanding of the distribution of C, H, N, and O isotopes in cometary organics. The isotopic composition of meteoritic organic matter is better understood and can serve as a useful analog for the cometary case.     

Morphology–Composition–Isotopes: Recent Results from Observations

This article presents some recent imaging and spectroscopic observations that led to results which are significant for understanding the properties of comet nuclei. The coma morphology and/or composition were investigated for 12 comets belonging to different dynamical classes. The data analysis showed that the coma morphology of three non-periodic comets is not consistent with the general assumption that dynamically new comets still have a relatively uniform nucleus surface and therefore do not exhibit gas and/or dust jets in their coma. The determination of carbon and nitrogen isotopic ratios revealed the same values for all comets investigated at various heliocentric distances. However, the relative abundance of the rare nitrogen isotope ¹⁵N is about twice as high as in the Earth’s atmosphere. Observations of comets at splitting events and during outbursts led to indications for differences between material from the nucleus surface and the interior. The monitoring of the induced outburst of 9P/Temple revealed that under non-steady state conditions the fast disintegration of species is detectable.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

Reservoirs for Comets: Compositional Differences Based on Infrared Observations

Tracing measured compositions of comets to their origins continues to be of keen interest to cometary scientists and to dynamical modelers of Solar System formation and evolution. This requires building a taxonomy of comets from both present-day dynamical reservoirs: the Kuiper Belt (hereafter KB), sampled through observation of ecliptic comets (primarily Jupiter Family comets, or JFCs), and the Oort cloud (OC), represented observationally by the long-period comets and by Halley Family comets (HFCs). Because of their short orbital periods, JFCs are subjected to more frequent exposure to solar radiation compared with OC comets. The recent apparitions of the JFCs 9P/Tempel 1 and 73P/Schwassmann-Wachmann 3 permitted detailed observations of material issuing from below their surfaces—these comets added significantly to the compositional database on this dynamical class, which is under-represented in studies of cometary parent volatiles. This chapter reviews the latest techniques developed for analysis of high-resolution spectral observations from ～2–5 μm, and compares measured abundances of native ices among comets. While no clear compositional delineation can be drawn along dynamical lines, interesting comparisons can be made. The sub-surface composition of comet 9P, as revealed by the Deep Impact ejecta, was similar to the majority of OC comets studied. Meanwhile, 73P was depleted in all native ices except HCN, similar to the disintegrated OC comet C/1999 S4 (LINEAR). These results suggest that 73P may have formed in the inner giant planets’ region while 9P formed farther out or, alternatively, that both JFCs formed farther from the Sun but with 73P forming later in time.     

Ptolemy – an Instrument to Measure Stable Isotopic Ratios of Key Volatiles on a Cometary Nucleus

A fundamental goal of cometary studies is to determine the exact relationship between these bodies and the Solar System – the question(s) can be summarised as follows: did comets originate during the same events that spawned the Sun and planets, are they more primitive bodies that record a pre-solar history, or are they interstellar materials collected in relatively more recent times? Now, whatever the origin of comets, it is entirely possible that they could, in part, contain interstellar or pre-solar components – indeed, it seems rather likely in light of the fact that primitive meteorites contain such entities. These particular components are likely to be refractory (dust, macromolecular organic complexes, etc.). Of more relevance to the issues above are the volatile constituents, which make up the bulk of a comet's mass. Since these materials, by their very nature, volatilise during perihelion passage of a comet they can, in some instances, be detected and measured spectroscopically. Perhaps the most useful species for isotopic investigations are C₂, HCN and CN. Unfortunately, spectroscopic measurements can only currently be made with accuracies of ±10 to ±20%. As such it is very often not practical to conclude anything further than the fact that isotopic measurements are compatible with ‘`solar’' values, which tends to imply an origin from the margins of the solar accretion disk. But there is another problem with the spectroscopic measurements – since these are made on gaseous species in the coma (and relatively minor species at that) it is impossible to be certain that these represent the true nuclear values. In other words, if the processes of sublimation, active jetting, and photochemistry in the coma impart isotopic fractionation, the spectroscopic measurements could give a false impression of the true isotope ratios. What is required is an experiment capable of measuring isotopic ratios at the very surface of a comet. Herein we describe the Ptolemy instrument, which is included on the Philae lander as part of the Rosetta mission to 67P/Churyumov-Gerasimenko. The major objective of Ptolemy is a detailed appraisal of the nature and isotopic compositions of all materials present at the surface of a comet.     

Morphological Structure and Chemical Composition of Cometary Nuclei and Dust

The chemical composition of comet nuclei derived from current data on interstellar dust ingredients and comet dust and coma molecules are shown to be substantially consistent with each other in both refractory and volatile components. When limited by relative cosmic abundances the water in comet nuclei is constrained to be close to 30% by mass and the refractory to volatile ratio is close to 1:1. The morphological structure of comet nuclei, as deduced from comet dust infrared continuum and spectral emission properties, is described by a fluffy (porous) aggregate of tenth micron silicate core-organic refractory mantle particle on which outer mantles of predominantly H₂O ices contain embedded carbonaceous and polycyclic aromatic hydrocarbon (PAH) type particles of size in the of 1 - 10nm range. This revised version was published online in June 2006 with corrections to the Cover Date.     

MIDAS – The Micro-Imaging Dust Analysis System for the Rosetta Mission

The International Rosetta Mission is set for a rendezvous with Comet 67 P/Churyumov-Gerasimenko in 2014. On its 10 year journey to the comet, the spacecraft will also perform a fly-by of the two asteroids Stein and Lutetia in 2008 and 2010, respectively. The mission goal is to study the origin of comets, the relationship between cometary and interstellar material and its implications with regard to the origin of the Solar System. Measurements will be performed that shed light into the development of cometary activity and the processes in the surface layer of the nucleus and the inner coma. The Micro-Imaging Dust Analysis System (MIDAS) instrument is an essential element of Rosetta’s scientific payload. It will provide 3D images and statistical parameters of pristine cometary particles in the nm-μm range from Comet 67P/Churyumov-Gerasimenko. According to cometary dust models and experience gained from the Giotto and Vega missions to 1P/Halley, there appears to be an abundance of particles in this size range, which also covers the building blocks of pristine interplanetary dust particles. The dust collector of MIDAS will point at the comet and collect particles drifting outwards from the nucleus surface. MIDAS is based on an Atomic Force Microscope (AFM), a type of scanning microprobe able to image small structures in 3D. AFM images provide morphological and statistical information on the dust population, including texture, shape, size and flux. Although the AFM uses proven laboratory technology, MIDAS is its first such application in space. This paper describes the scientific objectives and background, the technical implementation and the capabilities of MIDAS as they stand after the commissioning of the flight instrument, and the implications for cometary measurements.     

Rare Atoms,Molecules and Radicals in the Coma of P/Halley

We have searched for rare molecules and radicals in the coma of P/Halley using the ion data obtained by IMS-Giotto. Whereas our established methods were used in the ionosphere, a new model was developed for the interpretation of the ion data in the outer coma. Ne/H₂O < 1.5 × 10^-3 was determined in the coma of the comet. Upper limits for the production of Na were derived from the very low abundance of Na⁺. Methyl cyanide and (probably) ethyl cyanide were identified with abundances of CH₃CN/H₂O = (1.4 ± .6) × 10^-3 and C₂H₅CN/H₂O = (2.8 ± 1.6) × 10^-4. These results and upper limits for other N-bearing species confirm that nitrogen is depleted in the Halley material. C₄H was identified and a point source strength of C₄H/H₂O = (2.3 ± .8) × 10^-3 was derived. Our upper limit for C₃H is lower than the abundance of C₄H. This is in agreement with the enhanced abundances of C_nH species with even numbers of C-atoms found in interstellar molecular clouds, suggesting that the C₄H in Halley was synthesized under molecular cloud conditions. Thus, C₄H and other organics with unpaired electrons may turn out to be indicators for a molecular cloud origin of cometary constituents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Cometary dynamics

The modern theory of cometary dynamics is based on Oort's hypothesis that the solar system is surrounded by a spherically symmetric cloud of 10¹¹ to 10¹² comets extending out to interstellar distances. Dynamical modeling and analysis of cometary motion have confirmed the ability of the Oort hypothesis to explain the observed distribution of energies for the long-period comet orbits. The motion of comets in the Oort cloud is controlled by perturbations from random passing stars, interstellar clouds, and the galactic gravitational field. Additionally, comets which enter the planetary region are perturbed by the major planets and by nongravitational forces resulting from jetting of volatiles on the surfaces of the cometary nuclei. The current Oort cloud is estimated to have a radius of 6 to 8 × 10⁴ AU, and to contain some 2 × 10¹² comets with a total mass of 7 to 8 Earth masses. Evidence has begun to accumulate for the existence of a massive inner Oort cloud extending from just beyond the orbit of Neptune to 10⁴ AU or more, with a population up to 100 times that of the outer Oort cloud. This inner cloud may serve as a reservoir to replenish the outer cloud as comets are stripped away by the various perturbers, and may also provide a more efficient source for the short-period comets. Recent suggestions of an unseen solar companion star or a tenth planet orbiting in the inner cloud and causing periodic comet showers on the Earth are likely unfounded. The formation site of the comets in the Oort cloud was likely the extended nebula accretion disc reaching from about 15 to 500 AU from the forming protosun. Comets which escape from the Oort cloud contribute to the flux of interstellar comets, though capture of interstellar comets by the solar system is extremely unlikely. The existence of Oort clouds around other main sequence stars has been suggested by the detection by the IRAS spacecraft of cool dust shells around about 10% of nearby stars.