The Distributed CO in Comet Halley

Examination of the spatial distribution of CO intensity of Comet Halley indicates that a large fraction of CO originates from the refractory organic component in the coma, rather than directly from the volatiles in the nucleus. Based on the fluffy aggregate interstellar dust comet model, we have estimated the upper limits of the total amount of CO provided by coma dust. The implications from the comparison of the predicted results with the observed value have been discussed. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Chemical Composition of Interstellar Matter at the Solar Location

The Local Interstellar Cloud (LIC) surrounds the Solar System and sets the boundary conditions for the heliosphere. Using both in situ and absorption line data towards ε CMa we are able to constrain both the ionization and the gas phase abundances of the LIC gas at the Solar Location. We find that the abundances are consistent with all of the carbonaceous dust grains having been destroyed, and in fact with a supersolar abundance of C. The constituents of silicate grains, Si, Mg, and Fe, appear to be sub-solar, indicating that silicate dust is present in the LIC. N, O and S are close to the solar values.     

Distributed Sources in Comets

The distribution of some molecules and radicals (H₂CO, CO, HNC, CN,?…) in the atmosphere of several comets cannot be explained only by a direct sublimation from the nucleus, or by gas phase processes in the coma. Such molecules are in part the result of a distributed source in the coma, which could be the photo and thermal degradation of dust. We present a review of the degradation processes and discuss possible interpretations of the observations in which the degradation of solid complex organic material in dust particles seems to play a major role. The knowledge of such gas production mechanisms provides important clues on the chemical nature of the refractory organic material contained in comet nuclei.     

On the Flux of Water and Minor Volatiles from the Surface of Comet Nuclei

Surface temperature and the available effective energy strongly influence the mass flux of H₂O and minor volatiles from the nucleus. We perform computer simulations to model the gas flux from volatile, icy components in porous ice-dust surfaces, in order to better understand results from observations of comets. Our model assumes a porous body containing dust, one major ice component (H₂O) and up to eight minor components of higher volatility (e.g. CO, CH₄, CH₃OH, HCN, C₂H₂, H₂S), The body's porous structure is modeled as a bundle of tubes with a given tortuosity and an initially constant pore diameter. Heat is conducted by the matrix and carried by the vapors. The model includes radially inward and outward flowing vapor within the body, escape of outward flowing gas from the body, complete depletion of less volatile ices in outer layers, and recondensation of vapor in deeper, cooler layers. From the calculations we obtain temperature profiles and changes in relative chemical abundances, porosity and pore size distribution as a function of depth, and the gas flux into the interior and into the atmosphere for each of the volatiles at various positions of the body in its orbit. In this paper we relate the observed relative molecular abundances in the coma of Comet C/1995 O1 (Hale-Bopp) and of Comet 46P/Wirtanen to molecular fluxes at the surface calculated from our model. This revised version was published online in June 2006 with corrections to the Cover Date.     

The organic matter of comet Halley as inferred by joint gas phase and solid phase analyses

During encounters with comet Halley, the experiment PICCA onboard GIOTTO measured the gas phase organic ion composition of the coma and the experiment PUMA onboard VEGA-1 measured the dust composition. Joining both results, we obtain a consistent picture of the parent organic matter from which dust and gas is produced. One recognizes a complex unsaturated polycondensate, which splits during coma-formation into the more refractory C=C,C-N-containing dust part, and the more volatile C=C,C-O-containing gas part. The responsible exothermal chemical reactions, which are triggered by the sunlight, may play a major role in the dynamics of coma formation.This paper is a shortened and upgraded version of Krueger, F.R., Korth, A., and Kissel, J.: 1989, in S. Chang (ed.) Proc. of the ROSETTA Conf., Milpitas CA, January 1989, submitted.     

Comets and Chemical Composition

It is commonly believed that comets are made of primordial material. As a consequence, they can reveal more information about the origin of our solar system. To interpret the coma composition measurements of comet Churyumov–Gerasimenko that will be collected by the Rosetta mission, models of the coma chemistry have to be constructed. However, programming the chemistry of a cometary coma is extremely complex due to the large number of species and reactions involved. Moreover, such a program needs to be very flexible as one may want to extend, change, or update the set of species, reactions, and reaction rates. Therefore, we developed software to manage a database of species and reactions and to generate code automatically to compute source/loss balances. This database includes the data from the UMIST database and the ion–molecule reactions collected by V.G. Anicich. To use all these databases together, a lot of practical problems need to be solved, but the result is an enormous source of information about chemical reactions that can be used in chemical models, not only for comets but also for other applications.     

OB Associations, Wolf–Rayet Stars, and the Origin of Galactic Cosmic Rays

We have measured the isotopic abundances of neon and a number of other species in the galactic cosmic rays (GCRs) using the Cosmic Ray Isotope Spectrometer (CRIS) aboard the ACE spacecraft. Our data are compared to recent results from two-component (Wolf–Rayet material plus solar-like mixtures) Wolf–Rayet (WR) models. The three largest deviations of galactic cosmic ray isotope ratios from solar-system ratios predicted by these models, ¹²C/¹⁶O, ²²Ne/²⁰Ne, and ⁵⁸Fe/⁵⁶Fe, are very close to those observed. All of the isotopic ratios that we have measured are consistent with a GCR source consisting of ∼20% of WR material mixed with ∼80% material with solar-system composition. Since WR stars are evolutionary products of OB stars, and most OB stars exist in OB associations that form superbubbles, the good agreement of our data with WR models suggests that OB associations within superbubbles are the likely source of at least a substantial fraction of GCRs. In previous work it has been shown that the primary ⁵⁹Ni (which decays only by electron-capture) in GCRs has decayed, indicating a time interval between nucleosynthesis and acceleration of >10⁵ y. It has been suggested that in the OB association environment, ejecta from supernovae might be accelerated by the high velocity WR winds on a time scale that is short compared to the half-life of ⁵⁹Ni. Thus the ⁵⁹Ni might not have time to decay and this would cast doubt upon the OB association origin of cosmic rays. In this paper we suggest a scenario that should allow much of the ⁵⁹Ni to decay in the OB association environment and conclude that the hypothesis of the OB association origin of cosmic rays appears to be viable.     

The Local Bubble and Interstellar Material Near the Sun

The properties of interstellar matter at the Sun are regulated by our location with respect to a void in the local matter distribution, known as the Local Bubble. The Local Bubble (LB) is bounded by associations of massive stars and fossil supernovae that have disrupted dense interstellar matter (ISM), driving low density intermediate velocity ISM into the void. The Sun appears to be located in one of these flows of low density material. This nearby interstellar matter, dubbed the Local Fluff, has a bulk velocity of ∼19 km s⁻¹ in the local standard of rest. The flow is coming from the direction of the gas and dust ring formed where the Loop I supernova remnant merges into the LB. Optical polarization data suggest that the local interstellar magnetic field lines are draped over the heliosphere. A longstanding discrepancy between the high thermal pressure of plasma filling the LB and low thermal pressures in the embedded Local Fluff cloudlets is partially mitigated when the ram pressure component parallel to the cloudlet flow direction is included.     

On the Prediction of CO Outgassing from Comets Hale-Bopp and Wirtanen

The gas flux from a volatile icy-dust mixture is computed using a comet nucleus thermal model in order to study the evolution of CO outgassing during several apparitions from long-period Comet Hale-Bopp and short-period Comet Wirtanen. The comet model assumes a spherical, porous body containing a dust component, one major ice component (H₂O), and one minor ice component of higher volatility (CO). The initial chemical composition is assumed to be homogeneous. The following processes are taken into account: heat and gas diffusion inside the rotating nucleus; release of outward diffusing gas from the comet nucleus; chemical differentiation by sublimation of volatile ices in the surface layers and recondensation of gas in deeper, cooler layers. A 2-D time dependent solution is obtained through the dependence of the boundary conditions on the local solar illumination as the nucleus rotates. The model for Comet Hale-Bopp was compared with observational measurements (Biver et al., 1999). The best agreement was obtained for a model with amorphous water ice and CO, assuming that a part of the latter is trapped by the water ice, another part is condensed as an independent ice phase. The model confirms that sublimation of CO ice at large heliocentric distance produces a gradual increase in the comet's activity as it approaches the Sun. Crystallization of amorphous water ice begins at 7 AU from the Sun, but no outbursts were found. Seasonal effects and thermal inertia of the nucleus material lead to larger CO outgassing rates as the comet recedes from the Sun. In the second part of this work the model was run with the orbital parameters of Comet Wirtanen. Unlike Comet Hale-Bopp, the predicted CO outgassing from Comet Wirtanen is almost constant throughout its orbit. Such behavior can be explained by a thermally evolved and chemically differentiated comet nucleus. This revised version was published online in June 2006 with corrections to the Cover Date.     

Changes in the Structure of Comet Nuclei Due to Radioactive Heating

The initial structure of a comet nucleus is most probably a homogeneous, porous, fine-grained mixture of dust and ices, predominantly water. The water ice is presumably amorphous and includes considerable fractions of occluded gases. This structure undergoes significant changes during the early evolution of the nucleus at large heliocentric distances, due to internal radiogenic heating. Structural changes occur mainly as a result of gas flow through the porous medium: the gas pressure that builds up in the interior is capable of breaking the fragile structure and altering the pore sizes and porosity. These effects are modeled and followed numerically, testing a large number of parameters. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Composition of Cosmic Rays and the Mixing of the Interstellar Medium

The differences between the composition of Galactic cosmic rays and that of the interstellar medium are manifold, and they contain a wealth of information about the varying processes that created them. These differences reveal much about the initial mixing of freshly synthesized matter, the chemistry and differentiation of the interstellar medium, and the mechanisms and environment of ion injection and acceleration. Here we briefly explore these processes and show how they combine to create the peculiar, but potentially universal, composition of the cosmic rays and how measurements of the composition can provide a unique measure of the mixing ratio of the fresh supernova ejecta and the old interstellar medium in this initial phase of interstellar mixing. In particular, we show that the major abundance differences between the cosmic rays and the average interstellar medium can all result from cosmic ray ion injection by sputtering and scattering from fast refractory oxide grains in a mix of fresh supernova ejecta and old interstellar material. Since the bulk of the Galactic supernovae occur in the cores of superbubbles, the bulk of the cosmic rays are accelerated there out of such a mix. We show that the major abundance differences all imply a mixing ratio of the total masses of fresh supernova ejecta and old interstellar material in such cores is roughly 1 to 4. That means that the metallicity of ∼3 times solar, since the ejecta has a metallicity of ∼8 times that of the present interstellar medium.     

From Coma Abundances to Nucleus Composition

A major goal of comet research is to determine conditions in the outer solar nebula based on the chemical composition and structure of comet nuclei. The old view was to use coma abundances directly for the chemical composition of the nucleus. However, since the composition of the coma changes with heliocentric distance, r, the new view is that the nucleus composition msut be determined from analysis of coma mixing ratios as a function of r. Taking advantage of new observing technology and the early detection of the very active Comet Hale-Bopp (C/1995 O1) allows us to determine the coma mixing ratios over a large range of heliocentric distances. In our analysis we assume three sources for the coma gas: (1) the surface of the nucleus (releasing water vapor), (2) the interior of the porous nucleus (releasing many species more volatile than water), and (3) the distributed source (releasing gases from ices and hydrocarbon polycondensates trapped and contained in coma dust). Molecules diffusing inside the nucleus are sublimated by heat transported into the interior. The mixing ratios in the coma are modeled assuming various chemical compositions and structural parameters of the spinning nucleus as it moves in its orbit from large heliocentric distance through perihelion. We have combined several sets of observational data of Comet Hale-Bopp for H₂O (from OH) and CO, covering the spectrum range from radio to UV. Many inconsistencies in the data were uncovered and reported to the observers for a reanalysis. Since post-perihelion data are still sparse, we have combined pre- and post-perihelion data. The resulting mixing ratio of CO relative to H₂O as a function of r is presented with a preliminary analysis that still needs to be expanded further. Our fit to the data indicates that the total CO release rate (from the nucleus and distributed sources) relative to that of H₂O is 30% near perihelion. This revised version was published online in June 2006 with corrections to the Cover Date.     

The Rosetta Alpha Particle X-Ray Spectrometer (APXS)

The Alpha Particle X-Ray Spectrometer (APXS) is a small instrument to determine the elemental composition of a given sample. For the ESA Rosetta mission, the periodical comet 67P/Churyumov-Gerasimenko was selected as the target comet, where the lander PHILAE (after landing) will carry out in-situ observations. One of the instruments onboard is the APXS to make measurements on the landing site. The APXS science goal is to provide basic compositional data of the comet surface. As comets consist of a mixture of ice and dust, the dust component can be characterized and compared with known meteoritic compositions. Various element ratios can be used to evaluate whether chemical fractionations occurred in cometary material by comparing them with known chondritic material. To enable observations of the local environment, APXS measurements of several spots on the surface and one spot as function of temperature can be made. Repetitive measurements as function of heliocentric distance can elucidate thermal processes at work. By measuring samples that were obtained by drilling subsurface material can be analyzed. The accumulated APXS data can be used to shed light on state, evolution, and origin of 67P/Churyumov- Gerasimenko.     

Late Stages of Stellar Evolution

A large fraction of ISO observing time was used to study the late stages of stellar evolution. Many molecular and solid state features, including crystalline silicates and the rotational lines of water vapour, were detected for the first time in the spectra of (post-)Asymptotic Giant Branch (AGB) stars. Their analysis has greatly improved our knowledge of stellar atmospheres and circumstellar environments. A surprising number of objects, particularly young planetary nebulae with Wolf-Rayet (WR) central stars, were found to exhibit emission features in their ISO spectra that are characteristic of both oxygen-rich and carbon-rich dust species, while far-IR observations of the PDR around NGC 7027 led to the first detections of the rotational line spectra of CH and CH⁺. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Structural evolution of cometary surfaces

Comets with a high content of organics and light molecules are expected under cosmic radiation to gain a relatively unreactive crust and less volatile material to some ten metres deep. Interstellar dust impacts act to loosen and turn over 1 cm of the surface. We discuss how far this accords with observations of cometary dust halos and new versus old comets. Two key material properties have emerged from recent studies. Firstly, the source of cometary volatiles is not ice in the sense of material with a single sublimation energy. Secondly, the particulates are not simply mineral dust but include much organic material, some of which undergoes chemical processing and exchanges with the gaseous environment. Consistent with these properties, a coherent crust rather than a mantle of loose grains would build up to cover much of the nucleus of periodic comets. It would consolidate by cooking in the solar radiation, especially at peak temperatures around perihelion. There are two disjoint surface phases: one of volatile material, the other the refractory crust, the former deepening into crater-like hollows over successive apparitions. The transition to non-volatile crust is unstable, subject to competing consolidation and disruption processes, and sensitive to seasonal changes. A comet dims and becomes asteroidal as the inert crust extends over the erosion craters, and may only be rejuvenated via collision with a boulder-sized impactor or perturbation of the orbit to smaller perihelion distance.     

Origins of Cometary Materials

In this introductory presentation, material is categorized according to our state of knowledge: What do we know, what do we think we know but don’t know certainly, and what do we not know but often describe it as if it were a well-established fact about comets, their nuclei, their composition, and processes within comets and their nuclei. The material is presented not with the intend to criticize laboratory work simulating condition in comet nuclei, or observers analyzing their observations, nor modelers using data from both these sources to improve our understanding and make predictions. The intent is to provoke discussion and dialog between these groups to avoid overstating the results. What is a Comet? A comet is a diffuse appearing celestial phenomenon moving in an orbit about the Sun. The central body, the nucleus, is composed of ice and dust. It is the source of all cometary activity, including comae and tails. We distinguish between molecular (including atoms and ions) and dust comae. At heliocentric distances of about 1 AU and less, the hydrogen coma typically has dimensions larger than the Sun. The tails are composed of dust, neutral atoms and molecules, and plasma.     

Stellar flares

Radio and X-ray observations of stellar flares provide the most direct probes of energy relaase particle acceleration, and energy transport on stars other than the Sun. In this review, the observational basis for our understanding of the flare phenomenon on other stars is briefly described and outstanding interpretive and theoretical issues are discussed. I shall confine my attention to objects which are solar-like, to the extent that they possess deep convective envelopes and display activity which is presumed to be magnetic in origin. These include pre-main sequence objects, classical flare stars, and close binaries. Future directions are briefly discussed.     

The Cool Interstellar Medium

Infrared spectroscopy and photometry with ISO covering most of the emission range of the interstellar medium has led to important progress in the understanding of the physics and chemistry of the gas, the nature and evolution of the dust grains and also the coupling between the gas and the grains. We review here the ISO results on the cool and low-excitation regions of the interstellar medium, where T _gas≲ 500 K, n _H∼ 100–10⁵ cm⁻³ and the electron density is a few 10⁻⁴. JEL codes: D24, L60, 047 Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Ptolemy – an Instrument to Measure Stable Isotopic Ratios of Key Volatiles on a Cometary Nucleus

A fundamental goal of cometary studies is to determine the exact relationship between these bodies and the Solar System – the question(s) can be summarised as follows: did comets originate during the same events that spawned the Sun and planets, are they more primitive bodies that record a pre-solar history, or are they interstellar materials collected in relatively more recent times? Now, whatever the origin of comets, it is entirely possible that they could, in part, contain interstellar or pre-solar components – indeed, it seems rather likely in light of the fact that primitive meteorites contain such entities. These particular components are likely to be refractory (dust, macromolecular organic complexes, etc.). Of more relevance to the issues above are the volatile constituents, which make up the bulk of a comet's mass. Since these materials, by their very nature, volatilise during perihelion passage of a comet they can, in some instances, be detected and measured spectroscopically. Perhaps the most useful species for isotopic investigations are C₂, HCN and CN. Unfortunately, spectroscopic measurements can only currently be made with accuracies of ±10 to ±20%. As such it is very often not practical to conclude anything further than the fact that isotopic measurements are compatible with ‘`solar’' values, which tends to imply an origin from the margins of the solar accretion disk. But there is another problem with the spectroscopic measurements – since these are made on gaseous species in the coma (and relatively minor species at that) it is impossible to be certain that these represent the true nuclear values. In other words, if the processes of sublimation, active jetting, and photochemistry in the coma impart isotopic fractionation, the spectroscopic measurements could give a false impression of the true isotope ratios. What is required is an experiment capable of measuring isotopic ratios at the very surface of a comet. Herein we describe the Ptolemy instrument, which is included on the Philae lander as part of the Rosetta mission to 67P/Churyumov-Gerasimenko. The major objective of Ptolemy is a detailed appraisal of the nature and isotopic compositions of all materials present at the surface of a comet.     

Presolar Isotopic Signatures in Meteorites and Comets: New Insights from the Rosetta Mission to Comet 67P/Churyumov–Gerasimenko

Comets are considered the most primitive planetary bodies in our Solar System, i.e., they should have best preserved the solid components of the matter from which our Solar System formed. ESA’s recent Rosetta mission to Jupiter family comet 67P/Churyumov–Gerasimenko (67P/CG) has provided a wealth of isotope data which expanded the existing data sets on isotopic compositions of comets considerably. In this paper we review our current knowledge on the isotopic compositions of H, C, N, O, Si, S, Ar, and Xe in primitive Solar System materials studied in terrestrial laboratories and how the Rosetta data acquired with the ROSINA (Rosetta Orbiter Sensor for Ion and Neutral Analysis) and COSIMA (COmetary Secondary Ion Mass Analyzer) mass spectrometer fit into this picture. The H, Si, S, and Xe isotope data of comet 67P/CG suggest that this comet might be particularly primitive and might have preserved large amounts of unprocessed presolar matter. We address the question whether the refractory Si component of 67P/CG contains a presolar isotopic fingerprint from a nearby Type II supernova (SN) and discuss to which extent C and O isotope anomalies originating from presolar grains should be observable in dust from 67P/CG. Finally, we explore whether the isotopic fingerprint of a potential late SN contribution to the formation site of 67P/CG in the solar nebula can be seen in the volatile component of 67P/CG.