Effect of boron doping on waterproof and dielectric properties of polyborosiloxane coating on SiO2f/SiO2 composites

A hydrophobic coating of the silica fiber reinforced silica composites (SiO_2f/SiO₂) was synthesized by sol-gel method using methyltriethoxy-silane (MTES) and boric acid (B(OH)₃) as raw materials. The relationship among boron doping, chemical structure of precursors and durability of hydrophobic coatings was discussed. The Si-O-B and methyl groups were successfully introduced in the gel precursors according to the FT-IR and XPS results. The resins were filled in the internal and surface holes of the SiO_2f/SiO₂ composites partially or completely, which is beneficial to reduce the physical adsorption of the moisture. In addition, hydroxyl groups of the SiO_2f/SiO₂ composites reacted with the resins and hydrophobic methyl groups were introduced, leading to the reduction of the chemical adsorption of water. Also, the boron doping was beneficial to enhancing the physical cross-linking between the coating and the SiO_2f/SiO₂ composites, and improved the adhesion of the coating to the substrate. The results show that the optimal hydrophobic coating with contact angle 130.33°, moisture absorption 0.33% and adhesion level 1 is obtained when the molar ratio of MTES to B(OH)₃ is 10:4. The real permittivity of M10B4 is constant in the range of 2.32–2.51 and the dielectric tangent loss is constant in the range of 5.5 × 10⁻⁴–8.7 × 10⁻³. The hydrophobic coating has excellent dielectric properties.     

Diamond wheel grinding characteristics of 3D orthogonal quartz fiber reinforced silica ceramic matrix composite

Fiber-reinforced silica ceramic matrix composites (SiO_2f/SiO₂) have gained extensive attention in recent years for its applications in aeronautics field such as radar radome and window. However, the machining properties and mechanism of the material remain unclear. The features and mechanical properties of the material itself have a significant influence on both its machining characteristics and surface integrity. Thus, a full-factor grinding experiment is conducted using a 3D orthogonal SiO_2f/SiO₂ aiming to obtain its machining characteristics. The effects of grinding parameters and tools on the grinding force, surface roughness, and material damage type are investigated using a dynamometer, Scanning Electron Microscope (SEM), and Acoustic Emission (AE) analysis. The AE frequency band is analyzed, and a semi-analytical force model is established to study the difference between a single grain and wheel grinding. It was found that the changes in surface roughness correlate with the changes in grinding force, with fiber fracture being the main reason behind the increase in grinding force. Finally, the material removal mechanism was studied based on the AE analysis. It was found that the removal mechanism is fiber fracture dominated with matrix crack and debonding, and the primary sources of energy consumption are fiber fracture and friction.     

低温耐油蒙脱土/ 氢化丁腈的制备和性能研究

采用热机械共混的方法,制备了有机蒙脱土(OMMT)/低温氢化丁腈(HNBR)的橡胶材料.热混炼工艺增强了OMMT在氢化丁腈中的分散性能,从而获得了性能优异的HNBR橡胶.SAXS、SEM和TEM照片展示了OMMT主要以插层结构和少量聚集体存在HNBR橡胶中.DSC曲线和压缩耐寒系数测试表明,少量添加OMMT,可在不明显限制HNBR橡胶分子链的运动条件下,提高HNBR填料网络密度,增加橡胶内部的网络协同密度,从而增强HNBR橡胶的低温弹性.少量OMMT( ＜10 phr)可大幅度提高HNBR橡胶的力学性能,但随着OMMT添加量继续增加,橡胶力学性能提高不明显.DMA测试表明,添加OMMT可提高其和HNBR橡胶的结合力及分散效果,成为增强HNBR橡胶力学性能的主要原因;与纯HNBR相比可提高橡胶的耐油性能.因此OMMT/HNBR复合材料是一种具有低温液压密封应用前景的橡胶材料.     

弯曲纤维对SiO2f/SiO2复合材料拉伸强度的影响

以SiO_(2f)织物作为增强相,采用循环浸渍固化工艺,制备了SiO_(2f)/SiO_2复合材料。在制备过程中,通过对SiO_(2f)织物进行模压处理,使SiO_(2f)呈现出不同程度的弯曲,测定了纤维弯曲后复合材料的拉伸强度,研究了纤维弯曲时复合材料的断裂过程。结果表明:弯曲纤维将导致复合材料的拉伸强度下降,最低拉伸强度仅为5.5 MPa,纤维弯曲时复合材料的断裂过程为逐层断裂,断裂应变增加,最大断裂应变达到1.19%。     

Microstructure and high-temperature oxidation behavior of plasma-sprayed Si/Yb2SiO5 environmental barrier coatings

An environmental barrier coating (EBC) consisting of a silicon bond coat and an Yb₂SiO₅ top-coat was sprayed on a carbon fibers reinforced SiC ceramic matrix composite (CMC) by atmospheric plasma spray (APS). The microstructure of the coating annealed at 1300 °C and its high-temperature oxidation behavior at 1350 °C were investigated. The significant mass loss of silica during the plasma spray process led to the formation of Yb₂SiO₅ and Yb₂O₃ binary phases in the top-coat. Eutectics of Yb₂SiO₅ and Yb₂O₃ were precipitated in the top-coat, and channel cracks were formed in the top-coat after 20 h annealing because of the mismatch between the coefficients of thermal expansion (CTEs) of Yb₂SiO₅ and the SiC substrate. The EBC effectively improved the oxidation resistance of the CMC substrate. The channel cracks in the Yb₂SiO₅ top-coat provided inward diffusion channels for oxygen and led to the formation of oxidation delamination cracks in the bond coat, finally resulting in spallation failure of the coating after 80 h oxidation.     

石墨烯/二氧化硅三维杂化材料的制备及其在改性酚醛泡沫中的应用

为了得到结构和力学性能良好的酚醛泡沫,利用原位生成的方法制备了石墨烯/二氧化硅(GNPs/SiO_2)杂化材料,并将其用于酚醛泡沫的制备当中。对杂化材料进行了红外光谱分析,透射电镜以及X射线衍射分析,验证了石墨烯表面SiO_2球体(粒径在150~180 nm)的存在。对泡沫的结构和压缩性能进行对比分析,发现三维杂化材料相比二维石墨烯能够更好的改善酚醛泡沫的泡孔结构,杂化材料为0.5wt%时,GNPs/SiO_2改性酚醛泡沫的泡孔尺寸更小,结构更均匀;同时杂化材料改性酚醛泡沫表现出更优异的力学性能,其压缩强度和弹性模量分别达到0.22和4.1 MPa,比纯酚醛泡沫分别提高了91%和86%。     

Non-linear resonant excitation of whistler mode waves in the Earth's ionosphere

We examine the resonant non-linear interaction in the Earth's ionosphere of two powerful high frequency radio beams with frequencies f ₁ and f ₂ (both larger than the plasma frequency at F2_max) and wave numbers k ₁ and k ₂ such that a whistler mode wave can be excited with a frequency f ₃ = f ₁ — f ₂ and a wave number k ₃ = k ₁ – k ₂. The feasibility of an effective ground based installation, sited at low latitudes, is discussed and the field strength of the wave emerging from a 10 km wide ionospheric region illuminated by the beams is evaluated for a range of transmitted frequencies, beam orientations and plasma frequencies in the interaction region. It is suggested that the longitude dependence of the enhancement of VLF noise bands detected by the Ariel 3 satellite may be due to a non-linear interaction of this type between any two or more medium wavelength signals from areas where there is a high concentration of commercial broadcasting stations, such as the NE region of the U.S.A.     

Accurate measurements of local skin friction coefficient using hot-wire anemometry

The practicality and accuracy of many existing methods of local skin friction measurement suffer when the boundary layer flow under consideration is non-canonical. Such shortcomings are exacerbated in three-dimensional flows, by the necessity to map local c_f over a wider area in order to characterise fully the contribution to global skin friction. These problems have led the authors to seek novel experimental methods of c_f measurement. The technique proposed herein utilises velocity measurements made using hot-wire anemometry combined with accurate positioning of the sensor element in respect to the test surface. In essence it is proposed that the local skin friction can be evaluated via a single velocity measurement made at a known wall-normal distance within the linear region of the viscous sublayer. This technique relies on accurate probe positioning, and two methods of achieving this are outlined. A study of the hot-wire characteristics in near-wall proximity has revealed a previously unnoticed feature corresponding to probe–wall contact. It is shown that this anomaly can be used as a positional flag to accurately locate the aerodynamic origin of the hot-wire sensor. A second technique using a laser triangulation displacement sensor is also outlined. Both positional techniques are shown to offer positioning to a sufficient level of accuracy for the proposed c_f measurement technique. Single-point local c_f measurement is tested experimentally, demonstrating the improved repeatability and standard error as predicted by initial error analysis. In this way it is shown that a single $\text{90}\text{s}$ velocity sample coupled with accurate wall positioning can define local c_f to a standard error of σ_cf≈1.0%. Analysis of error contributions reveals that longer sampling periods can realise even greater accuracy. The proposed technique is also used to measure local c_f in a three-dimensional boundary layer where micro-vortex generators have introduced large-scale spanwise distortions. This is an example of an application in a non-canonical boundary layer, and initial results show that the method is capable of providing repeatable comparative spanwise-averaged skin friction results to within approximately ±1%. The technique is immediately applicable to researchers using hot-wire anemometry in low Reynolds number flow over electrically non-conductive test surfaces.     

不同填料对氢化丁腈橡胶耐烧蚀材料性能的影响

以氢化丁腈橡胶(HNBR)为基体,分别添加有机纤维1、有机纤维2、碳纤维粉和纳米无机物,通过形貌分析和X射线能谱仪(EDS),研究不同用量下不同烧蚀填料对HNBR烧蚀性能及力学性能的影响,发现在该试验条件下,添加有机纤维1和纳米无机物的HNBR能获得较好的烧蚀性能;添加有机纤维1时HNBR材料的力学性能很差,纳米无机物的加入对其力学性能影响不大;添加有机纤维2和碳纤维粉的HNBR力学性能变化不大,但烧蚀性能不理想。     

富氢/富氧燃气同轴剪切气-气喷嘴性能仿真分析

采用正交试验设计方法对富氢/富氧燃气同轴剪切气-气喷嘴设计参数氧压降比、燃氧速度比、氧喷嘴出口壁厚进行组合,数值模拟单喷嘴燃烧室燃烧流场,研究喷嘴设计参数及参数之间的交互作用对燃烧性能和燃烧室热载性能的影响,评价指标为燃烧长度、燃烧室壁面平均燃气温度和喷注面板平均燃气温度.仿真结果表明,燃氧速度比对燃烧与热载有显著影响,氧压降比与氢氧燃氧速度比的交互作用影响明显,分析结果对气-气喷嘴试验设计有重要指导意义.      

Small scale structure of magnetospheric electron density through on-line tracking of plasma resonances

The plasma resonance phenomena observed at f _pe, nf _ce, and f _qn by the GEOS-1 S-301 relaxation sounder are identified through a pattern recognition software process implemented in a mini-computer which receives on-line the compressed data. First, this processing system distributes in real time f _pe and f _ce measurements to the ground media. Second, it drives and controls automatically the S-301 on-board experiment by sending appropriate telecommands: the tracking of resonances is performed by shortening the frequency sweeps to a narrow range centered on the resonance location. Examples of such tracking sequences are presented, exhibiting sampling rates of the electron density measurements from once every 22 s (slowest rate) to once every 86 ms (highest rate available). The results give evidence of the existence of very small scale structures in the magnetospheric density, having characteristic sizes of the order of a few 10² m or/and a few 10^-1 s. The relative amplitude of these density fluctuations is typically 1%. Because of satellite spinning, fixed frequency sounding sequences allow to measure in a few seconds the directivity features of the plasma resonance signals. Examples of directional patterns in the plane perpendicular to the geomagnetic field are presented: the electrostatic nature of the waves received at f _pe, nf _ce, and f _qe being consistent with these patterns, the corresponding k vector orientations become available. The Bernstein modes properties are used to interpret the cf _ce and f _qe results.     

Radio emissions from the outer heliosphere

For nearly fifteen years the Voyager 1 and 2 spacecraft have been detecting an unusual radio emission in the outer heliosphere in the frequency range from about 2 to 3 kHz, Two major events have been observed, the first in 1983–84 and the second in 1992–93. In both cases the onset of the radio emission occurred about 400 days after a period of intense solar activity, the first in mid-July 1982, and the second in May–June 1991. These two periods of solar activity produced the two deepest cosmic ray Forbush decreases ever observed. Forbush decreases are indicative of a system of strong shocks and associated disturbances propagating outward through the heliosphere. The radio emission is believed to have been produced when this system of shocks and disturbances interacted with one of the outer boundaries of the heliosphere, most likely in the vicinity of the the heliopause. The emission is believed to be generated by the shock-driven Langmuir-wave mode conversion mechanism, which produces radiation at the plasma frequency (f _p ) and at twice the plasma frequency (2f _p ). From the 400-day travel time and the known speed of the shocks, the distance to the interaction region can be computed, and is estimated to be in the range from about 110 to 160 AU.Abbreviations PWS Plasma Wave Subsystem - AU Astronomical Unit - DSN Deep Space Network - NASA National Aeronautics and Space Administration - GMIR Global Merged Interaction Region - MHD Magnetohydrodynamic - CME coronal mass ejection - f _p plasma frequency - R radial distance - AGC automatic gain control     

Properties of Ground Level Enhancement Events and the Associated Solar Eruptions During Solar Cycle 23

Solar cycle 23 witnessed the most complete set of observations of coronal mass ejections (CMEs) associated with the Ground Level Enhancement (GLE) events. We present an overview of the observed properties of the GLEs and those of the two associated phenomena, viz., flares and CMEs, both being potential sources of particle acceleration. Although we do not find a striking correlation between the GLE intensity and the parameters of flares and CMEs, the solar eruptions are very intense involving X-class flares and extreme CME speeds (average ～2000?km/s). An M7.1 flare and a 1200?km/s CME are the weakest events in the list of 16 GLE events. Most (80?%) of the CMEs are full halos with the three non-halos having widths in the range 167 to 212?degrees. The active regions in which the GLE events originate are generally large: 1290?msh (median 1010?msh) compared to 934?msh (median: 790?msh) for SEP-producing active regions. For accurate estimation of the CME height at the time of metric type?II onset and GLE particle release, we estimated the initial acceleration of the CMEs using flare and CME observations. The initial acceleration of GLE-associated CMEs is much larger (by a factor of 2) than that of ordinary CMEs (2.3?km/s² vs. 1?km/s²). We confirmed the initial acceleration for two events for which CME measurements are available in the inner corona. The GLE particle release is delayed with respect to the onset of all electromagnetic signatures of the eruptions: type?II bursts, low frequency type?III bursts, soft X-ray flares and CMEs. The presence of metric type?II radio bursts some 17?min (median: 16?min; range: 3 to 48?min) before the GLE onset indicates shock formation well before the particle release. The release of GLE particles occurs when the CMEs reach an average height of ～3.09?R _s (median: 3.18?R _s ; range: 1.71 to 4.01?R _s ) for well-connected events (source longitude in the range W20–W90). For poorly connected events, the average CME height at GLE particle release is ～66?% larger (mean: 5.18?R _s ; median: 4.61?R _s ; range: 2.75–8.49?R _s ). The longitudinal dependence is consistent with shock accelerations because the shocks from poorly connected events need to expand more to cross the field lines connecting to an Earth observer. On the other hand, the CME height at metric type?II burst onset has no longitudinal dependence because electromagnetic signals do not require magnetic connectivity to the observer. For several events, the GLE particle release is very close to the time of first appearance of the CME in the coronagraphic field of view, so we independently confirmed the CME height at particle release. The CME height at metric type?II burst onset is in the narrow range 1.29 to 1.8?R _s , with mean and median values of 1.53 and 1.47?R _s . The CME heights at metric type?II burst onset and GLE particle release correspond to the minimum and maximum in the Alfvén speed profile. The increase in CME speed between these two heights suggests an increase in Alfvénic Mach number from?2 to?3. The CME heights at GLE particle release are in good agreement with those obtained from the velocity dispersion analysis (Reames in Astrophys. J. 693:812, 2009a; Astrophys. J. 706:844, 2009b) including the source longitude dependence. We also discuss the implications of the delay of GLE particle release with respect to complex type?III bursts by ～18?min (median: 16?in; range: 2 to 44?min) for the flare acceleration mechanism. A?similar analysis is also performed on the delay of particle release relative to the hard X-ray emission.     

Corrosion Inhibition of SiC_p/5A06 Aluminum Metal Matrix Composite by Cerium Conversion Treatment

This article studies the effects of the CeCl₃ concentrations in conversion solutions with and without addition of NaCl, pH-values of conversion solution, drying temperature, time and temperature of immersion on the Ce-conversion coatings for corrosion protection of the SiC_p/5A06 Al-MMC and 5A06 Al-alloy in the 3.5% NaCl aqueous solution at room temperature. Potentiodynamic polarization tests reveal that the Ce-conversion treatment could markedly improve the pitting corrosion resistance of the composite and the matrix alloy in chloride containing environment. The best corrosion resistance effects are obtained for the samples treatment in 1‰ CeCl₃·7H₂O/ 3.5% NaCl solution at 45 °C for 60 min, followed by drying at 100 °C for 30 min. Examinations by means of scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) indicate that this behavior is due to the precipitation of Ce-oxides/hydroxides on the cathodic intermetallics and the Al-oxide film on the rest of the metal matrix.     

RANS simulations on combustion and emission characteristics of a premixed NH3/H2 swirling flame with reduced chemical kinetic model

Ammonia (NH₃) is considered as a potential alternative carbon free fuel to reduce greenhouse gas emission to meet the increasingly stringent emission requirements. Co-burning NH₃ and H₂ is an effective way to overcome ammonia’s relative low burning velocity. In this work, 3D Reynolds Averaged Navier-Stokes (RANS) numerical simulations are conducted on a premixed NH₃/H₂ swirling flame with reduced chemical kinetic mechanism. The effects of (A) overall equivalence ratio Φ and (B) hydrogen blended molar fraction X_H2 on combustion and emission characteristics are examined. The present results show that when 100%NH₃-0%H₂-air are burnt, the NO emission and unburned NH₃ of at the swirling combustor outlet has the opposite varying trends. With the increase of Φ, NO emission is found to be decreased, while the unburnt ammonia emission is increased. NH₂ → HNO, NH → HNO and HNO → NO sub-paths are found to play a critical role in NO formation. Normalized reaction rate of all these three sub-paths is shown to be decreased with increased Φ. Hydrogen addition is shown to significantly increase the laminar burning velocity of the mixed fuel. However, adding H₂ does not affect the critical equivalence ratio corresponding to the maximum burning velocity. The emission trend of NO and unburnt NH₃ with increased Φ is unchanged by blending H₂. NO emission with increased X_H2 is increased slightly less at a larger Φ than that at a smaller Φ. In addition, reaction rates of NH₂ → HNO and HNO → NO sub-paths are decreased with increased X_H2, when Φ is larger. Under all tested cases, blending H₂ with NH₃ reduces the unburned NH₃ emission, especially for rich combustion conditions. In summary, the present work provides research finding on supporting applying ammonia with hydrogen blended in low-emission gas turbine engines.     

Joining of SiO2 ceramic and TC4 alloy by nanoparticles modified brazing filler metal

Nano-Al₂O₃ particles modified AgCuNi filler was adopted to braze the SiO₂ ceramic and TC4. The effects of filler size as well as the brazing temperature on the interfacial microstructure and mechanical property of the joints were investigated. Nanoscale filler reduced the phases dimension and promoted the homogeneous distribution of microstructure, obtaining a higher joint strength when compared to microscale filler. The increase of brazing temperature made the accelerating dissolution and diffusion of Ti, which promoted the increase of thickness of Ti₄O₇ + TiSi₂ layer adjacent to SiO₂ ceramic and diffusion layer zone nearby TC4 alloy. The hypoeutectic structure was produced in the brazing seam due to the high Ti content. The maximum shear strength of ∼40 MPa was obtained at 950 °C for 10 min.     

描述弹塑性材料损伤演变行为的3种计算方法的研究与应用

借助于双向组合坐标系,就弹塑性材料的损伤演变速率和寿命提出了3种计算方法.它包括:单参数法、比值法、乘积法,同时本文给出了许多新的计算方程,还提供了一个同各个常用材料参数有着函数关系的综合性材料常数的新概念.这些常用参数有:疲劳强度系数σ'f、疲劳强度指数b'1、疲劳延性系数ε'f、疲劳延性指数c'1、平均应力、平均应变和临界加载时间等等.用汽车的一个零件做了实例计算,并对计算结果进行了一些比较.预计这些计算方法对避免过多的疲劳试验,对节省疲劳试验的时间、人力和资金,对方便工程应用在某种程度上将有着实际意义.     

Reception of the NKL (Jim Creek) transmitter onboard GEOS-1

At the beginning of the GEOS lifetime, some attempts have been made for taking advantage of the passes over Alaska. GEOS was then commanded in a fixed mode and the corresponding telemetry data were recorded at the NASA stations. For two passes over Jim Creek (48°2N–121°9W) where a powerful VLF transmitter (f ₀ = 18.6 kHz) is located, GEOS was put in a specific mode in order to study the magnetospheric electromagnetic field in the vicinity of f ₀. The results of one pass (June 11, from 0755 UT) are presented here.During this pass, a strong enhancement of all the e.m. components at f ₀ has been observed for a specific period of time, when GEOS was very near to the exact conjugacy with NKL. The distance, as measured on the ground, over which the signal was above -6 dB from the maximum is of the order of 800 km. During the corresponding period of time (0740–0750 UT), the satellite altitude varied between 8000 and 6000 km. The magnetospheric region where the signal is strong appears to be structured, as if there were many ducts.Preliminary results concerning the polarization characteristics of the signal are presented. In the absence of precise measurements of these characteristics, the comparison between the electric and magnetic components of the received signal is not easy to interpret. An examination of the onboard computed correlograms (in the frequency range from f ₀ -0.6 kHz to f ₀ +3.3 kHz) shows that, for this pass, no VLF emissions were triggered by NKL, at the altitude of the satellite.     

Brazing of C/C composite and Ti-6Al-4V with graphene strengthened AgCuTi filler: Effects of graphene on wettability,microstructure and mechanical properties

Graphene nanosheets(GNSs) strengthened AgCuTi composite filler(AgCuTi_G) was used to braze C/C composite and Ti-6Al-4V. The effects of GNSs on the wettability of AgCuTi_G filler on the C/C composite surface and the interfacial microstructure and mechanical properties of brazed joints were investigated. The results indicate that the addition of GNSs reduced the wettability of AgCuTi_G. The interfacial microstructure of brazed joints evolved with the addition of GNSs, where Ti_3Cu_4 and TiCu_4 were converted to TiCu and the thickness of the reaction layer adjacent to the base material decreased. The maximum shear strength of joints brazed at 0.3 wt% GNSs was 23.3 MPa(880℃/10 min). Further adding GNSs deteriorated the shear strength of the joints. Fracture of the joints occurred in the C/C composite substrate and the TiC layer adjacent to C/C composite.