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利用差示扫描量热法(DSC)得到端羟基聚醚(HTPE)推进剂(H01和H02)在不同升温速率下热分解曲线,用Kissinger公式和Ozawa公式计算了H01和H02热分解的表观活化能;利用绝热加速量热仪(ARC)对H01和H02进行绝热量热测试,得到H01和H02的热分解特性参数。结果表明:HTPE推进剂(基础配方为HTPE/A3/AP/Al/PSAN)中相稳定硝酸铵(PSAN)/高氯酸铵(AP)含量比值增加对推进剂的初始分解峰影响不大,HTPE推进剂的第一步分解是增塑剂A3的热分解,H01和H02的表观活化能分别为127.28kJ·mol~(-1)和123.43kJ·mol~(-1);在绝热条件下,H01的起始分解温度较高(147.78℃),高于H02的起始分解温度(136.44℃),反应结束后,两种物质系统的最大压力分别为0.709 MPa和0.531 MPa;H01的绝热温升(246.94℃)高于H02(184.47℃),发生热分解反应时,严重度更大,初始的热分解反应更为剧烈。因此,PSAN/AP含量比值增加有助于降低HTPE推进剂在热刺激下的响应程度。 相似文献
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PBT复合固体推进剂的热分解特性 总被引:1,自引:0,他引:1
《固体火箭技术》2017,(6)
为了研究PBT复合固体推进剂的热分解过程,分别采用差示扫描量热仪(DSC)和绝热加速量热仪(ARC),对复合固体推进剂及各单组分的热分解特性进行了研究,并对其进行了慢烤试验。DSC的试验结果表明,在温升速率为10℃/min的条件下,PBT复合推进剂的初始分解温度为183.6℃;推进剂组分中增塑剂BU的初始分解温度最低,为192.9℃,表明复合推进剂的热分解过程是从BU开始。在ARC试验中,推进剂在绝热条件下有三段放热过程,第一段放热过程的初始分解温度为121.7℃,且第一阶段的热分解并未直接引发其他组分的后续热分解反应。在慢烤试验中,PBT复合推进剂中最先分解的组分为BU,且BU的分解并未导致样品整体发生反应。根据DSC的测试结果,利用Kissinger法计算得到BU的热分解活化能为137.8 k J/mol,PBT复合推进剂第一段放热峰的表观活化能为101.7 k J/mol。 相似文献
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六硝基六氮杂异伍兹烷(CL-20)在3,4-二硝基呋咱基氧化呋咱(DNTF)基熔铸炸药中应用前景广阔,从实验分析和动力学模拟两方面入手,研究了DNTF/CL-20双组元体系(1∶1,质量比)热分解特性及机理。采用高压差示扫描量热(PDSC)技术考察了双组元体系的热分解特性,并通过Kissinger方程得到了其热分解动力学参数;采用同步热分析-红外-质谱(TG/DSC-FTIR-MS)联用技术研究了双组元体系热分解产物的组成及种类,推测了其热分解机理;采用耐驰热动力学软件获得了1.0 MPa下双组元体系的热分解动力学参数。结果表明:DNTF/CL-20双组元体系在1.0 MPa下的热分解过程中,CL-20会因低共熔导致分解峰温降低,产生的气相产物会促进DNTF的分解,进而引起其峰温前移;DNTF/CL-20双组元体系热分解的初始步骤为CL-20中的N—NO2断裂,产生具有催化作用的气相分子,致使其笼状结构裂解,并引起DNTF的呋咱环和氧化呋咱环于N—O键处断裂,最终生成后续生成NO、CO、CO2、N2O、H2 相似文献
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《固体火箭技术》2020,(2)
为研究HMX含量对HTPE推进剂热安全性的影响,采用DSC、ARC和大尺寸程序控温仪开展多尺度条件下HTPE固体推进剂(HT01~HT04样品,HMX含量分别为0%、5%、10%和15%。)的热分解特性研究,获得了样品的热分解动力学参数,分析了其热解机理。DSC和ARC实验结果均显示,随着HTPE推进剂中HMX含量增加,推进剂的初始分解温度升高,热稳定性提高。ARC实验中,HT01~HT04样品修正后的绝热温升分别为819.9、1194.2、1278.9、1833.0℃,放热量分别为1639.8、2388.4、2557.9、3666.1 J/g,即随着HMX含量增加,HTPE推进剂的能量释放速率和总能量均增加。慢速烤燃试验结果显示,HT01~HT04样品的响应温度分别为119.6、120.4、122.7、122.8℃,HT01~HT03样品的响应等级均为燃烧反应,HT04样品的响应等级为爆燃反应。 相似文献
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采用非限定烤燃试验,测定了高固含量改性双基推进剂药柱的热爆炸临界温度,讨论了固含量与临界温度的关系及临界温度的尺度效应;通过高压热分解研究,获得了高固体含量推进剂热分解反应非等温动力学参数,探讨了固含量对临界温度的影响机理。结果表明,固含量由0%增加至50%,热爆炸临界温度由134.5℃上升到156.1℃,3 MPa压力下第一热分解峰温由201.8℃上升到206.2℃(β=10℃/min),表明热稳定性增加;长径比为1的GLX?4药柱临界温度与直径的对数呈线性关系。此外,随着固含量升高,热分解活化能由161.0 kJ/mol升高到181.9 kJ/mol,揭示了烤燃试验热获得的爆炸临界温度升高这一现象的高压热分解动力学理论依据。 相似文献
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含CL-20的NEPE推进剂热分解 总被引:1,自引:0,他引:1
借助热重-微商热重(TG-DTG)试验和差示扫描量热(DSC)试验研究了含CL-20的NEPE推进剂的热分解特性,探索了主要组分NG、CL-20、AP和催化剂之间的相互作用。实验结果表明,该推进剂的热分解过程分3个阶段:增塑剂(NG)的挥发和分解,PEG CL-20的分解,AP的分解。CL-20促进了NG和PEG的分解,NG与PEG并未影响CL-20的分解。AP的加入促进了CL-20的分解,同时CL-20也使AP的分解由单质2步分解合并为1步。Al粉在该体系中与其他组分的相互作用较弱。催化剂Ct1和Ct2在一定程度上抑制了推进剂中NG、CL-20和AP的起始分解,对于NG起始分解的抑制作用更为明显,当温度升高,抑制作用消失即分解开始时,分解速率大幅提高,从而使推进剂热分解的放热历程缩短,致使推进剂燃速提高。 相似文献
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空间交会对接光学敏感器测量的实验研究 总被引:1,自引:1,他引:1
光学敏感器通常用作空间交会对接最后阶段的测量敏感器。本文研究了光学成像敏感器的测量方法,并在此基础上进行了物理仿真实验。实验结果表明,当距离为1m左右对直径40cm的目标模拟器进行测量时.位置测量精度优于1mm,姿态测量精度优于0.4°。 相似文献
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基于CFD的涡轮泵转子密封流体激振研究进展 总被引:2,自引:0,他引:2
介绍了密封流体激振对转子稳定性的影响,重点论述了利用计算流体力学(CFD)方法进行密封流体激振研究的理论和试验测量方法,对当前研究中存在的难点、重点问题结合国内外发展情况进行了探讨,提出需要发展通用性更好的非稳态数值方法,并利用流体激振的特性来设计密封结构,改善转子动力特性。 相似文献
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提出采用多反馈延迟的改进卷积处理技术实现雷达杂波模拟,克服了单反馈延迟输出杂波数据周期重复的缺点,使杂波数据在整个I周期内不重复,带来的好处是杂波逼真度高.采用大容量动态存储技术实现数据存储电路的设计,优点是方便快捷地为卷积器提供数据. 相似文献
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赵忠泽 《华北航天工业学院学报》2003,13(3):20-21,25
本文介绍了一种Z1Cr18Ni9Ti零件的制造方法,即用铸造方法。这种方法可以节省材料,提高效率,降低成本,并在此基础上探讨了有效的熔炼和铸造工艺。 相似文献
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Pablo de Len 《Acta Astronautica》2009,65(11-12):1789-1795
One of the most important developers of liquid propellant rocket engines in Argentina was Polish-born Ricardo Dyrgalla. Dyrgalla immigrated to Argentina from the United Kingdom in 1946, where he had been studying German weapons development at the end of the Second World War. A trained pilot and aeronautical engineer, he understood the intricacies of rocket propulsion and was eager to find practical applications to his recently gained knowledge.Dyrgalla arrived in Argentina during Juan Perón's first presidency, a time when technicians from all over Europe were being recruited to work in various projects for the recently created Argentine Air Force.Shortly after immigrating, Dyrgalla proposed to develop an advanced air-launched weapon, the Tábano, based on a rocket engine of his design, the AN-1. After a successful development program, the Tábano was tested between 1949 and 1951; however, the project was canceled by the government shortly after. Today, the AN-1 rocket engine is recognized as the first liquid propellant rocket to be developed in South America. Besides the AN-1, Dyrgalla also developed several other rockets systems in Argentina, including the PROSON, a solid-propellant rocket launcher developed by the Argentine Institute of Science and Technology for the Armed Forces (CITEFA). In the late 1960s, Dyrgalla and his family relocated to Brazil due mostly to the lack of continuation of rocket development in Argentina. There, he worked for the Institute of Aerospace Technology (ITA) until his untimely death in 1970. Ricardo Dyrgalla deserves to be recognized among the world's rocket pioneers and his contribution to the science and engineering of rocketry deserves a special place in the history of South America's rocketry and space flight advocacy programs. 相似文献
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The links between Earth and space exploration occur across a broad spectrum, from the use of satellite technology to support environmental monitoring and habitat protection to the study of extreme environments on Earth to prepare for the exploration of other planets. Taking the view that Earth and space exploration are part of a mutually beneficial continuum is in contrast to the more traditionally segregated view of these areas of activity. In its most polarized manifestation, space exploration is regarded as a waste of money, distracting from solving problems here at home, while environmental research is seen to be introspective, distracting from expansive visions of exploring the frontier of space. The Earth and Space Foundation was established in 1994 to help further mutually beneficial links by funding innovative field projects around the world that work at the broad interface between environmental and space sciences, thus encouraging the two communities to work together to solve the challenges facing society. This paper describes the work of the foundation and the philosophy behind its programmes. 相似文献
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培养创造能力是高等教育的重要任务,是时代的要求,要开展创造教育,培养学生的创造力就必须建设一支具有创造性素质的教师队伍。 相似文献