Solar Variability and Climate Impact on Terrestrial Planets

Some possible factors of climate changes and of long term climate evolution are discussed with regard of the three terrestrial planets, Earth, Venus and Mars. Two positive feedback mechanisms involving liquid water, i.e., the albedo mechanism and the greenhouse effect of water vapour, are described. These feedback mechanisms respond to small external forcings, such as resulting from solar or astronomical constants variability, which might thus result in large influences on climatic changes on Earth. On Venus, reactions of the atmosphere with surface minerals play an important role in the climate system, but the involved time scales are much larger. On Mars, climate is changing through variations of the polar axis inclination over time scales of ～10⁵–10⁶ years. Growing evidence also exists that a major climatic change happened on Mars some 3.5 to 3.8 Gigayears ago, leading to the disappearance of liquid water on the planet surface by eliminating most of the CO₂ atmosphere greenhouse power. This change might be due to a large surge of the solar wind, or to atmospheric erosion by large bodies impacts. Indeed, except for their thermospheric temperature response, there is currently little evidence for an effect of long-term solar variability on the climate of Venus and Mars. This fact is possibly due to the absence of liquid water on these terrestrial planets.     

Helium, Oxygen, Proton, and Electron (HOPE) Mass Spectrometer for the Radiation Belt Storm Probes Mission

The HOPE mass spectrometer of the Radiation Belt Storm Probes (RBSP) mission (renamed the Van Allen Probes) is designed to measure the in situ plasma ion and electron fluxes over 4π sr at each RBSP spacecraft within the terrestrial radiation belts. The scientific goal is to understand the underlying physical processes that govern the radiation belt structure and dynamics. Spectral measurements for both ions and electrons are acquired over 1 eV to 50 keV in 36 log-spaced steps at an energy resolution ΔE _FWHM/E≈15 %. The dominant ion species (H⁺, He⁺, and O⁺) of the magnetosphere are identified using foil-based time-of-flight (TOF) mass spectrometry with channel electron multiplier (CEM) detectors. Angular measurements are derived using five polar pixels coplanar with the spacecraft spin axis, and up to 16 azimuthal bins are acquired for each polar pixel over time as the spacecraft spins. Ion and electron measurements are acquired on alternate spacecraft spins. HOPE incorporates several new methods to minimize and monitor the background induced by penetrating particles in the harsh environment of the radiation belts. The absolute efficiencies of detection are continuously monitored, enabling precise, quantitative measurements of electron and ion fluxes and ion species abundances throughout the mission. We describe the engineering approaches for plasma measurements in the radiation belts and present summaries of HOPE measurement strategy and performance.     

The Planets and Titan Observed by ISO

Infrared spectroscopic observations of planets and Saturn's satellite Titan with the Infrared Space Observatory led to many significant discoveries that improved our understanding on the formation, physics and chemistry of these objects. The prime results achieved by ISO are: (1) a new and consistent determination of the D/H ratios on the giant planets and Titan; (2) the first precise measurement of the ¹⁵N/¹⁴N ratio in Jupiter, a valuable indicator of the protosolar nitrogen isotopic ratio; (3) the first detection of an external oxygen flux for all giant planets and Titan; (4) the first detection of some stratospheric hydrocarbons (CH₃, C₂H₄, CH₃C₂H, C₄H₂, C₆H₆); (5) the first detection of tropospheric water in Saturn; (6) the tentative detection of carbonate minerals on Mars; (7) the first thermal lightcurve of Pluto. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Vertical distribution of disequilibrium species in Jupiter's troposphere

Sources of organic matter and inorganic tracers on Jupiter, including solar UV photolysis, lightning discharges, and convective quenching of hot gases from the lower atmosphere, are reviewed in light of Earth-based and Voyager data with the purpose of predicting the tropospheric steady-state abundances and vertical distributions of HCN, CH₂O, and other species.It is concluded that a steady-state mole fraction of HCN in the Jovian troposphere of only 10^-12 could be maintained by vertical transport of hot gases from the deep atmosphere. The observed HCN abundance (roughly X_HCN = 10^-9) appears to be due to photochemical reactions.After HCN, the most abundant organic disequilibrium species in the troposphere is probably C₂H₆, derived from direct photolysis of CH₄ at high altitudes, with a mole fracton of 10^-10 at the H₂O cloud level. Inorganic tracers of disequilibrium processes are also briefly summarized.     

Vibrational relaxation of CO2 (m,nl, p) in a CO2-N2 mixture. Part 1: Survey of available data

The knowledge of the vibrational relaxation reaction rates of diatomic and triatomic molecules is required for the modelling of numerous gaseous mixtures such as the Earth atmosphere (involving radiation transfer phenomena), exhaust plumes, afterbody wakes, Mars atmosphere, shock waves and chemical lasers. It enables a better understanding of the chemical reaction product rates and provides the populations of the radiating levels. In this study, we consider the few lowest vibrational levels of a CO₂-N₂ mixture and the V-T and V-V energy transfer processes between these levels. The reaction rates given by experimental and theoretical studies and by different surveys of data supplied by a bibliographic search are presented. Then, comparisons of the data available for the most important processes are shown. The usual assumptions concerning the vibrational relaxation of CO₂ (m, n^l, p) are recalled and briefly discussed.     

Isotopes in comets: Implications from Cr in carbonaceous chondrites

According to their chemical composition, rich in volatile compounds, comets are thought to be primitive materials. They may provide prime samples for the study of nucleosynthetic components of the solar system and of the processes occurring during the formation of the outer planets. Their origin is largely a matter of conjecture. Chromium isotopic measurements in carbonaceous chondrites illustrate how the non-volatile part of cometary material can be investigated both for isotopic heterogeneity and for the extinct nuclide ⁵³Mn. Questions like the possible presence of ²⁶Al as a heat source can also be addressed by these measurements.     

The Interior Structure, Composition, and Evolution of Giant Planets

We discuss our current understanding of the interior structure and thermal evolution of giant planets. This includes the gas giants, such as Jupiter and Saturn, that are primarily composed of hydrogen and helium, as well as the “ice giants,” such as Uranus and Neptune, which are primarily composed of elements heavier than H/He. The effect of different hydrogen equations of state (including new first-principles computations) on Jupiter’s core mass and heavy element distribution is detailed. This variety of the hydrogen equations of state translate into an uncertainty in Jupiter’s core mass of 18M _⊕ . For Uranus and Neptune we find deep envelope metallicities up to 0.95, perhaps indicating the existence of an eroded core, as also supported by their low luminosity. We discuss the results of simple cooling models of our solar system’s planets, and show that more complex thermal evolution models may be necessary to understand their cooling history. We review how measurements of the masses and radii of the nearly 50 transiting extrasolar giant planets are changing our understanding of giant planets. In particular a fraction of these planets appear to be larger than can be accommodated by standard models of planetary contraction. We review the proposed explanations for the radii of these planets. We also discuss very young giant planets, which are being directly imaged with ground- and space-based telescopes.     

Feedstocks of the Terrestrial Planets

The processes of planet formation in our Solar System resulted in a final product of a small number of discreet planets and planetesimals characterized by clear compositional distinctions. A key advance on this subject was provided when nucleosynthetic isotopic variability was discovered between different meteorite groups and the terrestrial planets. This information has now been coupled with theoretical models of planetesimal growth and giant planet migration to better understand the nature of the materials accumulated into the terrestrial planets. First order conclusions include that carbonaceous chondrites appear to contribute a much smaller mass fraction to the terrestrial planets than previously suspected, that gas-driven giant planet migration could have pushed volatile-rich material into the inner Solar System, and that planetesimal formation was occurring on a sufficiently rapid time scale that global melting of asteroid-sized objects was instigated by radioactive decay of ²⁶Al. The isotopic evidence highlights the important role of enstatite chondrites, or something with their mix of nucleosynthetic components, as feedstock for the terrestrial planets. A common degree of depletion of moderately volatile elements in the terrestrial planets points to a mechanism that can effectively separate volatile and refractory elements over a spatial scale the size of the whole inner Solar System. The large variability in iron to silicon ratios between both different meteorite groups and between the terrestrial planets suggests that mechanisms that can segregate iron metal from silicate should be given greater importance in future investigations. Such processes likely include both density separation of small grains in the nebula, but also preferential impact erosion of either the mantle or core from differentiated planets/planetesimals. The latter highlights the important role for giant impacts and collisional erosion during the late stages of planet formation.     

Ions in the Terrestrial Atmosphere and Other Solar System Atmospheres

Charged molecular clusters, traditionally called small ions, carry electric currents in atmospheres. Charged airborne particles, or aerosol ions, play an important role in generation and evolution of atmospheric aerosols. Growth of ions depends on the trace gas content, which is highly variable in the time and space. Even at sub-ppb concentrations, electrically active organic compounds (e.g. pyridine derivatives) can affect the ion composition and size. The size and mobility are closely related, although the form of the relationship varies depending on the critical diameter, which, at 273 K, is about 1.6 nm. For ions smaller than this the separation of quantum levels exceeds the average thermal energy, allowing use of a molecular aggregate model for the size-mobility relation. For larger ions the size-mobility relation approaches the Stokes-Cunningham-Millikan law. The lifetime of a cluster ion in the terrestrial lower atmosphere is about one minute, determined by the balance between ion production rate, ion-ion recombination, and ion-aerosol attachment.     

Aeronomy of Extra-Solar Giant Planets

The intense stellar UV radiation field incident upon extra-solar giant planets causes profound changes to their upper atmospheres. Upper atmospheric temperatures can be tens of thousands of kelvins, causing thermal dissociation of H₂ to H. The stellar ionizing flux converts H to H⁺. The high temperatures also drive large escape rates of H, but for all but the planets with the smallest orbits, this flux is not large enough to affect planet evolution. The escape rate is large enough to drag off heavier atoms such as C and O. For very small orbits, when the hill sphere is inside the atmosphere, escape is unfettered and can affect planet evolution.     

Formation of Planetesimals and Accretion of the Terrestrial Planets

Planetesimals formed in the solar nebula by collisional coagulation. Dust aggregates settled toward the central plane, the larger ones growing by sweeping up smaller ones. A thin, dense layer of particles formed; shear-generated turbulence and differential motions induced by gas drag inhibited gravitational instability. Growth proceeded by collisions, producing planetesimals on a timescale of a few thousand years in the terrestrial zone. For bodies smaller than about a kilometer, motions were dominated by gas drag, and impact velocities decreased with size. At larger sizes gravitational interactions became significant, and velocities increased due to mutual perturbations. Larger bodies then grew more rapidly, this ``runaway' led to formation of tens to hundreds of lunar- to Mars-sized planetary embryos in the zone of terrestrial planets. The final accretion of these bodies into a few planets involved large impacts, and occurred on a timescale of 10⁷ to 10⁸ years. This scenario gives a reasonably consistent picture of the origin of the terrestrial planets, but does not account for the anomalously low eccentricities of the Earth and Venus. This revised version was published online in June 2006 with corrections to the Cover Date.     

Atmospheric Ion-induced Aerosol Nucleation

Ion-induced nucleation has been suggested to be a potentially important mechanism for atmospheric aerosol formation. Ions are formed in the background atmosphere by galactic cosmic rays. A possible connection between galactic cosmic rays and cloudiness has been However, the predictions of current atmospheric nucleation models are highly uncertain because the models are usually based on the liquid drop model that estimates cluster thermodynamics based on bulk properties (e.g., liquid drop density and surface tension). Sulfuric acid (H₂SO₄) and water are assumed to be the most important nucleating agents in the free troposphere. Measurements of the molecular thermodynamics for the growth and evaporation of cluster ions containing H₂SO₄ and H₂O were performed using a temperature-controlled laminar flow reactor coupled to a linear quadrupole mass spectrometer as well as a temperature-controlled ion trap mass spectrometer. The measurements were complemented by quantum chemical calculations of the cluster ion structures. The analysis yielded a complete set of H₂SO₄ and H₂O binding thermodynamics extending from molecular cluster ions to the bulk, based on experimental thermodynamics for the small clusters. The data were incorporated into a kinetic aerosol model to yield quantitative predictions of the rate of ion-induced nucleation for atmospheric conditions. The model predicts that the negative ion-H₂SO₄-H₂O nucleation mechanism is an efficient source of new particles in the middle and upper troposphere.     

Isotopic Fractionation by Gravitational Escape

Present natural data bases for abundances of the isotopic compositions of noble gases, carbon and nitrogen inventories can be found in the Sun, the solar wind, meteorites and the planetary atmospheres and crustal reservoirs. Mass distributions in the various volatile reservoirs provide boundary conditions which must be satisfied in modelling the history of the present atmospheres. Such boundary conditions are constraints posed by comparison of isotopic ratios in primordial volatile sources with the isotopic pattern which was found on the planets and their satellites. Observations from space missions and Earth-based spectroscopic telescope observations of Venus, Mars and Saturn's major satellite Titan show that the atmospheric evolution of these planetary bodies to their present states was affected by processes capable of fractionating their elements and isotopes. The isotope ratios of D/H in the atmospheres of Venus and Mars indicate evidence for their planetary water inventories. Venus' H₂O content may have been at least 0.3% of a terrestrial ocean. Analysis of the D/H ratio on Mars imply that a global H₂O ocean with a depth of ≤ 30 m was lost since the end of hydrodynamic escape. Calculations of the time evolution of the ¹⁵N/¹⁴N isotope anomalies in the atmospheres of Mars and Titan show that the Martian atmosphere was at least ≥ 20 times denser than at present and that the mass of Titan's early atmosphere was about 30 times greater than its present value. A detailed study of gravitational fractionation of isotopes in planetary atmospheres furthermore indicates a much higher solar wind mass flux of the early Sun during the first half billion years. This revised version was published online in August 2006 with corrections to the Cover Date.     

Neutron measurements in space

The experimental measurements of the neutron flux and energy spectrum in space since 1964 are reviewed and related to the theoretical predictions. A discussion of the neutron sources is presented. The difficulties associated with neutron measurements of both the atmospheric neutron leakage flux and solar neutrons are included. Particular emphasis is placed upon the neutron leakage flux and energy measurements at energies greater than about 1 MeV. The possibilities of CRAND as a source for the energetic trapped protons are discussed in light of recent measurements of the 10–100 MeV neutron flux. The current status of the solar neutron flux observations is also presented.The primary purposes of neutron measurements in space have been to determine the neutron leakage flux from the atmosphere of the Earth and the solar neutron flux. As a consequence of the inefficient methods for neutron detection and the difficulties of conducting the measurements in the presence of the galactic and solar cosmic-ray backgrounds, the experimental results are very conflicting. It is the purpose of this review to interpret and discuss recent neutron measurements. In order to understand these results the theoretical predictions of the neutron fluxes and energy spectra from possible neutron sources will be briefly presented. Since comparisons of the different neutron measurements depend critically upon the experimental techniques, we will briefly discuss neutron detection methods applicable to space measurements. The emphasis will be upon measurements since 1964 made outside the Earth's atmosphere, but considerable reference will be made to high energy neutron experiments conducted within the Earth's atmosphere at < 10g cm^-2 altitude. A review of earlier neutron measurements of terrestrial and solar neutrons has been made by Haymes (1965).     

Photoemission Phenomena in the Solar System

Much of what we know about the atmospheres of the planets and other bodies in the solar system comes from detection of photons over a wide wavelength range, from X-rays to radio waves. In this chapter, we present current information in various categories—measurements of the airglows of the terrestrial planets, the dayglows of the outer planets and satellites, aurora throughout the solar system, observations of cometary spectra, and the emission of X-rays from a variety of planetary bodies.     

Enrichment of the Hot Intracluster Medium: Observations

Four decades ago, the firm detection of an Fe-K emission feature in the X-ray spectrum of the Perseus cluster revealed the presence of iron in its hot intracluster medium (ICM). With more advanced missions successfully launched over the last 20 years, this discovery has been extended to many other metals and to the hot atmospheres of many other galaxy clusters, groups, and giant elliptical galaxies, as evidence that the elemental bricks of life—synthesized by stars and supernovae—are also found at the largest scales of the Universe. Because the ICM, emitting in X-rays, is in collisional ionisation equilibrium, its elemental abundances can in principle be accurately measured. These abundance measurements, in turn, are valuable to constrain the physics and environmental conditions of the Type Ia and core-collapse supernovae that exploded and enriched the ICM over the entire cluster volume. On the other hand, the spatial distribution of metals across the ICM constitutes a remarkable signature of the chemical history and evolution of clusters, groups, and ellipticals. Here, we summarise the most significant achievements in measuring elemental abundances in the ICM, from the very first attempts up to the era of XMM-Newton, Chandra, and Suzaku and the unprecedented results obtained by Hitomi. We also discuss the current systematic limitations of these measurements and how the future missions XRISM and Athena will further improve our current knowledge of the ICM enrichment.     

Magnetic Fields of the Outer Planets

The rapidly rotating giant planets of the outer solar system all possess strong dynamo-driven magnetic fields that carve a large cavity in the flowing magnetized solar wind. Each planet brings a unique facet to the study of planetary magnetism. Jupiter possesses the largest planetary magnetic moment, 1.55×10²⁰ Tm³, 2×10⁴ times larger than the terrestrial magnetic moment whose axis of symmetry is offset about 10° from the rotation axis, a tilt angle very similar to that of the Earth. Saturn has a dipole magnetic moment of 4.6×10¹⁸ Tm³ or 600 times that of the Earth, but unlike the Earth and Jupiter, the tilt of this magnetic moment is less than 1° to the rotation axis. The other two gas giants, Uranus and Neptune, have unusual magnetic fields as well, not only because of their tilts but also because of the harmonic content of their internal fields. Uranus has two anomalous tilts, of its rotation axis and of its dipole axis. Unlike the other planets, the rotation axis of Uranus is tilted 97.5° to the normal to its orbital plane. Its magnetic dipole moment of 3.9×10¹⁷ Tm³ is about 50 times the terrestrial moment with a tilt angle of close to 60° to the rotation axis of the planet. In contrast, Neptune with a more normal obliquity has a magnetic moment of 2.2×10¹⁷ Tm³ or slightly over 25 times the terrestrial moment. The tilt angle of this moment is 47°, smaller than that of Uranus but much larger than those of the Earth, Jupiter and Saturn. These two planets have such high harmonic content in their fields that the single flyby of Voyager was unable to resolve the higher degree coefficients accurately. The four gas giants have no apparent surface features that reflect the motion of the deep interior, so the magnetic field has been used to attempt to provide this information. This approach works very well at Jupiter where there is a significant tilt of the dipole and a long baseline of magnetic field measurements (Pioneer 10 to Galileo). The rotation rate is 870.536° per day corresponding to a (System III) period of 9 h 55 min 26.704 s. At Saturn, it has been much more difficult to determine the equivalent rotation period. The most probable rotation period of the interior is close to 10 h 33 min, but at this writing, the number is still uncertain. For Uranus and Neptune, the magnetic field is better suited for the determination of the planetary rotation period but the baseline is too short. While it is possible that the smaller planetary bodies of the outer solar system, too, have magnetic fields or once had, but the current missions to Vesta, Ceres and Pluto do not include magnetic measurements.     

Vibrational relaxation of CO2(m,nl, p) in a CO2N2 mixture. Part 2: Application to a one-dimensional problem

In order to quantify the relaxation mechanism of CO₂(m, n^l, p), the vibrational level populations are calculated for a particular test-case: the vibrational relaxation of a CO₂N₂ mixture along the stagnation streamline in a reentry problem. The N₂ species is chosen as a collision partner because it is a component existing in numerous gaseous mixtures (cf. Part. 1). Excitation and deexcitation processes are taken following Nickerson and Herzfeld. The Navier-Stokes code CELHYO for the simulation of hypersonic laminar viscous flows in chemical and thermal nonequilibrium is used with a new one-dimensional approach, reduction of the Navier-Stokes equations along the stagnation streamline. Mass fraction and ‘vibrational temperature’ distributions of every vibrational level, considered as an independent chemical species, are presented for the two different CO₂N₂ mixture compositions. The validity of the usual assumptions for the vibrational mechanism is examined on the basis of the obtained results.     

A Comparative Study of the Influence of the Active Young Sun on the Early Atmospheres of Earth, Venus, and Mars

Because the solar radiation and particle environment plays a major role in all atmospheric processes such as ionization, dissociation, heating of the upper atmospheres, and thermal and non-thermal atmospheric loss processes, the long-time evolution of planetary atmospheres and their water inventories can only be understood within the context of the evolving Sun. We compare the effect of solar induced X-ray and EUV (XUV) heating on the upper atmospheres of Earth, Venus and Mars since the time when the Sun arrived at the Zero-Age-Main-Sequence (ZAMS) about 4.6 Gyr ago. We apply a diffusive-gravitational equilibrium and thermal balance model for studying heating of the early thermospheres by photodissociation and ionization processes, due to exothermic chemical reactions and cooling by IR-radiating molecules like CO₂, NO, OH, etc. Our model simulations result in extended thermospheres for early Earth, Venus and Mars. The exospheric temperatures obtained for all the three planets during this time period lead to diffusion-limited hydrodynamic escape of atomic hydrogen and high Jeans’ escape rates for heavier species like H₂, He, C, N, O, etc. The duration of this blow-off phase for atomic hydrogen depends essentially on the mixing ratios of CO₂, N₂ and H₂O in the atmospheres and could last from ∼100 to several hundred million years. Furthermore, we study the efficiency of various non-thermal atmospheric loss processes on Venus and Mars and investigate the possible protecting effect of the early martian magnetosphere against solar wind induced ion pick up erosion. We find that the early martian magnetic field could decrease the ion-related non-thermal escape rates by a great amount. It is possible that non-magnetized early Mars could have lost its whole atmosphere due to the combined effect of its extended upper atmosphere and a dense solar wind plasma flow of the young Sun during about 200 Myr after the Sun arrived at the ZAMS. Depending on the solar wind parameters, our model simulations for early Venus show that ion pick up by strong solar wind from a non-magnetized planet could erode up to an equivalent amount of ∼250 bar of O⁺ ions during the first several hundred million years. This accumulated loss corresponds to an equivalent mass of ∼1 terrestrial ocean (TO (1 TO ∼1.39×10²⁴ g or expressed as partial pressure, about 265 bar, which corresponds to ∼2900 m average depth)). Finally, we discuss and compare our findings with the results of preceding studies.     

Origin of planetary atmospheres

The near absence of noble gases on earth, other than those of radioactive origin, indicates that the earth was formed by the accumulation of planetesimals; this process systematically excluded all constituents that did not enter into the solid phase. The atmosphere and the ocean with many of its dissolved salts have arisen from gases emitted from the earth's interior, a process that continues today. The oxygen in the earth's atmosphere plus a greater quantity that has been removed from the atmosphere to oxidize geologic materials, has arisen mainly from a small excess of photosynthesis over decay of organic material. The atmospheres of Mars and Venus have probably arisen in a manner similar to the atmosphere on earth, by emission from the planetary interiors. However, they have not received any oxygen from photosynthesis and so are nearly oxygen free. Mars has very little water in its atmosphere, and this can be explained by its lower than freezing average surface temperature. Venus also has very little water, and this requires an ad hoc explanation; one possibility is that Venus was formed from much drier planetesimals than was the earth. Mercury and the moon are virtually without atmospheres. Although some gases may be emitted from their interiors, they are presumably rapidly lost by escape. Whatever atmosphere they possess is probably due to the neutralized solar wind that impinges upon them. The outer planets retained volatiles, including hydrogen and helium, to a much greater extent than did the terrestrial planets.